CN109837603A - A kind of preparation method of sun-proof mosquito proof cool feeling fabric - Google Patents
A kind of preparation method of sun-proof mosquito proof cool feeling fabric Download PDFInfo
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- CN109837603A CN109837603A CN201910159734.7A CN201910159734A CN109837603A CN 109837603 A CN109837603 A CN 109837603A CN 201910159734 A CN201910159734 A CN 201910159734A CN 109837603 A CN109837603 A CN 109837603A
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Abstract
The invention discloses a kind of preparation methods of sun-proof mosquito proof cool feeling fabric, are made by primary raw material of functional yarn.Functional yarn is prepared by the following method: conduction powder, uvioresistant powder are blended to obtain blend with polymer, prepare functional yarn after blend spinning.After above-mentioned fabric completes dyeing, the finishing agent with anti-mosquito functions is dried in technique arrangement to fabric by soaking-rolling-, finally obtains sun-proof mosquito proof cool feeling fabric.The present invention provides the functional textile facing materials and preparation method thereof that one kind can solve several big pain spots of summer clothes, such fabric has sun-proof, mosquito proof and contact cool feeling three zones simultaneously, it can be used for being processed into summer clothes and other accessories, wearing comfort is vdiverse in function.
Description
Technical field
The present invention relates to a kind of fabrics, and in particular to a kind of function textile with sun-proof mosquito proof and cool feeling function
Fabric can be used for making the dress ornament of summer dress and the accessory of wearing.
Background technique
Sunny summer, often temperature was higher, and sunlight is more sufficient, and the intensity of ultraviolet light is also relatively high.Though ultraviolet light is to people
Some benefit of body, but drawback is more.The shorter ultraviolet light of wavelength is the killer of skin, it be it is tanned, skin loses bullet
Property gloss, aging, color spot, fuel-displaced arch-criminal, less serious case can make skin burn, and skin seems dry, coarse after solarization, may be used also when serious
It can induce cutaneum carcinoma.
Mostly appropriate ultraviolet light screener or absorbent is generally added in existing Sun-shield garment fabric in coating agent, with coating
Device carries out precision thin coating in fabric surface, and then drying and necessary heat treatment forms thin film in fabric surface, this
Class method fastness to washing difference and feel are affected.
Meanwhile summer is mosquito multiple season again, mosquito endangers the mankind larger, not only work, the life of influence people
Living and sleep, it is often more important that infect disease.Mosquito is when biting the animals or humans for carrying virus or disease, then bites
It will be made one when Healthy People pathogenic.There are about more than one hundred million people every year infects various diseases by mosquito, is investigated according to the World Health Organization aobvious
Show, mosquito is the most animal of the annual kill mankind, annual to be up to million person-times.
Summary of the invention
Technical problem underlying to be solved by this invention:
(1) existing Sun-shield garment mostly uses sun-proof coating with fabric or fabric is made excessively fine and close, the former durability
Bad, the latter's dress is excessively sultry, and body-sensing is poor.
(2) there has been no have sun-proof, mosquito proof and contact cool feeling (meeting national coherent detection standard) three big function simultaneously
The textile of energy.
In order to solve the above technical problems, the present invention, which passes through, selects functional yarn, and use functions of textile fabrics final finishing
Technique prepares a kind of textile that is ventilative comfortable and having sun-proof, mosquito proof and contact cool feeling three zones simultaneously.Specific skill
Art scheme is as follows:
The first aspect of the present invention provides a kind of preparation method of functional yarn, includes the following steps:
(1) conduction powder, uvioresistant powder are blended to obtain blend with polymer；
(2) functional yarn is obtained after blend spinning.
In one embodiment, conduction powder includes layer silicate mineral.
In one embodiment, layer silicate mineral includes mica nano-powder of the particle size range in 100~300nm,
Weight accounting of the mica nano-powder in functional yarn is less than 5%.
In one embodiment, uvioresistant powder selects zinc oxide, titanium dioxide or silicon-dioxide powdery.
In one embodiment, uvioresistant powder selects Zinc oxide powder of the particle size range in 100~200nm, zinc oxide
Weight accounting of the powder in functional yarn is less than 5%.
In one embodiment, polymer includes polyamide.
The second aspect of the present invention provides the fabric being made into using above-mentioned functional yarn as primary raw material.
In one embodiment, fabric complete dyeing after, by the finishing agent with anti-mosquito functions by soak-roll-
Technique is dried to arrange onto fabric.
In one embodiment, finishing agent selects Permethrin.
In one embodiment, ultraviolet absorbing agent is added in dyeing and/or when technique arrangement is rolled-dried in leaching-in fabric.
The beneficial effects of the present invention are: realizing a kind of multifunctional textile product fabric with sun-proof, mosquito proof, cool feeling
Preparation method.The functional textile facing material of summer several big pain spots can be solved by providing one kind, while being had sun-proof, mosquito proof and being connect
Cool feeling three zones are touched, can be used for being processed into clothes and other accessories.
Detailed description of the invention
Fig. 1 is the process flow diagram that the present invention prepares sun-proof mosquito proof cool feeling fabric；
Fig. 2 is functional yarn cross section 1000 times of amplifications under an electron microscope in a preferred embodiment of the present invention
Microgram.
Specific embodiment
Fig. 1 illustrates the process flow chart that the present invention prepares sun-proof mosquito proof cool feeling fabric, is divided into several stages, below in detail
Thin description:
First stage prepares the blend of functional powder and polymer.
After the functional powder of the micron of multiple functions or Nano grade is directly blended with polymer, blend is obtained.
Functional powder refers to conduction powder and uvioresistant powder.
Layer silicate mineral powder of the conduction powder preferable particle size less than 1 micron.It is highly preferred that conduction powder selects grain
Diameter range is in the mica nano-powder of 100~300nm, and weight accounting of the mica nano-powder in functional yarn is less than 5%.
Mica is the general name for the water aluminium silicate mineral that family has layer structure.The thermal resistance of mica is smaller, and hot-fluid is close
After mica, hot-fluid can preferentially flow to the smallest channel of thermal resistance, can regard as, and mica powder acts as the role of heat sink, accelerate
The transmitting of heat contacts the cool feeling that moment is generated after skin to reach cooling effect.
Uvioresistant powder selects zinc oxide, titanium dioxide or silicon-dioxide powdery of the partial size less than 1 micron.It is highly preferred that
Uvioresistant powder selects zinc oxide (ZnO) nano-powder with ultraviolet screener performance, and zinc oxide nano-powder is in function
Weight accounting in property yarn is less than 5%.
Maximum to the reflection of light, scattered quantum when diameter of particle is equal to or less than the half of optical wavelength, shield effectiveness is most
It is good.In general, the smaller performance of particle diameter of nanometer powder is more excellent, but also easier reunion simultaneously, therefore take into account agglomeration and function
Energy property comprehensively considers, and mica chooses particle size range in 100~300nm, Zinc oxide powder partial size preferably 100~200nm model
It encloses.
Zinc oxide is made of the valence band full of electronics and not conduction band that the unoccupied orbital of electronics is formed, when by purple
When outside line is irradiated, electronics generates energy level transition, and by ground state transition to excitation state, excitation state is unstable state, final still to return
To ground state, the energy of ultraviolet light is finally converted into other energy and is discharged, while the zinc oxide of nano-scale has ultraviolet light
There are stronger scattering and albedo, some ultra violet rays can be reflected.
Polymer preferred polyamide.Polyamide is also known as nylon, as garment material, with numerous excellent properties: wearability,
Breaking strength, elongation at break, elastic recovery rate, fatigue durability, hygroscopicity, dyeability, optical property, resistance to optical activity, heat resistance,
Chemical-resistant.
In a preferred embodiment, above-mentioned mica nano-powder and zinc oxide nano-powder is vacuum dried, it is dry
100 DEG C of temperature, time 20h, so that the moisture content of powder is less than 120ppm.It is blended in mass ratio with polyamide slice, quality is pressed
According to the ratio of 2% mica nano-powder, 3% zinc oxide nano-powder and 95% polyamide slice, while it is total to add two kinds of powders
The dispersing agent of 1% amount of quality.It is added in high-speed mixer, mixed at high speed 2min under the conditions of 180 DEG C, 5000r/min, makes
Standby surface layer out is uniformly coated with the blending polyamide slice of functional powder.
Second stage, polymer spinning, is made functional yarn.
Polyamide yarn is blended by high-speed spinning machine, step preparation in above-mentioned mixed blended slice.After boundling,
Prepare the functional yarn of various specifications.Technological parameter are as follows: melting, spinning temperature are 260~280 DEG C, draw ratio 1.2, winding speed
Degree is 4500m/min.1000 times enlarged drawings such as Fig. 2 institute of the modified yarn cross section at scanning electron microscope (SEM)
Show, powder is more evenly distributed in each position of yarn.Obtaining yarn through this step is containing nano mica powder and oxygen
Change the polyamide yarn of zinc nano-powder.
Phase III, using functional yarn as primary raw material woven fabric.
In one embodiment, the functional yarn of the 40D/24F DTY of above-mentioned technique preparation, and plaiting 20D ammonia are chosen
Plain weave single jersey, grammes per square metre 185g/m is made by circular weft knitting machine in synthetic fibre2, component ratio is that 85% polyamide yarn (includes nanometer
Mica powder and zinc oxide nano-powder) and 15% spandex.Herein, DTY means draw textured yarn, is carried out on elasticizer device
It consecutively or simultaneously stretches, the finished silk after twister deformation processing.
Fourth stage, dyeing fabric.
Ultraviolet absorbing agent is added in fabric in dye bath, makes the ultraviolet resistance of fabric more preferably.Purple in this step
Ultraviolet absorbers also can be omitted.
5th stage, anti-mosquito functions arrange.
Above-mentioned fabric passes through leaching-after the processes such as pre-treatment, dyeing, by the textile finish with anti-mosquito functions
Technique is rolled-dried, is arranged onto fabric.Concrete technology condition are as follows: Permethrin 45g/L, crosslinking agent 20g/L, softening agent 15g/L, face
Expect liquid carrying rate 80%, drying and shaping 1min at 135 DEG C.Ultraviolet absorbing agent can also be added in this finishing technique.
Permethrin has high efficient protected effect to various insects such as mosquito, ant, cockroach, dust mite, pretty young woman, ticks.Pass through beam
It ties up sodium channel and the speed of service of nervous system is declined.This reaction is related with temperature, has to cold-blooded animal (insect etc.)
Effect, is safe and harmless for homeothermal animal (mankind etc.).
The sun-proof mosquito proof cool feeling fabric of above method preparation, is tested respectively with respective country standard.
(1) cool feeling test is carried out with GB/T 35263
Contact cool feeling, skin contact wink inch with the fabric lower than its temperature, cause skin table and heat it is rapidly losing,
Temperature wink declines, using the nice and cool feeling formed after temperature-sensitive nerve endings reflection to brain in skin.Contact cool feeling coefficient
With character qmaxIt indicates, unit is J/ (cm2·s)。
Test method is: under the conditions of defined experimental enviroment, temperature is higher than to the hot detection plate and sample contacts of sample,
Measurement heat detection plate temperature changes with time, and calculates its contact cool feeling coefficient (qmax), it thus can characterize the contact wink of sample
Between cool feeling performance.qmaxNumerical value is bigger, indicates that skin feel is stronger to cool feeling degree；Numerical value is smaller, indicates skin feel to cool feeling
Degree is weaker.Work as qmax≥0.15J/(cm2It s), is that evaluation has the instantaneous cool feeling of contact.
Sun-proof mosquito proof cool feeling fabric in the present invention carries out third party's detection by above-mentioned 35263 detection method of GB/T,
Contact cool feeling coefficient average value is 0.24J/ (cm2S), meet national standard, there is contact cool feeling performance.
(2) sun-proof test is carried out with GB/T 18830
It is sun-proof primarily to preventing injury of the ultraviolet light in daylight to skin.Solar UV irradiation refers to wavelength
For the electromagnetic radiation of 280~400nm.UVA therein refers to wavelength in the solar UV irradiation of 315~400nm.It is therein
UVB refers to wavelength in the solar UV irradiation of 280~315nm.
UV protection factor refers to: calculated ultraviolet radiation average effect and skin have fabric when skin is unshielded
The ratio of calculated ultraviolet radiation average effect when protection.UV protection factor is indicated with UPF.
Test method: with monochromatic or polychrome ultraviolet rays irradiated samples, collecting total spectral transmission ray, determines total
Spectral transmittance, and calculate the UV protection factor UPF value of style.When UPF > 40 of sample, and T (UVA)AVWhen < 5%,
It can be described as " antiultraviolet product ".
Sun-proof mosquito proof cool feeling fabric in the present invention carries out third party's detection by above-mentioned 18830 detection method of GB/T,
UPF average value 614, T (UVA) average value 2.00%, T (UVB) average value 0.08% meet the standard of UPF > 50 of the national standard.
Herein, T (UVA) refers to the transmittance of UVA, and T (UVB) refers to the transmittance of UVB.
(3) mosquito proof test is carried out with GB/T 30126
Test method: the mosquito with certain attack is placed in the space of sample, and wherein sample invests human body or confession
On blood device, counts mosquito at the appointed time and in sample to be tested and control sample surface stop falling number, fabric is evaluated with scattering ratio
Mosquito-proof performance.Evaluation criterion see the table below 1.
Table 1
| Mosquito-proof grading | A grades | B grades | C grades |
| Scattering ratio ruler | > 70% | 70%~50% | <50%,>30% |
| Repellent effect | With extremely strong repellent effect | With good repellent effect | With repellent effect |
Sun-proof mosquito proof cool feeling fabric in the present invention carries out third-party testing by 30126 detection method of GB/T, to mosquito
The scattering ratio of worm is 83.70%, has extremely strong repellent effect to mosquito.
The preferred embodiment of the present invention has been described in detail above.It should be appreciated that those skilled in the art without
It needs creative work according to the present invention can conceive and makes many modifications and variations.Therefore, all technologies in the art
Personnel are available by logical analysis, reasoning, or a limited experiment on the basis of existing technology under this invention's idea
Technical solution, all should be within the scope of protection determined by the claims.
Claims (10)
1. a kind of preparation method of functional yarn, which comprises the steps of:
(1) conduction powder, uvioresistant powder are blended to obtain blend with polymer；
(2) functional yarn is obtained after the blend spinning.
2. a kind of preparation method of functional yarn according to claim 1, which is characterized in that the conduction powder includes
Layer silicate mineral.
3. a kind of preparation method of functional yarn according to claim 2, which is characterized in that layered silicate mine
Object includes mica nano-powder of the particle size range in 100~300nm, and the mica nano-powder is in the functional yarn
Weight accounting is less than 5%.
4. a kind of preparation method of functional yarn according to claim 1, which is characterized in that the uvioresistant powder choosing
With zinc oxide, titanium dioxide or silicon-dioxide powdery.
5. a kind of preparation method of functional yarn according to claim 4, which is characterized in that the uvioresistant powder choosing
Zinc oxide powder with particle size range in 100~200nm, weight accounting of the Zinc oxide powder in the functional yarn
Less than 5%.
6. a kind of preparation method of functional yarn according to claim 1, which is characterized in that the polymer includes poly-
Amide.
7. a kind of fabric preparation method, which is characterized in that the fabric is with functional yams described in any one of claim 1~6
Line is made into for primary raw material.
8. a kind of fabric preparation method according to claim 7, which is characterized in that after the fabric completes dyeing,
Finishing agent with anti-mosquito functions is dried in technique arrangement to the fabric by soaking-rolling-.
9. a kind of fabric preparation method according to claim 8, which is characterized in that the finishing agent selects Permethrin.
10. a kind of fabric preparation method according to claim 8, which is characterized in that the fabric dyeing when and/or
Soak-roll-dry technique arrange when, be added ultraviolet absorbing agent.
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| CN111074409A (en) * | 2019-12-09 | 2020-04-28 | 浙江正辉纺织有限公司 | Mosquito-proof spandex blended knitted fabric and production method thereof |
| CN113215713A (en) * | 2021-06-18 | 2021-08-06 | 广东兆联纺织有限公司 | Odor-removing UV-resistant cool fabric and preparation method thereof |
| CN116356446A (en) * | 2023-04-12 | 2023-06-30 | 鸭鸭股份公司 | Raw yarn mosquito-repellent sun-proof fabric and preparation method thereof |
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Application publication date: 20190604 |