CN105433431B - A kind of electronic cigarette liquid and electronic cigarette - Google Patents
A kind of electronic cigarette liquid and electronic cigarette Download PDFInfo
- Publication number
- CN105433431B CN105433431B CN201511007089.5A CN201511007089A CN105433431B CN 105433431 B CN105433431 B CN 105433431B CN 201511007089 A CN201511007089 A CN 201511007089A CN 105433431 B CN105433431 B CN 105433431B
- Authority
- CN
- China
- Prior art keywords
- electronic cigarette
- cigarette liquid
- perfumery
- liquid
- base solvent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24F—SMOKERS' REQUISITES; MATCH BOXES; SIMULATED SMOKING DEVICES
- A24F47/00—Smokers' requisites not otherwise provided for
-
- A24F47/004—
Abstract
The present invention relates to a kind of electronic cigarette liquid and electronic cigarettes, belong to electronic cigarette field.Electronic cigarette liquid provided by the invention, including base solvent and cause perfumery, the cause perfumery are using pipe tobacco or offal as raw material, and distillation obtains under conditions of temperature is 150~250 DEG C, is aerobic or oxygen-enriched.The pleasant impression of the electronic cigarette liquid is cleaner, delicate mouthfeel.
Description
The application be application for a patent for invention (application number: 201410633690.4, the applying date: 2014.11.12, invention name
Claim: a kind of electronic cigarette liquid) divisional application.
Technical field
The present invention relates to a kind of electronic cigarette liquid and electronic cigarettes, belong to electronic cigarette field.
Background technique
With the raising of people 's material life level, smoking becomes the hot spot of social concerns with health problem.In this back
Under scape, the research of the novel tobaccos product such as low temperature cigarette, electronic cigarette more and more attention has been paid to.
Electronic cigarette belongs to one kind of new tobacco products, and basic technique principle is, when sucking electronic cigarette, electronic cigarette electricity
Pond powers to electronic smoke atomizer, and atomizer is started to work, and the tobacco juice being stored in electronic cigarette is atomized and generates smog.Electronics
Tobacco juice in cigarette, also referred to as " tobacco tar ", are stored in adsorbent material, are commonly called as " adsorption cotton ".Tobacco juice in electronic cigarette, actually one
A formula essence, when sucking electronic cigarette, atomization is " smog ", and smog includes the objects such as the glycerol evaporated in essence, propylene glycol
The fragrance matter evaporated in matter and essence.
The composition of electronic cigarette liquid can be roughly divided into two parts, and a part is to cause perfumery；A part is base solvent, is used for
Dissolution causes perfumery.Solvent can be water, be also possible to some organic solvents of glycerol, propylene glycol, and part organic solvent also has itself
There is certain fragrance.Common base solvent is one or more of glycerol, propylene glycol, ethyl alcohol, and wherein solvent can also add
Enter water and increases the polarity of solvent to increase the dissolubility of polarity aroma component.
Compared with the form that traditional cigarette is burnt with cigarette provides sense organ satisfaction to smoker, sense of the electronic cigarette to smoker
Official's evaluation, often tobacco flavor is thin, lacks the peculiar burnt odor of burning tobacco bring.
104026729 A of Chinese patent CN discloses a kind of electronic cigarette liquid with burnt odor fragrance, it is to utilize white granulated sugar
Perhaps brown sugar is that raw material carries out caramelization with offal, pipe tobacco or cigarette ash at a certain temperature, is obtained with burnt odor fragrance
Product.This product is divided into two parts, and a part is to cause perfumery, i.e. pipe tobacco or offal is warming up to 180-250 DEG C and is heated at reflux
Product after 10-20 min；Another part is base solvent, i.e. the mixed solvent of the glycerol of 10-50 mL, second alcohol and water.But
This tobacco juice baking is fragrant denseer, and mouthfeel is not pure enough.
Summary of the invention
The present invention is the above-mentioned technical problem solved, and the preparation method for providing a kind of burnt odor electronic cigarette liquid overcomes existing skill
Not pure enough the defect of electronic cigarette liquid mouthfeel in art, makes the fragrance of electronic cigarette closer to traditional cigarette.
The technical scheme is that providing a kind of electronic cigarette liquid, including base solvent and cause perfumery, base solvent is matter
The mixed liquor for measuring the glycerol that water, mass percent that percentage is 10% are 70% and the ethyl alcohol that mass percent is 20%, causes fragrant
Object is to lead to B3F offal as raw material using Yunnan Shao, and distillation obtains under conditions of temperature is 180 DEG C, is aerobic or oxygen-enriched；It is described to have
Oxygen or it is oxygen-enriched refer to air draught is passed through in distillation process, air draught is sucked by vacuum pump；The cause perfumery is by being condensed
Part and by base solvent absorb part form.
Further, the flow velocity of the air draught is 100mL/min.
Another technical solution of the invention is to provide a kind of electronic cigarette, uses above-mentioned electronic cigarette liquid.
The auxiliary material in specification can be one of described cause perfumery or a variety of, increase auxiliary material so that in tobacco juice
Certain smell is more prominent, is suitble to different types of consumer.In addition, auxiliary material is also possible to other common additives.
The present invention burns and sucks mechanism, design heating preparation experiment, the pyrolytical condition of simulated combustion cigarette, system by dissecting cigarette
It is standby and effectively collect aroma component, electronic cigarette liquid is fabricated to applied to electronic cigarette.
In order to preferably simulate the pyrolytical condition of result of combustion of tobacco, it is necessary to release fragrance matter when burning to traditional cigarette
Mechanism is dissected: cigarette is different with chemical reaction according to its temperature change when burning, and can be divided into three different regions, i.e.,
High temperature combustion zone A, pyrolysis distillation zone B and low temperature cold coagulation zone C.Wherein the temperature of high temperature combustion zone is higher, and about 600~900
DEG C, the product of generation is mainly gaseous substance, such as the rudimentary hydrocarbon compound of carbon dioxide, carbon monoxide, water, hydrogen, methane and
Some free radicals.The product in the area is little to the contribution of flue gas aroma component, and predominantly pyrolysis distillation zone B provides heat source.Burning
The characteristics of cone, which is followed by, is pyrolyzed distillation zone B, the area is that the pyrolysis distillation zone oxygen supply at combustion cone center is insufficient, and reaction is to lack
It is carried out under oxygen condition.Thermal current from high temperature combustion zone provides heat source, results in the complicated chemical variation of pyrolysis distillation zone.
Many substances in pipe tobacco carry out the chemical reaction of violent complexity herein, such as thermal decomposition, thermal synthesis, destructive distillation, polymerization, condensation, oneself
It is reacted by base etc., most compounds in flue gas are all formed herein, it is clear that important aroma component in flue gas
It is to be generated in the pyrolysis distillation area B.It is known as condensing filtering area C from pyrolysis distillation zone to the end of cigarette.Here, the temperature of flue gas
Room temperature is down to by 100 DEG C.
The present invention has found by repeated multiple times experiment, and when being depressurized to 10 mmHg, heating produces fragrant temperature 150~250
DEG C, the aroma substance of similar burning cigarette can be obtained.Temperature is too low, and obtained aroma component burnt odor is inadequate；Temperature is excessively high, cigarette
Smoked gas is overweight, has and heavier is charred taste.For temperature at 180~200 DEG C, sensory evaluating smoking's evaluation effect is best.
The use of circulating cooling liquid can be preferably by the cooling simultaneously maximum journey of the volatility aroma component steamed when evaporative distillation
The collection of degree.The temperature range of circulating cooling liquid is -10~-5 DEG C.
It is preferably 0.01~0.2 g/ml that concentration of the perfumery in base solvent is caused in the present invention, and perfumery concentration is caused to be lower than
The cigarette perfume of the electronic cigarette liquid of 0.01 g/ml is very weak, causes perfumery to be excessively difficult to directly be absorbed completely with base solvent, while may lead
It causes fragrance overrich and needs to be properly added base solvent dilution.
Detailed description of the invention
Fig. 1 is vacuum distillation apparatus figure used in the present invention.
Fig. 2 is the GC-MS figure of fragrance component in 2 gained electronic cigarette liquid of the embodiment of the present invention.
In figure: 1, acetic acid；2,3- metliyl-butyric acid；3,2- metliyl-butyric acid；4,2- furancarbinol；5, cyclohexanone；6,2,4-
Dihydroxy -2,5- dimethyl -3(2H)-furans -3- ketone；7, maltol；8,DDMP；9,5- hydroxyl furfural；10-12, nicotine；13,
Nicotyrine；14, bipyridyl；15, three ketenes of soybean；16, three ketenes of soybean.
Specific embodiment
The invention will be further described combined with specific embodiments below.Following embodiment be intended to illustrate invention rather than
Limitation of the invention further.
Comparative example
The logical B3F offal of 20 Yunnan g Shaos is heated at 180 DEG C by Fig. 1 described device and collects 3 h of tobacco juice, condenser pipe
Temperature control be -10 DEG C, for vacuum degree control in 5 mmHg, absorbing liquid is 45 milliliters of base solvents, ingredient are as follows: quality percentage
Than the water for 10%, mass percent be 70% glycerol and mass percent be 20% ethyl alcohol mixed liquor, after distillation will
The absorbing liquid in condensate liquid and absorption bottle in condenser pipe merges up to tobacco juice.
It takes the above-mentioned tobacco juice of 1 mL to be added in electronic smoke atomizer, is smoked panel test by the personnel that smoke panel test of profession, electronic cigarette has significantly
It is more apparent to bake perfume, sootiness perfume (or spice) etc. for the burnt odor of result of combustion of tobacco.GC-MS detection is carried out to the tobacco juice of comparative example, obtains map as schemed
Shown in 2, analysis it can be concluded that, be common fragrance component in tobacco.
Embodiment
Carry out the fragrant experiment of aerobic or oxygen-enriched production referring to comparative example, specifically feeds intake and reaction temperature and reaction time etc. are complete
Implement according to comparative example, the difference is that only: the flask of oil bath heating in the device of Fig. 1 is inserted into a hollow glass
Pipe, communicates pipe tobacco or offal in flask with outside air, and the entire perfume device that produces forms certain air under the drive of pump
Air-flow, air draught are maintained at 100 mL/min.The tobacco juice that the aerobic or oxygen-enriched tobacco juice and comparative example being prepared obtain, sense organ
It smokes panel test evaluation, evaluation result: both having burnt odor possessed by apparent burning tobacco, the former obtains tobacco juice that i.e. embodiment obtains
The tobacco juice baking arrived is fragrant denseer, and the electronic cigarette for the tobacco juice production that the latter, that is, comparative example obtains pleasant impression of smoking is cleaner, mouthfeel
It is finer and smoother.
Claims (3)
1. a kind of electronic cigarette liquid, including base solvent and cause perfumery, base solvent be mass percent be 10% water, quality
The mixed liquor for the ethyl alcohol that the glycerol and mass percent that percentage is 70% are 20%, causing perfumery is to lead to B3F offal with Yunnan Shao
For raw material, distillation is obtained under conditions of temperature is 180 DEG C, is aerobic；It is described it is aerobic refer to air gas is passed through in distillation process
Stream, air draught are sucked by vacuum pump；It is described that perfumery is caused to form by the part that is condensed and by the part that base solvent absorbs.
2. electronic cigarette liquid as described in claim 1, which is characterized in that the flow velocity of the air draught is 100mL/min.
3. a kind of electronic cigarette, it is characterised in that: use electronic cigarette liquid described in as claimed in claim 1 or 22.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511007089.5A CN105433431B (en) | 2014-11-12 | 2014-11-12 | A kind of electronic cigarette liquid and electronic cigarette |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511007089.5A CN105433431B (en) | 2014-11-12 | 2014-11-12 | A kind of electronic cigarette liquid and electronic cigarette |
| CN201410633690.4A CN104287084B (en) | 2014-11-12 | 2014-11-12 | A kind of electronic cigarette liquid and electronic cigarette |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410633690.4A Division CN104287084B (en) | 2014-11-12 | 2014-11-12 | A kind of electronic cigarette liquid and electronic cigarette |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105433431A CN105433431A (en) | 2016-03-30 |
| CN105433431B true CN105433431B (en) | 2018-12-07 |
Family
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Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511007089.5A Active CN105433431B (en) | 2014-11-12 | 2014-11-12 | A kind of electronic cigarette liquid and electronic cigarette |
| CN201410633690.4A Active CN104287084B (en) | 2014-11-12 | 2014-11-12 | A kind of electronic cigarette liquid and electronic cigarette |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410633690.4A Active CN104287084B (en) | 2014-11-12 | 2014-11-12 | A kind of electronic cigarette liquid and electronic cigarette |
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| CN (2) | CN105433431B (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104720096A (en) * | 2015-02-11 | 2015-06-24 | 湖南中烟工业有限责任公司 | Tobacco aroma generating material, electronic cigarette juice and electronic cigarette |
| CN107189857B (en) * | 2017-07-07 | 2023-10-27 | 重庆中烟工业有限责任公司 | Device and method for preparing smoke flavor |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101806685A (en) * | 2010-04-22 | 2010-08-18 | 上海烟草（集团）公司 | Tobacco aerobic cracking analysis method and sample injection system |
| CN104026728A (en) * | 2014-06-25 | 2014-09-10 | 湖南中烟工业有限责任公司 | Electronic tobacco juice with baking aroma |
Family Cites Families (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4150677A (en) * | 1977-01-24 | 1979-04-24 | Philip Morris Incorporated | Treatment of tobacco |
| US5038802A (en) * | 1988-12-21 | 1991-08-13 | R. J. Reynolds Tobacco Company | Flavor substances for smoking articles |
| US5666977A (en) * | 1993-06-10 | 1997-09-16 | Philip Morris Incorporated | Electrical smoking article using liquid tobacco flavor medium delivery system |
| CN103124501B (en) * | 2011-06-22 | 2015-06-03 | 张重光 | Harmless cigarette made by tobacco |
| CN102349699B (en) * | 2011-07-04 | 2013-07-03 | 郑俊祥 | Preparation method for electronic cigarette liquid |
| CN102936535B (en) * | 2012-11-23 | 2014-02-12 | 中国烟草总公司郑州烟草研究院 | Preparation method and application of natural tobacco aroma enhancer |
| US8794245B1 (en) * | 2013-01-17 | 2014-08-05 | Njoy, Inc. | Aroma pack for an electronic cigarette |
| CN103070472A (en) * | 2013-01-25 | 2013-05-01 | 红云红河烟草(集团)有限责任公司 | Electronic cigarette liquid capable of effectively improving sensory quality of electronic cigarette |
| CN103263080A (en) * | 2013-05-23 | 2013-08-28 | 红云红河烟草(集团)有限责任公司 | Method for preparing sweet and fragrant type electric heating cigarette liquid |
| CN103627525A (en) * | 2013-09-11 | 2014-03-12 | 上海聚华科技股份有限公司 | Method for preparing tobacco essential oil by reduced pressure distillation |
| CN104026734B (en) * | 2014-06-13 | 2016-04-13 | 广西中烟工业有限责任公司 | A kind of preparation method of tobacco flavor electronics tobacco tar |
| CN104026729B (en) * | 2014-06-25 | 2015-11-04 | 湖南中烟工业有限责任公司 | A kind of electronic cigarette liquid with burnt odor fragrance |
-
2014
- 2014-11-12 CN CN201511007089.5A patent/CN105433431B/en active Active
- 2014-11-12 CN CN201410633690.4A patent/CN104287084B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101806685A (en) * | 2010-04-22 | 2010-08-18 | 上海烟草（集团）公司 | Tobacco aerobic cracking analysis method and sample injection system |
| CN104026728A (en) * | 2014-06-25 | 2014-09-10 | 湖南中烟工业有限责任公司 | Electronic tobacco juice with baking aroma |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105433431A (en) | 2016-03-30 |
| CN104287084B (en) | 2016-06-08 |
| CN104287084A (en) | 2015-01-21 |
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