CN105504901A - Environmental-friendly wall mask material and preparation method thereof - Google Patents
Environmental-friendly wall mask material and preparation method thereof Download PDFInfo
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- CN105504901A CN105504901A CN201610064801.3A CN201610064801A CN105504901A CN 105504901 A CN105504901 A CN 105504901A CN 201610064801 A CN201610064801 A CN 201610064801A CN 105504901 A CN105504901 A CN 105504901A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/34—Filling pastes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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Abstract
The invention discloses an environmental-friendly wall mask material and a preparation method thereof. The mask material comprises the following components in percentage by weight: 5-10 percent of negative ion powder, 5-10 percent of nano TiO2 powder, 1-5 percent of a silver ion preparation, 10-15 percent of an inorganic wrapping agent, 4-8 percent of coalescing agents and 50-80 percent of putty powder. The wall mask material disclosed by the invention is blended into appropriate knife coating consistency in the using process by using clean water, and the wall mask material is coated on internal walls and ceiling to absorb carbon dioxide and is cured to form a mask layer. The wall mask material can achieve the effects of permanently releasing negative ions, reducing indoor PM2.5, inhibiting activities of bacterial viruses, proofing fungi, controlling mould, performing catalytic degradation on formaldehyde and other poisonous and harmful gases in air, so that the effects of improving the indoor air quality, resisting bacteria and controlling mould are achieved.
Description
Technical field
The present invention relates to building material technical field, be specifically related to a kind of environment friendly wall face-mask material and preparation method thereof.
Background technology
Along with the raising of people's living standard, more and more higher to the demand of living environment, require comfortable while, more focus on the impact of the health of Environmental insults.The living environment of house decoration and modern has close contacting, people when working, learning or being in rest all prolonged in the environment of various house ornamentation, be in process of assembling, body of wall face-mask material, as coating, putty etc. are absolutely necessary material.But the problem that the indoor pollution that these finishing material cause affects HUMAN HEALTH gets more and more, people more and more pay close attention to the feature of environmental protection of indoor paint, and on the impact that HUMAN HEALTH produces.Various wholesome environmental friendly indoor body of wall face-mask material arises at the historic moment.
The main component of negative ion powder is tourmalinite, and the silicate minerals of the aluminium of tourmalinite to be a kind of with boracic be feature, sodium, iron, lithium ring texture, has piezoelectricity and thermoelectric effect.The change of envrionment temperature and pressure can cause the potential difference of tourmaline crystal, and ambient air is ionized, and is electronically attached to contiguous water and oxygen molecule and makes it be converted into negative aeroion, can reach the object purified air to a certain extent by what hit.In addition, because of pyroelectricity and piezoelectricity make its polar ion cause dipole moment to change to produce in equilibrium theory of tide vibration can the electromagnetic radiation of far infrared band, fiber far-infrared warm function to a certain degree can be made add ultra-fine tourmaline in man-made fiber after.Therefore, tourmalinite is a kind of environmental friendliness and environment-friendly function material.But tourmalinite also exists some shortcoming and defect: one be that whiteness is low, color is dark, generally darkly, brown, dark green isochrome, color and luster can not meet the requirement of above-mentioned Application Areas, particularly coating and man-made fiber application; Two are, itself does not possess photo-catalysis function and anti-microbial property, and when being used as material for air purification, function is limited.
Since 20 century 70s, nano-TiO
2be proved to be a kind of efficient, nontoxic, environment amenable photocatalyst material of stable performance, TiO
2excite the light induced electron of rear generation and hole can with the H being adsorbed on photocatalyst surface by illumination
2o, OH-and O
2generate hydroxyl radical free radical and the superoxide radical with strong oxidizing property after reaction, these free radicals can be adsorbed on the material decomposition of catalyst surface, generate CO
2, H
2the simple small molecules inorganics such as O.
Summary of the invention
An object of the present invention is to solve at least the problems referred to above and/or defect, and the advantage will illustrated at least is below provided.
In order to realize according to these objects of the present invention and other advantage, provide one one kinds of environment friendly wall face-mask materials, this face-mask material comprises each component of following weight percent: negative ion powder 5 ~ 10%, nano-TiO
2powder 5 ~ 10%, silver-ion formulations 1 ~ 5%, inorganic coating agent 10 ~ 15%, film coalescence aid 4 ~ 8%, putty powder 50 ~ 80%.
Preferably, described face-mask material also comprises the composition of following weight percent: flow agent 0.1 ~ 0.5%, dispersion agent 0.1 ~ 0.5%, defoamer 0.1 ~ 0.5%, thickening material 0.1 ~ 0.5%, antisettling agent 0.1 ~ 0.5%, sanitas 0.1 ~ 0.5%, anti-formaldehyde agent 0.1 ~ 0.5%.
Preferably, described face-mask material comprises each component of following weight percent: negative ion powder 10%, nano-TiO
2powder 8%, silver-ion formulations 3%, inorganic coating agent 12%, film coalescence aid 6%, putty powder 60%, flow agent 0.1%, dispersion agent 0.2%, defoamer 0.1%, thickening material 0.2%, antisettling agent 0.1%, sanitas 0.1%, anti-formaldehyde agent 0.2%.
Preferably, described negative ion powder comprises the composition of following weight percent: 20 ~ 40%SiO
2, 20 ~ 40%Al
2o
3, 0.1 ~ 0.5%CaO, 1 ~ 3%MgO, 10 ~ 20%Fe
2o
3, 2 ~ 5%FeO, 5 ~ 10%B
2o
3, 0.5 ~ 1%Na
2o, 0.05 ~ 1%K
2o; The granularity of described negative ion powder is 0.3 ~ 0.5um.
Preferably, described silver-ion formulations be silver citrate, ammonia Silver Nitrate, sulfonic acid pyridine silver, Norxin silver-colored in the mixing of one or more.
Preferably, described inorganic coating agent is cement, Ca (OH)
2, the mixing of one or more in water glass.
Preferably, described film coalescence aid is the mixing of one or more in Vltra tears, Xylo-Mucine, polyvinylpyrrolidone, polyvinyl alcohol, xanthan gum.
Preferably, described putty powder comprises each component of following weight part: volcanic ash 30-50 part, calcium carbonate 10-30 part, hydroxypropyl starch ether 2-5 part, silica powder 5-10 part, polyacrylamide 1-3 part, Na-alginate 1-3 part, bamboo-carbon fibre 2 ~ 5 parts, probiotic powder 1-3 part.
Preferably, described dispersion agent is the one in 1-ethyl-3-methylimidazolium chloride, 1-butyl-3-methylimidazolium chloride, 1-ethyl-3-methylimidazole acetate, 1,3-methylimidazole a tetrafluoro borate, 1-ethyl-3-methylimidazole lactic acid; Described thickening material is the one in Natvosol, sodium bentonite, sodium polyacrylate; Described sanitas is the one in isothiazolinone, nitrogenous sulphur ring compound, s-triazine; Described anti-formaldehyde agent is 2-imidazolidone.
The present invention also provides a kind of method preparing above-mentioned environment friendly wall face-mask material, comprises the following steps:
Step one, negative ion powder is ground into the particle of 0.3 ~ 0.5um, then adds in the water of 2 ~ 5 times of weight, then add nano-TiO
2powder, soak 1 ~ 3h after stirring 30 ~ 60min, then under microwave frequency 2450MHz, power 300-400W, process 5-10min, then filter, filter cake is dried at 60-70 DEG C, is ground into the powder that granularity is less than 0.5um;
Step 2, silver-ion formulations is added in the water of 1 ~ 3 times of weight, then add inorganic coating agent, stir 1 ~ 3 hour, filter, with distilled water flushing to neutral, shift as in reactor, through 180-200 DEG C of steam treatment 1 ~ 3 hour, take out, dry, obtain antibacterial material;
Step 3, powder putty powder, step one obtained, step 2 obtain antibacterial material and add in ball mill, be milled to granularity and be less than 0.5 μm, then the material after ball milling is added in mixing machine, and add flow agent, defoamer, thickening material, antisettling agent, sanitas, to be warming up to 70-80 DEG C after the speed of 3000 ~ 5000r/min mixing 5-10min, add film coalescence aid again, continue mixing 10-15min, cooling down adds anti-formaldehyde agent and dispersion agent after 30-40 DEG C subsequently, continue mixing 5-10min, obtain mixture;
Step 4, mixture joined in spray-drier dry, pulverize, namely obtain body of wall face-mask material.
In the present invention, negative ion powder adopts dry method and wet pulverization to become to be ground into the particle of 0.3 ~ 0.5um, can ensure that its crystal perfection can cook nucleator again, addition is 5 ~ 10wt%, good dispersity in facial mask, can ensure the whiteness of facial mask, fully excites again the effect of anion releasing.Nano-TiO
2powder is the white pigment of tool height hiding rare, and granule surface area is large, and easily reunite, its addition, 5 ~ 10%, is conducive to being scattered in facial mask.
In the present invention, silver-ion formulations adopts nano level silver ions (Ag
+), nano level silver ions can kill known all pathogenic bacterium substantially: streptococcus aureus, intestinal bacteria, pseudomonas, Legionella bacteria, Salmonellas.Nano level silver ions is added in body of wall face-mask material and can strengthen antibacterial bacteria-eliminating efficacy.
In the present invention, the few insufficient strength of addition of inorganic coating agent, easily come off, addition causes integument too thick more, affects transmission effect, therefore selects addition at 10 ~ 15wt% by great many of experiments, especially selects Ca (OH)
2not only can play solidification, go back the CO in Absorbable rod air
2gas, purifies air.
In the present invention, film coalescence aid generally adopts friendly macromolecular material, can play and be rolled into membrane interaction, and film forming can be made again to possess toughness, and consumption is advisable at 4-8%, and usage quantity height often causes construction effort, and cost is higher.
In the present invention, defoamer is a class material known in those skilled in the art, and comprise amides defoamer, polyethers defoamer, imines defoamer etc., its effect is to prevent body of wall face-mask material from use producing bubble.
In the present invention, flow agent is a class material known in those skilled in the art, comprise crylic acid resin flow agent, urea-formaldehyde resin class flow agent, terpolycyantoamino-formaldehyde resin class flow agent etc., its effect gathers to form the new resin molding of one deck to surface, the surface tension of film is tended to balance, thus impels the printing rete of body of wall face-mask material to become smooth, even.
In the present invention, antisettling agent is a class material known in those skilled in the art, comprise quaternary ammonium salt high-molecular copolymer, anionic carboxylic acid interpolymer, non-ionic polyurethane class etc., its objective is the sedimentation preventing body of wall face-mask material in use each composition, stablize the state of each composition in body of wall face-mask material.
In the present invention, the preparation method of described putty powder is: by volcanic ash 30-50 part, calcium carbonate 10-30 part, hydroxypropyl starch ether 2-5 part, silica powder 5-10 part, polyacrylamide 1-3 part, Na-alginate 1-3 part, bamboo-carbon fibre 2 ~ 5 points, probiotic powder 1-3 part, add in mixing vessel, under the rotating speed of 3000-5000r/min, mix 10-60min, obtain putty powder.
The present invention at least comprises following beneficial effect: body of wall face-mask material of the present invention is in use by the blade coating denseness that clean water furnishing is suitable, by body of wall face-mask material is coated on indoor wall, top ceiling, in absorption chamber, carbon dioxide solidification forms one deck facial mask.Not only can permanent anion releasing, reduce indoor PM2.5, and can the activity of anti-bacteria virus, fungi-proofing except mould, the toxic and harmfuls such as the formaldehyde in catalyzed degradation air, thus reach and improve IAQ (indoor air quality), antibacterial except mould effect.
Part is embodied by explanation below by other advantage of the present invention, target and feature, part also will by research and practice of the present invention by those skilled in the art is understood.
Embodiment:
Below in conjunction with embodiment, the present invention is described in further detail, can implement according to this with reference to specification sheets word to make those skilled in the art.
Should be appreciated that used hereinly such as " to have ", other element one or more do not allotted in " comprising " and " comprising " term or the existence of its combination or interpolation.
Embodiment 1:
A kind of environment friendly wall face-mask material, this face-mask material comprises each component of following weight percent: negative ion powder 10%, nano-TiO
2powder 10%, silver citrate 5%, cement 15%, Vltra tears 8%, putty powder 52%.
The preparation method of described face-mask material is:
Step one, negative ion powder is ground into the particle of 0.5um, then adds in the water of 2 times of weight, then add nano-TiO
2powder, soak 1h after stirring 30min, then under microwave frequency 2450MHz, power 400W, process 10min, then filter, filter cake is dried at 70 DEG C, is ground into the powder that granularity is less than 0.5um;
Step 2, silver citrate to be added in the water of 2 times of weight, then add cement, stir 1 hour, filter, with distilled water flushing to neutral, shift as in reactor, through 180 DEG C of steam treatment 3 hours, take out, dry, obtain antibacterial material;
Step 3, powder putty powder, step one obtained, step 2 obtain antibacterial material and add in ball mill, be milled to granularity and be less than 0.5 μm, then the material after ball milling is added in mixing machine, to be warming up to 80 DEG C after the speed of 3000 ~ 5000r/min mixing 10min, add Vltra tears again, continue mixing 10min, obtain mixture;
Step 4, mixture joined in spray-drier dry, pulverize, namely obtain body of wall face-mask material.
Described negative ion powder comprises the composition of following weight percent: 35.5%SiO
2, 34.8%Al
2o
3, 0.4%CaO, 1.42%MgO, 14%Fe
2o
3, 3.89%FeO, 8.96%B
2o
3, 0.74%Na
2o, 0.29%K
2o.
The preparation method of described putty powder is: by volcanic ash 50kg, calcium carbonate 10-30kg, hydroxypropyl starch ether 5kg, silica powder 5kg, polyacrylamide 3kg, Na-alginate 3kg, bamboo-carbon fibre 5kg, probiotic powder 1kg, add in mixing vessel, under the rotating speed of 5000r/min, mix 60min, obtain putty powder.
Embodiment 2:
A kind of environment friendly wall face-mask material, this face-mask material comprises each component of following weight percent: negative ion powder 10%, nano-TiO
2powder 8%, sulfonic acid pyridine silver 3%, 12%Ca (OH)
2, Xylo-Mucine 6%, putty powder 60%, flow agent 0.1%, 1-ethyl-3-methylimidazolium chloride 0.2%, defoamer 0.1%, sodium polyacrylate 0.2%, antisettling agent 0.1%, isothiazolinone 0.1%, 2-imidazolidone 0.2%.
The preparation method of described face-mask material is:
Step one, negative ion powder is ground into the particle of 0.5um, then adds in the water of 2 times of weight, then add nano-TiO
2powder, soak 3h after stirring 30min, then under microwave frequency 2450MHz, power 300W, process 5min, then filter, filter cake is dried at 70 DEG C, is ground into the powder that granularity is less than 0.5um;
Step 2, silver-ion formulations is added in the water of 3 times of weight, then add Ca (OH)
2, stir 3 hours, filter, with distilled water flushing to neutral, shift as in reactor, through 200 DEG C of steam treatment 3 hours, take out, dry, obtain antibacterial material;
Step 3, powder putty powder, step one obtained, step 2 obtain antibacterial material and add in ball mill, be milled to granularity and be less than 0.5 μm, then the material after ball milling is added in mixing machine, and add flow agent, defoamer, sodium polyacrylate, antisettling agent, isothiazolinone, to be warming up to 80 DEG C after the speed of 5000r/min mixing 10min, add Xylo-Mucine again, continue mixing 15min, 2-imidazolidone and 1-ethyl-3-methylimidazolium chloride is added subsequently after cooling down to 40 DEG C, continue mixing 10min, obtain mixture;
Step 4, mixture joined in spray-drier dry, pulverize, namely obtain body of wall face-mask material.
Described negative ion powder comprises the composition of following weight percent: 35.5%SiO
2, 34.8%Al
2o
3, 0.4%CaO, 1.42%MgO, 14%Fe
2o
3, 3.89%FeO, 8.96%B
2o
3, 0.74%Na
2o, 0.29%K
2o.
The preparation method of described putty powder is: by volcanic ash 50kg, calcium carbonate 10-30kg, hydroxypropyl starch ether 5kg, silica powder 5kg, polyacrylamide 3kg, Na-alginate 3kg, bamboo-carbon fibre 5kg, probiotic powder 1kg, add in mixing vessel, under the rotating speed of 5000r/min, mix 60min, obtain putty powder.
Embodiment 3:
A kind of environment friendly wall face-mask material, this face-mask material comprises each component of following weight percent: negative ion powder 10%, nano-TiO
2powder 10%, Norxin silver 5%, water glass 10%, polyvinylpyrrolidone 5%, putty powder 58.6%, flow agent 0.2%, 1-ethyl-3-methylimidazole acetate 0.2%, defoamer 0.2%, sodium bentonite 0.2%, antisettling agent 0.2%, s-triazine 0.2%, 2-imidazolidone 0.2%.
The preparation method of described face-mask material is:
Step one, negative ion powder is ground into the particle of 0.5um, then adds in the water of 2 times of weight, then add nano-TiO
2powder, soak 3h after stirring 30min, then under microwave frequency 2450MHz, power 300W, process 5min, then filter, filter cake is dried at 70 DEG C, is ground into the powder that granularity is less than 0.5um;
Step 2, to be added in the water of 3 times of weight by Norxin silver, then add water glass, stirs 3 hours, filter, with distilled water flushing to neutral, shift as in reactor, through 200 DEG C of steam treatment 3 hours, take out, drying, obtained antibacterial material;
Step 3, powder putty powder, step one obtained, step 2 obtain antibacterial material and add in ball mill, be milled to granularity and be less than 0.5 μm, then the material after ball milling is added in mixing machine, and add flow agent, defoamer, sodium bentonite, antisettling agent, s-triazine, to be warming up to 80 DEG C after the speed of 5000r/min mixing 10min, add polyvinylpyrrolidone again, continue mixing 15min, 2-imidazolidone and 1-ethyl-3-methylimidazole acetate is added subsequently after cooling down to 40 DEG C, continue mixing 10min, obtain mixture;
Step 4, mixture joined in spray-drier dry, pulverize, namely obtain body of wall face-mask material.
Described negative ion powder comprises the composition of following weight percent: 35.5%SiO
2, 34.8%Al
2o
3, 0.4%CaO, 1.42%MgO, 14%Fe
2o
3, 3.89%FeO, 8.96%B
2o
3, 0.74%Na
2o, 0.29%K
2o.
The preparation method of described putty powder is: by volcanic ash 30kg, calcium carbonate 20kg, hydroxypropyl starch ether 3kg, silica powder 5kg, polyacrylamide 3kg, Na-alginate 2kg, bamboo-carbon fibre 5kg, probiotic powder 2kg, add in mixing vessel, under the rotating speed of 5000r/min, mix 60min, obtain putty powder.
Embodiment 4:
A kind of environment friendly wall face-mask material, this face-mask material comprises each component of following weight percent: negative ion powder 10%, nano-TiO
2powder 5%, ammonia Silver Nitrate 5%, cement 15%, xanthan gum 5%, putty powder 56.5%, flow agent 0.5%, 1-ethyl-3-methylimidazole lactic acid 0.5%, defoamer 0.5%, Natvosol 0.5%, antisettling agent 0.5%, s-triazine 0.5%, 2-imidazolidone 0.5%.
The preparation method of described face-mask material is:
Step one, negative ion powder is ground into the particle of 0.3um, then adds in the water of 3 times of weight, then add nano-TiO
2powder, soak 3h after stirring 30min, then under microwave frequency 2450MHz, power 300W, process 5min, then filter, filter cake is dried at 60 DEG C, is ground into the powder that granularity is less than 0.5um;
Step 2, ammonia Silver Nitrate to be added in the water of 3 times of weight, then add cement, stir 3 hours, filter, with distilled water flushing to neutral, shift as in reactor, through 180 DEG C of steam treatment 3 hours, take out, dry, obtain antibacterial material;
Step 3, powder putty powder, step one obtained, step 2 obtain antibacterial material and add in ball mill, be milled to granularity and be less than 0.5 μm, then the material after ball milling is added in mixing machine, and add flow agent, defoamer, Natvosol, antisettling agent, s-triazine, to be warming up to 80 DEG C after the speed of 5000r/min mixing 10min, add xanthan gum again, continue mixing 15min, 2-imidazolidone and 1-ethyl-3-methylimidazole lactic acid is added subsequently after cooling down to 40 DEG C, continue mixing 10min, obtain mixture;
Step 4, mixture joined in spray-drier dry, pulverize, namely obtain body of wall face-mask material.
Described negative ion powder comprises the composition of following weight percent: 35.5%SiO
2, 34.8%Al
2o
3, 0.4%CaO, 1.42%MgO, 14%Fe
2o
3, 3.89%FeO, 8.96%B
2o
3, 0.74%Na
2o, 0.29%K
2o.
The preparation method of described putty powder is: by volcanic ash 50kg, calcium carbonate 20kg, hydroxypropyl starch ether 3kg, silica powder 5kg, polyacrylamide 1kg, Na-alginate 1kg, bamboo-carbon fibre 5kg, probiotic powder 2kg, add in mixing vessel, under the rotating speed of 5000r/min, mix 60min, obtain putty powder.
Embodiment 5:
A kind of environment friendly wall face-mask material, this face-mask material comprises each component of following weight percent: negative ion powder 10%, nano-TiO
2powder 5%, Norxin silver 5%, cement 15%, polyvinyl alcohol 5%, putty powder 56.5%, flow agent 0.5%, 1,3-methylimidazole a tetrafluoro borate 0.5%, defoamer 0.5%, Natvosol 0.5%, antisettling agent 0.5%, s-triazine 0.5%, 2-imidazolidone 0.5%.
The preparation method of described face-mask material is:
Step one, negative ion powder is ground into the particle of 0.5um, then adds in the water of 3 times of weight, then add nano-TiO
2powder, soak 2h after stirring 60min, then under microwave frequency 2450MHz, power 300W, process 10min, then filter, filter cake is dried at 60 DEG C, is ground into the powder that granularity is less than 0.5um;
Step 2, to be added in the water of 3 times of weight by Norxin silver silver, then add cement, stirs 3 hours, filter, with distilled water flushing to neutral, shift as in reactor, through 200 DEG C of steam treatment 3 hours, take out, drying, obtained antibacterial material;
Step 3, powder putty powder, step one obtained, step 2 obtain antibacterial material and add in ball mill, be milled to granularity and be less than 0.5 μm, then the material after ball milling is added in mixing machine, and add flow agent, defoamer, Natvosol, antisettling agent, s-triazine, to be warming up to 70 DEG C after the speed of 3000r/min mixing 10min, add polyvinyl alcohol again, continue mixing 10min, 2-imidazolidone and 1 is added subsequently after cooling down to 30 DEG C, 3-methylimidazole a tetrafluoro borate, continue mixing 10min, obtain mixture;
Step 4, mixture joined in spray-drier dry, pulverize, namely obtain body of wall face-mask material.
Described negative ion powder comprises the composition of following weight percent: 35.5%SiO
2, 34.8%Al
2o
3, 0.4%CaO, 1.42%MgO, 14%Fe
2o
3, 3.89%FeO, 8.96%B
2o
3, 0.74%Na
2o, 0.29%K
2o.
The preparation method of described putty powder is: by volcanic ash 40kg, calcium carbonate 20kg, hydroxypropyl starch ether 3kg, silica powder 5kg, polyacrylamide 1kg, Na-alginate 2kg, bamboo-carbon fibre 2kg, probiotic powder 1kg, add in mixing vessel, under the rotating speed of 5000r/min, mix 60min, obtain putty powder.
Embodiment 6:
A kind of environment friendly wall face-mask material, this face-mask material comprises each component of following weight percent: negative ion powder 10%, nano-TiO
2powder 5%, by weight ammonia Silver Nitrate and the Norxin silver 5% of 1:1 mixing, by weight the Ca (OH) of 2:1 mixing
2with cement 15%, xanthan gum 5%, putty powder 56.5%, flow agent 0.5%, 1-ethyl-3-methylimidazole lactic acid 0.5%, defoamer 0.5%, Natvosol 0.5%, antisettling agent 0.5%, s-triazine 0.5%, 2-imidazolidone 0.5%.
The preparation method of described face-mask material is:
Step one, negative ion powder is ground into the particle of 0.5um, then adds in the water of 2 times of weight, then add nano-TiO
2powder, soak 3h after stirring 30min, then under microwave frequency 2450MHz, power 300W, process 5min, then filter, filter cake is dried at 60 DEG C, is ground into the powder that granularity is less than 0.5um;
Step 2, by ammonia Silver Nitrate and Norxin silver add in the water of 3 times of weight, then add Ca (OH)
2and cement, stir 3 hours, filter, with distilled water flushing to neutral, shift as in reactor, through 200 DEG C of steam treatment 3 hours, take out, dry, obtain antibacterial material;
Step 3, powder putty powder, step one obtained, step 2 obtain antibacterial material and add in ball mill, be milled to granularity and be less than 0.5 μm, then the material after ball milling is added in mixing machine, and add flow agent, defoamer, Natvosol, antisettling agent, s-triazine, to be warming up to 80 DEG C after the speed of 4000r/min mixing 10min, add xanthan gum again, continue mixing 15min, 2-imidazolidone and 1-ethyl-3-methylimidazole lactic acid is added subsequently after cooling down to 40 DEG C, continue mixing 10min, obtain mixture;
Step 4, mixture joined in spray-drier dry, pulverize, namely obtain body of wall face-mask material.
Described negative ion powder comprises the composition of following weight percent: 35.5%SiO
2, 34.8%Al
2o
3, 0.4%CaO, 1.42%MgO, 14%Fe
2o
3, 3.89%FeO, 8.96%B
2o
3, 0.74%Na
2o, 0.29%K
2o.
The preparation method of described putty powder is: by volcanic ash 30kg, calcium carbonate 20kg, hydroxypropyl starch ether 3kg, silica powder 8kg, polyacrylamide 1kg, Na-alginate 3kg, bamboo-carbon fibre 5kg, probiotic powder 2kg, add in mixing vessel, under the rotating speed of 5000r/min, mix 60min, obtain putty powder.
Embodiment 7:
A kind of environment friendly wall face-mask material, this face-mask material comprises each component of following weight percent: negative ion powder 10%, nano-TiO
2powder 10%, Norxin silver 5%, by weight cement and the water glass 10% of 1:1, by weight polyvinylpyrrolidone and xanthan gum 5%, putty powder 58.6%, flow agent 0.2%, 1-ethyl-3-methylimidazole acetate 0.2%, defoamer 0.2%, sodium bentonite 0.2%, antisettling agent 0.2%, s-triazine 0.2%, the 2-imidazolidone 0.2% of 1:1 mixing.
The preparation method of described face-mask material is:
Step one, negative ion powder is ground into the particle of 0.5um, then adds in the water of 2 times of weight, then add nano-TiO
2powder, soak 3h after stirring 30min, then under microwave frequency 2450MHz, power 300W, process 5min, then filter, filter cake is dried at 70 DEG C, is ground into the powder that granularity is less than 0.5um;
Step 2, add in the water of 3 times of weight by Norxin silver, then add cement and water glass, stirs 3 hours, filter, with distilled water flushing to neutral, shift as in reactor, through 180 DEG C of steam treatment 3 hours, take out, drying, obtained antibacterial material;
Step 3, powder putty powder, step one obtained, step 2 obtain antibacterial material and add in ball mill, be milled to granularity and be less than 0.5 μm, then the material after ball milling is added in mixing machine, and add flow agent, defoamer, sodium bentonite, antisettling agent, s-triazine, to be warming up to 80 DEG C after the speed of 5000r/min mixing 10min, add polyvinylpyrrolidone and xanthan gum again, continue mixing 15min, 2-imidazolidone and 1-ethyl-3-methylimidazole acetate is added subsequently after cooling down to 40 DEG C, continue mixing 10min, obtain mixture;
Step 4, mixture joined in spray-drier dry, pulverize, namely obtain body of wall face-mask material.
Described negative ion powder comprises the composition of following weight percent: 35.5%SiO
2, 34.8%Al
2o
3, 0.4%CaO, 1.42%MgO, 14%Fe
2o
3, 3.89%FeO, 8.96%B
2o
3, 0.74%Na
2o, 0.29%K
2o.
The preparation method of described putty powder is: by volcanic ash 50kg, calcium carbonate 25kg, hydroxypropyl starch ether 3kg, silica powder 6kg, polyacrylamide 3kg, Na-alginate 1kg, bamboo-carbon fibre 3kg, probiotic powder 2kg, add in mixing vessel, under the rotating speed of 5000r/min, mix 60min, obtain putty powder.
Embodiment 8:
A kind of environment friendly wall face-mask material, this face-mask material comprises each component of following weight percent: negative ion powder 10%, nano-TiO
2powder 8%, silver-ion formulations 3%, inorganic coating agent 12%, film coalescence aid 6%, putty powder 60%, flow agent 0.1%, dispersion agent 0.2%, defoamer 0.1%, thickening material 0.2%, antisettling agent 0.1%, sanitas 0.1%, anti-formaldehyde agent 0.2%.
The preparation method of described face-mask material is:
Step one, negative ion powder is ground into the particle of 0.5um, then adds in the water of 3 times of weight, then add nano-TiO
2powder, soak 3h after stirring 60min, then under microwave frequency 2450MHz, power 400W, process 10min, then filter, filter cake is dried at 70 DEG C, is ground into the powder that granularity is less than 0.5um;
Step 2, silver-ion formulations is added in the water of 3 times of weight, then add inorganic coating agent, stir 2 hours, filter, with distilled water flushing to neutral, shift as in reactor, through 200 DEG C of steam treatment 2 hours, take out, dry, obtain antibacterial material;
Step 3, powder putty powder, step one obtained, step 2 obtain antibacterial material and add in ball mill, be milled to granularity and be less than 0.5 μm, then the material after ball milling is added in mixing machine, and add flow agent, defoamer, thickening material, antisettling agent, sanitas, to be warming up to 80 DEG C after the speed of 5000r/min mixing 10min, add film coalescence aid again, continue mixing 15min, anti-formaldehyde agent and dispersion agent is added subsequently after cooling down to 40 DEG C, continue mixing 10min, obtain mixture;
Step 4, mixture joined in spray-drier dry, pulverize, namely obtain body of wall face-mask material.
Described negative ion powder comprises the composition of following weight percent: 35.5%SiO
2, 34.8%Al
2o
3, 0.4%CaO, 1.42%MgO, 14%Fe
2o
3, 3.89%FeO, 8.96%B
2o
3, 0.74%Na
2o, 0.29%K
2o.
The preparation method of described putty powder is: by volcanic ash 40 parts, 20 parts, calcium carbonate, hydroxypropyl starch ether 4 parts, silica powder 8 parts, polyacrylamide 2 parts, Na-alginate 2 parts, bamboo-carbon fibre 3 points, probiotic powder 2 parts, adds in mixing vessel, under the rotating speed of 4000r/min, mix 30min, obtain putty powder.
Although embodiment of the present invention are open as above, but it is not restricted to listed in specification sheets and embodiment utilization, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details and illustrates here and the example described.
Claims (10)
1. an environment friendly wall face-mask material, is characterized in that, this face-mask material comprises each component of following weight percent: negative ion powder 5 ~ 10%, nano-TiO
2powder 5 ~ 10%, silver-ion formulations 1 ~ 5%, inorganic coating agent 10 ~ 15%, film coalescence aid 4 ~ 8%, putty powder 50 ~ 80%.
2. environment friendly wall face-mask material as claimed in claim 1, it is characterized in that, described face-mask material also comprises the composition of following weight percent: flow agent 0.1 ~ 0.5%, dispersion agent 0.1 ~ 0.5%, defoamer 0.1 ~ 0.5%, thickening material 0.1 ~ 0.5%, antisettling agent 0.1 ~ 0.5%, sanitas 0.1 ~ 0.5%, anti-formaldehyde agent 0.1 ~ 0.5%.
3. environment friendly wall face-mask material as claimed in claim 2, it is characterized in that, described face-mask material comprises each component of following weight percent: negative ion powder 10%, nano-TiO
2powder 8%, silver-ion formulations 3%, inorganic coating agent 12%, film coalescence aid 6%, putty powder 60%, flow agent 0.1%, dispersion agent 0.2%, defoamer 0.1%, thickening material 0.2%, antisettling agent 0.1%, sanitas 0.1%, anti-formaldehyde agent 0.2%.
4. environment friendly wall face-mask material as claimed in claim 1, it is characterized in that, described negative ion powder comprises the composition of following weight percent: 20 ~ 40%SiO
2, 20 ~ 40%Al
2o
3, 0.1 ~ 0.5%CaO, 1 ~ 3%MgO, 10 ~ 20%Fe
2o
3, 2 ~ 5%FeO, 5 ~ 10%B
2o
3, 0.5 ~ 1%Na
2o, 0.05 ~ 1%K
2o; The granularity of described negative ion powder is 0.3 ~ 0.5um.
5. environment friendly wall face-mask material as claimed in claim 1, is characterized in that, described silver-ion formulations is that silver citrate, ammonia Silver Nitrate, sulfonic acid pyridine are silver-colored, Norxin silver-colored in the mixing of one or more.
6. environment friendly wall face-mask material as claimed in claim 1, it is characterized in that, described inorganic coating agent is cement, Ca (OH)
2, the mixing of one or more in water glass.
7. environment friendly wall face-mask material as claimed in claim 1, it is characterized in that, described film coalescence aid is the mixing of one or more in Vltra tears, Xylo-Mucine, polyvinylpyrrolidone, polyvinyl alcohol, xanthan gum.
8. environment friendly wall face-mask material as claimed in claim 1, it is characterized in that, described putty powder comprises each component of following weight part: volcanic ash 30-50 part, calcium carbonate 10-30 part, hydroxypropyl starch ether 2-5 part, silica powder 5-10 part, polyacrylamide 1-3 part, Na-alginate 1-3 part, bamboo-carbon fibre 2 ~ 5 parts, probiotic powder 1-3 part.
9. environment friendly wall face-mask material as claimed in claim 2, it is characterized in that, described dispersion agent is the one in 1-ethyl-3-methylimidazolium chloride, 1-butyl-3-methylimidazolium chloride, 1-ethyl-3-methylimidazole acetate, 1,3-methylimidazole a tetrafluoro borate, 1-ethyl-3-methylimidazole lactic acid; Described thickening material is the one in Natvosol, sodium bentonite, sodium polyacrylate; Described sanitas is the one in isothiazolinone, nitrogenous sulphur ring compound, s-triazine; Described anti-formaldehyde agent is 2-imidazolidone.
10. prepare a method for environment friendly wall face-mask material as claimed in claim 2, it is characterized in that, comprise the following steps:
Step one, negative ion powder is ground into the particle of 0.3 ~ 0.5um, then adds in the water of 2 ~ 5 times of weight, then add nano-TiO
2powder, soak 1 ~ 3h after stirring 30 ~ 60min, then under microwave frequency 2450MHz, power 300-400W, process 5-10min, then filter, filter cake is dried at 60-70 DEG C, is ground into the powder that granularity is less than 0.5um;
Step 2, silver-ion formulations is added in the water of 1 ~ 3 times of weight, then add inorganic coating agent, stir 1 ~ 3 hour, filter, with distilled water flushing to neutral, shift as in reactor, through 180-200 DEG C of steam treatment 1 ~ 3 hour, take out, dry, obtain antibacterial material;
Step 3, powder putty powder, step one obtained, step 2 obtain antibacterial material and add in ball mill, be milled to granularity and be less than 0.5 μm, then the material after ball milling is added in mixing machine, and add flow agent, defoamer, thickening material, antisettling agent, sanitas, to be warming up to 70-80 DEG C after the speed of 3000 ~ 5000r/min mixing 5-10min, add film coalescence aid again, continue mixing 10-15min, cooling down adds anti-formaldehyde agent and dispersion agent after 30-40 DEG C subsequently, continue mixing 5-10min, obtain mixture;
Step 4, mixture joined in spray-drier dry, pulverize, namely obtain body of wall face-mask material.
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| CN107418267A (en) * | 2017-08-01 | 2017-12-01 | 福建皓尔宝新材料科技有限公司 | A kind of inorganic powder exterior coating |
| CN110922800A (en) * | 2019-12-10 | 2020-03-27 | 田明亮 | Inorganic coating with dual functions of flame retardance and aldehyde removal and manufacturing method thereof |
| CN111320888A (en) * | 2020-03-25 | 2020-06-23 | 广东长鑫环保科技有限公司 | Method for preparing anion paint with virus and bacteria removing function |
| CN112239589A (en) * | 2020-10-16 | 2021-01-19 | 安徽省长荣新材料科技有限公司 | Transparent PET (polyethylene terephthalate) film capable of catalytically degrading VOC (volatile organic compounds) and preparation method thereof |
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|---|---|
| CN105504901B (en) | 2017-12-19 |
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