CN105419550B - A kind of one-component coating composition modelled after an antique - Google Patents
A kind of one-component coating composition modelled after an antique Download PDFInfo
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- CN105419550B CN105419550B CN201511027975.4A CN201511027975A CN105419550B CN 105419550 B CN105419550 B CN 105419550B CN 201511027975 A CN201511027975 A CN 201511027975A CN 105419550 B CN105419550 B CN 105419550B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D145/00—Coating compositions based on homopolymers or copolymers of compounds having no unsaturated aliphatic radicals in a side chain, and having one or more carbon-to-carbon double bonds in a carbocyclic or in a heterocyclic system; Coating compositions based on derivatives of such polymers
- C09D145/02—Coumarone-indene polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention provides a kind of one-component coating compositions modelled after an antique, include the cosolvent of the true solvent and 10~25 parts by weight of the composite drier of the wetting dispersing agent of the paint film property reinforcing aids of the coumarone indene resin of 40~70 parts by weight, 4~6 parts by weight, 0.2~0.4 parts by weight, 0.3~0.6 parts by weight, 13~30 parts by weight.Compared with prior art, the weatherability of one-component provided by the invention coating modelled after an antique, paint film is outstanding, and acid resistance, has excellent water-resistance at alkali resistance, and flexibility is good, and the adhesive force on common ground is good, and high temperature resistant is not easy to return viscous, and coating smell itself is low, small toxicity.And using this coating composition to product multiple working after, product is done old, product is allowed to seem irregular figure; oxidation or the trace to fade; even generate the illusion of erosion wear so that a modern product shows pseudo-classic breath, while having due protective value to product.
Description
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of one-component coating composition modelled after an antique.
Background technology
Coating, popular name paint are to be coated in the body surface protected or decorated, and can be formed with coated article securely attached
The continuous film adds or does not add pigment, filler typically based on resin or oil or lotion, adds corresponding additive,
The thick liquid being formulated with organic solvent or water.Coating is a kind of material, and this material can use different construction technologies
Coated in object surface, is formed and adhered to securely, with some strength, continuous solid film.The film common name film formed in this way,
Also known as paint film or coating.By the coating of coating coating on a surface of an, the surface of coated article body is made to be isolated with surrounding medium,
To the protection played the role of to coated article body and decoration.According to function difference, coating includes：Decorative paint, anticorrosive paint,
Insulating moulding coating and fireproof coating etc..And according to the difference of application, and one-component coating and dual-component coating can be divided into, single group
Divide coating, typically belong to the coating for not needing crosslinking curing, it is only necessary to which solvent volatilization can form paint film (belonging to physical reactions)；It is double
Component paints, and usually belongs to the paint of crosslinking curing, and cross-linking reaction formation paint film is generated after two kinds of component mixing and (belongs to chemistry
Reaction).The difference of one-component and two-component is exactly that one-component need not add any auxiliary products, direct spraying or roller coating
Film-forming, and the addition curing agent that is then necessarily drawn to of two-component could film-forming.Thus, in practical application,
One-component coating is easy to construct since usage is simple, has larger advantage and foreground.
In recent years, as people's quality of life improves, class promotion and the pursuit of trend of back-to-ancients to culture and arts make
The unique feature that has of some articles of the remote past successfully attracts modern, thus modern product does old pseudo-classic also get over
Hair becomes a kind of fashion.The present ornameutal handiwork period is short, if storage tens, centuries are waited to wear and do not meet people really
Desired situation, so a kind of special coating modelled after an antique comes into being, it can be such that craftwork looks like to be furrowed by rain and wind, take off
Color, corrugation, weathering, erosion, color and luster differ or some ancient collections such as floating just have, and do old modelled after an antique, are returned to from the modern times long
Historical floods in so that product has apparent history breath, and the gloss naturally to fade, color are simple and unsophisticated and texture is graceful etc.
Feature all gives out the breath in long age from the inside to surface.
But do it is old processing be not really to wear, it is more existing with similar functions coating through can't stand ultraviolet light
Irradiation is easy dusting, and xanthochromia and flexibility are poor, and water resistance, the defects of acid resistance and alkali resistance are poor, seriously restricts
The actual effect of antique-imitation coating and development to more concrete application fields.
Therefore, how to obtain a kind of both there is certain weatherability, chemicals-resistant corrosive nature, and capable of reaching preferable
The coating composition modelled after an antique of feature modelled after an antique is always manufacturer's urgent problem to be solved.
Invention content
In view of this, the technical problem to be solved in the present invention is to provide a kind of one-component coating composition modelled after an antique, this hair
The coating composition of bright offer has preferable weatherability, chemicals-resistant corrosive nature, and and enough reaches preferable spy modelled after an antique
Sign.
The present invention provides a kind of one-component coating compositions modelled after an antique, including：
Preferably, the coumarone indene resin is the copolymer of benzofuran and indenes；
The paint film property reinforcing aids is polymer of the maleficent acid resin after over-churning.
Preferably, polymer of the maleficent acid resin after over-churning is Abietyl modified Malin's acid resin.
Preferably, the wetting dispersing agent is high molecular polymer polysiloxane solution.
The composite drier is the mixture of various metals carboxylate.
Preferably, the mixture of the various metals carboxylate be the carboxylate of cobalt, the carboxylate of zirconium, lanthanum carboxylate and
Two or more in the carboxylate of cerium.
Preferably, the true solvent is benzene compounds solvent；The cosolvent is that aromatic hydrocarbon or polycyclic aromatic hydrocarbons are molten
Agent.
Preferably, the benzene compounds solvent is one or more in toluene, dimethylbenzene, trimethylbenzene and ethylbenzene；Institute
It is durene, 150 to state aromatic hydrocarbon or polycyclic aromatic hydrocarbons solvent#Solvent naphtha and 200#It is one or more in solvent naphtha.
Preferably, the room temperature viscosity of the coating composition is 60~70KU；When the normal temperature cure of the coating composition
Between be 4~8 hours.
The present invention provides a kind of article, the surface recombination of the article has the list described in above-mentioned technical proposal any one
Component coating composition modelled after an antique.
Preferably, the article includes one or more in craftwork, the art work, building and dress ornament；
The material of the article is in timber, bamboo wood, plastics, gypsum, cement products, metal product, cotton and fiber
It is one or more.
The present invention provides a kind of one-component coating composition modelled after an antique, including the coumarone indene resin of 40~70 parts by weight, 4~
The paint film property reinforcing aids of 6 parts by weight, the wetting dispersing agent of 0.2~0.4 parts by weight, 0.3~0.6 parts by weight it is compound urge it is dry
Agent, 13~30 parts by weight true solvent and 10~25 parts by weight cosolvent.Compared with prior art, single group provided by the invention
Part coating modelled after an antique, the weatherability of paint film is outstanding, and acid resistance, has excellent water-resistance at alkali resistance, and flexibility is good, on common ground
Adhesive force it is good, high temperature resistant is not easy to return viscous, and coating smell itself is low, small toxicity.And it is multiple to product using this coating composition
After cooperation industry, product is done old, allows product to seem irregular figure, oxidation or the trace to fade even generate erosion
The illusion of abrasion a so that modern product shows decades, centuries even when pseudo-classic breath in thousands of years, while to production
Product have due protective value.It is hardness H, attached the experimental results showed that one-component coating composition modelled after an antique provided by the invention
Put forth effort to be 1 grade；In flexibility test, 2mm paint films are normal, and in anti-impact force test, 50cm paint films are normal, and with preferable
Resistance to acid and alkali.
Specific implementation mode
In order to further appreciate that the present invention, the preferred embodiments of the invention are described with reference to embodiment, but
It is it should be appreciated that these descriptions are only the feature and advantage further illustrated the present invention rather than to patent requirements of the present invention
Limitation.
All raw materials of the present invention, are not particularly limited its source, buying on the market or according to people in the art
It is prepared by conventional method known to member.
All raw materials of the present invention, are not particularly limited its purity, pure present invention preferably employs analyzing.
The present invention provides a kind of one-component coating compositions modelled after an antique, including：
The addition of coumarone indene resin of the present invention is preferably 40~70 parts by weight, more preferably 45~65 parts by weight,
More preferably 50~60 parts by weight, most preferably 53~27 parts by weight；The coumarone indene resin is not particularly limited in the present invention,
With coumarone indene resin well known to those skilled in the art, the present invention is preferably the copolymer of benzofuran and indenes.The present invention
The specific source of the copolymer of the benzofuran and indenes is not particularly limited, those skilled in the art can be according to conventional side
Method prepares or purchase, and the present invention is preferably the PR-120 of Ningbo Henghe material Science and Technology Co., Ltd..
The addition of paint film property reinforcing aids of the present invention is preferably 4~6 parts by weight, more preferably 4.2~5.8 weights
Measure part, more preferably 4.5~5.5 parts by weight, most preferably 4.8~5.2 parts by weight；The present invention helps paint film property enhancing
Agent is not particularly limited, and with paint film property reinforcing aids well known to those skilled in the art, the present invention is preferably dehydration apple
Polymer of the tartaric acid resin after over-churning, more preferably Abietyl modified Malin's acid resin.The present invention is to the Abietyl modified horse
The specific source of woods acid resin is not particularly limited, and those skilled in the art can prepare or buy, this hair according to conventional methods
The MR-1110 of bright preferably Ninghua County Li Feng Chemical Co., Ltd.s of Fujian Province.
In one-component coating composition modelled after an antique paint film property reinforcing aids is added, its role is to carry in the present invention
For good weatherability, hardness, adhesive force, high-temperature storage is not easy to after-tack, well the multi-chemicals such as water-fast, alkaline-resisting, acidproof
Erosion performance.
The addition of wetting dispersing agent of the present invention is preferably 0.2~0.4 parts by weight, more preferably 0.22~0.38 weight
Measure part, more preferably 0.25~0.35 parts by weight, most preferably 0.28~0.32 parts by weight；The present invention is to the wetting dispersing agent
It is not particularly limited, with wetting dispersing agent well known to those skilled in the art, the present invention is preferably that high molecular polymer is poly-
Siloxane solution.The specific source of the high molecular polymer polysiloxane solution is not particularly limited in the present invention, this field
Technical staff can according to conventional methods prepare or buy, and the present invention is preferably the HX4030 of Chemical Group company of Chinese China.
In one-component coating composition modelled after an antique wetting dispersing agent is added, its role is to fully adsorb in the present invention
In resin surface, have the characteristics that affinity is strong, adsorbs thickness, while keeping coating system viscosity stabilization.
The addition of composite drier of the present invention is preferably 0.3~0.6 parts by weight, more preferably 0.35~0.55 weight
Measure part, more preferably 0.4~0.5 parts by weight, most preferably 0.42~0.48 parts by weight；The present invention does not have the composite drier
There is special limitation, with composite drier well known to those skilled in the art, the present invention is preferably various metals carboxylate
Mixture, the more preferably carboxylate of cobalt, the carboxylate of zirconium, the carboxylate of lanthanum and cerium carboxylate in two or more.This
The specific source of the composite drier is not particularly limited in invention, and those skilled in the art can prepare according to conventional methods
Or purchase, the present invention is preferably the ZHV-10 of Wuxi Han Desen heavy chemicals Co., Ltd.
In one-component coating composition modelled after an antique composite drier is added, its role is to accelerate coating in the present invention
Rate of drying, including dry tack free and do solid work, prevent paint film magazines such as dust in drying process is by surrounding air from interfering
Effect.
The addition of true solvent of the present invention is preferably 13~30 parts by weight, more preferably 15~28 parts by weight, more excellent
It is selected as 18~25 parts by weight, most preferably 20~23 parts by weight；The true solvent is not particularly limited in the present invention, with this field
True solvent known to technical staff, the present invention are preferably benzene compounds solvent, more preferably toluene, dimethylbenzene, front three
It is one or more in benzene and ethylbenzene, most preferably dimethylbenzene.The present invention does not limit the specific source of the true solvent especially
System, those skilled in the art can according to conventional methods prepare or buy, and the present invention is preferably Huizhou City's limited public affairs of base chemical industry forever
The XYL of department.
True solvent is added in one-component coating composition modelled after an antique in the present invention, and its role is to dissolution of coatings systems
In resin and auxiliary agent, make to be originally used for the resin of solid phase, auxiliary agent is transformed into liquid phase and convenient for construction.
The addition of cosolvent of the present invention is preferably 10~25 parts by weight, more preferably 12~22 parts by weight, more excellent
It is selected as 15~20 parts by weight, most preferably 16~19 parts by weight；The cosolvent is not particularly limited in the present invention, with this field
Cosolvent known to technical staff, the present invention are preferably aromatic hydrocarbon or polycyclic aromatic hydrocarbons solvent, more preferably durene,
150#Solvent naphtha and 200#It is one or more in solvent naphtha, most preferably durene.The present invention is to the specific next of the cosolvent
Source is not particularly limited, and those skilled in the art can according to conventional methods prepare or buy, the present invention be preferably Huizhou City forever
The S-150 of base Chemical Co., Ltd..
Cosolvent is added in one-component coating composition modelled after an antique in the present invention, and its role is to directly dissolving is not set
Fat and auxiliary agent, but coating system viscosity is can significantly reduce, diluting effect is played, while price is less than true solvent to reduce coating
Product cost.
The present invention has obtained one-component coating composition modelled after an antique after above-mentioned various ingredients compound in proportion.This
The definition of the one-component coating composition is not particularly limited in invention, with one-component coating well known to those skilled in the art
The definition of composition.The property of the one-component coating composition is not particularly limited in the present invention, with art technology
The room temperature viscosity of the property of one-component coating composition known to personnel, one-component coating composition of the present invention is excellent
Select 60~70KU, more preferably 62~68KU, most preferably 64~66KU；The present invention is to the definition of the room temperature viscosity without spy
It does not limit, with the definition of the room temperature viscosity of coating well known to those skilled in the art, at preferably 20~30 DEG C of the present invention
The viscosity that stormer viscosity measures；The normal temperature cure time of one-component coating composition of the present invention is preferably 1~5 small
When, more preferably 1.5~4.5 hours, most preferably 2~4 hours.The present invention is to the definition of the normal temperature cure time without spy
It does not limit, with the definition of coating normal temperature cure time well known to those skilled in the art, the present invention is preferably surface drying time
With do solid work the sum of time；The surface drying time is preferably 1~3 hour, more preferably 1.5~2.5 hours, most preferably 2 hours；
Described to do solid work the time be preferably 3~5 hours, more preferably 3.5~4.5 hours, most preferably 4 hours.
Coating modelled after an antique provided by the invention is one-pack type coating, and coating need not additionally be added solid before constructing operation
Agent can be sealed 2 years, as long as being sufficiently stirred before construction, be limited without usage time.The coating composition of the present invention
Both good weatherability had been possessed, hardness, adhesive force, high-temperature storage is not easy to after-tack, well a variety ofization such as water-fast, alkaline-resisting, acidproof
Product erosion performance, but also with feature modelled after an antique.
The present invention also provides a kind of article, the surface recombination of the article has described in above-mentioned technical proposal any one
One-component coating composition modelled after an antique.
The article is not particularly limited in the present invention, and the article preferably includes craftwork, the art work, building and dress ornament
In one or more, more preferably craftwork, the art work, building or dress ornament.The present invention is to the material of the article without spy
It does not limit, it is preferably one or more in timber, bamboo wood, plastics, gypsum, cement products, metal product, cotton and fiber,
More preferably timber, bamboo wood, plastics, gypsum, cement products, metal product, cotton or fiber.The present invention compound does not have to described
Especially limitation, with compound definition well known to those skilled in the art, during the present invention is preferably sprayed, sprays and brushed
It is one or more, it more preferably sprays, spray or brushes.
The specific complex method of one-component coating composition modelled after an antique is not particularly limited in the present invention, art technology
Personnel can be adjusted and select according to actual use situation, article property and appearance requirement, and the present invention is preferably according to such as
Lower method carries out compound, first stirs coating, the operations such as is then sprayed, is brushed as needed, stirring evenly
Coating there is no usage time limitation, i.e., after construction, be sealed so that next time is continuing with.The present invention is to the list
The preparation method of component coating composition modelled after an antique is not particularly limited, with one-component well known to those skilled in the art coating modelled after an antique
The preparation method of composition, the present invention preferably uniformly mixing.
One-component coating composition modelled after an antique provided by the present invention, the weatherability of paint film is outstanding, acid resistance, alkali resistance, resistance to
Aqueous excellent, flexibility is good, and the adhesive force on common ground is good, and high temperature resistant is not easy to return viscous, and coating smell itself is low, toxicity
It is small；And this product does not need curing agent, can construct after stirring, and can spray, a variety of modes of operation such as brushing,
It is versatile and flexible；After this coating composition carries out multiple working to product, product is done old, product is allowed to seem irregular flower
Trace, oxidation or the trace to fade, even generate the illusion of erosion wear so that a modern product shows decades, several
Pseudo-classic breath in century-old or even thousands of year, while there is due protective value to product.The experimental results showed that the present invention provides
One-component coating composition modelled after an antique, hardness H, adhesive force are 1 grade；In flexibility test, 2mm paint films are normal, anti-impact force
In test, 50cm paint films are normal, and have preferable resistance to acid and alkali.
For a further understanding of the present invention, with reference to embodiment to one-component provided by the invention coating composition modelled after an antique
It illustrates, protection scope of the present invention is not limited by the following examples.
Coumarone indene resin is purchased from Ningbo Henghe material Science and Technology Co., Ltd., product grade PR-120.
Embodiment 1
One-component coating components modelled after an antique are as follows：
The coumarone indene resin of 40.5 parts by weight, the paint film property reinforcing aids of 4 parts by weight, manufacturer are Fujian Province's Ninghua County profit
Rich Chemical Co., Ltd., product grade MR-1110；The wetting dispersing agent of 0.2 parts by weight, manufacturer are Chinese China Chemical Group
Company, product grade HX4030；The composite drier of 0.3 parts by weight, manufacturer are Wuxi Han Desen heavy chemicals Co., Ltd,
Product grade is ZHV-10；The true solvent of 30 parts by weight, manufacturer are Yong Ji Chemical Co., Ltd.s of Huizhou City, product grade XYL；
The cosolvent of 25 parts by weight, manufacturer are Yong Ji Chemical Co., Ltd.s of Huizhou City, product grade S-150.
One-component manufactured in the present embodiment coating modelled after an antique is subjected to spray-coating operation, the ground of institute's application is made of metal
Product.This example coating is the very low sprayable operation coating of viscosity, is not required to additional addO-on therapy, stirring evenly can construct, resistance to
Time property is good, and chemicals-resistant corrosivity is good, and adhesive force is high, and hardness is big, there is feature modelled after an antique.
Embodiment 2
One-component coating components modelled after an antique are as follows：
The coumarone indene resin of 70 parts by weight, the paint film property reinforcing aids of 6 parts by weight, manufacturer are Fujian Province Ninghua County Li Feng
Chemical Co., Ltd., product grade MR-1110；The wetting dispersing agent of 0.4 parts by weight, manufacturer are that Chinese China Chemical Group is public
Department, product grade HX4030；The composite drier of 0.6 parts by weight, manufacturer are Wuhan Lion Rock painting Co., Ltd, production
Brand number is G-06；The true solvent of 13 parts by weight, manufacturer are Yong Ji Chemical Co., Ltd.s of Huizhou City, product grade XYL；10 weights
The cosolvent of part is measured, manufacturer is Yong Ji Chemical Co., Ltd.s of Huizhou City, product grade S-150.
One-component manufactured in the present embodiment coating modelled after an antique is carried out to brush application operation, the ground of institute's application is timber.This
Example coating, which is that viscosity is higher, brushes operation coating, is not required to additional addO-on therapy, stirring evenly can construct, weatherability
Good, chemicals-resistant corrosivity is good, and adhesive force is high, and hardness is big, there is feature modelled after an antique.
Paint film, which is formed, after doing solid work one-component coating modelled after an antique prepared by Examples 1 to 2 carries out mechanical property and corrosion resistance
It can wait, test result is listed in table 1, and table 1 is the practical coating of one-component coating modelled after an antique and existing common coating prepared by embodiment
Paint film contrast test.
The paint film contrast test of the practical coating of one-component coating modelled after an antique and existing common coating prepared by 1 embodiment of table
This product can also be detected by ROHS.
From the above results, the paint film that one-component provided by the invention coating modelled after an antique is formed after doing solid work has preferable resistance to
Hou Xing, hardness, adhesive force, high-temperature storage are not easy to after-tack, and the multi-chemicals erosion performance such as water-fast, alkaline-resisting, acidproof is again well
Has feature modelled after an antique.
Embodiment 3
One-component coating composition modelled after an antique is as follows：
The coumarone indene resin of 40.5 parts by weight, the paint film property reinforcing aids of 5 parts by weight, manufacturer are Ganzhou Dingnan County
Song Yuan Chemical Co., Ltd.s, product grade 424#, the wetting dispersing agent of 0.2 parts by weight, manufacturer is Chinese China Chemical Group
Company, product grade HX4030；The composite drier of 0.3 parts by weight, manufacturer are Wuxi Han Desen heavy chemicals Co., Ltd,
Product grade is ZHV-10；The true solvent trimethylbenzene of 29 parts by weight, the cosolvent durene of 25 parts by weight.
One-component manufactured in the present embodiment coating modelled after an antique is subjected to spray-coating operation, the ground of institute's application is gypsum.This
Example coating is the very low sprayable operation coating of viscosity, is not required to additional addO-on therapy, stirring evenly can construct, outstanding feature
Big for case hardness, resistance to marring is excellent, and shock resistance is good, there is feature modelled after an antique.
Paint film, which is formed, after doing solid work one-component paint spraying modelled after an antique prepared by the embodiment of the present invention 3 carries out mechanical property inspection
It surveys, one-component coating composition modelled after an antique provided by the invention, hardness H, adhesive force are 1 grade；In flexibility test, 2mm paint films
Normally, in anti-impact force test, 50cm paint films are normal, and have preferable resistance to acid and alkali.
Embodiment 4
One-component coating composition modelled after an antique is as follows：
The coumarone indene resin of 70 parts by weight, the paint film property reinforcing aids of 6 parts by weight, the wetting dispersing agent of 0.5 parts by weight,
Manufacturer is Chemical Group company of Chinese China, product grade HX4030；The composite drier of 0.5 parts by weight, manufacturer are Wuhan
Lion Rock painting Co., Ltd, product grade G-06, the true solvent ethylbenzene of 13 parts by weight, the cosolvent of 10 parts by weight,
Manufacturer is the S-200 of Yong Ji Chemical Co., Ltd.s of Huizhou City.
One-component manufactured in the present embodiment coating modelled after an antique is carried out to brush application operation, the ground of institute's application is cement system
Product.This example coating, which is that viscosity is higher, brushes operation coating, is not required to additional addO-on therapy, and stirring evenly can construct, and dashes forward
It is that rate of drying is fast to go out feature, and surface drying 1.5 hours does solid work the time 2.5 hours, and excellent heat-resisting quantity has feature modelled after an antique.
Paint film, which is formed, after doing solid work one-component paint spraying modelled after an antique prepared by the embodiment of the present invention 3 carries out mechanical property inspection
It surveys, one-component coating composition modelled after an antique provided by the invention, hardness H, adhesive force are 1 grade；In flexibility test, 2mm paint films
Normally, in anti-impact force test, 50cm paint films are normal, and have preferable resistance to acid and alkali.
The explanation of above example is only intended to facilitate the understanding of the method and its core concept of the invention.It should be pointed out that pair
For those skilled in the art, without departing from the principle of the present invention, the present invention can also be carried out
Some improvements and modifications, these improvement and modification are also fallen within the protection scope of the claims of the present invention.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest range caused.
Claims (7)
1. a kind of one-component coating composition modelled after an antique, which is characterized in that consist of the following compositions：
40 ~ 70 parts by weight of coumarone indene resin；
4 ~ 6 parts by weight of paint film property reinforcing aids；
0.2 ~ 0.4 parts by weight of wetting dispersing agent；
0.3 ~ 0.6 parts by weight of composite drier；
13 ~ 30 parts by weight of true solvent；
10 ~ 25 parts by weight of cosolvent；
The paint film property reinforcing aids is polymer of the maleficent acid resin after over-churning；The maleficent acid resin
Polymer after over-churning is Abietyl modified Malin's acid resin；
The true solvent is benzene compounds solvent；The benzene compounds solvent is in toluene, dimethylbenzene, trimethylbenzene and ethylbenzene
It is one or more；
The cosolvent is aromatic hydrocarbon or polycyclic aromatic hydrocarbons solvent；The aromatic hydrocarbon or polycyclic aromatic hydrocarbons solvent are tetramethyl
Benzene, 150#Solvent naphtha and 200#It is one or more in solvent naphtha.
2. one-component coating composition modelled after an antique according to claim 1, which is characterized in that the coumarone indene resin is benzo
The copolymer of furans and indenes.
3. one-component coating composition modelled after an antique according to claim 1, which is characterized in that the wetting dispersing agent is high score
Sub- polymer poly siloxane solution；
The composite drier is the mixture of various metals carboxylate.
4. one-component coating composition modelled after an antique according to claim 3, which is characterized in that the various metals carboxylate
Mixture is two or more in the carboxylate of the carboxylate of cobalt, the carboxylate of zirconium, the carboxylate of lanthanum and cerium.
5. one-component coating composition modelled after an antique according to claim 1, which is characterized in that the room temperature of the coating composition
Viscosity is 60 ~ 70KU；The normal temperature cure time of the coating composition is 4 ~ 8 hours.
6. a kind of article, which is characterized in that the one-component that the surface recombination of the article is had the right described in 1 ~ 5 any one of requirement
Coating composition modelled after an antique.
7. article according to claim 6, which is characterized in that the article includes craftwork, the art work, building and dress ornament
In it is one or more；
The material of the article is one kind in timber, bamboo wood, plastics, gypsum, cement products, metal product, cotton and fiber
Or it is a variety of.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201511027975.4A CN105419550B (en) | 2015-12-31 | 2015-12-31 | A kind of one-component coating composition modelled after an antique |
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| CN201511027975.4A CN105419550B (en) | 2015-12-31 | 2015-12-31 | A kind of one-component coating composition modelled after an antique |
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| CN105419550A CN105419550A (en) | 2016-03-23 |
| CN105419550B true CN105419550B (en) | 2018-11-02 |
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| CN107474628A (en) * | 2017-10-11 | 2017-12-15 | 至远彩色印刷工业（惠州）有限公司 | Beautiful LED cured printing ink compositions of a kind of color and luster and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1411035A (en) * | 1919-04-14 | 1922-03-28 | Du Pont | Coumarone coating composition |
| SU943259A1 (en) * | 1980-08-13 | 1982-07-15 | Бийский Лакокрасочный Завод | Film forming composition for producing varnish and paint materials |
| JP2001081359A (en) * | 1999-09-13 | 2001-03-27 | Mitsubishi Rayon Co Ltd | Coating composition, and article bearing dried coating film thereof |
| CN102803408A (en) * | 2010-01-26 | 2012-11-28 | 佐敦集团 | Antifouling composition |
| CN103725144A (en) * | 2013-11-19 | 2014-04-16 | 谭文平 | Anticorrosive paint and preparation method thereof |
-
2015
- 2015-12-31 CN CN201511027975.4A patent/CN105419550B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1411035A (en) * | 1919-04-14 | 1922-03-28 | Du Pont | Coumarone coating composition |
| SU943259A1 (en) * | 1980-08-13 | 1982-07-15 | Бийский Лакокрасочный Завод | Film forming composition for producing varnish and paint materials |
| JP2001081359A (en) * | 1999-09-13 | 2001-03-27 | Mitsubishi Rayon Co Ltd | Coating composition, and article bearing dried coating film thereof |
| CN102803408A (en) * | 2010-01-26 | 2012-11-28 | 佐敦集团 | Antifouling composition |
| CN103725144A (en) * | 2013-11-19 | 2014-04-16 | 谭文平 | Anticorrosive paint and preparation method thereof |
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|---|---|
| CN105419550A (en) | 2016-03-23 |
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Address after: Fuzhou city Xincuo town Suanling village in Fujian province (born 350300 Lin Yi diagonally opposite) Fuzhou East Exhibition Materials Co. Ltd. Co-patentee after: China Zhanchen New Materials Group Co.,Ltd. Patentee after: FUZHOU ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee after: Beijing zhanchen Intelligent Property Management Co.,Ltd. Co-patentee after: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee after: CHENGDU ZHANCHEN PAINTS Co.,Ltd. Address before: Fuzhou city Xincuo town Suanling village in Fujian province (born 350300 Lin Yi diagonally opposite) Fuzhou East Exhibition Materials Co. Ltd. Co-patentee before: China Zhanchen New Materials Group Co.,Ltd. Patentee before: FUZHOU ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: BEIJING ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: CHENGDU ZHANCHEN PAINTS Co.,Ltd. |
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Effective date of registration: 20200522 Address after: 350000, Fujian, Fuzhou bonded port processing trade zone supervision building, 2 floor, room 105, 211 intervals (Fuqing new town, 9 Jiang Jiang Road) (FTA test area) Co-patentee after: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Patentee after: FUZHOU ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee after: CHENGDU ZHANCHEN PAINTS Co.,Ltd. Co-patentee after: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Address before: Fuzhou city Xincuo town Suanling village in Fujian province (born 350300 Lin Yi diagonally opposite) Fuzhou East Exhibition Materials Co. Ltd. Co-patentee before: China Zhanchen New Materials Group Co.,Ltd. Patentee before: FUZHOU ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: SHANGHAI ZHANCHEN PAINT Co.,Ltd. Co-patentee before: Beijing zhanchen Intelligent Property Management Co.,Ltd. Co-patentee before: QINGDAO ZHANCHEN NEW MATERIAL Co.,Ltd. Co-patentee before: CHENGDU ZHANCHEN PAINTS Co.,Ltd. |