CN105421066A - 一种天然混合纺织整染抗菌助剂 - Google Patents
一种天然混合纺织整染抗菌助剂 Download PDFInfo
- Publication number
- CN105421066A CN105421066A CN201610017484.XA CN201610017484A CN105421066A CN 105421066 A CN105421066 A CN 105421066A CN 201610017484 A CN201610017484 A CN 201610017484A CN 105421066 A CN105421066 A CN 105421066A
- Authority
- CN
- China
- Prior art keywords
- natural
- adopts
- mixed textile
- accessory ingredient
- natural mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004753 textile Substances 0.000 title claims abstract description 25
- 230000000845 anti-microbial effect Effects 0.000 title abstract description 5
- 238000004043 dyeing Methods 0.000 title abstract 4
- 239000003242 anti bacterial agent Substances 0.000 claims abstract description 25
- 239000000839 emulsion Substances 0.000 claims abstract description 19
- 239000002086 nanomaterial Substances 0.000 claims abstract description 16
- 229920002472 Starch Polymers 0.000 claims abstract description 15
- 235000019698 starch Nutrition 0.000 claims abstract description 15
- 239000008107 starch Substances 0.000 claims abstract description 14
- 239000002270 dispersing agent Substances 0.000 claims abstract description 13
- 239000003999 initiator Substances 0.000 claims abstract description 13
- 239000000049 pigment Substances 0.000 claims abstract description 7
- 230000002421 anti-septic effect Effects 0.000 claims description 42
- 230000000844 anti-bacterial effect Effects 0.000 claims description 28
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 24
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 24
- 239000004615 ingredient Substances 0.000 claims description 21
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 18
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 7
- 229920002261 Corn starch Polymers 0.000 claims description 6
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 6
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004599 antimicrobial Substances 0.000 claims description 6
- 239000008120 corn starch Substances 0.000 claims description 6
- 235000019441 ethanol Nutrition 0.000 claims description 6
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 6
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 6
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 6
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 6
- 239000002904 solvent Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000004408 titanium dioxide Substances 0.000 claims description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 6
- 229920002101 Chitin Polymers 0.000 claims description 4
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 claims description 4
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 claims description 4
- 235000003351 Brassica cretica Nutrition 0.000 claims description 3
- 235000003343 Brassica rupestris Nutrition 0.000 claims description 3
- SCKXCAADGDQQCS-UHFFFAOYSA-N Performic acid Chemical compound OOC=O SCKXCAADGDQQCS-UHFFFAOYSA-N 0.000 claims description 3
- 229910001870 ammonium persulfate Inorganic materials 0.000 claims description 3
- QKSKPIVNLNLAAV-UHFFFAOYSA-N bis(2-chloroethyl) sulfide Chemical compound ClCCSCCCl QKSKPIVNLNLAAV-UHFFFAOYSA-N 0.000 claims description 3
- 239000004359 castor oil Substances 0.000 claims description 3
- 235000019438 castor oil Nutrition 0.000 claims description 3
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 3
- 235000010460 mustard Nutrition 0.000 claims description 3
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 2
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 2
- 235000019394 potassium persulphate Nutrition 0.000 claims description 2
- 244000056139 Brassica cretica Species 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000009286 beneficial effect Effects 0.000 abstract description 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 description 6
- 239000002002 slurry Substances 0.000 description 6
- 239000000463 material Substances 0.000 description 4
- 238000004513 sizing Methods 0.000 description 3
- 241000219198 Brassica Species 0.000 description 2
- 239000003899 bactericide agent Substances 0.000 description 2
- 238000001514 detection method Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000008520 organization Effects 0.000 description 2
- 239000011941 photocatalyst Substances 0.000 description 2
- 230000008569 process Effects 0.000 description 2
- 238000009955 starching Methods 0.000 description 2
- 206010010356 Congenital anomaly Diseases 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000001699 photocatalysis Effects 0.000 description 1
- 238000007146 photocatalysis Methods 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 230000000452 restraining effect Effects 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 238000009941 weaving Methods 0.000 description 1
- 238000004804 winding Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
- D06M15/11—Starch or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
本发明公开了一种天然混合纺织整染抗菌助剂，其配方包括：淀粉20-300份、纳米材料20-50份、颜料9-20份、水性引发剂2-5份、混合抗菌剂10-15份、分散剂5-8份和乳液15-19份。本发明提供的产品有利于降低环境负荷，提高生产效率，有利于降低生产成本，粘附力适中。
Description
技术领域
本发明属于纺织化学技术领域，具体涉及一种天然混合纺织整染抗菌助剂。
背景技术
浆料使纱条表面被覆一层光滑、耐磨、柔韧且有一定强度的浆膜，令纱条表面的缠绕纤维紧贴纱条的主干，降低纱条表面的摩擦系数，同时使部分浆液渗入纱线内部，增加纤维之间的粘附力，提高纱线的抗拉强度，以适应织造过程中的大张力、中打纬，减少断头提高效率。
纺织浆料发展到时至今日，已经不能满足各种各样的纱线品种以及浆纱工艺的要求，传统的三大浆料体系PVA、聚丙烯酸、变性淀粉，无论怎么优化组合，缺陷仍然十分明显。PVA由于在退浆后存在于浆液中难于降解，目前行业协会已经明确提出在上浆工艺中要少用或不用PVA，即使暂时抛开环保上浆的因素，行业也不能再将PVA即聚乙烯醇，视为“万能浆料”了，因为在高档细支高密的纱线上浆过程中，PVA的先天高强力反而成为一种制约因素，很多时候降低了织机效率。丙烯酸类浆料由于原料价格因素，越来越不具备性价比优势，且浆膜太软，并存在吸湿再粘的风险，在现有浆料格局中，逐渐沦为配角。变性淀粉由于浆膜脆硬，对纱线粘附力有限，使其虽然具有环保优势，但是在上浆中却无法单独使用。
发明内容
本发明的目的是提供一种天然混合纺织整染抗菌助剂，有利于降低环境负荷，提高生产效率，有利于降低生产成本，粘附力适中。
一种天然混合纺织整染抗菌助剂，其配方包括：淀粉20-300份、纳米材料20-50份、颜料9-20份、水性引发剂2-5份、混合抗菌剂10-15份、分散剂5-8份和乳液15-19份。
所述淀粉采用含水量为5-10%的玉米淀粉溶液。
所述纳米材料采用光触媒材料，所述纳米材料粒径为100-300nm。
所述纳米材料采用纳米二氧化钛，所述二氧化钛采用锐钛型二氧化钛，粒径为150-200nm。
所述水性引发剂采用过氧化氢、带有Fe2+的过氧化氢、带有亚硫酸氢盐的过氧化氢、叔丁基过氧化氢、过氧甲酸、过氧乙酸、过硫酸铵、过硫酸钠或过硫酸钾中的任意一种或至少两种的混合物。
所述抗菌剂采用天然抗菌剂与无机抗菌剂的混合物，所述天然抗菌剂与无机抗菌剂的比例为2:1。
所述无机抗菌剂采用纳米银抗菌剂。
所述天然抗菌剂为甲壳素、芥末、蓖麻油中的一种。
所述抗菌剂的混合方法是以无水乙醇为溶剂，先后加入天然抗菌剂与无机抗菌剂进行搅拌，以压力0.4MPa，温度60℃条件下密封反应0.5小时，冷却至室温。
所述乳液采用苯丙乳液。
所述分散剂采用聚乙烯吡咯烷酮溶液。
所述聚乙烯吡咯烷酮溶液是聚乙烯吡咯烷酮含量为8-18%的乙醇水溶液。
所述乙醇水溶液中乙醇含量为45-85%。
与现有技术相比，本发明具有以下有益效果：
1、本发明采用的混合杀菌剂，解决了天然杀菌剂耐热性较差，杀菌率低的问题。
2、本发明采用的纳米材料以光触媒材料为主，具有良好的接触性抗菌作用，能够起到抗菌效果长期有效，实用性强。
3、本发明提供的产品有利于降低环境负荷，提高生产效率，有利于降低生产成本，粘附力适中。
4、本发明无毒、无味、无腐蚀性，不易燃，属环保性产品，适用范围广，使用方便。
具体实施方式
下面结合实施例对本发明做进一步描述：
实施例1
一种天然混合纺织整染抗菌助剂，其配方包括：淀粉20份、纳米材料20份、颜料9份、水性引发剂2份、混合抗菌剂10份、分散剂5份和乳液15份。
所述淀粉采用含水量为5%的玉米淀粉溶液。
所述纳米材料采用纳米二氧化钛，所述二氧化钛采用锐钛型二氧化钛，粒径为150nm。
所述水性引发剂采用过氧化氢。
所述抗菌剂采用天然抗菌剂与无机抗菌剂的混合物，所述天然抗菌剂与无机抗菌剂的比例为2:1。
所述无机抗菌剂采用纳米银抗菌剂。
所述天然抗菌剂为甲壳素。
所述抗菌剂的混合方法是以无水乙醇为溶剂，先后加入天然抗菌剂与无机抗菌剂进行搅拌，以压力0.4MPa，温度60℃条件下密封反应0.5小时，冷却至室温。
所述乳液采用苯丙乳液。
所述分散剂采用聚乙烯吡咯烷酮溶液。
所述聚乙烯吡咯烷酮溶液是聚乙烯吡咯烷酮含量为8%的乙醇水溶液。
所述乙醇水溶液中乙醇含量为45%。
实施例2
一种天然混合纺织整染抗菌助剂，其配方包括：淀粉300份、纳米材料50份、颜料20份、水性引发剂5份、混合抗菌剂15份、分散剂8份和乳液19份。
所述淀粉采用含水量为10%的玉米淀粉溶液。
所述纳米材料采用纳米二氧化钛，所述二氧化钛采用锐钛型二氧化钛，粒径为200nm。
所述水性引发剂采用过氧甲酸。
所述抗菌剂采用天然抗菌剂与无机抗菌剂的混合物，所述天然抗菌剂与无机抗菌剂的比例为2:1。
所述无机抗菌剂采用纳米银抗菌剂。
所述天然抗菌剂为芥末。
所述抗菌剂的混合方法是以无水乙醇为溶剂，先后加入天然抗菌剂与无机抗菌剂进行搅拌，以压力0.4MPa，温度60℃条件下密封反应0.5小时，冷却至室温。
所述乳液采用苯丙乳液。
所述分散剂采用聚乙烯吡咯烷酮溶液。
所述聚乙烯吡咯烷酮溶液是聚乙烯吡咯烷酮含量为18%的乙醇水溶液。
所述乙醇水溶液中乙醇含量为85%。
实施例3
一种天然混合纺织整染抗菌助剂，其配方包括：淀粉100份、纳米材料30份、颜料12份、水性引发剂3份、混合抗菌剂12份、分散剂6份和乳液17份。
所述淀粉采用含水量为7%的玉米淀粉溶液。
所述纳米材料采用纳米二氧化钛，所述二氧化钛采用锐钛型二氧化钛，粒径为180nm。
所述水性引发剂采用过硫酸铵。
所述抗菌剂采用天然抗菌剂与无机抗菌剂的混合物，所述天然抗菌剂与无机抗菌剂的比例为2:1。
所述无机抗菌剂采用纳米银抗菌剂。
所述天然抗菌剂为蓖麻油。
所述抗菌剂的混合方法是以无水乙醇为溶剂，先后加入天然抗菌剂与无机抗菌剂进行搅拌，以压力0.4MPa，温度60℃条件下密封反应0.5小时，冷却至室温。
所述乳液采用苯丙乳液。
所述分散剂采用聚乙烯吡咯烷酮溶液。
所述聚乙烯吡咯烷酮溶液是聚乙烯吡咯烷酮含量为10%的乙醇水溶液。
所述乙醇水溶液中乙醇含量为60%。
实施例4
一种天然混合纺织整染抗菌助剂，其配方包括：淀粉200份、纳米材料35份、颜料14份、水性引发剂4份、混合抗菌剂14份、分散剂7份和乳液18份。
所述淀粉采用含水量为9%的玉米淀粉溶液。
所述纳米材料采用纳米二氧化钛，所述二氧化钛采用锐钛型二氧化钛，粒径为187nm。
所述水性引发剂采用过硫酸钠。
所述抗菌剂采用天然抗菌剂与无机抗菌剂的混合物，所述天然抗菌剂与无机抗菌剂的比例为2:1。
所述无机抗菌剂采用纳米银抗菌剂。
所述天然抗菌剂为甲壳素。
所述抗菌剂的混合方法是以无水乙醇为溶剂，先后加入天然抗菌剂与无机抗菌剂进行搅拌，以压力0.4MPa，温度60℃条件下密封反应0.5小时，冷却至室温。
所述乳液采用苯丙乳液。
所述分散剂采用聚乙烯吡咯烷酮溶液。
所述聚乙烯吡咯烷酮溶液是聚乙烯吡咯烷酮含量为16%的乙醇水溶液。
所述乙醇水溶液中乙醇含量为68%。
以国标《GB/T23763-2009光催化抗菌材料及制品抗菌性能的评价》为依据进行抗菌效果检测，检测效果如下：
| 实施例1 | 实施例2 | 实施例3 | 实施例4 | |
| 总抗菌率 | 99.91% | 99.94% | 99.95% | 99.99% |
| 重复性 | 99% | 99% | 99% | 99% |
经检测发现，本发明提供的抗菌助剂能够具有良好的抗菌效果以及良好的抗菌稳定性，重复性良好，能够长期使用。
以上所述仅为本发明的实施例，并不限制本发明，凡采用等同替换或等效变换的方式所获得的技术方案，均落在本发明的保护范围内。
Claims (12)
1.一种天然混合纺织整染抗菌助剂，其配方包括：淀粉20-300份、纳米材料20-50份、颜料9-20份、水性引发剂2-5份、混合抗菌剂10-15份、分散剂5-8份和乳液15-19份。
2.根据权利要求1所述的一种天然混合纺织整染抗菌助剂，其特征在于，所述淀粉采用含水量为5-10%的玉米淀粉溶液。
3.根据权利要求1所述的一种天然混合纺织整染抗菌助剂，其特征在于，所述纳米材料采用纳米二氧化钛，所述二氧化钛采用锐钛型二氧化钛，粒径为150-200nm。
4.根据权利要求1所述的一种天然混合纺织整染抗菌助剂，其特征在于，所述水性引发剂采用过氧化氢、带有Fe2+的过氧化氢、带有亚硫酸氢盐的过氧化氢、叔丁基过氧化氢、过氧甲酸、过氧乙酸、过硫酸铵、过硫酸钠或过硫酸钾中的任意一种或至少两种的混合物。
5.根据权利要求1所述的一种天然混合纺织整染抗菌助剂，其特征在于，所述抗菌剂采用天然抗菌剂与无机抗菌剂的混合物，所述天然抗菌剂与无机抗菌剂的比例为2:1。
6.根据权利要求5所述的一种天然混合纺织整染抗菌助剂，其特征在于，所述无机抗菌剂采用纳米银抗菌剂。
7.根据权利要求5所述的一种天然混合纺织整染抗菌助剂，其特征在于，所述天然抗菌剂为甲壳素、芥末、蓖麻油中的一种。
8.根据权利要求5所述的一种天然混合纺织整染抗菌助剂，其特征在于，所述抗菌剂的混合方法是以无水乙醇为溶剂，先后加入天然抗菌剂与无机抗菌剂进行搅拌，以压力0.4MPa，温度60℃条件下密封反应0.5小时，冷却至室温。
9.根据权利要求1所述的一种天然混合纺织整染抗菌助剂，其特征在于，所述乳液采用苯丙乳液。
10.根据权利要求1所述的一种天然混合纺织整染抗菌助剂，其特征在于，所述分散剂采用聚乙烯吡咯烷酮溶液。
11.根据权利要求10所述的一种天然混合纺织整染抗菌助剂，其特征在于，所述聚乙烯吡咯烷酮溶液是聚乙烯吡咯烷酮含量为8-18%的乙醇水溶液。
12.根据权利要求11所述的一种天然混合纺织整染抗菌助剂，其特征在于，所述乙醇水溶液中乙醇含量为45-85%。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610017484.XA CN105421066A (zh) | 2016-01-12 | 2016-01-12 | 一种天然混合纺织整染抗菌助剂 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610017484.XA CN105421066A (zh) | 2016-01-12 | 2016-01-12 | 一种天然混合纺织整染抗菌助剂 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105421066A true CN105421066A (zh) | 2016-03-23 |
Family
ID=55499585
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610017484.XA Pending CN105421066A (zh) | 2016-01-12 | 2016-01-12 | 一种天然混合纺织整染抗菌助剂 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105421066A (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105803767A (zh) * | 2016-04-29 | 2016-07-27 | 江苏苏扬服帽有限公司 | 一种高效抑菌抗静电剂、其制备方法及其应用 |
| CN106192403A (zh) * | 2016-07-10 | 2016-12-07 | 中山市绿浪助剂有限公司 | 一种天然混合纺织整染抗菌助剂 |
| CN113152096A (zh) * | 2021-04-28 | 2021-07-23 | 广东科峰新材料科技有限公司 | 抗菌抗静电的环保型纺织助剂及其制备方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103194902A (zh) * | 2013-04-19 | 2013-07-10 | 徐州众恒淀粉科技有限公司 | 一种用于纺织上浆的纺织助剂及其制备方法 |
| CN104233782A (zh) * | 2014-08-29 | 2014-12-24 | 句容市石狮冲压件厂 | 一种户外服用织物处理剂 |
| CN104358120A (zh) * | 2014-11-28 | 2015-02-18 | 杨帆 | 一种棉织物整理用印染前助剂 |
| CN104695207A (zh) * | 2013-12-04 | 2015-06-10 | 郑辉安 | 一种纺织浆料助剂 |
| CN105113242A (zh) * | 2015-09-11 | 2015-12-02 | 无锡市长安曙光手套厂 | 一种用于纺织上浆的纺织助剂及其制备方法 |
-
2016
- 2016-01-12 CN CN201610017484.XA patent/CN105421066A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103194902A (zh) * | 2013-04-19 | 2013-07-10 | 徐州众恒淀粉科技有限公司 | 一种用于纺织上浆的纺织助剂及其制备方法 |
| CN104695207A (zh) * | 2013-12-04 | 2015-06-10 | 郑辉安 | 一种纺织浆料助剂 |
| CN104233782A (zh) * | 2014-08-29 | 2014-12-24 | 句容市石狮冲压件厂 | 一种户外服用织物处理剂 |
| CN104358120A (zh) * | 2014-11-28 | 2015-02-18 | 杨帆 | 一种棉织物整理用印染前助剂 |
| CN105113242A (zh) * | 2015-09-11 | 2015-12-02 | 无锡市长安曙光手套厂 | 一种用于纺织上浆的纺织助剂及其制备方法 |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105803767A (zh) * | 2016-04-29 | 2016-07-27 | 江苏苏扬服帽有限公司 | 一种高效抑菌抗静电剂、其制备方法及其应用 |
| CN106192403A (zh) * | 2016-07-10 | 2016-12-07 | 中山市绿浪助剂有限公司 | 一种天然混合纺织整染抗菌助剂 |
| CN113152096A (zh) * | 2021-04-28 | 2021-07-23 | 广东科峰新材料科技有限公司 | 抗菌抗静电的环保型纺织助剂及其制备方法 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105421066A (zh) | 一种天然混合纺织整染抗菌助剂 | |
| CN105544207A (zh) | 一种水性纺织整染抗菌助剂 | |
| EP1897893B1 (de) | Stärke-chitosan-mischung, verfahren zu ihrer herstellung und ihre verwendung | |
| CN102850878A (zh) | 一种耐候外墙漆及其制备方法 | |
| CN105255262A (zh) | 一种水性抗菌涂料 | |
| CN105113242A (zh) | 一种用于纺织上浆的纺织助剂及其制备方法 | |
| CN103666275A (zh) | 一种水性防菌防霉涂料 | |
| CN107447592A (zh) | 一种用于瓦楞纸板的疏水抗菌剂和疏水抗菌增强瓦楞纸板及制备方法 | |
| CN104947426A (zh) | 一种改进的淀粉纺织浆料 | |
| CN103046313A (zh) | 一种布料整理液 | |
| CN105463829A (zh) | 一种油性纺织整染抗菌助剂 | |
| CN105950026A (zh) | 一种纸管胶 | |
| CN107841875A (zh) | 水性聚氨酯浆料 | |
| CN107151829A (zh) | 一种抗菌抗紫外自清洁复合型涤纶的制备方法 | |
| CN102372977A (zh) | 一种纳米弹性乳胶漆 | |
| CN101545204A (zh) | 纺织经纱上浆浆料 | |
| CN106192403A (zh) | 一种天然混合纺织整染抗菌助剂 | |
| CN106381065A (zh) | 一种新型的水性防锈涂料 | |
| CN105647312A (zh) | 一种抗菌耐酸碱防腐涂料 | |
| CN104046065A (zh) | 一种防晒乳胶漆 | |
| CN106223118A (zh) | 一种除菌防臭的防锈原纸及其制备方法 | |
| CN114318948A (zh) | 一种抗菌浸渍纸及其制备方法与应用 | |
| CN108149472A (zh) | 一种环保型纺织浆料 | |
| CN105885558A (zh) | 一种具有高附着力耐腐蚀性能的涂料及其制备方法 | |
| CN106010360A (zh) | 一种墙纸用湿胶及其制备方法 |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160323 |