CN105418799A - 一种壳寡糖碘络合物及其制备方法和应用 - Google Patents
一种壳寡糖碘络合物及其制备方法和应用 Download PDFInfo
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- CN105418799A CN105418799A CN201510963218.1A CN201510963218A CN105418799A CN 105418799 A CN105418799 A CN 105418799A CN 201510963218 A CN201510963218 A CN 201510963218A CN 105418799 A CN105418799 A CN 105418799A
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- oligochitosan
- iodine
- iodine complex
- chitosan oligosaccharide
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- 229920001661 Chitosan Polymers 0.000 title claims abstract description 94
- 229910052740 iodine Inorganic materials 0.000 title claims abstract description 61
- 239000011630 iodine Substances 0.000 title claims abstract description 61
- 238000002360 preparation method Methods 0.000 title claims abstract description 20
- 238000010668 complexation reaction Methods 0.000 title description 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 claims abstract description 53
- 244000052616 bacterial pathogen Species 0.000 claims abstract description 24
- 241000196324 Embryophyta Species 0.000 claims abstract description 22
- 241000894006 Bacteria Species 0.000 claims abstract description 17
- 239000007787 solid Substances 0.000 claims abstract description 14
- 239000007788 liquid Substances 0.000 claims abstract description 13
- 201000010099 disease Diseases 0.000 claims abstract description 11
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 11
- 241000191967 Staphylococcus aureus Species 0.000 claims abstract description 9
- 230000006196 deacetylation Effects 0.000 claims abstract description 9
- 238000003381 deacetylation reaction Methods 0.000 claims abstract description 9
- 229920000742 Cotton Polymers 0.000 claims abstract description 8
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 8
- 235000009566 rice Nutrition 0.000 claims abstract description 8
- 241000607142 Salmonella Species 0.000 claims abstract description 7
- 238000000034 method Methods 0.000 claims abstract description 6
- 244000000010 microbial pathogen Species 0.000 claims abstract description 6
- 240000007594 Oryza sativa Species 0.000 claims abstract 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 34
- 229960000935 dehydrated alcohol Drugs 0.000 claims description 25
- 150000001875 compounds Chemical class 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 238000006243 chemical reaction Methods 0.000 claims description 10
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 8
- 238000002156 mixing Methods 0.000 claims description 8
- 241001530056 Athelia rolfsii Species 0.000 claims description 7
- 230000000968 intestinal effect Effects 0.000 claims description 7
- 238000001035 drying Methods 0.000 claims description 5
- 238000001556 precipitation Methods 0.000 claims description 5
- 238000000967 suction filtration Methods 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 208000035143 Bacterial infection Diseases 0.000 claims description 3
- 208000022362 bacterial infectious disease Diseases 0.000 claims description 3
- 230000002538 fungal effect Effects 0.000 claims description 3
- 230000002401 inhibitory effect Effects 0.000 abstract description 22
- 230000000694 effects Effects 0.000 abstract description 8
- 230000001954 sterilising effect Effects 0.000 abstract description 6
- 238000004659 sterilization and disinfection Methods 0.000 abstract description 6
- 230000012010 growth Effects 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 3
- 230000002265 prevention Effects 0.000 abstract description 2
- RQFQJYYMBWVMQG-IXDPLRRUSA-N chitotriose Chemical compound O[C@@H]1[C@@H](N)[C@H](O)O[C@H](CO)[C@H]1O[C@H]1[C@H](N)[C@@H](O)[C@H](O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)N)[C@@H](CO)O1 RQFQJYYMBWVMQG-IXDPLRRUSA-N 0.000 abstract 2
- 241000193830 Bacillus <bacterium> Species 0.000 abstract 1
- 210000001072 colon Anatomy 0.000 abstract 1
- 230000000536 complexating effect Effects 0.000 abstract 1
- 239000012429 reaction media Substances 0.000 abstract 1
- 229920001542 oligosaccharide Polymers 0.000 description 11
- 150000002482 oligosaccharides Chemical class 0.000 description 9
- 230000000844 anti-bacterial effect Effects 0.000 description 8
- 241000209094 Oryza Species 0.000 description 6
- 241000233866 Fungi Species 0.000 description 5
- 230000008901 benefit Effects 0.000 description 4
- 239000002609 medium Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000005740 Boscalid Substances 0.000 description 3
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- -1 boscalid amine Chemical class 0.000 description 3
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- 230000003385 bacteriostatic effect Effects 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 229960004756 ethanol Drugs 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 238000011534 incubation Methods 0.000 description 2
- 230000001939 inductive effect Effects 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
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- 239000013641 positive control Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000004562 water dispersible granule Substances 0.000 description 2
- BITDLWAQPKSXTF-UHFFFAOYSA-M 1-[(3-nitrophenyl)methoxymethyl]pyridin-1-ium;chloride Chemical compound [Cl-].[O-][N+](=O)C1=CC=CC(COC[N+]=2C=CC=CC=2)=C1 BITDLWAQPKSXTF-UHFFFAOYSA-M 0.000 description 1
- MSWZFWKMSRAUBD-IVMDWMLBSA-N 2-amino-2-deoxy-D-glucopyranose Chemical compound N[C@H]1C(O)O[C@H](CO)[C@@H](O)[C@@H]1O MSWZFWKMSRAUBD-IVMDWMLBSA-N 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 208000035240 Disease Resistance Diseases 0.000 description 1
- 239000006137 Luria-Bertani broth Substances 0.000 description 1
- 208000031888 Mycoses Diseases 0.000 description 1
- 241000082085 Verticillium <Phyllachorales> Species 0.000 description 1
- 208000036142 Viral infection Diseases 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- MSWZFWKMSRAUBD-UHFFFAOYSA-N beta-D-galactosamine Natural products NC1C(O)OC(CO)C(O)C1O MSWZFWKMSRAUBD-UHFFFAOYSA-N 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
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- 230000001276 controlling effect Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 210000003298 dental enamel Anatomy 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000018109 developmental process Effects 0.000 description 1
- 238000010790 dilution Methods 0.000 description 1
- 239000012895 dilution Substances 0.000 description 1
- 230000006806 disease prevention Effects 0.000 description 1
- 230000000857 drug effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 229960002442 glucosamine Drugs 0.000 description 1
- 239000001963 growth medium Substances 0.000 description 1
- 239000003630 growth substance Substances 0.000 description 1
- 230000012447 hatching Effects 0.000 description 1
- 239000000413 hydrolysate Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229960002581 moroxydine hydrochloride Drugs 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 244000144977 poultry Species 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000001850 reproductive effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 238000011218 seed culture Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B37/00—Preparation of polysaccharides not provided for in groups C08B1/00 - C08B35/00; Derivatives thereof
- C08B37/0006—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid
- C08B37/0024—Homoglycans, i.e. polysaccharides having a main chain consisting of one single sugar, e.g. colominic acid beta-D-Glucans; (beta-1,3)-D-Glucans, e.g. paramylon, coriolan, sclerotan, pachyman, callose, scleroglucan, schizophyllan, laminaran, lentinan or curdlan; (beta-1,6)-D-Glucans, e.g. pustulan; (beta-1,4)-D-Glucans; (beta-1,3)(beta-1,4)-D-Glucans, e.g. lichenan; Derivatives thereof
- C08B37/0027—2-Acetamido-2-deoxy-beta-glucans; Derivatives thereof
- C08B37/003—Chitin, i.e. 2-acetamido-2-deoxy-(beta-1,4)-D-glucan or N-acetyl-beta-1,4-D-glucosamine; Chitosan, i.e. deacetylated product of chitin or (beta-1,4)-D-glucosamine; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N55/00—Biocides, pest repellants or attractants, or plant growth regulators, containing organic compounds containing elements other than carbon, hydrogen, halogen, oxygen, nitrogen and sulfur
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N59/00—Biocides, pest repellants or attractants, or plant growth regulators containing elements or inorganic compounds
- A01N59/12—Iodine, e.g. iodophors; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H1/00—Processes for the preparation of sugar derivatives
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07H—SUGARS; DERIVATIVES THEREOF; NUCLEOSIDES; NUCLEOTIDES; NUCLEIC ACIDS
- C07H5/00—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium
- C07H5/04—Compounds containing saccharide radicals in which the hetero bonds to oxygen have been replaced by the same number of hetero bonds to halogen, nitrogen, sulfur, selenium, or tellurium to nitrogen
- C07H5/06—Aminosugars
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Wood Science & Technology (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Genetics & Genomics (AREA)
- Dentistry (AREA)
- Biotechnology (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
苹果腐烂致病菌 | 棉花枯萎致病菌 | 水稻纹枯致病菌 | |
最小抑菌浓度 | 最小抑菌浓度 | 最小抑菌浓度 | |
本发明 | 1.0% | 1.0% | 1.0% |
壳寡糖 | 4% | 6.5% | 4% |
啶酰菌胺 | 4% | 3% | 3% |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510963218.1A CN105418799B (zh) | 2015-12-18 | 2015-12-18 | 一种壳寡糖碘络合物及其制备方法和应用 |
Applications Claiming Priority (1)
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CN201510963218.1A CN105418799B (zh) | 2015-12-18 | 2015-12-18 | 一种壳寡糖碘络合物及其制备方法和应用 |
Publications (2)
Publication Number | Publication Date |
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CN105418799A true CN105418799A (zh) | 2016-03-23 |
CN105418799B CN105418799B (zh) | 2018-08-17 |
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CN201510963218.1A Active CN105418799B (zh) | 2015-12-18 | 2015-12-18 | 一种壳寡糖碘络合物及其制备方法和应用 |
Country Status (1)
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CN (1) | CN105418799B (zh) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109354633A (zh) * | 2018-11-14 | 2019-02-19 | 黄河三角洲京博化工研究院有限公司 | 一种壳寡糖锌螯合物及其制备方法和应用 |
CN111848827A (zh) * | 2020-06-10 | 2020-10-30 | 青岛海大生物集团有限公司 | 一种新型绿藻多糖杀菌剂及其制备方法 |
CN113969298A (zh) * | 2021-11-25 | 2022-01-25 | 京博农化科技有限公司 | 一种6-羧基壳寡糖-铜络合物的制备方法及其制备产品的应用 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5538955A (en) * | 1993-05-07 | 1996-07-23 | Development Biotechnological Processes S.N.C Di Pelliccia Maria Teresa | Process for the preparation of iodinated biopolymers having disinfectant and cicatrizing activity, and the iodinated biopolymers obtainable thereby |
CN103304304A (zh) * | 2012-03-13 | 2013-09-18 | 中国海洋大学生物工程开发有限公司 | 一种碘化壳寡糖海藻生物肥料的制备方法 |
CN103975949A (zh) * | 2014-05-23 | 2014-08-13 | 青岛科技大学 | 一种壳聚糖碘液及其制备方法 |
-
2015
- 2015-12-18 CN CN201510963218.1A patent/CN105418799B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5538955A (en) * | 1993-05-07 | 1996-07-23 | Development Biotechnological Processes S.N.C Di Pelliccia Maria Teresa | Process for the preparation of iodinated biopolymers having disinfectant and cicatrizing activity, and the iodinated biopolymers obtainable thereby |
CN103304304A (zh) * | 2012-03-13 | 2013-09-18 | 中国海洋大学生物工程开发有限公司 | 一种碘化壳寡糖海藻生物肥料的制备方法 |
CN103975949A (zh) * | 2014-05-23 | 2014-08-13 | 青岛科技大学 | 一种壳聚糖碘液及其制备方法 |
Non-Patent Citations (3)
Title |
---|
侯春林等: "《几丁质与医学(第2版)》", 31 May 2008, 上海科学技术出版社 * |
史书睿: ""壳聚糖衍生物-碘复合物的制备及其杀菌性能的研究"", 《中国优秀硕士学位论文全文数据库 工程科技I辑》 * |
蒋挺大: "《壳聚糖(第2版)》", 31 January 2007, 化学工业出版社 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109354633A (zh) * | 2018-11-14 | 2019-02-19 | 黄河三角洲京博化工研究院有限公司 | 一种壳寡糖锌螯合物及其制备方法和应用 |
CN111848827A (zh) * | 2020-06-10 | 2020-10-30 | 青岛海大生物集团有限公司 | 一种新型绿藻多糖杀菌剂及其制备方法 |
CN113969298A (zh) * | 2021-11-25 | 2022-01-25 | 京博农化科技有限公司 | 一种6-羧基壳寡糖-铜络合物的制备方法及其制备产品的应用 |
CN113969298B (zh) * | 2021-11-25 | 2024-02-13 | 山东京博农化科技股份有限公司 | 一种6-羧基壳寡糖-铜络合物的制备方法及其制备产品的应用 |
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Application publication date: 20160323 Assignee: Shandong Jingbo Yilin Garden Construction Co.,Ltd. Assignor: CHAMBROAD CHEMICAL INDUSTRY RESEARCH INSTITUTE Co.,Ltd. Contract record no.: 2019370000015 Denomination of invention: Chitosan oligosaccharide-iodine complex as well as preparation method and application thereof Granted publication date: 20180817 License type: Common License Record date: 20190201 |
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Effective date of registration: 20240529 Address after: 256500 Boxing Economic Development Zone, Shandong, Binzhou Patentee after: Shandong Jingbo Agrochemical Technology Co.,Ltd. Country or region after: China Address before: 256500 Boxing Economic Development Zone, Shandong, Binzhou Patentee before: CHAMBROAD CHEMICAL INDUSTRY RESEARCH INSTITUTE Co.,Ltd. Country or region before: China |