CN107418267A - A kind of inorganic powder exterior coating - Google Patents
A kind of inorganic powder exterior coating Download PDFInfo
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- CN107418267A CN107418267A CN201710646102.4A CN201710646102A CN107418267A CN 107418267 A CN107418267 A CN 107418267A CN 201710646102 A CN201710646102 A CN 201710646102A CN 107418267 A CN107418267 A CN 107418267A
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
- C09D5/1662—Synthetic film-forming substance
- C09D5/1675—Polyorganosiloxane-containing compositions
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of inorganic powder exterior coating,Formaldehyde is dispelled using high-efficiency cold catalyst material,Benzene,Dimethylbenzene,Toluene,The pernicious gases such as TVOC,Generate water and carbon dioxide,Utilize the high intensity that haydite is husky,Water proofing property,Frost resistance,Increase the water proofing property of coating,Frost resistance,Rub resistance,Utilize sodium silicate,Bentonite and organic siliconresin provide cohesive force to coating,Utilize the organic siliconresin smeared outside coating,Improve the stain resistance of coating,The temperature-change resistance of coating is improved using organic siliconresin,Bending resistance,Utilize the powerful adhesive force of organic siliconresin,Improve the stripper-resistance of coating,Utilize the inoxidizability of dibutyl hydroxy toluene,Improve the resistance to ag(e)ing of coating,Discoloration-resistant and capability of resistance to radiation,The present invention has pernicious gas ability in adsorption cleaning air,And there is water proofing property,Stain resistance,Temperature-change resistance,Resistance to ag(e)ing,Stripper-resistance,Discoloration-resistant and capability of resistance to radiation,Odorlessness and environmental protection.
Description
Technical field
The present invention relates to a kind of inorganic coating, specifically a kind of inorganic powder exterior coating.
Background technology
Inorganic powder coating (English:Inorganicpowderpaint it is) that a kind of plus water is used, easily scrapes and criticize, saving of labor saves
Material, newest environmental protection coating material, is using polymeric material as main additive, is equipped with high-quality mineral aggregate, filler and natural ore deposit
Thing is refined, and has function, the inorganic powder coating such as ventilative, durable, waterproof, green extensive in developed country
The inner, external wall for being applied to building instead of coating and ceramic tile is decorated, and coating layer thickness is and common typically between 1.5-2.5 millimeters
Emulsion paint lacquer painting thickness is only 0.1 millimeter, therefore can obtain fabulous texture and three-dimensional decorative effect, and its waterproof effect is good, is inhaled
Photosensitiveness is good, beautiful, ecological, environmental protective bright in colour;But the inorganic powder exterior coating used on the market at present purifies without air adsorption
Effect, and stain resistance, temperature-change resistance, resistance to ag(e)ing, stripper-resistance, discoloration-resistant and capability of resistance to radiation are poor.
Bibliography:Inorganic dry powder painting.
The content of the invention
It is an object of the invention to provide a kind of inorganic powder exterior coating, is asked with solve to propose in above-mentioned background technology
Topic.
To achieve the above object, the present invention provides following technical scheme:
A kind of inorganic powder exterior coating, the component of its raw material by weight are:Calcium chloride 10-20 parts, potassium silicate 30-35
Part, calcium carbonate 15-25 parts, bentonite 3-7 parts, wollastonite in powder 25-35 parts, haydite sand 10-15 parts, nanometer anion powder 5-15
Part, sodium silicate 25-35 parts, dibutyl hydroxy toluene 3-5 parts, organic siliconresin 5-8 parts, high-specific surface area inorganic active material
25-35 parts.
A kind of inorganic powder exterior coating, the component of its raw material by weight are:Calcium chloride 10,33 parts of potassium silicate, carbonic acid
20 parts of calcium, 5 parts of bentonite, 30 parts of wollastonite in powder, haydite are husky 13 parts, 10 parts of nanometer anion powder, 30 parts of sodium silicate, dibutyl hydroxyl
3 parts of base toluene, 5 parts of organic siliconresin, 30 parts of high-specific surface area inorganic active material.
A kind of preparation method of inorganic powder exterior coating, it is comprised the following steps that:
A, organic siliconresin is prepared:Phenyl trichlorosilane and dichloromethyl phenylsilane are mixed to form mixture, then
Organic solvent toluene is added into mixture makes its hydrolysis, and the acid removed in hydrolysate is then washed with water, finally to hydrolysis
Product carries out polycondensation and forms the organic siliconresin of highly cross-linked dimensional network structure, methyl and phenyl in the organic siliconresin
Ratio be 1:3;
B, high-specific surface area inorganic active Carbon Materials are placed on immersion 10-20 minutes in active liquid, then carry out microwave
High-efficiency cold catalyst material is obtained after processing, high-efficiency cold catalyst material is put into pulverizer and crushed;
C, calcium chloride, potassium silicate, calcium carbonate, bentonite, wollastonite in powder, haydite sand, nanometer anion powder, sodium silicate and
High-efficiency cold catalyst material powder is put into pressurized high speed rotary impact in grinding powder paint machine, and mixing, scattered, stranding occur for raw material
Rub, roll range of motion, then dibutyl hydroxy toluene is added to be put into mixer and stirred;
D, obtained electrodeless powdery paints in step C is put into dryer and dried;
A kind of inorganic powder exterior coating, its application method are:Inorganic powder coating and water are put into inorganic powder together
Coating special electric puddler stirs, and stirs 4-6 minutes for the first time, then stands 10-15 minutes, stirs 4-6 minutes for the second time,
Then 10-15 minutes are stood, third time stirs 4-6 minutes, 5-8 minutes is stood, when stirring in liquid condition
Smear, after the completion of smearing, smear one layer of organic siliconresin again after coating is dry and hard.
As the further scheme of the present invention:The fineness of grind of each raw material of inorganic powder exterior coating is in the step B
2-5 microns.
As the further scheme of the present invention:Drying time is 50-60 minutes in the step C.
As the further scheme of the present invention:Drying temperature is 80-90 degrees Celsius in the step C.
As the further scheme of the present invention:Mixing time in the step B is 35-45 minutes.
As the further scheme of the present invention:The ratio of inorganic powder coating and water is 1 in the application method:2.
As further scheme of the invention:Stirred in three times in the application method.
Compared with prior art, the beneficial effects of the invention are as follows:The present invention is produced using nanometer anion powder to be had to human body
The anion of benefit, the pernicious gases such as formaldehyde, benzene, dimethylbenzene, toluene, TVOC are dispelled using high-efficiency cold catalyst material, generate water
And carbon dioxide, using the husky high intensity of haydite, water proofing property, frost resistance, the water proofing property for increasing coating, frost resistance, rub resistance,
Cohesive force is provided to coating using sodium silicate, bentonite and organic siliconresin, using the organic siliconresin smeared outside coating, is carried
The high stain resistance of coating, temperature-change resistance, the bending resistance of coating are improved using organic siliconresin, strong using organic siliconresin
Big adhesive force, the stripper-resistance of coating is improved, using the inoxidizability of dibutyl hydroxy toluene, improve the resistance to old of coating
The property changed, discoloration-resistant and capability of resistance to radiation, the present invention have a pernicious gas ability in adsorption cleaning air, and with water proofing property,
Stain resistance, temperature-change resistance, resistance to ag(e)ing, stripper-resistance, discoloration-resistant and capability of resistance to radiation, odorlessness and environmental protection.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based in the present invention
Embodiment, the every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of inorganic powder exterior coating, the raw material of inorganic powder exterior coating are the component of following parts by weight:Calcium chloride
10th, 30 parts of potassium silicate, 15 parts of calcium carbonate, 3 parts of bentonite, 25 parts of wollastonite in powder, 10 parts of haydite sand, 5 parts of nanometer anion powder, two
3 parts of butylated hydroxytoluene, 5 parts of organic siliconresin, 25 parts of sodium silicate, 20 parts of high-specific surface area inorganic active material;
A kind of preparation method of inorganic powder exterior coating, it is comprised the following steps that:
A, organic siliconresin is prepared:Phenyl trichlorosilane and dichloromethyl phenylsilane are mixed to form mixture, then
Organic solvent toluene is added into mixture makes its hydrolysis, and the acid removed in hydrolysate is then washed with water, finally to hydrolysis
Product carries out polycondensation and forms the organic siliconresin of highly cross-linked dimensional network structure, methyl and phenyl in the organic siliconresin
Ratio be 1:3;
B, high-specific surface area inorganic active Carbon Materials are placed in active liquid and soaked 10 minutes, then carry out microwave treatment
After obtain high-efficiency cold catalyst material, high-efficiency cold catalyst material is put into pulverizer and crushed;
C, potassium silicate, calcium carbonate, bentonite, wollastonite in powder, haydite sand, nanometer anion powder, sodium silicate and efficiently it is cold
Catalyst material powder is put into pressurized high speed rotary impact in grinding powder paint machine, and raw material is by mixing, scattered, rubbing, rolling
Move to fineness and reach 2 microns, then dibutyl hydroxy toluene is added to be put into mixer and stirred 35 minutes;
D, obtained electrodeless powdery paints in step C is put into dryer and dried, drying time is 50 minutes, dries temperature
Spend for 80 degrees Celsius;
A kind of inorganic powder exterior coating, its application method are:Inorganic powder coating and water are put into inorganic powder together
Coating special electric puddler stirs, and the ratio of inorganic powder coating and water is 1:2, stirring in three times, stirs 4 points for the first time
Clock, 10 minutes then are stood, second of stirring 4 minutes, then stand 10 minutes, third time stirring 4 minutes, stood 5 minutes, fill
Dividing to stir can smear in during liquid condition, after the completion of smearing, smear one layer of organic siliconresin again after coating is dry and hard.
Embodiment 2
A kind of inorganic powder exterior coating, the component of its raw material by weight are:Calcium chloride 15,33 parts of potassium silicate, carbonic acid
20 parts of calcium, 5 parts of bentonite, 30 parts of wollastonite in powder, haydite are husky 13 parts, 10 parts of nanometer anion powder, 30 parts of sodium silicate, dibutyl hydroxyl
4 parts of base toluene, 7 parts of organic siliconresin, 30 parts of high-specific surface area inorganic active material;
A kind of preparation method of inorganic powder exterior coating, it is comprised the following steps that:
A, organic siliconresin is prepared:Phenyl trichlorosilane and dichloromethyl phenylsilane are mixed to form mixture, then
Organic solvent toluene is added into mixture makes its hydrolysis, and the acid removed in hydrolysate is then washed with water, finally to hydrolysis
Product carries out polycondensation and forms the organic siliconresin of highly cross-linked dimensional network structure, methyl and phenyl in the organic siliconresin
Ratio be 1:3;
B, high-specific surface area inorganic active Carbon Materials are placed in active liquid and soaked 15 minutes, then carry out microwave treatment
After obtain high-efficiency cold catalyst material, high-efficiency cold catalyst material is put into pulverizer and crushed;
C, potassium silicate, calcium carbonate, bentonite, wollastonite in powder, haydite sand, nanometer anion powder, sodium silicate and efficiently it is cold
Catalyst material powder is put into pressurized high speed rotary impact in grinding powder paint machine, and raw material is by mixing, scattered, rubbing, rolling
Move to fineness and reach 3.5 microns, then dibutyl hydroxy toluene is added to be put into mixer and stirred 40 minutes;
D, obtained electrodeless powdery paints in step C is put into dryer and dried, drying time is 55 minutes, dries temperature
Spend for 85 degrees Celsius;
A kind of inorganic powder exterior coating, its application method are:Inorganic powder coating and water are put into inorganic powder together
Coating special electric puddler stirs, and the ratio of inorganic powder coating and water is 1:2, stirring in three times, stirs 5 points for the first time
Clock, 13 minutes then are stood, second of stirring 5 minutes, then stand 13 minutes, third time stirring 5 minutes, stood 7 minutes, fill
Dividing to stir can smear in during liquid condition, after the completion of smearing, smear one layer of organic siliconresin again after coating is dry and hard.
Embodiment 3
A kind of inorganic powder exterior coating, the component of its raw material by weight are:Calcium chloride 20,35 parts of potassium silicate, carbonic acid
25 parts of calcium, 7 parts of bentonite, 35 parts of wollastonite in powder, haydite are husky 15 parts, 15 parts of nanometer anion powder, 35 parts of sodium silicate, dibutyl hydroxyl
5 parts of base toluene, 8 parts of organic siliconresin, 35 parts of high-specific surface area inorganic active material;
A kind of preparation method of inorganic powder exterior coating, it is comprised the following steps that:
A, organic siliconresin is prepared:Phenyl trichlorosilane and dichloromethyl phenylsilane are mixed to form mixture, then
Organic solvent toluene is added into mixture makes its hydrolysis, and the acid removed in hydrolysate is then washed with water, finally to hydrolysis
Product carries out polycondensation and forms the organic siliconresin of highly cross-linked dimensional network structure, methyl and phenyl in the organic siliconresin
Ratio be 1:3;
B, high-specific surface area inorganic active Carbon Materials are placed in active liquid and soaked 20 minutes, then carry out microwave treatment
After obtain high-efficiency cold catalyst material, high-efficiency cold catalyst material is put into pulverizer and crushed;
C, potassium silicate, calcium carbonate, bentonite, wollastonite in powder, haydite sand, nanometer anion powder, sodium silicate and efficiently it is cold
Catalyst material powder is put into pressurized high speed rotary impact in grinding powder paint machine, and raw material is by mixing, scattered, rubbing, rolling
Move to fineness and reach 5 microns, then dibutyl hydroxy toluene is added to be put into mixer and stirred 45 minutes;
D, obtained electrodeless powdery paints in step C is put into dryer and dried, drying time is 60 minutes, dries temperature
Spend for 90 degrees Celsius;
A kind of inorganic powder exterior coating, its application method are:Inorganic powder coating and water are put into inorganic powder together
Coating special electric puddler stirs, and the ratio of inorganic powder coating and water is 1:2, stirring in three times, stirs 6 points for the first time
Clock, 15 minutes then are stood, second of stirring 6 minutes, then stand 15 minutes, third time stirring 6 minutes, stood 8 minutes, fill
Dividing to stir can smear in during liquid condition, after the completion of smearing, smear one layer of organic siliconresin again after coating is dry and hard.
The present invention operation principle be:The present invention produces the anion beneficial to human body, profit using nanometer anion powder
The pernicious gases such as formaldehyde, benzene, dimethylbenzene, toluene, TVOC are dispelled with high-efficiency cold catalyst material, generate water and carbon dioxide, are utilized
The husky high intensity of haydite, water proofing property, frost resistance, the water proofing property for increasing coating, frost resistance, rub resistance, utilize sodium silicate, swelling
Soil and organic siliconresin provide cohesive force to coating, using the organic siliconresin smeared outside coating, improve the resistance to of coating and are stained with
Dirt, temperature-change resistance, the bending resistance of coating are improved using organic siliconresin, using the powerful adhesive force of organic siliconresin, is carried
The high stripper-resistance of coating, using the inoxidizability of dibutyl hydroxy toluene, improve resistance to ag(e)ing, the discoloration-resistant of coating
And capability of resistance to radiation, the present invention have pernicious gas ability in adsorption cleaning air, and with water proofing property, stain resistance, heatproof
Denaturation, resistance to ag(e)ing, stripper-resistance, discoloration-resistant and capability of resistance to radiation, odorlessness and environmental protection.
It is obvious to a person skilled in the art that the invention is not restricted to the details of above-mentioned one exemplary embodiment, Er Qie
In the case of without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, embodiment all should be regarded as exemplary, and be nonrestrictive, the scope of the present invention is by appended power
Profit requires rather than described above limits, it is intended that all in the implication and scope of the equivalency of claim by falling
Change is included in the present invention.
Moreover, it will be appreciated that although the present specification is described in terms of embodiments, not each embodiment is only wrapped
Containing an independent technical scheme, this narrating mode of specification is only that those skilled in the art should for clarity
Using specification as an entirety, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
It is appreciated that other embodiment.
Claims (10)
1. a kind of inorganic powder exterior coating, it is characterised in that the component of its raw material by weight is:Calcium chloride 10-20 parts, silicon
Sour potassium 30-35 parts, calcium carbonate 15-25 parts, bentonite 3-7 parts, wollastonite in powder 25-35 parts, haydite sand 10-15 parts, nanometer bear from
Sub- powder 5-15 parts, sodium silicate 25-35 parts, dibutyl hydroxy toluene 3-5 parts, organic siliconresin 5-8 parts, the inorganic work of high-specific surface area
Property material 25-35 parts.
2. a kind of inorganic powder exterior coating, it is characterised in that the component of its raw material by weight is:Calcium chloride 10, potassium silicate
33 parts, 20 parts of calcium carbonate, 5 parts of bentonite, 30 parts of wollastonite in powder, haydite be husky 13 parts, 10 parts of nanometer anion powder, sodium silicate 30
Part, 3 parts of dibutyl hydroxy toluene, 5 parts of organic siliconresin, 30 parts of high-specific surface area inorganic active material.
A kind of 3. preparation method of inorganic powder exterior coating as described in claim 1-2, it is characterised in that:Its specific steps
It is as follows:
A, organic siliconresin is prepared:Phenyl trichlorosilane and dichloromethyl phenylsilane are mixed to form mixture, then to mixed
Organic solvent toluene is added in compound makes its hydrolysis, the acid removed in hydrolysate is then washed with water, finally to hydrolysate
Carry out polycondensation and form the organic siliconresin of highly cross-linked dimensional network structure, the ratio of methyl and phenyl in the organic siliconresin
Example is 1:3;
B, high-specific surface area inorganic active Carbon Materials are placed on immersion 10-20 minutes in active liquid, then carry out microwave treatment
After obtain high-efficiency cold catalyst material, high-efficiency cold catalyst material is put into pulverizer and crushed;
C, calcium chloride, potassium silicate, calcium carbonate, bentonite, wollastonite in powder, haydite sand, nanometer anion powder, sodium silicate and efficiently
Cold catalyst material powder is put into pressurized high speed rotary impact in grinding powder paint machine, raw material occur mixing, scattered, rubbing,
Range of motion is rolled, then dibutyl hydroxy toluene is added to be put into mixer and stirred;
D, obtained electrodeless powdery paints in step C is put into dryer and dried.
4. a kind of inorganic powder exterior coating according to claim 1-2, it is characterised in that its application method is, nothing
Machine powdery paints and water are put into the stirring of inorganic powder coating special electric puddler together, stir 4-6 minutes, Ran Houjing for the first time
10-15 minutes are put, second of stirring 4-6 minute, then stand 10-15 minutes, third time stirs 4-6 minutes, stands 5-8 and divides
Clock, stirring can smear in during liquid condition, after the completion of smearing, smear one layer of organosilicon tree again after coating is dry and hard
Fat.
A kind of 5. preparation method of inorganic powder exterior coating according to claim 4, it is characterised in that:The step B
The fineness of grind of middle each raw material of inorganic powder exterior coating is 2-5 microns.
A kind of 6. preparation method of inorganic powder exterior coating according to claim 4, it is characterised in that:The step B
Middle mixing time is 35-45.
A kind of 7. preparation method of inorganic powder exterior coating according to claim 4, it is characterised in that:The step C
Middle drying time is 50-60 minutes.
A kind of 8. preparation method of inorganic powder exterior coating according to claim 4, it is characterised in that:The step C
Middle drying temperature is 80-90 degrees Celsius.
9. a kind of inorganic powder exterior coating according to claim 5, it is characterised in that the inorganic powder coating and water
Ratio be 1:2.
10. a kind of inorganic powder exterior coating according to claim 5, it is characterised in that the stirring is in three times.
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2017
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CN103086681A (en) * | 2013-03-08 | 2013-05-08 | 河南工业大学 | Visible-light nano titanium dioxide photocatalysis sterilization purification solid powder coating |
CN103709799A (en) * | 2013-12-13 | 2014-04-09 | 广州市维多纳环保科技有限公司 | Inorganic multifunctional paint taking potassium silicate as film-forming substance, and preparation method thereof |
CN105504901A (en) * | 2016-01-29 | 2016-04-20 | 广元大汉科技有限责任公司 | Environmental-friendly wall mask material and preparation method thereof |
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Application publication date: 20171201 |