CN105462299A - Aqueous wall body coating and preparation method thereof - Google Patents
Aqueous wall body coating and preparation method thereof Download PDFInfo
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- CN105462299A CN105462299A CN201510988299.0A CN201510988299A CN105462299A CN 105462299 A CN105462299 A CN 105462299A CN 201510988299 A CN201510988299 A CN 201510988299A CN 105462299 A CN105462299 A CN 105462299A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
Abstract
The invention provides aqueous wall body coating and a preparation method thereof. The aqueous wall body coating provided by the invention is prepared by mixing the following components in parts by weight: 80 to 120 parts of magnesium oxide, 30 to 50 parts of magnesium sulfate, 40 to 50 parts of water and 10 to 40 parts of auxiliary materials. According to the aqueous wall body coating, the magnesium oxide and the magnesium sulfate are used as film-forming substances so that the coating with better strength and good waterproof performance can be obtained without adding organic matters, and the coating also has a better adhesive force on a wall body.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of water-thinned wall paint and preparation method thereof.
Background technology
At present, low-carbon energy-saving environmental protection has become Global Sustainable Development strategy, and building energy conservation environmental protection is the key of city energy-conserving and environment-protective, and account for Economic development GDP proportion comparatively large, each state all pays much attention to.In building energy conservation environmental protection, body of wall energy-conserving and environment-protective are most important things, especially tropical Island, heat, and in coating, objectionable impurities volatilization is fast, and heat-insulating and energy-saving, health environment-friendly have become coating for wall surface key issue in the urgent need to address.In addition, reducing costs also is the important selection solving society and the market requirement.
Based on the importance of building wall paint energy-conserving and environment-protective, people are also trying to explore Application and Development novel energy-saving environment-friendly coating.But the coating for wall surface of current use is all containing organic composition, in use toxicity is larger to make coating.And the diatom ooze coating of rising in recent years avoids with an organic solvent, but this coating intensity is bad, and not water-fast.
Therefore, organic solvent-free is obtained and the coating of intensity and water-tolerant is the problem needing at present to solve.
Summary of the invention
In view of this, technical problem to be solved by this invention is to provide a kind of water-thinned wall paint and preparation method thereof, and water-thinned wall paint provided by the invention is not only containing organic solvent, and the intensity of coating and water-tolerant.
The invention provides a kind of water-thinned wall paint, with weight parts, comprising:
Preferably, described magnesium sulfate is one or both in anhydrous magnesium sulfate and magnesium sulfate heptahydrate.
Preferably, described magnesium oxide is 90 ~ 110 weight parts.
Preferably, described magnesium sulfate is 35 ~ 45 weight parts.
Preferably, described auxiliary material is one or more in properties-correcting agent, anti-fissuring agent, auxiliary agent and functional stuffing.
Preferably, described properties-correcting agent is one or more in methylcellulose gum, citric acid, phosphoric acid and water glass.
Preferably, described anti-fissuring agent is one or more in silicon carbide fiber, sapphire whisker and polypropylene fibre.
Preferably, described auxiliary agent is one or more in kaolin, titanium dioxide, quartz sand, calcium carbonate and barium sulfate.
Preferably, described functional stuffing is one or more in hollow glass micropearl, hollow ceramic microspheres and nano-ceramic powder.
Present invention also offers a kind of preparation method of water-thinned wall paint of the present invention, comprising:
The auxiliary material of the magnesium sulfate of the magnesium oxide of 80 ~ 120 weight parts, 30 ~ 50 weight parts, the water of 40 ~ 50 weight parts and 10 ~ 40 weight parts is mixed, obtains water-thinned wall paint.
Compared with prior art, water-thinned wall paint provided by the invention, by the magnesium oxide by 80 ~ 120 weight parts, the magnesium sulfate of 30 ~ 50 weight parts, the water of 40 ~ 50 weight parts and the auxiliary material of 10 ~ 40 weight parts are mixed to get, wherein the present invention using magnesium oxide and magnesium sulfate as filmogen, make in the coating obtained, not need interpolation organic substance that intensity can be obtained better, the coating that water resistance is good, and it is also better to the sticking power of body of wall, experimental result shows, the hardness of coating provided by the invention reaches 3H, sticking power is 1 grade, and water resistance is water-intake rate is less than 6%.
Embodiment
The invention provides a kind of water-thinned wall paint, with weight parts, comprising:
According to the present invention, magnesium oxide of the present invention, described magnesian granularity is preferably 800 ~ 2000 orders, is more preferably 1000 ~ 1500 orders; In described magnesium oxide, the content of activated magnesia is preferably more than 85wt%, is more preferably 90wt% ~ 85wt%; In described water-thinned wall paint, described magnesian content is preferably 90 ~ 110 weight parts, is more preferably 100 ~ 105 weight parts.
According to the present invention, described magnesium sulfate is preferably one or more in anhydrous magnesium sulfate and magnesium sulfate heptahydrate, and in described water-thinned wall paint, the content of described magnesium sulfate is preferably 35 ~ 45 weight parts, is more preferably 40 ~ 42 weight parts.
According to the present invention, in described water-thinned wall paint, the content of described water is preferably 35 ~ 45 weight parts, is more preferably 40 ~ 42 weight parts.
According to the present invention, in described water-thinned wall paint, the content of described auxiliary material is preferably 11 ~ 35 weight parts, is more preferably 15 ~ 30 weight parts, most preferably is 20 ~ 25 weight parts.Described auxiliary material is preferably one or more in properties-correcting agent, anti-fissuring agent, auxiliary agent and functional stuffing, is more preferably properties-correcting agent, anti-fissuring agent, auxiliary agent and functional stuffing; When auxiliary material is properties-correcting agent, anti-fissuring agent, auxiliary agent and functional stuffing, the weight ratio of described properties-correcting agent, anti-fissuring agent, auxiliary agent and functional stuffing is preferably (1 ~ 3): (0.1 ~ 0.3): (5 ~ 10): (5 ~ 15), be more preferably (1.5 ~ 2.5): (0.15 ~ 0.25): (6 ~ 9): (6 ~ 12), most preferably be (1.8 ~ 2): (0.18 ~ 0.2): (7 ~ 8): (7 ~ 10).Wherein, described properties-correcting agent is preferably one or more in methylcellulose gum, citric acid, phosphoric acid and water glass, is more preferably methylcellulose gum, citric acid, phosphoric acid or water glass; Described anti-fissuring agent is preferably one or more in silicon carbide fiber, sapphire whisker and polypropylene fibre, is more preferably silicon carbide fiber, sapphire whisker or polypropylene fibre; Described auxiliary agent is preferably one or more in kaolin, titanium dioxide, quartz sand, calcium carbonate and barium sulfate, and what be more preferably in kaolin, titanium dioxide, quartz sand, calcium carbonate and barium sulfate is two or more, is more preferably kaolin and titanium dioxide; Described functional stuffing is preferably one or more in hollow glass micropearl, hollow ceramic microspheres and nano-ceramic powder, is more preferably hollow glass micropearl, hollow ceramic microspheres or nano-ceramic powder.
Present invention also offers a kind of preparation method of water-thinned wall paint of the present invention, comprising:
The auxiliary material of the magnesium sulfate of the magnesium oxide of 80 ~ 120 weight parts, 30 ~ 50 weight parts, the water of 40 ~ 50 weight parts and 10 ~ 40 weight parts is mixed, obtains water-thinned wall paint.
According to the present invention, the auxiliary material of the magnesium sulfate of the magnesium oxide of 80 ~ 120 weight parts, 30 ~ 50 weight parts, the water of 40 ~ 50 weight parts and 10 ~ 40 weight parts mixes by the present invention, obtains water-thinned wall paint; Wherein, described magnesium oxide, granularity is preferably 800 ~ 2000 orders, is more preferably 1000 ~ 1500 orders; In described magnesium oxide, the content of activated magnesia is preferably more than 85wt%, is more preferably 90wt% ~ 85wt%; Described magnesian consumption is preferably 90 ~ 110 weight parts, is more preferably 100 ~ 105 weight parts.Described magnesium sulfate is preferably one or more in anhydrous magnesium sulfate and magnesium sulfate heptahydrate, and the consumption of described magnesium sulfate is preferably 35 ~ 45 weight parts, is more preferably 40 ~ 42 weight parts.The consumption of described water is preferably 35 ~ 45 weight parts, is more preferably 40 ~ 42 weight parts.The consumption of described auxiliary material is preferably 11 ~ 35 weight parts, is more preferably 15 ~ 30 weight parts, most preferably is 20 ~ 25 weight parts.Described auxiliary material is preferably one or more in properties-correcting agent, anti-fissuring agent, auxiliary agent and functional stuffing, is more preferably properties-correcting agent, anti-fissuring agent, auxiliary agent and functional stuffing; When auxiliary material is properties-correcting agent, anti-fissuring agent, auxiliary agent and functional stuffing, the weight ratio of described properties-correcting agent, anti-fissuring agent, auxiliary agent and functional stuffing is preferably (1 ~ 3): (0.1 ~ 0.3): (5 ~ 10): (5 ~ 15), be more preferably (1.5 ~ 2.5): (0.15 ~ 0.25): (6 ~ 9): (6 ~ 12), most preferably be (1.8 ~ 2): (0.18 ~ 0.2): (7 ~ 8): (7 ~ 10).Wherein, described properties-correcting agent is preferably one or more in methylcellulose gum, citric acid, phosphoric acid and water glass, is more preferably methylcellulose gum, citric acid, phosphoric acid or water glass; Described anti-fissuring agent is preferably one or more in silicon carbide fiber, sapphire whisker and polypropylene fibre, is more preferably silicon carbide fiber, sapphire whisker or polypropylene fibre; Described auxiliary agent is preferably one or more in kaolin, titanium dioxide, quartz sand, calcium carbonate and barium sulfate, and what be more preferably in kaolin, titanium dioxide, quartz sand, calcium carbonate and barium sulfate is two or more, is more preferably kaolin and titanium dioxide; Described functional stuffing is preferably one or more in hollow glass micropearl, hollow ceramic microspheres and nano-ceramic powder, is more preferably hollow glass micropearl, hollow ceramic microspheres or nano-ceramic powder.
In the present invention, the method for the present invention to mixing does not have particular requirement, well known to a person skilled in the art the method for water-borne coatings mixing.The magnesium sulfate of the water of 40 ~ 50 weight parts and 30 ~ 50 weight parts preferably first mixes by the present invention, and then adds the magnesium oxide of 80 ~ 120 weight parts and the auxiliary material mixing of 10 ~ 40 weight parts, obtains water-thinned wall paint.
Water-thinned wall paint provided by the invention, by the auxiliary material of the magnesium sulfate of the magnesium oxide of 80 ~ 120 weight parts, 30 ~ 50 weight parts, the water of 40 ~ 50 weight parts and 10 ~ 40 weight parts is mixed to get, wherein the present invention using magnesium oxide and magnesium sulfate as filmogen, make in the coating obtained, not need to add organic substance and can obtain the coating that intensity is better, water resistance is good, and also better to the sticking power of body of wall.
Technical scheme below in conjunction with the embodiment of the present invention is clearly and completely described, and obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
By water 50 weight part, after the mixing of magnesium sulfate heptahydrate 40 weight part, add properties-correcting agent (0.5 weight part methylcellulose gum, 0.5 parts by weight of lemon acid) 1 weight part, anti-fissuring agent silicon carbide fiber 0.3 weight part, auxiliary agent kaolin 3 weight part, auxiliary agent titanium dioxide 3 weight part, hollow glass micropearl 6 weight part, (activated magnesia accounts for 85% to magnesium oxide, granularity 1000 order) 100 weight parts, stir, namely obtain water-thinned wall paint.
The water-thinned wall paint obtained is carried out film to the cement plate of class body of wall, and result shows, this film normal temperature 10min surface drying, after 24h, coating is done solid work.
Detect according to the sticking power of GB1720-89 (79) standard to coating, result shows, its adhesion strength 1 grade.
Detect according to the hardness of GB/T6739-1996 standard to coating, result shows, its hardness 3H.
The plate being coated with coating is immersed in the water 4 hours, and then detect its water-intake rate, result shows, its water-intake rate is 4%.
Embodiment 2:
By water 50 weight part, after the mixing of magnesium sulfate heptahydrate 45 weight part, add 0.65 weight part methylcellulose gum, 0.65 parts by weight of lemon acid and 0.65 weight parts water glass, anti-fissuring agent aluminum oxide 0.2 weight part, auxiliary agent kaolin 4 weight part, auxiliary agent titanium dioxide 4 weight part, hollow glass micropearl 6 weight part, (activated magnesia accounts for 85% to magnesium oxide, granularity 1000 order) 100 weight parts, stir, namely obtain water-thinned wall paint.
The water-thinned wall paint obtained is carried out film to the cement plate of class body of wall, and result shows, this film normal temperature 10min surface drying, after 24h, coating is done solid work.
Detect according to the sticking power of GB1720-89 (79) standard to coating, result shows, its adhesion strength 1 grade.
Detect according to the hardness of GB/T6739-1996 standard to coating, result shows, its hardness 3H.
The plate being coated with coating is immersed in the water 4 hours, and then detect its water-intake rate, result shows, its water-intake rate is 5%.
Embodiment 3:
By water 50 weight part, after the mixing of magnesium sulfate heptahydrate 50 weight part, add methylcellulose gum 1 weight part, citric acid 1 weight part, phosphatase 11 weight part, anti-fissuring agent polypropylene fibre 0.3 weight part, auxiliary agent kaolin 5 weight part, auxiliary agent titanium dioxide 5 weight part, hollow glass micropearl 8 weight part, (activated magnesia accounts for 85% to magnesium oxide, granularity 1000 order) 100 weight parts, stir, namely obtain water-thinned wall paint.
The water-thinned wall paint obtained is carried out film to the cement plate of class body of wall, and result shows, this film normal temperature 10min surface drying, after 24h, coating is done solid work.
Detect according to the sticking power of GB1720-89 (79) standard to coating, result shows, its adhesion strength 1 grade.
Detect according to the hardness of GB/T6739-1996 standard to coating, result shows, its hardness 3H.
The plate being coated with coating is immersed in the water 4 hours, and then detect its water-intake rate, result shows, its water-intake rate is 3.5%.
The explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
Claims (10)
1. a water-thinned wall paint, with weight parts, comprising:
2. coating according to claim 1, is characterized in that, described magnesium sulfate is one or both in anhydrous magnesium sulfate and magnesium sulfate heptahydrate.
3. coating according to claim 1, is characterized in that, described magnesium oxide is 90 ~ 110 weight parts.
4. coating according to claim 1, is characterized in that, described magnesium sulfate is 35 ~ 45 weight parts.
5. coating according to claim 1, is characterized in that, described auxiliary material is one or more in properties-correcting agent, anti-fissuring agent, auxiliary agent and functional stuffing.
6. coating according to claim 5, is characterized in that, described properties-correcting agent is one or more in methylcellulose gum, citric acid, phosphoric acid and water glass.
7. coating according to claim 5, is characterized in that, described anti-fissuring agent is one or more in silicon carbide fiber, sapphire whisker and polypropylene fibre.
8. coating according to claim 5, is characterized in that, described auxiliary agent is one or more in kaolin, titanium dioxide, quartz sand, calcium carbonate and barium sulfate.
9. coating according to claim 5, is characterized in that, described functional stuffing is one or more in hollow glass micropearl, hollow ceramic microspheres and nano-ceramic powder.
10. a preparation method for the water-thinned wall paint described in claim 1 ~ 9 any one, comprising:
The auxiliary material of the magnesium sulfate of the magnesium oxide of 80 ~ 120 weight parts, 30 ~ 50 weight parts, the water of 40 ~ 50 weight parts and 10 ~ 40 weight parts is mixed, obtains water-thinned wall paint.
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CN201510988299.0A CN105462299A (en) | 2015-12-25 | 2015-12-25 | Aqueous wall body coating and preparation method thereof |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL2019107B1 (en) * | 2017-06-22 | 2019-01-07 | Champion Link Int Corp | Panel suitable for assembling a floor or wall covering, and the like covering |
CN109336542A (en) * | 2018-12-12 | 2019-02-15 | 重庆科恒建材集团有限公司 | A kind of heat-conductive coating and preparation method for floor heating module radiating surface |
CN113429812A (en) * | 2021-08-17 | 2021-09-24 | 海南大学 | Composite anticorrosive paint and preparation method thereof |
CN114249993A (en) * | 2021-12-28 | 2022-03-29 | 海南大学 | Multifunctional three-dimensional hydrophobic coating and coating for buildings |
CN115368107A (en) * | 2022-06-15 | 2022-11-22 | 霍军伟 | Dry powder type artistic texture coating |
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CN1590470A (en) * | 2004-01-15 | 2005-03-09 | 苏幸全 | Water environmentel protection type inner and external well mineral varnish paint and its prepqration method |
CN1792947A (en) * | 2005-11-18 | 2006-06-28 | 王祖军 | Sulfur magnesium citrate material and application thereof |
CN103788745A (en) * | 2014-01-29 | 2014-05-14 | 长沙市芙蓉区群翔建筑涂料厂 | Elastic anti-cracking energy-saving putty cream for exterior walls and production method thereof |
CN104788076A (en) * | 2015-03-16 | 2015-07-22 | 深圳琦美龙新建材科技有限公司 | Magnesium-based inorganic heat insulation coating and preparation method thereof |
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2015
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JPH09142914A (en) * | 1995-11-28 | 1997-06-03 | Rihitaa Corp:Kk | Magnesia cement composition and carbonaceous formed product |
CN1590470A (en) * | 2004-01-15 | 2005-03-09 | 苏幸全 | Water environmentel protection type inner and external well mineral varnish paint and its prepqration method |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL2019107B1 (en) * | 2017-06-22 | 2019-01-07 | Champion Link Int Corp | Panel suitable for assembling a floor or wall covering, and the like covering |
CN109336542A (en) * | 2018-12-12 | 2019-02-15 | 重庆科恒建材集团有限公司 | A kind of heat-conductive coating and preparation method for floor heating module radiating surface |
CN109336542B (en) * | 2018-12-12 | 2021-06-04 | 重庆科恒建材集团有限公司 | Heat-conducting coating for heat dissipation surface of floor heating module and preparation method thereof |
CN113429812A (en) * | 2021-08-17 | 2021-09-24 | 海南大学 | Composite anticorrosive paint and preparation method thereof |
CN114249993A (en) * | 2021-12-28 | 2022-03-29 | 海南大学 | Multifunctional three-dimensional hydrophobic coating and coating for buildings |
CN115368107A (en) * | 2022-06-15 | 2022-11-22 | 霍军伟 | Dry powder type artistic texture coating |
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