CN105483495A - 一种锅炉管防护涂层 - Google Patents

一种锅炉管防护涂层 Download PDF

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Publication number
CN105483495A
CN105483495A CN201510900269.XA CN201510900269A CN105483495A CN 105483495 A CN105483495 A CN 105483495A CN 201510900269 A CN201510900269 A CN 201510900269A CN 105483495 A CN105483495 A CN 105483495A
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China
Prior art keywords
protective coating
percent
surplus
weight percentage
coated material
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CN201510900269.XA
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English (en)
Inventor
陆玉华
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Jiangsu Dongfang Electric Power Boiler Fittings Co Ltd
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Jiangsu Dongfang Electric Power Boiler Fittings Co Ltd
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Priority to CN201510900269.XA priority Critical patent/CN105483495A/zh
Publication of CN105483495A publication Critical patent/CN105483495A/zh
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/02Alloys containing less than 50% by weight of each constituent containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/052Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 40%
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C19/00Alloys based on nickel or cobalt
    • C22C19/03Alloys based on nickel or cobalt based on nickel
    • C22C19/05Alloys based on nickel or cobalt based on nickel with chromium
    • C22C19/051Alloys based on nickel or cobalt based on nickel with chromium and Mo or W
    • C22C19/053Alloys based on nickel or cobalt based on nickel with chromium and Mo or W with the maximum Cr content being at least 30% but less than 40%
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C4/00Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
    • C23C4/04Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
    • C23C4/06Metallic material

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

本发明公开了一种锅炉管防护涂层,该涂层材料按重量百分比由下列组分组成:Ni:30-45%,Cr:15-20%,Ti:5-8%,Al:1-3%,Si:5-10%,Fe:6-10%,Mo:12-16%,Cu:1-3%,B:0.5-1%,Nb:0.5-1%,余量为不可避免的杂质。本发明公开的锅炉管防护涂层具有较高的耐腐蚀磨损能力,与基体结合力强,可有效地延长锅炉管的使用寿命。

Description

一种锅炉管防护涂层
技术领域
本发明涉及一种锅炉管防护涂层。
背景技术
锅炉管使用时经常处于高温和高压条件,管子在高温烟气和水蒸气的作用下会发生磨损和腐蚀,造成的生产危害和经济损失十分大。腐蚀和磨损发生的主要原因是高温下锅炉中沸腾的高硬度粒子对管壁高速冲刷,同时燃烧产生的SO2等有毒气体对管壁有强烈的腐蚀作用,此外腐蚀产生的FeS在高温下硬度很低,加剧了管壁的磨损。因此在工程应用中,就需要对锅炉管道采取一定的防护措施,以降低其磨损和腐蚀速度,提高管道使用年限,降低总成本。
发明内容
本发明的目的是提供一种锅炉管防护涂层,以提高锅炉管的耐腐蚀磨损能力。
该涂层材料按重量百分比由下列组分组成:Ni:30-45%,Cr:15-20%,Ti:5-8%,Al:1-3%,Si:5-10%,Fe:6-10%,Mo:12-16%,Cu:1-3%,B:0.5-1%,Nb:0.5-1%,余量为不可避免的杂质。
优选地,该涂层材料按重量百分比由下列组分组成:Ni:40-42%,Cr:18-20%,Ti:6-7%,Al:1-2%,Si:8-9%,Fe:8-10%,Mo:14-15%,Cu:1-2%,B:0.5-0.8%,Nb:0.5-0.8%,余量为不可避免的杂质。
更优选地,该涂层材料按重量百分比由下列组分组成:Ni:40%,Cr:18%,Ti:6%,Al:1%,Si:8%,Fe:9%,Mo:14%,Cu:2%,B:0.5%,Nb:0.5%,余量为不可避免的杂质。
上述锅炉管防护涂层采用等离子喷涂工艺喷涂,电压设为50-60V,电流为450-550-A,主气压为0.6Mpa,次气压为0.5Mpa,送分量为10g/min,喷涂距离为100mm,喷涂制成的涂层厚度为0.3-0.5mm。
本发明的优点和有益效果在于:1)该涂层材料具有优异的抗氧化、氮化、硫化能力;2)采用等离子喷涂工艺,增强了本发明中涂层材料与基体的结合力,并且涂层的厚度较薄;3)该涂层的使用寿命强,继而增强了锅炉管的使用寿命,节约了成本。
具体实施方式
下面结合实施例,对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案,而不能以此来限制本发明的保护范围。
本发明具体实施的技术方案是:
实施例一
一种锅炉管防护涂层,该涂层材料按重量百分比由下列组分组成:Ni:40%,Cr:18%,Ti:6%,Al:1%,Si:8%,Fe:9%,Mo:14%,Cu:2%,B:0.5%,Nb:0.5%,余量为不可避免的杂质。
实施例二
一种锅炉管防护涂层,该涂层材料按重量百分比由下列组分组成:Ni:35%,Cr:20%,Ti:8%,Al:2%,Si:8%,Fe:7%,Mo:13%,Cu:1%,B:0.5%,Nb:0.5%,余量为不可避免的杂质。
实施例三
一种锅炉管防护涂层,该涂层材料按重量百分比由下列组分组成:Ni:42%,Cr:16%,Ti:7%,Al:2%,Si:6%,Fe:8%,Mo:12%,Cu:1%,B:1%,Nb:0.5%,余量为不可避免的杂质。
以上所述仅是本发明的优选实施方式,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明技术原理的前提下,还可以做出若干改进和润饰,这些改进和润饰也应视为本发明的保护范围。

Claims (4)

1.一种锅炉管防护涂层,其特征在于,所述的涂层材料按重量百分比由下列组分组成:Ni:30-45%,Cr:15-20%,Ti:5-8%,Al:1-3%,Si:5-10%,Fe:6-10%,Mo:12-16%,Cu:1-3%,B:0.5-1%,Nb:0.5-1%,余量为不可避免的杂质。
2.根据权利要求1中所述的锅炉管防护涂层,其特征在于,采用等离子喷涂工艺喷涂,电压设为50-60V,电流为450-550-A,主气压为0.6Mpa,次气压为0.5Mpa,送分量为10g/min,喷涂距离为100mm。
3.根据权利要求2中所述的锅炉管防护涂层,其特征在于,所述的涂层材料按重量百分比由下列组分组成:Ni:40-42%,Cr:18-20%,Ti:6-7%,Al:1-2%,Si:8-9%,Fe:8-10%,Mo:14-15%,Cu:1-2%,B:0.5-0.8%,Nb:0.5-0.8%,余量为不可避免的杂质。
4.根据权利要求3中所述的锅炉管防护涂层,其特征在于,所述的涂层材料按重量百分比由下列组分组成:Ni:40%,Cr:18%,Ti:6%,Al:1%,Si:8%,Fe:9%,Mo:14%,Cu:2%,B:0.5%,Nb:0.5%,余量为不可避免的杂质。
CN201510900269.XA 2015-12-09 2015-12-09 一种锅炉管防护涂层 Pending CN105483495A (zh)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108467974A (zh) * 2018-06-25 2018-08-31 山东大学 一种锅炉换热管的镍基防护涂层及其制备方法
CN111520702A (zh) * 2020-06-05 2020-08-11 江苏科环新材料有限公司 具有双重防护的防爆型锅炉用管及其制备方法
CN113088796A (zh) * 2021-03-04 2021-07-09 南昌大学 一种应用于高温氧化性含氯气氛的Ti改性904L合金的制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102808108A (zh) * 2012-08-24 2012-12-05 朱小英 一种锅炉管道防护涂层材料的制备方法
CN104313532A (zh) * 2014-11-04 2015-01-28 长安大学 一种锅炉管束用耐蚀耐磨钼基非晶涂层的制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102808108A (zh) * 2012-08-24 2012-12-05 朱小英 一种锅炉管道防护涂层材料的制备方法
CN104313532A (zh) * 2014-11-04 2015-01-28 长安大学 一种锅炉管束用耐蚀耐磨钼基非晶涂层的制备方法

Non-Patent Citations (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108467974A (zh) * 2018-06-25 2018-08-31 山东大学 一种锅炉换热管的镍基防护涂层及其制备方法
CN111520702A (zh) * 2020-06-05 2020-08-11 江苏科环新材料有限公司 具有双重防护的防爆型锅炉用管及其制备方法
CN113088796A (zh) * 2021-03-04 2021-07-09 南昌大学 一种应用于高温氧化性含氯气氛的Ti改性904L合金的制备方法

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