CN105419194A - 异丙基二油酸酰氧基钛酸酯非金属粉体活化剂 - Google Patents

异丙基二油酸酰氧基钛酸酯非金属粉体活化剂 Download PDF

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CN105419194A
CN105419194A CN201510860539.9A CN201510860539A CN105419194A CN 105419194 A CN105419194 A CN 105419194A CN 201510860539 A CN201510860539 A CN 201510860539A CN 105419194 A CN105419194 A CN 105419194A
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李伟强
廖煜明
杨毅
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    • C09C3/00—Treatment in general of inorganic materials, other than fibrous fillers, to enhance their pigmenting or filling properties
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Abstract

本发明的异丙基二油酸酰氧基钛酸酯非金属粉体活化剂，由异丙基二油酸酰氧基(二辛基磷酸酰氧基)钛酸酯5-8份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，甘油三醋酸酯5-6份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，γ-缩水甘油醚氧丙基三甲氧基硅烷25-30份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水550-600份组成；具有设计科学合理，工艺简单，安全可靠性，易于控制，操作方便，适合大规模生产，生产成本低等优点。

Description

异丙基二油酸酰氧基钛酸酯非金属粉体活化剂
技术领域
本发明属于一种生产非金属粉体用的功能助剂。
背景技术
目前，碳酸钙已广泛应用于造纸、塑料、塑料薄膜、化纤、橡胶、胶粘剂、密封剂、日用化工、化妆品、建材、涂料、油漆、油墨、油灰、封蜡、腻子、毡层包装、医药、食品(如口香糖、巧克力)、饲料中，其作用有：增加产品体积、降低成本，改善加工性能(如调节粘度、流变性能、硫化性能)，提高尺寸稳定性，补强或半补强，提高印刷性能，提高物理性能(如耐热性、消光性、耐磨性、阻燃性、白度、光泽度)等；为获得更优越的性能，均采用助剂进行活化处理。
发明内容
本发明的目的在于；提出一种异丙基二油酸酰氧基钛酸酯非金属粉体活化剂其制备方法。
本发明的异丙基二油酸酰氧基钛酸酯非金属粉体活化剂，其特征在于：以重量计，其配方由异丙基二油酸酰氧基(二辛基磷酸酰氧基)钛酸酯5-8份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，甘油三醋酸酯5-6份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，γ-缩水甘油醚氧丙基三甲氧基硅烷25-30份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水550-600份组成。
本发明的异丙基二油酸酰氧基钛酸酯非金属粉体活化剂的制备方法，其特征在于：以重量计，其配方由异丙基二油酸酰氧基(二辛基磷酸酰氧基)钛酸酯5-8份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，甘油三醋酸酯5-6份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，γ-缩水甘油醚氧丙基三甲氧基硅烷25-30份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水550-600份组成；先用乙醇将松香铕树脂溶解，加入水550-600份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
本发明与现有技术相比其有益效果是：具有设计科学合理，工艺简单，安全可靠性，易于控制，操作方便，适合大规模生产，生产成本低等优点。
具体实施方式
下面结合实施例对本发明作进一步说明，但本发明的实施方式不限于此。
本发明的所有原料可购买获得。
实施例1，本发明的异丙基二油酸酰氧基钛酸酯非金属粉体活化剂的制备，其特征在于：以重量计，其配方由异丙基二油酸酰氧基(二辛基磷酸酰氧基)钛酸酯5-8份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，甘油三醋酸酯5-6份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，γ-缩水甘油醚氧丙基三甲氧基硅烷25-30份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水550-600份组成；先用乙醇将松香铕树脂溶解，加入水550-600份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
实施例2，本发明的异丙基二油酸酰氧基钛酸酯非金属粉体活化剂的制备，其特征在于：以重量计，其配方由异丙基二油酸酰氧基(二辛基磷酸酰氧基)钛酸酯5-8份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3份，椰子油脂肪酸二乙醇酰胺25份，碳酸钠5份，丙烯酸钠-4-乙烯基吡啶共聚物3份，甘油三醋酸酯5份，二辛基锡10份，聚乙烯醇缩醛树脂3份，缩水甘油醚氧丙基三甲氧基硅烷25份，乙醇20-30份，水550-600份组成；先用乙醇将松香铕树脂溶解，加入水550-600份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
实施例3，本发明的异丙基二油酸酰氧基钛酸酯非金属粉体活化剂的制备，其特征在于：以重量计，其配方由异丙基二油酸酰氧基(二辛基磷酸酰氧基)钛酸酯5-8份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂8份，椰子油脂肪酸二乙醇酰胺30份，碳酸钠8份，丙烯酸钠-4-乙烯基吡啶共聚物5份，甘油三醋酸酯6份，二辛基锡12份，聚乙烯醇缩醛树脂5份，缩水甘油醚氧丙基三甲氧基硅烷30份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水550-600份组成；先用乙醇将松香铕树脂溶解，加入水550-600份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
实施例4，本发明的异丙基二油酸酰氧基钛酸酯非金属粉体活化剂的制备，其特征在于：以重量计，其配方由异丙基二油酸酰氧基(二辛基磷酸酰氧基)钛酸酯5-8份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3份，椰子油脂肪酸二乙醇酰胺30份，碳酸钠5份，丙烯酸钠-4-乙烯基吡啶共聚物5份，甘油三醋酸酯5份，二辛基锡12份，聚乙烯醇缩醛树脂3份，缩水甘油醚氧丙基三甲氧基硅烷25份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水550-600份组成；先用乙醇将松香铕树脂溶解，加入水550-600份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
本发明的产品，经生产厂商使用，生产改性超细重质碳酸钙功能产品，反应效果很好。
部分原料说明：
1、所述季戊四醇松香铕树脂，可优选按中国专利专利号为ZL201410078259.8的方法制得。
2、氨乙基丙氨丙基甲基甲氧基硅烷，实施例用南京旭杨化工有限公司产品，商品名：覆膜砂高效增强剂硅XY-812。
3、γ-缩水甘油醚氧丙基三甲氧基硅烷分子式：C9H2005Si
4、异丙基二油酸酰氧基(二辛基磷酸酰氧基)钛酸酯，分子式：C55H111O9Ti。

Claims (2)

1.一种异丙基二油酸酰氧基钛酸酯非金属粉体活化剂，其特征在于：以重量计，其配方由异丙基二油酸酰氧基(二辛基磷酸酰氧基)钛酸酯5-8份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，甘油三醋酸酯5-6份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，γ-缩水甘油醚氧丙基三甲氧基硅烷25-30份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水550-600份组成。
2.一种异丙基二油酸酰氧基钛酸酯非金属粉体活化剂的制备方法，其特征在于：以重量计，其配方由异丙基二油酸酰氧基(二辛基磷酸酰氧基)钛酸酯5-8份，氨乙基丙氨丙基甲基甲氧基硅烷5-6份，二丙二醇单丁醚5-8份，季戊四醇松香铕树脂3-8份，椰子油脂肪酸二乙醇酰胺25-30份，碳酸钠5-8份，丙烯酸钠-4-乙烯基吡啶共聚物3-5份，甘油三醋酸酯5-6份，氧化二辛基锡10--12份，聚乙烯醇缩醛树脂3-5份，γ-缩水甘油醚氧丙基三甲氧基硅烷25-30份，十二烷基二甲基苄基溴化铵3-5份，乙醇20-30份，水550-600份组成；先用乙醇将松香铕树脂溶解，加入水550-600份后，加入全部原料混合均匀，在85～95℃下搅拌20-30分钟，即得产品。
CN201510860539.9A 2015-11-26 2015-11-26 异丙基二油酸酰氧基钛酸酯非金属粉体活化剂 Pending CN105419194A (zh)

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103820032A (zh) * 2014-03-05 2014-05-28 张雅静 季戊四醇松香铕树脂制备方法
CN104403246A (zh) * 2014-10-31 2015-03-11 廖文成 超细碳酸钙粉体缩醛改性剂

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103820032A (zh) * 2014-03-05 2014-05-28 张雅静 季戊四醇松香铕树脂制备方法
CN104403246A (zh) * 2014-10-31 2015-03-11 廖文成 超细碳酸钙粉体缩醛改性剂

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