CN112048913A - Durable anti-ultraviolet finishing process for light and thin real silk or silk-containing fabric - Google Patents
Durable anti-ultraviolet finishing process for light and thin real silk or silk-containing fabric Download PDFInfo
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- CN112048913A CN112048913A CN202010912326.7A CN202010912326A CN112048913A CN 112048913 A CN112048913 A CN 112048913A CN 202010912326 A CN202010912326 A CN 202010912326A CN 112048913 A CN112048913 A CN 112048913A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/10—Animal fibres
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/25—Resistance to light or sun, i.e. protection of the textile itself as well as UV shielding materials or treatment compositions therefor; Anti-yellowing treatments
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention relates to a light and thin silk or silk-containing fabric durable uvioresistant finishing process, which comprises the following steps: 1) mixing an anti-ultraviolet finishing agent, a PU finishing agent and water to prepare a finishing liquid, and finishing the finishing liquid on the fabric in a dipping or padding mode; 2) the padding mode is as follows: the real silk or silk-containing fabric is passed through a mangle filled with the finishing liquid, so that the liquid carrying rate is 75-90%; the impregnation method is specifically as follows: putting the light silk or silk-containing fabric into a rotating cage washing machine or a dyeing machine filled with the finishing liquid, and soaking for 10-20 minutes at the temperature of 30 ℃; 3) finally, the fabric is baked by a setting machine; 4) and performing preshrinking treatment. The invention can be applied to the ultraviolet-resistant finishing of light and thin real silk and real silk-containing fabrics, the UPF can reach 50+, and the sun-proof function on light and thin real silk or silk-containing clothes worn in summer can be realized; after the finished fabric is washed by hands for 10-15 times or dry-cleaned for 5-10 times, the UPF can still reach more than 40, and the fabric has good ultraviolet resistance.
Description
Technical Field
The invention relates to a durable anti-ultraviolet finishing process for light and thin real silk or silk-containing fabrics, which has obvious anti-ultraviolet effect after finishing light and thin real silk or silk-containing fabrics and still has good anti-ultraviolet performance after being washed for many times.
Background
The ultraviolet ray is an electromagnetic wave with the wavelength range of 200-400 nm, the skin of a human body is very sensitive to the ultraviolet ray, and under the condition of no protection, the skin can be seriously damaged and even cause skin cancer after long-time sunlight irradiation. Therefore, the harm of ultraviolet radiation to human body is more and more paid attention.
The ultraviolet rays can be divided into three sections of UVC (200 nm-280 nm), UVB (280 nm-320 nm) and UVA (320 nm-400 nm) according to the wavelength, wherein the UVC is almost completely blocked by the atmosphere and hardly causes damage to human bodies. The ultraviolet rays which really penetrate through the barrier of the atmospheric ozone layer and reach the earth surface account for 1% of UVB and 99% of UVA. UVB is the main factor causing erythema in sunburn, while UVA has strong penetration ability, and can penetrate the surface layer of the skin to directly reach the dermis layer, which can cause serious tissue damage and even cause skin cancer. Thus, with the growing awareness of human health protection, the demand for various sunscreens and sun-protecting textiles is also rapidly increasing.
Currently, there are two main types of finishing agents used for textiles to resist ultraviolet radiation: one is ultraviolet absorbent, which is organic compound, such as cinnamic acid, salicylic acid, benzophenone, and diphenyl alkane. The ultraviolet protective coating generally absorbs ultraviolet rays with the wavelength range of 290-320 nm, and the protection on ultraviolet rays in UVA wave bands is not complete enough; moreover, the skin-care product has certain irritation to the skin and is easy to cause skin allergy; the other is ultraviolet screening agent, which is nano-sized or micro-sized TiO2、ZnO、SiO2、A12O3Inorganic materials with good reflection, scattering or absorption effects on ultraviolet rays, such as Chinese patent with publication number CN102433602A, publication number of 2012, 05 and 02, the method for producing durable ultraviolet-proof nylon-6 fiber uses nano ZnO and nano CeO2。
Real silk or silk-containing fabrics are light, smooth, soft and comfortable, and are deeply popular with people. Summer is the season with the strongest sunlight, but the clothes worn by people in summer are also lighter and thinner, the ultraviolet penetration rate of the light and thin fabric is high, and under the situation that ozone holes are more severe, the damage of ultraviolet radiation to the skin is more and more serious, so that the research and improvement of the ultraviolet-resistant finishing of the light and thin fabric have good market prospect and social significance.
Disclosure of Invention
The invention aims to overcome the defects in the prior art and provide a durable uvioresistant finishing process for light and thin silk or silk-containing fabric, which enables the fabric to obtain good durable uvioresistant performance.
The technical scheme adopted by the invention for solving the problems is as follows: the durable uvioresistant finishing process for the light and thin real silk or silk-containing fabric is characterized in that: the method comprises the following steps:
1) mixing an anti-ultraviolet finishing agent, a PU finishing agent and water to prepare a finishing liquid, and finishing the finishing liquid on the fabric in a dipping or padding mode;
2) the padding mode is as follows: the concentration of the uvioresistant finishing agent in the finishing liquid is 30-50g/L, the concentration of the PU finishing agent is 20-40 g/L, and real silk or silk-containing fabric passes through a mangle filled with the finishing liquid to enable the liquid carrying rate of the real silk or silk-containing fabric to be 75-90%; the light and thin real silk or silk-containing fabric needs to be soaked and rolled for multiple times, so that the soaking and rolling are uniform and effective, and the finishing liquid fully permeates into the light and thin real silk or silk-containing fabric;
the impregnation method is specifically as follows: the concentration of the uvioresistant finishing agent in the finishing liquid is 10-20g/L, the concentration of the PU finishing agent is 5-10 g/L, the light and thin real silk or silk-containing fabric is placed into a rotating cage washing machine or a dyeing machine filled with the finishing liquid, the light and thin real silk or silk-containing fabric is soaked for 10-20 minutes at the temperature of 30 ℃, and the finishing liquid needs to be ensured to uniformly permeate into the light and thin real silk or silk-containing fabric;
3) finally, the fabric is baked by a setting machine at the baking temperature of 140-150 ℃ for 90-110 s, and the finishing agent can form a film on the surface of light and thin real silk or silk-containing fabric and be firmly combined with the fabric through high-temperature baking to obtain a finished fabric;
4) overfeeding is carried out on the finished fabric on a pre-shrinking machine according to the proportion of 5-10%, pre-shrinking treatment is carried out on the finished fabric, the density of the fabric is tighter through pre-shrinking, gaps among yarns are reduced or even disappear through the extrusion effect of the pre-shrinking machine or the film shielding effect formed by auxiliary agents on the surface of the fabric, and therefore the ultraviolet resistance of the fabric is improved.
Preferably, the finishing liquid consists of an anti-ultraviolet finishing agent, a PU finishing agent and water, and the weight ratio of the anti-ultraviolet finishing agent to the PU finishing agent is (1: 0.4) - (1: 1.2).
Preferably, the anti-ultraviolet finishing agent of the invention is one or two of travertine 6160, UVR of ludafu and HTUV100 of hette.
Preferably, the PU finishing agent of the invention is one or two of a topina finishing agent BAYPRET NANO-PU, a transfer multifunctional finishing agent 6220 and an Ohio finishing agent RPU.
Preferably, the grammes per square metre of the light and thin real silk or silk-containing fabric is 50g/m2。
Compared with the prior art, the invention has the following advantages and effects: can be applied to light and thin real silk and real silk-containing fabric (50-100 g/m)2) The ultraviolet-resistant finishing has the UPF of 50+ and can realize the sun-resistant function on light and thin real silk or silk-containing clothes worn in summer; after the finished fabric is washed by hands for 10-15 times or dry-cleaned for 5-10 times, the UPF can still reach more than 40, and the fabric has good ultraviolet resistance.
The invention researches and improves the ultraviolet resistance of light and thin real silk or silk-containing fabric worn in summer, adopts the finishing liquid prepared by the ultraviolet-resistant finishing agent with absorption and reflection dual functions and the PU finishing agent with good film-forming property to finish the light and thin real silk or silk-containing fabric, and the real silk fabric finished by the invention has good ultraviolet resistance.
Detailed Description
The present invention is further illustrated by the following examples, which are illustrative of the present invention and are not to be construed as being limited thereto.
Example 1:
fabric: 15263 twill silk (gram weight: 78 g/m)2)
1) 200ml of water is fed into the tank body, 6g of ultraviolet-resistant finishing agent and 4g of PU finishing agent are added into the tank body, and the mixture is uniformly mixed to prepare finishing liquid.
2) The fabric is padded with the finishing liquid, and the liquid carrying rate is 80%.
3) And (3) baking the fabric by a setting machine, wherein the baking temperature is 150 ℃, and the baking time is 90s, so as to obtain the finished fabric.
4) And overfeeding the finished fabric on a pre-shrinking machine according to the proportion of 8 percent, and pre-shrinking the finished fabric.
The anti-ultraviolet finishing effect of the fabric is as follows:
example 2:
fabric: 19004 twill silk (gram weight: 60 g/m)2)
1) 200ml of water is fed into the tank body, 8g of ultraviolet-resistant finishing agent and 6g of PU finishing agent are added into the tank body, and the mixture is uniformly mixed to prepare finishing liquid.
2) The fabric was padded with the above finishing liquor at a liquor pick-up of 75%.
3) And (3) baking the fabric by a setting machine, wherein the baking temperature is 145 ℃, and the baking time is 100s to obtain the finished fabric.
4) And overfeeding the finished fabric on a pre-shrinking machine according to the proportion of 10 percent, and pre-shrinking the finished fabric.
The anti-ultraviolet finishing effect of the fabric is as follows:
example 3:
fabric: 19011 twill silk (gram weight: 52 g/m)2)
1) 200ml of water is fed into the tank body, 10g of ultraviolet-resistant finishing agent and 8g of PU finishing agent are added into the tank body, and the mixture is uniformly mixed to prepare finishing liquid.
2) The fabric was padded with the above finishing liquor at a liquor pick-up of 85%.
3) And (3) baking the fabric by a setting machine, wherein the baking temperature is 140 ℃, and the baking time is 105s to obtain the finished fabric.
4) And overfeeding the finished fabric on a pre-shrinking machine according to the proportion of 5 percent, and pre-shrinking the finished fabric.
The anti-ultraviolet finishing effect of the fabric is as follows:
example 4:
fabric: 12102 double-crepe (gram weight: 60 g/m)2)
1) 200ml of water is fed into the tank body, 10g of ultraviolet-resistant finishing agent and 8g of PU finishing agent are added into the tank body, and the mixture is uniformly mixed to prepare finishing liquid.
2) The fabric is padded with the finishing liquid, and the liquid carrying rate is 90%.
3) And (3) baking the fabric by a setting machine, wherein the baking temperature is 150 ℃, and the baking time is 90s to obtain the finished fabric.
4) And overfeeding the finished fabric on a pre-shrinking machine according to the proportion of 6 percent, and pre-shrinking the finished fabric.
The anti-ultraviolet finishing effect of the fabric is as follows:
example 5:
fabric: 12777 double crepe georgette (gram weight: 80 g/m)2)
1) 400ml of water is fed into the rotary cage washing machine, 6g of ultraviolet-resistant finishing agent and 4g of PU finishing agent are added into a machine tank, and the mixture is uniformly mixed to prepare finishing liquid.
2) The fabric was immersed in a washing machine for 20min at a temperature of 30 ℃.
3) And (3) dehydrating the fabric, and then baking the dehydrated fabric by a setting machine, wherein the baking temperature is 145 ℃, and the baking time is 110s to obtain the finished fabric.
4) And overfeeding the finished fabric on a pre-shrinking machine according to the proportion of 7 percent, and pre-shrinking the finished fabric.
The anti-ultraviolet finishing effect of the fabric is as follows:
example 6:
fabric: 14654 crepe forging (gram weight: 71 g/m)2)
1) 400ml of water is fed into the rotary cage washing machine, 8g of ultraviolet-resistant finishing agent and 4g of PU finishing agent are added into a machine tank, and the mixture is uniformly mixed to prepare finishing liquid.
2) The fabric was immersed in a washing machine for 18min at a temperature of 30 ℃.
3) And (3) baking the fabric by a setting machine, wherein the baking temperature is 140 ℃, and the baking time is 105s to obtain the finished fabric.
4) And overfeeding the finished fabric on a pre-shrinking machine according to the proportion of 8 percent, and pre-shrinking the finished fabric.
The anti-ultraviolet finishing effect of the fabric is as follows:
example 7:
fabric: silk-bonded twill (gram weight: 77.5 g/m)2)
1) 400ml of water is fed into the rotary cage washing machine, 8g of ultraviolet-resistant finishing agent and 3g of PU finishing agent are added into a machine tank, and the mixture is uniformly mixed to prepare finishing liquid.
2) The fabric was immersed in a washing machine for 15min at a temperature of 30 ℃.
3) And (3) baking the fabric by a setting machine, wherein the baking temperature is 140 ℃, and the baking time is 105s to obtain the finished fabric.
4) And overfeeding the finished fabric on a pre-shrinking machine according to the proportion of 5 percent, and pre-shrinking the finished fabric.
The anti-ultraviolet finishing effect of the fabric is as follows:
example 8:
fabric: silk floss (gram weight: 67 g/m)2)
1) 400ml of water is fed into the rotary cage washing machine, 4g of ultraviolet-resistant finishing agent and 2g of PU finishing agent are added into a machine tank, and the mixture is uniformly mixed to prepare finishing liquid.
2) The fabric was immersed in a washing machine for 10min at a temperature of 30 ℃.
3) And (3) baking the fabric by a setting machine, wherein the baking temperature is 140 ℃, and the baking time is 105s to obtain the finished fabric.
4) And overfeeding the finished fabric on a pre-shrinking machine according to the proportion of 10 percent, and pre-shrinking the finished fabric.
The anti-ultraviolet finishing effect of the fabric is as follows:
according to the invention, the anti-ultraviolet finishing agent and the PU finishing agent are mixed with water to prepare the finishing liquid for dipping or padding finishing the light and thin real silk or silk-containing fabric by controlling the using amounts of the anti-ultraviolet finishing agent and the PU finishing agent, so that the light and thin real silk or silk-containing fabric can obtain good durable anti-ultraviolet performance. The invention is applied to the ultraviolet-resistant finishing of light and thin fabrics, and the UPF can reach 50+The light and thin real silk or silk-containing clothes worn in summer can have the sun-proof function; and after the finished fabric is washed by hands for 10-15 times or is dry-cleaned for 5-10 times, the UPF can still reach more than 40, and the fabric has good ultraviolet resistance. The invention is not limited to light and thin fabrics, and can also be applied to thicker real silk or silk-containing fabrics (more than 100g/m 2).
Although the present invention has been described with reference to the above embodiments, it should be understood that the scope of the present invention is not limited thereto, and that various changes and modifications can be made by those skilled in the art without departing from the spirit and scope of the present invention.
Claims (5)
1. A light and thin silk or silk-containing fabric durable anti-ultraviolet finishing process is characterized in that: the method comprises the following steps:
1) mixing an anti-ultraviolet finishing agent, a PU finishing agent and water to prepare a finishing liquid, and finishing the finishing liquid on light and thin real silk or silk-containing fabric in a dipping or padding mode;
2) the padding mode is as follows: the concentration of the uvioresistant finishing agent in the finishing liquid is 30-50g/L, the concentration of the PU finishing agent is 20-40 g/L, and the light and thin real silk or silk-containing fabric passes through a mangle filled with the finishing liquid to enable the liquid carrying rate to be 75-90%; the light and thin real silk or silk-containing fabric needs to be soaked and rolled for a plurality of times, so that the soaking and rolling are uniform and effective, and the finishing liquid fully permeates into the light and thin real silk or silk-containing fabric;
the impregnation method is specifically as follows: the concentration of the uvioresistant finishing agent in the finishing liquid is 10-20g/L, the concentration of the PU finishing agent is 5-10 g/L, and the light and thin real silk or silk-containing fabric is placed into a rotating cage washing machine or a dyeing machine filled with the finishing liquid and is soaked for 10-20 minutes at the temperature of 30 ℃, so that the finishing liquid can uniformly permeate into the light and thin real silk or silk-containing fabric;
3) baking the dipped or padded light and thin real silk or silk-containing fabric by a setting machine, wherein the baking temperature is 140-150 ℃, and the baking time is 90-110 s, so as to obtain a finished fabric;
4) and overfeeding the finished fabric on a pre-shrinking machine according to the proportion of 5-10%, and pre-shrinking the finished fabric.
2. The durable ultraviolet-resistant finishing process for light and thin real silk or silk-containing fabric according to claim 1, characterized in that: the finishing liquid consists of an anti-ultraviolet finishing agent, a PU finishing agent and water, and the weight ratio of the anti-ultraviolet finishing agent to the PU finishing agent is (1: 0.4) - (1: 1.2).
3. The durable ultraviolet-resistant finishing process for light and thin real silk or silk-containing fabric according to claim 1, characterized in that: the uvioresistant finishing agent is one or two of transmissible 6160, UVR of Ludouv and HTUV100 of Hertt uvioresistant finishing agent.
4. The durable ultraviolet-resistant finishing process for light and thin real silk or silk-containing fabric according to claim 1, characterized in that: the PU finishing agent is one or two of a tropina finishing agent BAYPRET NANO-PU, a transfer multifunctional finishing agent 6220 and an Ohio finishing agent RPU.
5. The durable ultraviolet-resistant finishing process for light and thin real silk or silk-containing fabric according to claim 1, characterized in that: the light silk or silk-containing fabric has a minimum gram weight of 50g/m2。
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| CN202010912326.7A CN112048913B (en) | 2020-09-02 | 2020-09-02 | Durable uvioresistant finishing process for light and thin real silk or silk-containing fabric |
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| CN202010912326.7A CN112048913B (en) | 2020-09-02 | 2020-09-02 | Durable uvioresistant finishing process for light and thin real silk or silk-containing fabric |
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| CN112048913B CN112048913B (en) | 2023-02-10 |
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Cited By (1)
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| CN114318850A (en) * | 2021-12-31 | 2022-04-12 | 宿迁豹子头科技股份有限公司 | Method for carrying out anti-ultraviolet finishing on all-cotton textile or garment piece |
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| CN114318850A (en) * | 2021-12-31 | 2022-04-12 | 宿迁豹子头科技股份有限公司 | Method for carrying out anti-ultraviolet finishing on all-cotton textile or garment piece |
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| CN112048913B (en) | 2023-02-10 |
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Address after: Room 1804, No. 105, Stadium Road, Gongshu District, Hangzhou, Zhejiang 310005 Applicant after: Zhejiang Silk Technology Co.,Ltd. Address before: 311308 159 Chuangye street, Qingshanhu street, Lin'an District, Hangzhou City, Zhejiang Province Applicant before: Zhejiang Silk Technology Co.,Ltd. |
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