CN105400372A - Wear-resistant coating material - Google Patents
Wear-resistant coating material Download PDFInfo
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- CN105400372A CN105400372A CN201510939666.8A CN201510939666A CN105400372A CN 105400372 A CN105400372 A CN 105400372A CN 201510939666 A CN201510939666 A CN 201510939666A CN 105400372 A CN105400372 A CN 105400372A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/14—Glass
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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Abstract
A wear-resistant coating material includes a main agent including 10-60 parts of epoxy resin, a curing agent including 5-50 parts of an organic amine substance and 0.5-18 parts of an accelerator, and 0.5-20 parts of a coupling agent, 5-20 parts of a toughening agent, 100-600 parts of an abrasive material, 10-60 parts of fibers and 5-20 parts of a thixotropic agent which are included in the main agent and/or the curing agent. In an actual use process, the wear-resistant coating material enables the life of a new specimen to be extended to 1.5-2 times that of an original specimen, sometimes, enables the life to reach 4 times that of the original specimen under a working condition with a larger-particle material, and also can be repeatedly repaired.
Description
Technical field
The present invention relates to a kind of abrasion-resistant coating material.
Background technology
In the machinery equipment of the conveying of particle or slurry, processing and process, metal parts will produce wearing and tearing in use for some time thus scrap.If adopt wear-resistant coating carry out surface treatment to new metal parts or repair the metal parts after scrapping that weares and teares, thus the work-ing life of metal parts can be extended, reduce production cost.
The method that more current producers also attempt adopting epoxy resin to add abrasive material (silicon carbide, silicon carbide, high alumina ceramic) is repaired, effect is general, be difficult to the work-ing life reaching new workpiece, namely use import wear Protection agent reparation often also not reach the life-span of new workpiece half, the working strength that dismounting not only increases service worker frequently also have impact on normal production run.Contriver relies on the basis of ten several years wear-resistant coating development & production, and also trial epoxy material and abrasion resistant polyurethane material have carried out the reparative experiment work of a large amount of mechanical means, find simple epoxy material and polyurethane material still limited to the work-ing life of extension device.
Summary of the invention
The object of this invention is to provide a kind of abrasion-resistant coating material, be used for improving work-ing life of machinery equipment.
Contriver draws on empirical basis for many years, and abrasion-resistant coating material must meet the following conditions:
1. there is excellent bonding force, not only will form powerful bonding to substrate metal matrix, also require to form strong binding to the abrasive grain in material.
2. the cohesive strength of material wants high, and modulus wants large, once there be damage location to occur, can not under the washing away of particle Quick Extended and cause wear-resistant coating global failure.
3. material will have enough toughness and anti-fatigue ability, can resist the continuous impact of larger particles in material and not damage.
Therefore, the present invention proposes a kind of novel wear resistant coated material, and this material comprises:
Host, comprises epoxy resin 10-60 part;
Solidifying agent, comprises organic amine substance 5-50 part and promotor 0.5-18 part;
Be included in the coupling agent 0.5-20 part in host and/or solidifying agent, toughner 5-20 part, abrasive material 100-600 part, fiber 10-60 part and thixotropic agent 5-20 part.
Wherein, coupling agent can select KH550, KH560 or other coupling agent; Promotor can select DMP-30 or other promotor; Thixotropic agent can select gas phase or precipitated silica.
Host in the present invention and solidifying agent are configured separately in preparation process, and various component forms through Homogeneous phase mixing.During onsite application, then host and solidifying agent are carried out used in combination.
Under preferable case, during use, the proportioning of host and solidifying agent is 3: 1 ~ 4: 1.
Under preferable case, wherein organic amine material is selected from the one or more combination in phenolic aldehyde amine, contracting amine, aromatic amine, aliphatic amide, aliphatic cyclic amine, polymeric amide.
Under preferable case, wherein toughner is selected from the one or more combination in strange scholar's toughner, paracril, thiorubber.When selecting strange scholar's toughner, being added in host and preparing burden.
Under preferable case, wherein abrasive material is selected from the one or more combination in corundum in granules, silicon-carbide particle, high alumina ceramic particle.Wherein abrasive grain scope is 20 μm of-5mm, follows grain size distribution principle, carries out grating with the abrasive material being no less than 2 kinds of granularities.
In abrasion-resistant coating material of the present invention, add bulk strength and toughness that appropriate fiber significantly can strengthen coating.Fiber is preferably in aramid fiber, carbon fiber and glass fibre.When added fiber filament diameter less than 50 μm, length is when 0.5-2mm, and coating is under the operating mode of withstand large granule impact, and its effect is particularly remarkable.
Resin alloy polyphenylene oxide is nontoxic, transparent, relative density is little, have that excellent physical strength, proof stress are lax, creep resistance, thermotolerance, water tolerance, water-fast vapor permeability, dimensional stability.In abrasion-resistant coating material of the present invention, add the polyphenylene oxide micro mist of ultra-fine (particle diameter is below 20 μm), significantly can reduce the porosity in coating, improve the degree of compactness of coating, thus the shock resistance of coating and antistripping ability are significantly improved.
In use the frictional coefficient of coating need be reduced with the friction resistance of particle or slurries in order to reduce coating; appropriate antifriction material is also added with, wherein the flake graphite of the preferred self-lubricating property excellence of antifriction material, molybdenumdisulphide and boron nitride in abrasion-resistant coating material of the present invention.
In order to improve the work-ing life of coating further, in host of the present invention, be also added with appropriate NDI-PTMG modified epoxy.Contriver chooses and carrys out modified epoxy with 1,5-naphthalene diisocyanate (NDI) and PTMG (PTMG) base polyurethane prepolymer for use as.The rigidity of NDI molecule in NDI-PTMG system polyurethane elastomerics, regularity, symmetry are high, PTMG intensity, wear resistance are good, make NDI-PTMG system fundamentally can improve the degree that is separated of polyurethane system, obtain more excellent mechanical property and physicals, the characteristics such as goods have that high abrasion, high heat-resisting, high strength, high resilience, interior heat-dissipating are little, excellent dynamic performance, oil resistant, corrosion-resistant, radiation hardness, life-span are long, can be described as the material that best performance in urethane is different.But the application of this type of urethane is affected due to the performed polymer poor stability of NDI system.The excellent properties of NDI-PTMG system be incorporated into epoxy systems and utilize epoxy systems intensity is high, modulus is large feature can obtain a kind of basestocks of wear-resistant coating of excellent combination property, solving again the shortcoming that NDI system can not be stored simultaneously.
The basic procedure of NDI-PTMG modified epoxy is as follows: PTMG is fed into reactor heating and vacuumizes, then the NDI of melting is dropped into, (such as 80 ~ 110 DEG C) fully react at a proper temperature, drop into the epoxy resin measured again, make the part of hydroxyl cross-linking reaction on NCO group and epoxy molecule chain, thus obtain the epoxy resin that oxirane value is the NDI-PTMG modification of about 0.2.Wherein the ratio of components of NDI, PTMG and epoxy resin is preferably mol ratio 1.3-3.1: 1: 2-4.
Facts have proved, the wear-resistant coating wear resisting property adding NDI-PTMG modified epoxy is more than 1.5 times of high-chromium alloy; Shock resistance also improves several times than simple epoxy resin wear-resistant coating simultaneously.
Abrasion-resistant coating material of the present invention can be applied in the reparations such as Pulp pump, whizzer, magnetic separator, flotation cell, swirler (containing dense medium cyclone), pipeline, elbow, chute, Blower Housing, apparatus for separating fine powder from coarst powder, fly-ash separator, cyclone cylinder, powder separating machine, desulfuration absorbing tower and pre-protection.
Adopt abrasion-resistant coating material of the present invention in actual use, 1.5 ~ 2 times of new workpiece life-span can be extended, sometimes even can reach the life-span of 4 times for the operating mode that material particles is larger, and can repeatedly repeatedly repair.
Embodiment
Utilized the tailings pump of abrasion-resistant coating material of the present invention to Xiangyang Long Manglin Products Co., Ltd to carry out for many years put into practice repair.The work-ing life of new rich chromium cast iron tailings pump is generally 30-90 days, and the rich chromium cast iron tailings pump after scrapping to wear and tear, for repairing object, adopts abrasion-resistant coating material of the present invention to repair it.Specific construction technique is as follows:
(1) sandblasting is carried out to workpiece surface, obtain surface that is clean, dry, alligatoring.
(2) prepare high strength primer and be coated on the workpiece surface of sandblasting.
(3) prepare modified abrasion resistant coating and be coated on uncured primer surface and compacting.
(4) ambient cure or be heating and curing, conditions permit employing of trying one's best is heating and curing.
(5) repair matching part and reach fitted position.
(6) non-matching part is brushed face glue or is sprayed paint.
Onsite application is carried out to the rich chromium cast iron tailings pump after repairing, monitors its life-span.
" part " is herein by weight.
Embodiment 1
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, 69 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
69 days work-ing life after repairing.
Embodiment 2
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 8 parts, coupling agent KH5500.5 part, promotor 0.5 part, 70 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
80 days work-ing life after repairing.
Embodiment 3
Host: epoxy resin 35 parts, toughner paracril 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, 69 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
70 days work-ing life after repairing.
Embodiment 4
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, toughner paracril 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 8 parts, coupling agent KH5500.5 part, promotor 0.5 part, 70 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
81 days work-ing life after repairing.
Embodiment 5
Host: epoxy resin 35 parts, toughner thiorubber 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, 69 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
62 days work-ing life after repairing.
Embodiment 6
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, toughner thiorubber 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 8 parts, coupling agent KH5500.5 part, promotor 0.5 part, 70 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
73 days work-ing life after repairing.
Embodiment 7
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 260 parts, silicon carbide, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, 69 parts, silicon carbide, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
72 days work-ing life after repairing.
Embodiment 8
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, strange scholar's toughner 5 parts, 260 parts, silicon carbide, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 8 parts, coupling agent KH5500.5 part, promotor 0.5 part, 70 parts, silicon carbide, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
83 days work-ing life after repairing.
Embodiment 9
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 69 parts, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
77 days work-ing life after repairing
Embodiment 10
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 8 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 70 parts, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
88 days work-ing life after repairing
Embodiment 11
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, aramid fiber 15 parts, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 69 parts, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
77 days work-ing life after repairing.
Embodiment 12
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, aramid fiber 15 parts, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 8 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 70 parts, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
88 days work-ing life after repairing.
Embodiment 13
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, pottery 69 parts, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
77 days work-ing life after repairing.
Embodiment 14
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 8 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 70 parts, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
88 days work-ing life after repairing.
Embodiment 15
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: aromatic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, pottery 72.5 parts, thixotropic agent 1 part.
Host: solidifying agent=4: 1.
85 days work-ing life after repairing.
Embodiment 16
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: aromatic amine 5 parts, coupling agent KH5500.5 part, promotor 0.5 part, pottery 73 parts, thixotropic agent 1 part.
Host: solidifying agent=4: 1.
96 days work-ing life after repairing.
Embodiment 17
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: contracting amine 12 parts, coupling agent KH5500.5 part, promotor 0.5 part, pottery 65 parts, thixotropic agent 2 parts.
Host: solidifying agent=4: 1.
81 days work-ing life after repairing.
Embodiment 18
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: contracting amine 11 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 66 parts, thixotropic agent 2 parts.
Host: solidifying agent=4: 1.
92 days work-ing life after repairing.
Embodiment 19
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 6 parts, aliphatic cyclic amine 6 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 65 parts, thixotropic agent 2 parts.
Host: solidifying agent=4: 1.
95 days work-ing life after repairing.
Embodiment 20
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, strange scholar's toughner 5 parts, high alumina ceramic 260 parts, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 65 parts, thixotropic agent 2 parts.
Host: solidifying agent=4: 1.
93 days work-ing life after repairing.
Embodiment 21
Host: epoxy resin 35 parts, strange scholar's toughner 4 parts, paracril 5 parts, 254 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 7 parts, polymeric amide 4 parts, coupling agent KH5500.5 part, promotor 0.5 part, 67 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
87 days work-ing life after repairing.
Embodiment 22
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, strange scholar's toughner 4 parts, paracril 5 parts, 254 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 6.5 parts, kymene part, coupling agent KH5500.5 part, promotor 0.5 part, 68.5 parts, corundum, thixotropic agent 1.5 parts.
98 days work-ing life after repairing.
Embodiment 23
Host: epoxy resin 35 parts, strange scholar's toughner 4 parts, paracril 5 parts, 254 parts, silicon carbide, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 7 parts, polymeric amide 4 parts, coupling agent KH5500.5 part, promotor 0.5 part, 67 parts, silicon carbide, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
90 days work-ing life after repairing.
Embodiment 24
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, strange scholar's toughner 4 parts, paracril 5 parts, 254 parts, silicon carbide, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 6.5 parts, kymene part, coupling agent KH5500.5 part, promotor 0.5 part, 68.5 parts, silicon carbide, thixotropic agent 1.5 parts.
101 days work-ing life after repairing.
Embodiment 25
Host: epoxy resin 35 parts, strange scholar's toughner 4 parts, paracril 5 parts, high alumina ceramic 254 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 7 parts, polymeric amide 4 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 67 parts, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
95 days work-ing life after repairing.
Embodiment 26
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, strange scholar's toughner 4 parts, paracril 5 parts, high alumina ceramic 254 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 6.5 parts, kymene part, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 68.5 parts, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
106 days work-ing life after repairing.
Embodiment 27
Host: epoxy resin 35 parts, paracril 7 parts, 258 parts, silicon carbide, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: aromatic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 72.5 parts, thixotropic agent 1 part.
Host: solidifying agent=4: 1.
89 days work-ing life after repairing.
Embodiment 28
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, paracril 7 parts, 258 parts, silicon carbide, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: aromatic amine 5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 73 parts, thixotropic agent 1 part.
Host: solidifying agent=4: 1.
101 days work-ing life after repairing.
Embodiment 29
Host: epoxy resin 35 parts, high alumina ceramic 265 parts, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 6 parts, aliphatic cyclic amine 6 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 93 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
112 days work-ing life after repairing.
Embodiment 30
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, high alumina ceramic 265 parts, 15 parts, carbon fiber, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 94 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
124 days work-ing life after repairing.
Embodiment 31
Host: epoxy resin 20 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 5 parts, coupling agent KH5500.5 part, promotor 0.5 part, 68.5 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
60 days work-ing life after repairing.
Embodiment 32
Host: epoxy resin 50 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 12 parts, coupling agent KH5500.5 part, promotor 0.5 part, 69 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
58 days work-ing life after repairing.
Embodiment 33
Host: NDI-PTMG modified epoxy 10 parts, epoxy resin 25 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 8 parts, coupling agent KH5500.5 part, promotor 0.5 part, 70 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
73 days work-ing life after repairing.
Embodiment 34
Host: NDI-PTMG modified epoxy 25 parts, epoxy resin 10 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 8 parts, coupling agent KH5500.5 part, promotor 0.5 part, 70 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
81 days work-ing life after repairing.
Embodiment 35
Host: epoxy resin 35 parts, strange scholar's toughner 0 part, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, 68 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
57 days work-ing life after repairing.
Embodiment 36
Host: epoxy resin 35 parts, strange scholar's toughner 10 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, 70 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
62 days work-ing life after repairing.
Embodiment 37
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 160 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, 44 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
42 days work-ing life after repairing.
Embodiment 38
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 360 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, 93 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
59 days work-ing life after repairing.
Embodiment 39
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 1 part, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, 65 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
38 days work-ing life after repairing.
Embodiment 40
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 0 part, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, 65 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
38 days work-ing life after repairing.
Embodiment 41
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 30 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0.5 part, 72 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
59 days work-ing life after repairing.
Embodiment 42
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 6 parts, coupling agent KH5500.5 part, promotor 0.5 part, 72 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
26 days work-ing life after repairing.
Embodiment 43
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 12 parts, coupling agent KH5500.5 part, promotor 0.5 part, 72 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
53 days work-ing life after repairing.
Embodiment 44
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500 part, promotor 0.5 part, 72 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
68 days work-ing life after repairing.
Embodiment 45
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5501 part, promotor 0.5 part, 75 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
69 days work-ing life after repairing.
Embodiment 46
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 0 part, 75 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
67 days work-ing life after repairing.
Embodiment 47
Host: epoxy resin 35 parts, strange scholar's toughner 5 parts, 260 parts, corundum, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: phenolic aldehyde amine 9 parts, coupling agent KH5500.5 part, promotor 1 part, 75 parts, corundum, thixotropic agent 1.5 parts.
Host: solidifying agent=4: 1.
69 days work-ing life after repairing.
Embodiment 48
Host: epoxy resin 35 parts, high alumina ceramic 265 parts, polyphenylene oxide 15,15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 6 parts, aliphatic cyclic amine 6 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 102 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
119 days work-ing life after repairing.
Embodiment 49
Host: epoxy resin 35 parts, high alumina ceramic 265 parts, polyphenylene oxide 25,15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 6 parts, aliphatic cyclic amine 6 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 105 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
126 days work-ing life after repairing.
Embodiment 50
Host: epoxy resin 35 parts, high alumina ceramic 265 parts, polyphenylene oxide 35,15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 6 parts, aliphatic cyclic amine 6 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 109 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
127 days work-ing life after repairing.
Embodiment 51
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, polyphenylene oxide 25 parts, high alumina ceramic 265 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 102 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
136 days work-ing life after repairing.
Embodiment 52
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, polyphenylene oxide 35 parts, high alumina ceramic 265 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 105 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
152 days work-ing life after repairing.
Embodiment 53
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, polyphenylene oxide 45 parts, high alumina ceramic 265 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 109 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
152 days work-ing life after repairing.
Embodiment 54
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, polyphenylene oxide 35 parts, high alumina ceramic 265 parts, flake graphite 5 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 106 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
155 days work-ing life after repairing.
Embodiment 55
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, polyphenylene oxide 35 parts, high alumina ceramic 265 parts, molybdenumdisulphide 5 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 106 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
155 days work-ing life after repairing.
Embodiment 56
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, polyphenylene oxide 35 parts, high alumina ceramic 265 parts, boron nitride 5 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 106 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
155 days work-ing life after repairing.
Embodiment 57
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, polyphenylene oxide 35 parts, high alumina ceramic 265 parts, flake graphite 15 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 110 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
161 days work-ing life after repairing.
Embodiment 58
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, polyphenylene oxide 35 parts, high alumina ceramic 265 parts, flake graphite 25 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic 113 parts, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
162 days work-ing life after repairing.
Embodiment 59
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, polyphenylene oxide 35 parts, high alumina ceramic ball φ 1mm180 part, 85 parts, silicon carbide 36 order, flake graphite 25 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic ball φ 1mm80 part, 33 parts, silicon carbide 36 order, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
178 days work-ing life after repairing.
Embodiment 60
Host: NDI-PTMG modified epoxy 18 parts, epoxy resin 17 parts, polyphenylene oxide 35 parts, high alumina ceramic ball φ 1mm150 part, 80 parts, silicon carbide 36 order, 35 parts, silicon carbide 80 order, flake graphite 25 parts, 15 parts, glass fibre, thixotropic agent 5 parts.
Solidifying agent: aliphatic amide 5.5 parts, aliphatic cyclic amine 5.5 parts, coupling agent KH5500.5 part, promotor 0.5 part, high alumina ceramic ball φ 1mm65 part, 35 parts, silicon carbide 36 order, 13 parts, silicon carbide 80 order, thixotropic agent 1 part.
Host: solidifying agent=3: 1.
186 days work-ing life after repairing.
Can be found out by above embodiment, adopt abrasion-resistant coating material of the present invention in actual use, general life size repairs 1.5 ~ 2 times that the life-span can reach the new workpiece life-span, sometimes even can reach the life-span of 4 times, and can repeatedly repeatedly repair for the operating mode that material particles is larger.60 days tailings pump entrance pipe nipple life-spans of Xiangyang Long Manglin Products Co., Ltd, 90 days pump housing life-spans, utilize BD7044 (formula of embodiment 60) to scrap workpieces repair on May 28th, 2015 installation run so far (on December 7th, 2015) still operation.
Utilize reparation material of the present invention also to prepare wear-resistant coating for whizzer, magnetic separator, flotation cell, swirler (containing dense medium cyclone) simultaneously, all obtain good result of use, as BD709 (formula of embodiment 10) impact-resistant abrasion-proof coating can solve the gouging abrasion of falling from high altitude material in barrel of magnetic separator.The swirler, horizontal centrifuge of ball mill and dense medium separation can fill up damaged ceramic lining brick.Also good than the epoxy wear Protection agent of import in the result of use of vertical centrifugal machine feeding mouth blade surface.The effect exceeding imported product is all obtained in the application of the internal surfaces such as pipeline, elbow, chute, Blower Housing, apparatus for separating fine powder from coarst powder, fly-ash separator, cyclone cylinder, powder separating machine, desulfuration absorbing tower.
Claims (10)
1. an abrasion-resistant coating material, comprising:
Host, comprises epoxy resin 10-60 part;
Solidifying agent, comprises organic amine substance 5-50 part and promotor 0.5-18 part;
Be included in the coupling agent 0.5-20 part in host and/or solidifying agent, toughner 5-20 part, abrasive material 100-600 part, fiber 10-60 part and thixotropic agent 5-20 part.
2. abrasion-resistant coating material according to claim 1, wherein abrasive grain scope is 20 μm of-5mm, follows grain size distribution principle, carries out grating with the abrasive material being no less than 2 kinds of granularities.
3. abrasion-resistant coating material according to claim 1, wherein organic amine material is selected from the one or more combination in phenolic aldehyde amine, contracting amine, aromatic amine, aliphatic amide, aliphatic cyclic amine, polymeric amide.
4. abrasion-resistant coating material according to claim 1, wherein toughner is selected from the one or more combination in strange scholar's toughner, paracril, thiorubber.
5. abrasion-resistant coating material according to claim 1, wherein fiber is selected from the one or more combination in aramid fiber, carbon fiber, glass fibre.
6. abrasion-resistant coating material according to claim 1, wherein abrasive material is selected from the one or more combination in corundum in granules, silicon-carbide particle, high alumina ceramic particle.
7. abrasion-resistant coating material according to claim 1, is also included in the polyphenylene oxide 10-80 part in host and/or solidifying agent.
8. abrasion-resistant coating material according to claim 1, wherein also comprises NDI-PTMG modified epoxy 5-30 part in host.
9. abrasion-resistant coating material according to claim 1, is also included in the antifriction material 5-30 part in host and/or solidifying agent.
10. abrasion-resistant coating material according to claim 7, wherein antifriction material is selected from the one or more combination in flake graphite, molybdenumdisulphide, boron nitride.
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| CN114559009A (en) * | 2022-02-28 | 2022-05-31 | 玉环市东南塑胶机电有限公司 | Wear-resistant aluminum alloy shell for high-voltage GIS and machining process thereof |
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| CN116023840A (en) * | 2022-09-28 | 2023-04-28 | 天津鹰麟管材设备有限公司 | Nano ceramic anti-corrosion material |
| CN116023840B (en) * | 2022-09-28 | 2024-04-12 | 天津鹰麟管材设备有限公司 | Nano ceramic anti-corrosion material |
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