CN105483904A - Dyeing and finishing method for tencel/bamboo pulp fiber blended fabric - Google Patents
Dyeing and finishing method for tencel/bamboo pulp fiber blended fabric Download PDFInfo
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- CN105483904A CN105483904A CN201510844759.2A CN201510844759A CN105483904A CN 105483904 A CN105483904 A CN 105483904A CN 201510844759 A CN201510844759 A CN 201510844759A CN 105483904 A CN105483904 A CN 105483904A
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- D—TEXTILES; PAPER
- D03—WEAVING
- D03D—WOVEN FABRICS; METHODS OF WEAVING; LOOMS
- D03D15/00—Woven fabrics characterised by the material, structure or properties of the fibres, filaments, yarns, threads or other warp or weft elements used
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B13/00—Treatment of textile materials with liquids, gases or vapours with aid of vibration
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B3/00—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating
- D06B3/10—Passing of textile materials through liquids, gases or vapours to effect treatment, e.g. washing, dyeing, bleaching, sizing, impregnating of fabrics
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
- D06B7/00—Mercerising, e.g. lustring by mercerising
- D06B7/08—Mercerising, e.g. lustring by mercerising of fabrics of indefinite length
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C15/00—Calendering, pressing, ironing, glossing or glazing textile fabrics
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C19/00—Breaking or softening of fabrics
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C9/00—Singeing
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Treatment Of Fiber Materials (AREA)
Abstract
The invention provides a dyeing and finishing method for tencel/bamboo pulp fiber blended fabric. Gray fabric is sequentially subjected to singeing, enzyme rolling and cold piling, washing, cold piling, mercerizing, tentering and whitening, printing, ageing, washing, softening and shaping, calendaring and pre-shrinking, and then the tencel/bamboo pulp fiber blended fabric is obtained, wherein the caustic soda concentration in the mercerizing process ranges from 80 g/L to 90 g/L. The dyeing and finishing method is mainly used for dyeing and finishing the tencel/bamboo pulp fiber blended fabric, and warp and weft of the fabric are tencel/bamboo pulp fiber blended yarn. The shrinkage rate of the obtained tencel/bamboo pulp fiber blended fabric is within the range from +2% to -4%, and the fabric is soft in hand feeling, smooth in fabric cover and free of deformation.
Description
Technical field
The invention belongs to textile dyeing and finishing processing technique field, be specifically related to a kind of sky silk/bamboo pulp fibre blending shell-fabric dyeing and finishing processing method.
Background technology
It silk and viscose are all one of regenerated celulose fibre, however due to sky silk different with the processing method of viscose, cause the performance between fiber differ larger.Bamboo pulp viscose fiber is the one of viscose, is take bamboo pulp as raw material, is prepared from by the wet spinning technology of viscose.Therefore, bamboo pulp fiber not only has every key property of viscose, also has the performances such as the biocidal property of bamboo fibre.
Regenerated celulose fibre is viscose especially, its fiber is dry, wet breaking strength and degree of crystallinity lower, fracture elongation is larger.In dyeing and printing process process, have water and external force to fabric effect.The easy moisture absorption of hydroxyl polar group that regenerated celulose fibre is a large amount of, can in conjunction with a large amount of water; Simultaneously again due to the effect of water, fiber generation swelling, the diameter of fiber becomes large, and fabric shrinks.The degree of crystallinity of the regenerated celulose fibres such as it silk, model and viscose glue is all low many compared with the degree of crystallinity of the native cellulose fibres such as linen-cotton, therefore a large amount of hydrophilic groups is had in unformed area, the fabric be made up of these fibers is in dyeing and finishing process, once be immersed in the water, moisture expantion can be there is, cause the diameter of fiber to become large, then make the diameter of yarn thicker, finally cause the shrink of fabric.
The degree of crystallinity of regenerated celulose fibre is all low many compared with the degree of crystallinity of the native cellulose fibres such as linen-cotton, and therefore these regenerated celulose fibres can not adopt the technique of the native cellulose fibres such as linen-cotton to process.The regenerated celulose fibre of low-crystallinity is under the effect of alkali,-OH can enter the amorphous region of fiber easily, the hydrogen bond of macromolecular chain can by-OH to breaking, the surface of crystal region also can be etched by-OH simultaneously, the degree of crystallinity of fiber is caused to reduce further, namely cause, between fiber macromolecular chain, slippage more easily occurs, even fiber damages; Hydrophilic radical hydroxyl simultaneously contained by fiber can be more, make fabric washing shrinkage larger, powerfully reduce, and it is poorer that the dimensionally stable of fabric becomes.
Water is to fiber, and especially for regenerated celulose fibre, water is a kind of swelling agent.There is a large amount of hydrophilic radical hydroxyls in regenerated celulose fibre, and the degree of crystallinity of fiber is lower, and under the effect of water, anisotropic expansion can occur, namely radial and axial expansion can occur fiber, and especially cross-wise direction occurs acutely swelling.Because once the cross section of fiber expands (fiber radial direction is elongated), cause yarn thicker, yarn becomes large (namely the Qu Qubo of fabric becomes large) around the stroke on yarn vertical with it, and the total length of yarn is constant, then only have and make up the large required fibre length of its stroke change by the contraction of fabric, thus create shrinkage.Wet with under External Force Acting, fabric can by stretching in various degree, fabric is made to be in a unsure state, when fabric runs into water again, due to the imbibition of water, fiber can change from original pseudostationary state to a new stable state, and the washing shrinkage macroscopically showing as fabric is larger, the final serviceability affecting bed necessaries, original size diminishes.
Therefore, regenerated celulose fibre fabric goods, especially containing the fabric of viscose, the more difficult control of its washing shrinkage, fabric DIMENSIONAL STABILITY is poor.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art and provide a kind of sky silk/bamboo pulp fibre blending shell-fabric dyeing and finishing processing method, gained fabric washing shrinkage is low, good stability of the dimension.
A kind of sky silk/bamboo pulp fibre blending shell-fabric dyeing and finishing processing method, grey cloth is brightened through enzyme cold dome of singing, roll, wash water, cold dome, mercerising, tentering successively, stamp, evaporate, wash, softness sizing, calendering, preshrunk operation, to obtain final product; Wherein, in mercerizing process, concentration of caustic soda is 80-90g/L.
Further, caustic dip time 20-30s in described mercerizing process.
Further, in described cold dome operation, concentration of caustic soda is 10-15g/L, and hydrogen peroxide concentration is 12-15g/L, band liquid measure 70%-80%.
Further, it is 1-2g/L that described tentering brightens VBL concentration in operation, and amount of urea is 40-50g/L.
Further, in described calendering operation, pressure is 12-15kg, and the speed of a motor vehicle is 20-30m/min, and temperature is 90-100 DEG C.
Further, in described shrinking processes, the speed of a motor vehicle is 15-25m/min, and bearing roller pressure is 30-40kN, and bearing roller temperature is 120-135 DEG C.
The washing shrinkage of sky of the present invention silk/bamboo pulp fibre blending fabric is within+2% ~-4%, and fabric is soft.
Detailed description of the invention:
Below by detailed description of the invention, the present invention is described in further detail.But it will be understood to those of skill in the art that the following example only for illustration of the present invention, and should not be considered as limiting scope of the present invention.Unreceipted concrete technology or condition person in embodiment, according to the technology described by the document in this area or condition (such as with reference to " dyeing and finishing technology and principle " that Zhao Tao writes, China Textiles Press, 2009) or carry out according to product description.Agents useful for same or the unreceipted production firm person of instrument, being can by the conventional products of commercial acquisition.
Dyeing and finishing technology of the present invention is mainly used for sky silk/bamboo pulp fibre blending shell-fabric dyeing and finishing, this fabric be sky silk/bamboo pulp fibre blending yarn through weft yarn, its main step includes that the grey cloth carried out successively is singed, rolled enzyme cold dome, wash water, cold dome, mercerising, tentering brighten, stamp, evaporate, wash, soft sizing, calendering, preshrunk operation.
Regenerated celulose fibre is more responsive to soda bath, the degree of crystallinity of the degree of crystallinity of regenerated celulose fibre especially viscose is lower only has 30%, the degree of crystallinity about 50% of it silk, under the swelling of water, the cortex of fiber is opened, it is swelling that sodium ion and hydrated ion thereof enter the further swelling of fibrous inside, and hydroxide ion breaks the hydrogen bond between the large molecule of fiber further, thus macromolecular chain then slippage can occur under the effect of external force.If mercerising concentration of caustic soda is comparatively large, then have fiber especially viscose that violent swelling can occur is swelling, the hydrogen bond between the large molecule of final viscose can be opened completely, and viscose glue brute force can be badly damaged, and viscose " is dissolved "; Meanwhile, due to fabric parectasis, feel hardens viscous.When the caustic soda of high concentration is used as mercerising, the viscosity of soda bath is higher, and fabric is comparatively thick and heavy in addition, now easily causes surperficial mercerising, finally causes DIMENSIONAL STABILITY and washing shrinkage all poor.If concentration of caustic soda is too low, then not there is the effect of light mercerising.This is mainly because heavy fabric is under the speed of a motor vehicle faster, and the caustic dip time is comparatively large, and water, hydration sodium ion, hydroxide ion also have little time to penetrate into inside, the hydration sodium ion on surface and the water in hydroxide ion Ji Beihou road clean to washing away.Therefore, under certain caustic dip time and certain concentration of caustic soda, it is thicker to there is the swelling yarn that causes in fiber, relative Qu Qubo between warp thread and weft yarn uprises, and then the gap smaller between yarn and yarn, it is more tight that fabric becomes, and finally cannot shrink again, or the trend that chance water shrinks again becomes less.In conjunction with washing shrinkage (+2% ~-4%) and the feel requirement of fabric, mercerising concentration of caustic soda is adopted to be 80-90g/L, caustic dip time 20-30s.
Starch size on fabric, after amylase destarch, can be resolved into micromolecular polysaccharide and be washed away by fabric.But finish residual on fabric, not by impurity such as the polysaccharide of complete eccysis, printing quality and the feel of fabric can be affected.Therefore, by adding a certain amount of caustic soda, emulsification, saponification are carried out to finish, and make it be distributed in water.If amount of caustic soda is excessive, the time of in addition banking up longer (factory is 20-24h the general normal temperature time of banking up), the degree of fiber swelling is comparatively large, increases the slippage between fiber macromolecular chain, and then cause the damage of fabric brute force, the increase of washing shrinkage; Meanwhile, the membership that adds of too much caustic soda makes decomposing hydrogen dioxide solution violent, easily causes decomposition and increase fabric producing broken hole probability.If amount of caustic soda is too small, then cannot by finish emulsification, saponification, Ze Duihou road stamp has larger impact.Therefore, cold dome operation adopts concentration of caustic soda to be 10-15g/L, and hydrogen peroxide concentration is 12-15g/L, band liquid measure 70%-80%.
Because viscose and tencel fiber all have cortex construction, urea has higher hygroscopicity and polarity, the cortex of fiber can be opened when stamp, is conducive to contaminating the upper dye of material on fiber and set.Brightening VBL concentration in operation at tentering is 1-2g/L, and amount of urea is 40-50g/L.
Embodiment 1
Specification: 106.5 '/(sky silk LF/ bamboo pulp fiber 50/50) 21s/2* (sky silk LF/ bamboo pulp fiber 50/50) 21s/2/80*45,3/1 left twill.
By above-mentioned fabric successively through following steps:
1, singe: gas singeing, speed of a motor vehicle 110m/min, two is just two anti-, and thoroughly burn, roll enzyme fire extinguishing, bank up 6-7 hour, and amylase consumption is 15g/L.
2, wash water: oxalic acid 5g/L, 5 lattice hot water wash, dry, cloth bed cropping.
3, cold dome: 10g/L, hydrogen peroxide concentration is 12g/L, and band liquid measure 80%, bank up time 24h.
4, mercerising: carry out mercerising on straight roller mercerizing range, wherein 30, Leng Jian district caustic dip roller, 18, thermokalite district caustic dip roller, 5 lattice hot water wash, caustic soda 80g/L, caustic dip time 30s.
5, tentering brightens: on 25 meters of long stenters, carry out tentering arrangement.VBL concentration is 1g/L, and amount of urea is 40g/L.
6, stamp evaporates washing for known technology, repeats no more.
7, soft sizing: Monforts setting machine, beats maximum overfeeding, speed of a motor vehicle 30m/min, temperature 170 DEG C.
8, calendering: three rolling ray machines, pressure 12kg, speed of a motor vehicle 20m/min, temperature 100 DEG C.
9, preshrunk: Monforts preshrinking machine, speed of a motor vehicle 15m/min, bearing roller pressure is 30kN, and bearing roller temperature is 135 DEG C.
Embodiment 2
Specification: 106.5 '/(sky silk LF/ bamboo pulp fiber 50/50) 21s/2* (sky silk LF/ bamboo pulp fiber 50/50) 21s/2/78*48,3/1 twill left to right.
By above-mentioned fabric successively through following steps:
1, singe: gas singeing, speed of a motor vehicle 110m/min, two is just two anti-, and thoroughly burn, roll enzyme fire extinguishing, bank up 6-7 hour, and amylase consumption is 15g/L.
2, wash water: oxalic acid 5g/L, 5 lattice hot water wash, dry, cloth bed cropping.
3, cold dome: 15g/L, hydrogen peroxide concentration is 15g/L, and band liquid measure 70%, bank up time 20h.
4, mercerising: carry out mercerising on straight roller mercerizing range, wherein 30, Leng Jian district caustic dip roller, 18, thermokalite district caustic dip roller, 5 lattice hot water wash, caustic soda 90g/L, caustic dip time 20s.
5, tentering brightens: on Monforts setting machine, carry out tentering arrangement.VBL concentration is 2g/L, and amount of urea is 50g/L.
6, stamp evaporates washing for known technology, repeats no more.
7, soft sizing: Monforts setting machine, beats maximum overfeeding, speed of a motor vehicle 30m/min, temperature 170 DEG C.
8, calendering: three rolling ray machines, pressure 15kg, speed of a motor vehicle 30m/min, temperature 90 DEG C.
9, preshrunk: Monforts preshrinking machine, speed of a motor vehicle 25m/min, bearing roller pressure is 40kN, and bearing roller temperature is 120 DEG C.
Embodiment 3
Specification: 106.5 '/(sky silk LF/ bamboo pulp fiber 50/50) 21s/2* (sky silk LF/ bamboo pulp fiber 50/50) 21s/2/76*50,3/1 left twill.
By above-mentioned fabric successively through following steps:
1, singe: gas singeing, speed of a motor vehicle 110m/min, two is just two anti-, and thoroughly burn, roll enzyme fire extinguishing, bank up 6-7 hour, and amylase consumption is 15g/L.
2, wash water: oxalic acid 5g/L, 5 lattice hot water wash, dry, cloth bed cropping.
3, cold dome: 13g/L, hydrogen peroxide concentration is 13g/L, and band liquid measure 70%, bank up time 24h.
4, mercerising: carry out mercerising on straight roller mercerizing range, wherein 30, Leng Jian district caustic dip roller, 18, thermokalite district caustic dip roller, 5 lattice hot water wash, caustic soda 85g/L, caustic dip time 26s.
5, tentering brightens: on Monforts setting machine, carry out tentering arrangement.VBL concentration is 1.5g/L, and amount of urea is 45g/L.
6, stamp evaporates washing for known technology, repeats no more.
7, soft sizing: Monforts setting machine, beats maximum overfeeding, speed of a motor vehicle 30m/min, temperature 170 DEG C.
8, calendering: three rolling ray machines, pressure 13kg, speed of a motor vehicle 25m/min, temperature 95 DEG C.
9, preshrunk: Monforts preshrinking machine, speed of a motor vehicle 20m/min, bearing roller pressure is 35kN, and bearing roller temperature is 130 DEG C.
Comparative example 1
The difference of the present embodiment and embodiment 2 is: in mercerizing process, concentration of caustic soda is 78g/L.
Comparative example 2
The difference of the present embodiment and embodiment 2 is: in mercerizing process, concentration of caustic soda is 92g/L.
Above-described embodiment gained fabric is carried out performance test, and result is as follows:
According to GB " evaluation of GB/T20944.3-2008 weaving anti-microbial property ", the bacteriostasis rate of gained fabric staphylococcus aureus is 99%, colibacillary bacteriostasis rate is 92%, the bacteriostasis rate of Candida albicans is 89%.Cloth cover is smooth, not distortion.
Claims (6)
1. sky silk/bamboo pulp fibre blending shell-fabric dyeing and finishing processing method, it is characterized in that: by grey cloth successively through singing, roll enzyme cold dome, wash water, cold dome, mercerising, tentering brighten, stamp, evaporate, wash, softness sizing, calendering, preshrunk operation, to obtain final product; Wherein, in mercerizing process, concentration of caustic soda is 80-90g/L.
2. sky according to claim 1 silk/bamboo pulp fibre blending shell-fabric dyeing and finishing processing method, is characterized in that: caustic dip time 20-30s in mercerizing process.
3. sky according to claim 1 silk/bamboo pulp fibre blending shell-fabric dyeing and finishing processing method, it is characterized in that: in described cold dome operation, concentration of caustic soda is 10-15g/L, hydrogen peroxide concentration is 12-15g/L, band liquid measure 70%-80%.
4. sky according to claim 1 silk/bamboo pulp fibre blending shell-fabric dyeing and finishing processing method, it is characterized in that: it is 1-2g/L that described tentering brightens VBL concentration in operation, amount of urea is 40-50g/L.
5. sky according to claim 1 silk/bamboo pulp fibre blending shell-fabric dyeing and finishing processing method, it is characterized in that: in described calendering operation, pressure is 12-15kg, the speed of a motor vehicle is 20-30m/min, and temperature is 90-100 DEG C.
6. sky according to claim 1 silk/bamboo pulp fibre blending shell-fabric dyeing and finishing processing method, it is characterized in that: in described shrinking processes, the speed of a motor vehicle is 15-25m/min, bearing roller pressure is 30-40kN, and bearing roller temperature is 120-135 DEG C.
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