CN105504439B - 一种用于3d打印的低密度陶瓷材料及其制备方法 - Google Patents
一种用于3d打印的低密度陶瓷材料及其制备方法 Download PDFInfo
- Publication number
- CN105504439B CN105504439B CN201510984513.5A CN201510984513A CN105504439B CN 105504439 B CN105504439 B CN 105504439B CN 201510984513 A CN201510984513 A CN 201510984513A CN 105504439 B CN105504439 B CN 105504439B
- Authority
- CN
- China
- Prior art keywords
- parts
- weight
- printing
- calcium carbonate
- low
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000010146 3D printing Methods 0.000 title claims abstract description 56
- 229910010293 ceramic material Inorganic materials 0.000 title claims abstract description 27
- 238000002360 preparation method Methods 0.000 title abstract description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 72
- 239000000463 material Substances 0.000 claims abstract description 45
- 239000000843 powder Substances 0.000 claims abstract description 41
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 36
- 241000219000 Populus Species 0.000 claims abstract description 33
- 239000004698 Polyethylene Substances 0.000 claims abstract description 26
- 229920000573 polyethylene Polymers 0.000 claims abstract description 26
- -1 polyethylene Polymers 0.000 claims abstract description 25
- 238000000034 method Methods 0.000 claims abstract description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000010439 graphite Substances 0.000 claims abstract description 16
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 16
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 11
- 150000004645 aluminates Chemical class 0.000 claims abstract description 11
- 229910000077 silane Inorganic materials 0.000 claims abstract description 11
- 238000002156 mixing Methods 0.000 claims description 21
- 239000002131 composite material Substances 0.000 claims description 15
- 238000012986 modification Methods 0.000 claims description 11
- 230000004048 modification Effects 0.000 claims description 11
- 229920001684 low density polyethylene Polymers 0.000 claims description 10
- 239000004702 low-density polyethylene Substances 0.000 claims description 10
- 239000000919 ceramic Substances 0.000 claims description 9
- 238000005453 pelletization Methods 0.000 claims description 7
- 229920000092 linear low density polyethylene Polymers 0.000 claims description 6
- 239000004707 linear low-density polyethylene Substances 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 claims 1
- FYHXNYLLNIKZMR-UHFFFAOYSA-N calcium;carbonic acid Chemical compound [Ca].OC(O)=O FYHXNYLLNIKZMR-UHFFFAOYSA-N 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 11
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 229920001903 high density polyethylene Polymers 0.000 description 7
- 239000004700 high-density polyethylene Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 238000011161 development Methods 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000006057 Non-nutritive feed additive Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000004927 fusion Effects 0.000 description 2
- 238000013035 low temperature curing Methods 0.000 description 2
- 239000012764 mineral filler Substances 0.000 description 2
- 230000001681 protective effect Effects 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000012779 reinforcing material Substances 0.000 description 2
- 239000013049 sediment Substances 0.000 description 2
- 238000007493 shaping process Methods 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004594 Masterbatch (MB) Substances 0.000 description 1
- 238000012356 Product development Methods 0.000 description 1
- 239000006087 Silane Coupling Agent Substances 0.000 description 1
- 229920001587 Wood-plastic composite Polymers 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011812 mixed powder Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002114 nanocomposite Substances 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 230000001737 promoting effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 229920001169 thermoplastic Polymers 0.000 description 1
- 239000004416 thermosoftening plastic Substances 0.000 description 1
- 239000012745 toughening agent Substances 0.000 description 1
- 238000005491 wire drawing Methods 0.000 description 1
- 239000011155 wood-plastic composite Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
Abstract
Description
指标 | 实施例1 | 实施例2 | 实施例3 | 实施例4 | 实施例5 |
密度 | 0.84 | 0.91 | 0.88 | 0.89 | 0.90 |
拉伸强度/MPa | 31 | 34 | 32 | 32 | 33 |
断裂伸长率/% | 3 | 5 | 4 | 3 | 4 |
弯曲强度/MPa | 27 | 32 | 29 | 30 | 31 |
冲击强度/MPa | 17 | 15 | 19 | 16 | 15 |
硬度 | 61 | 59 | 63 | 58 | 60 |
Claims (1)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510984513.5A CN105504439B (zh) | 2015-12-25 | 2015-12-25 | 一种用于3d打印的低密度陶瓷材料及其制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510984513.5A CN105504439B (zh) | 2015-12-25 | 2015-12-25 | 一种用于3d打印的低密度陶瓷材料及其制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN105504439A CN105504439A (zh) | 2016-04-20 |
CN105504439B true CN105504439B (zh) | 2017-11-14 |
Family
ID=55712778
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510984513.5A Active CN105504439B (zh) | 2015-12-25 | 2015-12-25 | 一种用于3d打印的低密度陶瓷材料及其制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105504439B (zh) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105965665A (zh) * | 2016-05-10 | 2016-09-28 | 江苏道勤新材料科技有限公司 | 一种软质陶瓷3d打印材料 |
KR20190086462A (ko) * | 2016-11-17 | 2019-07-22 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 중합체 및 중공 세라믹 미소구체를 포함하는 조성물 및 3차원 물품의 제조 방법 |
CN108102192A (zh) * | 2017-12-23 | 2018-06-01 | 季梅 | 一种耐腐蚀陶瓷材料及其制备方法和应用 |
CN108384224A (zh) * | 2018-01-24 | 2018-08-10 | 合肥智龙机械设计有限公司 | 一种综合性能好的3d打印陶瓷材料及其制备方法 |
CN114907119A (zh) * | 2022-03-15 | 2022-08-16 | 厉二军 | 一种用于3d打印的陶瓷材料及其制备方法 |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103937278B (zh) * | 2014-05-13 | 2016-09-07 | 江苏锦禾高新科技股份有限公司 | 一种3d打印木塑复合材料的制备方法 |
CN104861266A (zh) * | 2015-05-08 | 2015-08-26 | 浙江工业大学 | 一种高填充聚乙烯共混改性物及其制备方法和应用 |
-
2015
- 2015-12-25 CN CN201510984513.5A patent/CN105504439B/zh active Active
Also Published As
Publication number | Publication date |
---|---|
CN105504439A (zh) | 2016-04-20 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN105504439B (zh) | 一种用于3d打印的低密度陶瓷材料及其制备方法 | |
CN101701079B (zh) | 镁盐晶须增强烟用聚乙烯地膜母料的制备方法 | |
CN105504471B (zh) | 一种用于3d打印的环保抗菌材料及其制备方法 | |
CN104072935A (zh) | 一种用于3d打印的abs材料及其制造工艺 | |
CN102911454B (zh) | 一种高抗冲pvc/abs/cpe管材及其制备方法 | |
CN101638493A (zh) | 一种长玻璃纤维增强回收聚丙烯材料及其制备方法 | |
CN101698728B (zh) | 光亮型可注塑木塑复合材料及制备方法 | |
CN103937093A (zh) | 一种长玻璃纤维增强聚丙烯复合材料及其制备方法 | |
CN102585324A (zh) | 一种改善黄色指数和光泽度的聚乙烯组合物及其制造方法 | |
CN102964815B (zh) | 一种微观分散均匀的高性能纳米增强尼龙组合物及其制备方法 | |
CN107216517A (zh) | 一种超高分子量聚乙烯3d打印耗材的制备方法 | |
CN103450532B (zh) | 一种聚乙烯pe纳米级增强改性颗粒的制备方法 | |
CN104356585A (zh) | 高性能连续碳纤维增强abs复合材料及其制备方法 | |
CN106280429A (zh) | 一种高性能高挤出速率玻璃纤维增强尼龙66组合物 | |
CN104448569A (zh) | 仿大理石纹的免喷涂聚丙烯复合材料及制备方法与应用 | |
CN102702655A (zh) | 一种聚乙烯醇/高直链淀粉生物降解复合材料及其熔融制备方法 | |
CN104292640A (zh) | 高浸润性连续碳纤维增强聚丙烯复合材料及其制备方法 | |
CN104987681A (zh) | 一种无机填料协同增韧聚乳酸混杂材料及其制备方法 | |
CN102626963B (zh) | 塑料改性用纳米级功能母粒的制备方法 | |
CN103360683A (zh) | 改性聚丙烯复合体塑料填料及其制备方法 | |
CN103613842B (zh) | 一种高耐水木塑复合材料 | |
CN103408841B (zh) | 一种聚丙烯复合材料及其制备方法 | |
CN105504580B (zh) | 一种用于3d打印的隔声材料及其制备方法 | |
CN104788783B (zh) | 一种薄壁高强度内镶式滴灌带及其高速生产方法 | |
CN108003582B (zh) | 一种聚乳酸木塑复合线材及其制备方法和应用 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20170927 Address after: 318050 Zhejiang Province, Luqiao District, the new town of the former village of the first seven Wu District No. 3, No. 24, No. Applicant after: Luo Xianhua Address before: Qingyang District of Chengdu City, Sichuan province 610091 Dragon Industrial Port East Road 4 Applicant before: Chengdu Xinkeli Chemical Sci-Tech Co., Ltd. |
|
TA01 | Transfer of patent application right | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190426 Address after: No.1 Building, Dongguyuan, 22 Erwei Road, Dongli Economic Development Zone, Tianjin 300300 Patentee after: AVIC armor Technology Ltd Address before: 318050 24 new towns in the former seven villages in Xinqiao Town, Luqiao District, Taizhou, Zhejiang, China, 3 Patentee before: Luo Xianhua |
|
TR01 | Transfer of patent right |