CN1054215A - Flexible composite veneer for decoration - Google Patents
Flexible composite veneer for decoration Download PDFInfo
- Publication number
- CN1054215A CN1054215A CN 91107123 CN91107123A CN1054215A CN 1054215 A CN1054215 A CN 1054215A CN 91107123 CN91107123 CN 91107123 CN 91107123 A CN91107123 A CN 91107123A CN 1054215 A CN1054215 A CN 1054215A
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- Prior art keywords
- paper
- decoration
- flexible composite
- drying
- dipping
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Abstract
Flexible composite veneer for decoration belongs to furniture and indoor decoration plate.Adopt modified cyanurotriamide dipping overlay paper and facing paper, with ethene based thermoplastic resin immersion non-woven fabrics bottom, drying hot pressing forms, cost is low, good toughness, bending radius reaches more than the 19mm, can be used for plane and curved surface and decorates, and paper using amount is few, minimum thickness reaches 0.25mm, the back side does not need the sand hair, is easy to paste with other wood-based plate, and manufacturing process is simple, pollution-free, the not residual Toxic of interlayer, be a kind ofly inexpensively, attractive in appearance, wear-resisting, anti-scald, anti-drying, chemical-resistant resistance pollute the decorative panel of the good decorate properties of tool.
Description
The invention belongs to class of jobs, particularly furniture and indoor environment decorative sheet.
Disclosed CN1039999 A " multiple layer decorative compound sheet and preparation method " selects all kinds of corners timber for use, utilize natural vein, the color scheme of material to be spliced into beautiful pattern, adopt the adhesive pressing to form, cost is reduced, but it can only be used for plane decoration, and toughness is low, easily come unstuck, the production cycle is long, and cold pressing process reaches the release of 24 hours ability, make material cured, can only be used for environmental decoration.CN1039861 A " improving resin decorating veneer sheet ", though provide a kind of decorative panel that adopts melamine dip-coating surface paper, facing paper and the pressing of modification urea-formaldehyde dip-coating bottom paper to form to reduce cost of material, but, toughness and intensity all can not obviously improve, on the contrary the possibility that fragility is increased.More than all residual toxic phenol of pressing interlayer of two kinds of laminates, paper consuming amount is big, generally all bonding with 6 to 8 layers of paper, thickness just can reach the working strength requirement more than 0.6mm, and bending radius requires greater than 50mm, though can be used for furniture upholstery when using, but only limit to the plane decoration plate, the sheet material back side must the sand hair during use, just is easy to stick on the wood-based plate, and often deforms because of the bigger internal stress of generation again after pasting and phenomenon such as come unstuck.At the deficiency of above invention, the invention provides a kind of flexible composite veneer for decoration.
The objective of the invention is with overlay paper, facing paper and nonwoven is raw material, with modified cyanurotriamide and ethene based thermoplastic resin is that impregnating agent is to improve performance, a kind of little plane and dual-purpose flexible composite veneer for decoration of curved surface of good toughness, intensity height, thickness that can be used for curved surface of method production of employing drying, laminating hot pressing.
Purpose of the present invention can be realized by following measure.Produce the method for decorative laminate, be with special-purpose paper tabulation layer, decorative layer and bottom, stacked again pressing forms decorative panel behind the dip-coating resin, it is characterized in that being is structure sheaf by overlay paper, facing paper and nonwoven, overlay paper and facing paper dipping modified cyanurotriamide thermosetting resin, nonwoven dipping ethene based thermoplastic resin, the flexible composite veneer for decoration that drying, laminating hot pressing form.
Being prepared as follows of modified cyanurotriamide resin:
Prescription: the raw material proportioning is calculated with mol ratio
Melamine C
3H
6N
61
Formaldehyde CH
2O 1.5～3.0
Water H
2O 3～4
The consumption of modifier A is 5～20% of a mole.
Because melamine and formaldehyde carry out addition reaction in acid, alkaline medium, form various melamine methylols:
With the melamine water-soluble resin of modifier A modification, make the increase of dipping property stable resin, resin flow enhancing during curing, be used for flooding overlay paper and facing paper after, the methylol-CH in the resin
2OH and carboxyl-COO-ester group-COOR reacts, because in the cross-linked network-CH
2The increase of-key increases the flexibility of total, through the overlay paper and the decorative paper layer poststack of dipping modified cyanurotriamide, is layered on the nonwoven of dipping ethene based thermoplastic resin again.Because nonwoven itself has flexibility and stronger toughness, this just makes through the overlay paper of dipping modified cyanurotriamide, facing paper and stacked together after drying through the nonwoven of dipping ethene based thermoplastic resin, becomes possibility through being hot pressed into flexible composite veneer for decoration again.
Advantage of the present invention is: except that having existing decorative laminate superior function, pattern is true to nature, in a great variety, good wear-resistingly, anti-scald, anti-drying, chemical-resistant resistance pollution etc. are good ornamental outside owing to make bottom heat of immersion plastic resin with nonwoven, its vinyl acetate content reaches more than 80%, be strong polar group, so the back side does not need the sand hair and be easy to paste the toughness height with other wood-based plate, its bending radius can reach more than the 19mm, not only can be used for the plane but also can be used for the curved surface decorative sheet.Because paper consuming amount is low, minimum thickness can reach 0.25mm, and the ply of paper number is few, its thickness is decided by nonwoven, the consumption amount of resin is few, and the wood-based plate internal stress is little after pasting, and is difficult for bending and coming unstuck, hot pressing time is short, between 30-60min, shortened process time greatly, tensile strength is 100mpa, ball falling impact does not have cracking, no bubbling phenomenon after the experiment hot-water soak.Compared with the prior art the present invention tabulates in following:
Flexible composite laminate and commercially available decorative laminate comparison sheet
| Numbering | Project | Flexible composite veneer for decoration | Existing commercially available decorative laminate |
| 1 | The stacked number of plies | Overlay paper+facing paper+nonwoven is totally 3 layers of composition | Overlay paper+facing paper+bottom paper is totally 6～8 layers of composition |
| 2 | Impregnating resin | Modified cyanurotriamide resin ethene based thermoplastic resin | Melmac phenolic resins |
| 3 | Manufacturing procedure | Few (stacked number is few, and the backboard face does not need the sand hair) | Many (stacked number is many, the essential sand hair of backboard face) |
| 4 | Minimum thickness | 0.25mm | ＞0.6mm |
| 5 | Crooked least radius | 19mm | ＞50mm |
| 6 | Tensile strength | (the broken rate of carrying damage is big) greatly | Little (the broken rate of carrying damage is big) |
| Numbering | Project | Flexible composite veneer for decoration | Existing commercially available decorative laminate |
| 7 | Sticking Quality | Good | Difference |
| 8 | Cost | Low | High |
The invention will be further described below in conjunction with embodiment.With specification is 25～30g/m
2Dedicated paper be overlay paper, with 80～120g/m
2Dedicated paper make facing paper, the pickup of overlay paper and facing paper dipping modified cyanurotriamide resin is 100～160g/m
2, with 60～400g/m
2Nonwoven step dipping ethene based thermoplastic resin, pickup is 50～100g/m
2With overlay paper, facing paper and nonwoven drying behind the dipping, drying and volatilizing thing content is controlled at 8～12%, stacks gradually, hot pressing again, and hot pressing condition is: pressure 60～100mpa, 125～160 ℃ of temperature, time 30～60min.
Claims (1)
1, produces the method for decorative laminate, be with special-purpose paper tabulation layer, decorative layer and bottom, behind the dip-coating resin glue, stacked pressing forms, it is characterized in that making structure sheaf with overlay paper, facing paper and nonwoven, overlay paper and facing paper dipping modified cyanurotriamide thermosetting resin, nonwoven dipping ethene based thermoplastic resin, the flexible composite veneer for decoration that drying, laminating hot pressing form.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91107123 CN1054215A (en) | 1991-01-28 | 1991-01-28 | Flexible composite veneer for decoration |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 91107123 CN1054215A (en) | 1991-01-28 | 1991-01-28 | Flexible composite veneer for decoration |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1054215A true CN1054215A (en) | 1991-09-04 |
Family
ID=4908483
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91107123 Withdrawn CN1054215A (en) | 1991-01-28 | 1991-01-28 | Flexible composite veneer for decoration |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1054215A (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100348409C (en) * | 2003-01-08 | 2007-11-14 | 雅马哈发动机株式会社 | Decorative sheet, shaped product, automobile, and method for producing shaped product |
| CN100443685C (en) * | 2006-03-08 | 2008-12-17 | 辛集市家美特地板有限公司 | Wear-resisting stacked real-wood floor board and mfg. method |
| CN100535357C (en) * | 2004-06-04 | 2009-09-02 | Baa股份开发有限公司 | Cladding system and cladding method |
| CN101954767A (en) * | 2010-08-02 | 2011-01-26 | 庄启程 | Flexional thermosetting resin impregnated paper high-pressure laminating plate |
| CN101954768A (en) * | 2010-08-02 | 2011-01-26 | 庄启程 | Flexible thermosetting resin impregnated paper high-pressure laminated plate |
| CN103171211A (en) * | 2013-03-12 | 2013-06-26 | 河南永威安防股份有限公司 | Granulation-free ecological plate high-pressure decorative surface material and manufacturing method thereof |
| US8627631B2 (en) | 2000-06-20 | 2014-01-14 | Flooring Industries Limited, Sarl | Floor covering |
| US9255414B2 (en) | 2000-03-31 | 2016-02-09 | Pergo (Europe) Ab | Building panels |
| US9464444B2 (en) | 2010-01-15 | 2016-10-11 | Pergo (Europe) Ab | Set of panels comprising retaining profiles with a separate clip and method for inserting the clip |
| US9464443B2 (en) | 1998-10-06 | 2016-10-11 | Pergo (Europe) Ab | Flooring material comprising flooring elements which are assembled by means of separate flooring elements |
| US9593491B2 (en) | 2010-05-10 | 2017-03-14 | Pergo (Europe) Ab | Set of panels |
| CN107053373A (en) * | 2016-11-29 | 2017-08-18 | 王兆进 | A kind of preparation method of ornamental fiberboard |
| CN108215429A (en) * | 2017-12-29 | 2018-06-29 | 肖圣洁 | A kind of thermosetting resin-impregnated paper high-pressure laminated board and its preparation process |
| CN110499670A (en) * | 2019-09-02 | 2019-11-26 | 临沂大瑞木业有限公司 | A kind of multifunctionality impregnates production and the application method of paper composites |
| CN110641086A (en) * | 2019-11-14 | 2020-01-03 | 临沂大瑞木业有限公司 | Magnesite cement floor |
-
1991
- 1991-01-28 CN CN 91107123 patent/CN1054215A/en not_active Withdrawn
Cited By (39)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9464443B2 (en) | 1998-10-06 | 2016-10-11 | Pergo (Europe) Ab | Flooring material comprising flooring elements which are assembled by means of separate flooring elements |
| US9255414B2 (en) | 2000-03-31 | 2016-02-09 | Pergo (Europe) Ab | Building panels |
| US10626619B2 (en) | 2000-03-31 | 2020-04-21 | Unilin Nordic Ab | Flooring material |
| US10233653B2 (en) | 2000-03-31 | 2019-03-19 | Pergo (Europe) Ab | Flooring material |
| US10156078B2 (en) | 2000-03-31 | 2018-12-18 | Pergo (Europe) Ab | Building panels |
| US9677285B2 (en) | 2000-03-31 | 2017-06-13 | Pergo (Europe) Ab | Building panels |
| US9611656B2 (en) | 2000-03-31 | 2017-04-04 | Pergo (Europe) Ab | Building panels |
| US9534397B2 (en) | 2000-03-31 | 2017-01-03 | Pergo (Europe) Ab | Flooring material |
| US9316006B2 (en) | 2000-03-31 | 2016-04-19 | Pergo (Europe) Ab | Building panels |
| US9260869B2 (en) | 2000-03-31 | 2016-02-16 | Pergo (Europe) Ab | Building panels |
| US9388585B1 (en) | 2000-06-20 | 2016-07-12 | Flooring Industries Limited, Sarl | Floor covering |
| US9376823B1 (en) | 2000-06-20 | 2016-06-28 | Flooring Industries Limited, Sarl | Floor covering |
| US9234356B2 (en) | 2000-06-20 | 2016-01-12 | Flooring Industries Limited, Sarl | Floor covering |
| US10407920B2 (en) | 2000-06-20 | 2019-09-10 | Flooring Industries Limited, Sarl | Floor covering |
| US8904729B2 (en) | 2000-06-20 | 2014-12-09 | Flooring Industries Limited, Sarl | Floor covering |
| US8793958B2 (en) | 2000-06-20 | 2014-08-05 | Flooring Industries Limited, Sarl | Floor covering |
| US9334657B2 (en) | 2000-06-20 | 2016-05-10 | Flooring Industries Limted, Sarl | Floor covering |
| US9624676B2 (en) | 2000-06-20 | 2017-04-18 | Flooring Industries Limited, Sarl | Floor covering |
| US9068356B2 (en) | 2000-06-20 | 2015-06-30 | Flooring Industries Limited, Sarl | Floor covering |
| US9388586B1 (en) | 2000-06-20 | 2016-07-12 | Flooring Industries Limited, Sarl | Floor covering |
| US9394699B1 (en) | 2000-06-20 | 2016-07-19 | Flooring Industries Limited, Sarl | Floor covering |
| US10125498B2 (en) | 2000-06-20 | 2018-11-13 | Flooring Industries Limited, Sarl | Floor covering |
| US8631625B2 (en) | 2000-06-20 | 2014-01-21 | Flooring Industries Limited, Sarl | Floor covering |
| US9482013B2 (en) | 2000-06-20 | 2016-11-01 | Flooring Industries Limited, Sarl | Floor covering |
| US8627631B2 (en) | 2000-06-20 | 2014-01-14 | Flooring Industries Limited, Sarl | Floor covering |
| US9856657B2 (en) | 2000-06-20 | 2018-01-02 | Flooring Industries Limited, Sarl | Floor covering |
| CN100348409C (en) * | 2003-01-08 | 2007-11-14 | 雅马哈发动机株式会社 | Decorative sheet, shaped product, automobile, and method for producing shaped product |
| CN100535357C (en) * | 2004-06-04 | 2009-09-02 | Baa股份开发有限公司 | Cladding system and cladding method |
| CN100443685C (en) * | 2006-03-08 | 2008-12-17 | 辛集市家美特地板有限公司 | Wear-resisting stacked real-wood floor board and mfg. method |
| US9464444B2 (en) | 2010-01-15 | 2016-10-11 | Pergo (Europe) Ab | Set of panels comprising retaining profiles with a separate clip and method for inserting the clip |
| US9593491B2 (en) | 2010-05-10 | 2017-03-14 | Pergo (Europe) Ab | Set of panels |
| CN101954768A (en) * | 2010-08-02 | 2011-01-26 | 庄启程 | Flexible thermosetting resin impregnated paper high-pressure laminated plate |
| CN101954767A (en) * | 2010-08-02 | 2011-01-26 | 庄启程 | Flexional thermosetting resin impregnated paper high-pressure laminating plate |
| CN103171211A (en) * | 2013-03-12 | 2013-06-26 | 河南永威安防股份有限公司 | Granulation-free ecological plate high-pressure decorative surface material and manufacturing method thereof |
| CN103171211B (en) * | 2013-03-12 | 2015-05-20 | 河南永威安防股份有限公司 | Granulation-free ecological plate high-pressure decorative surface material and manufacturing method thereof |
| CN107053373A (en) * | 2016-11-29 | 2017-08-18 | 王兆进 | A kind of preparation method of ornamental fiberboard |
| CN108215429A (en) * | 2017-12-29 | 2018-06-29 | 肖圣洁 | A kind of thermosetting resin-impregnated paper high-pressure laminated board and its preparation process |
| CN110499670A (en) * | 2019-09-02 | 2019-11-26 | 临沂大瑞木业有限公司 | A kind of multifunctionality impregnates production and the application method of paper composites |
| CN110641086A (en) * | 2019-11-14 | 2020-01-03 | 临沂大瑞木业有限公司 | Magnesite cement floor |
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| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication |