CN101503593A - Anti-corrosive anti-abrasion coating powder for metal pipeline - Google Patents

Anti-corrosive anti-abrasion coating powder for metal pipeline Download PDF

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Publication number
CN101503593A
CN101503593A CNA2009100679740A CN200910067974A CN101503593A CN 101503593 A CN101503593 A CN 101503593A CN A2009100679740 A CNA2009100679740 A CN A2009100679740A CN 200910067974 A CN200910067974 A CN 200910067974A CN 101503593 A CN101503593 A CN 101503593A
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China
Prior art keywords
powder
epoxy
parts
coating powder
corrosive
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Pending
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CNA2009100679740A
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Chinese (zh)
Inventor
王志高
葛汇业
王胜利
杨瑛
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TIANJIN XINTE COATING TECHNOLOGY Co Ltd
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TIANJIN XINTE COATING TECHNOLOGY Co Ltd
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Priority to CNA2009100679740A priority Critical patent/CN101503593A/en
Publication of CN101503593A publication Critical patent/CN101503593A/en
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Abstract

The invention discloses a corrosion protection abrasionproof coating powder used for a metallic pipe. The coating powder takes home-made epoxy powder E12 and metlbond modified epoxy as a main body, takes dicyandiamide and sebacic dihydrazide as curing agents, adopts polyvinyl butyral and ultrahigh molecular weight polyethylene for toughening and levelling the powder, and adopts silicon carbide, cast stone powder and graphite for the support of antifriction self lubrication. The unique abrasionproof corrosion protection powder coating is formed by an energy-saving manufacturing process and hot melt painting. The coating powder emphasizes the abrasionproof characteristic based on the stress laid on the corrosion protection powder performance, is used for strengthening the inner wall surface abrasionproof function of a pumping well oil pipe in an oil field caused by the eccentric wear of a sucker rod, and is extensionally used for metallic parts needing the strengthened abrasionproof function in a corrosive environment.

Description

The anti-corrosive anti-abrasion coating powder that is used for metallic conduit
Technical field
The present invention relates to a kind of coated powder, especially a kind of anti-corrosive anti-abrasion coating powder that is used for metallic conduit.
Background technology
The coated powder that is used for transition pipeline at present, double antiseptic powder in sending as western gas east, Hangzhou Gulf Great Bridge foundation pile coating etc., be the composite type phenol formaldehyde epoxy resin mostly, curing system selecting side hydroxy polyethers, phenolic aldehyde macromolecular compound and the composite solidifying agent of negatively charged ion catalytic curing.Its performance can satisfy the requirement of steel pipeline anti-corrision powder near external like product level.
But present applied inner-walls of duct double antiseptic powder has good corrosion resistance.But there is anti-mechanical wear deficiency, particularly to dark oil well, because of the influence of verticality, sucker rod partial wear is inevitable, and according to certain elephant rough estimates, the rod and tube partial-wear well accounts for rod-pumped well about 30%, because of eccentrically worn tubing, sucker rod year condemnation factor more than 10%, reach myriametres up to a hundred.The tube wall of oil pipe also stands sucker rod partial wear and wear down, perforation for a long time except being corroded.Adopt the powder that only has antiseptic property, effect does not reach requirement.
Summary of the invention
Technical problem to be solved by this invention is, provides a kind of and has anticorrosionly, has the anti-corrosive anti-abrasion coating powder that is used for metallic conduit of good anti-erosion performance simultaneously again.
In order to solve the problems of the technologies described above, the technical solution used in the present invention is: a kind of anti-corrosive anti-abrasion coating powder that is used for metallic conduit, and the ratio of weight and number of this each component of powder is as follows:
Resins, epoxy E12 80-70
Phenol aldehyde modified Resins, epoxy 20-30
Dyhard RU 100 1.6-2.0
Sebacic dihydrazide 4.2-3.5
Polyvinyl butyral acetal 10-12
Ultrahigh molecular weight polyethylene(UHMWPE) 9-11
Glass-cermic powder 64-70
Silicon carbide 30-25
Graphite Powder 99 0.6-0.9
The parts by weight of this each component of powder are Resins, epoxy E12:80 part; Phenol aldehyde modified Resins, epoxy: 20 parts; 11 parts of ultra high molecular polyethylenes; Polyvinyl butyral acetal: 10 parts; Dyhard RU 100: 2 parts; 3.5 parts of sebacic dihydrazides; Glass-cermic powder: 66 parts; 28 parts in silicon carbide; Graphite Powder 99: 0.8 part.
The oxirane value 0.12-0.14 of described phenol aldehyde modified Resins, epoxy, softening temperature 105-112 ℃.
The molecular weight of described ultrahigh molecular weight polyethylene(UHMWPE) is 150 ten thousand-250 ten thousand.
The molecular weight of described ultrahigh molecular weight polyethylene(UHMWPE) is 2,000,000.
Described glass-cermic powder granularity is 300-500 orders.
Described glass-cermic powder granularity is 400 orders.
Described carborundum granularity is 300-500 purpose superfine silicon carbides.
Described carborundum granularity is 400 purpose superfine silicon carbides.
The size range of described worth powder is the 80-400 order.
The invention has the beneficial effects as follows: 1. cost is low, and starting material from the social market buying, are removed from the powder manufacturing and extruded, cool off, give the polymers broken process in the conventional powder process by the specification demand in the prescription, and energy-conservation province consumption effect is remarkable.2. can strengthen inwall anti scuffing function to new steel pipe, to old pipe or the tube wall that worn and torn, after surface treatment, use the technology of the present invention, with the pipeline size of resuming work, the pipeline quality of reparation can be higher than several times of former new product time limit of service.Improved the whole life that product uses.Accomplish that product is made, utilized, the resource of recirculation and the good combination of environment.And may extend into similar under the heavy corrosion environment demand to the wear resistance of metal parts.
Embodiment
The present invention is used for the anti-corrosive anti-abrasion coating powder of metallic conduit, and the ratio of weight and number of this each component of powder is as follows:
Resins, epoxy E12 80-70
Phenol aldehyde modified Resins, epoxy 20-30
Dyhard RU 100 1.6-2.0
Sebacic dihydrazide 4.2-3.5
Polyvinyl butyral acetal 10-12
Ultrahigh molecular weight polyethylene(UHMWPE) 9-11
Glass-cermic powder 64-70
Silicon carbide 30-25
Graphite Powder 99 0.6-0.9
The parts by weight of this each component of powder are Resins, epoxy E12:80 part; Phenol aldehyde modified Resins, epoxy: 20 parts; 11 parts of ultra high molecular polyethylenes; Polyvinyl butyral acetal: 10 parts; Dyhard RU 100: 2 parts; 3.5 parts of sebacic dihydrazides; Glass-cermic powder: 66 parts; 28 parts in silicon carbide; Graphite Powder 99: 0.8 part.
The oxirane value 0.12-0.14 of described phenol aldehyde modified Resins, epoxy, softening temperature 105-112 ℃.
The molecular weight of described ultrahigh molecular weight polyethylene(UHMWPE) is 150 ten thousand-250 ten thousand.
The molecular weight of described ultrahigh molecular weight polyethylene(UHMWPE) is 2,000,000.
Described glass-cermic powder granularity is 300-500 orders.
Described glass-cermic powder granularity is 400 orders.
Described carborundum granularity is 300-500 purpose superfine silicon carbides.
Described carborundum granularity is 400 purpose superfine silicon carbides.
The size range of the described powder that makes is the 80-400 order.
Below in conjunction with specific embodiment the present invention is described in further detail:
1, select lower-cost phenol aldehyde modified Resins, epoxy for use: the phenol aldehyde modified Resins, epoxy CT-7255 with Ciba is a primary standard, by the development and production of Zibo Li Geer industrial and trading company (oxirane value eg/100g0.12-0.14, softening temperature 105-112 ℃).In the novolac epoxy molecular structure a plurality of epoxy group(ing) can be arranged, the cross-linking density of cured product and fragrant density is all than higher, hardness of filming and thermotolerance, chemical resistance and all relatively good to the sticking power of base material.
2, Resins, epoxy E12: the one CY D-014 of Resins, epoxy factory of Ba Ling petro-chemical corporation, the bisphenol A type epoxy resin typical products of middle molecular weight, it is low to have price, the characteristics of good toughness.
3, in the solidifying agent with sebacic dihydrazide and Dyhard RU 100: not only save cost but also promote water tolerance.
4, ultrahigh molecular weight polyethylene(UHMWPE): wear-resisting anti-sour characteristic is arranged, the extremely low and self-lubricating function of the water-absorbent of having again.
5, superfine silicon carbide and glass-cermic powder are excellent wear-resistant fillers, cooperate the lubricated of Graphite Powder 99 to play a decisive role to inside pipe wall is wear-resistant.
Embodiment 1
Prescription is Resins, epoxy E12:80g; Phenol aldehyde modified Resins, epoxy 20g; Ultra high molecular polyethylene (molecular weight 2,000,000) 11g; Polyvinyl butyral acetal 10g; Dyhard RU 100 2g; Certain herbaceous plants with big flowers diacid two hydrazides 3.5g; Glass-cermic powder 66g (400 order); Superfine silicon carbide (400 order) 28g; Graphite Powder 99: 0.8.
Concrete preparation method:
(1) Resins, epoxy E12, phenol aldehyde modified Resins, epoxy are pulverized at pulverizer, 80 mesh sieves select.
(2) with glass-cermic powder, superfine silicon carbide drying (110 ℃ * 4 hours).
(3) (1), (2) and other components were mixed in mixing machine 45 minutes.
(4) take out whole powders and go out from 80 mesh sieves through pulverizer again, be finished product.
Embodiment 2
Prescription is Resins, epoxy E12:70g; Phenol aldehyde modified Resins, epoxy 30g; Ultra high molecular polyethylene (molecular weight 1,500,000) 11g; Polyvinyl butyral acetal 12g; Dyhard RU 100 1.6g; Certain herbaceous plants with big flowers diacid two hydrazides 4.2g; Glass-cermic powder 70g (300 order); Superfine silicon carbide (300 order) 25g; Graphite Powder 99: 0.9.
The preparation method is with embodiment 1.
Embodiment 3
Prescription is Resins, epoxy E12:80g; Phenol aldehyde modified Resins, epoxy 20g; Ultra high molecular polyethylene (molecular weight 1,500,000) 10g; Polyvinyl butyral acetal 10g; Dyhard RU 100 2.0g; Certain herbaceous plants with big flowers diacid two hydrazides 3.5g; Glass-cermic powder 64g (500 order); Superfine silicon carbide (500 order) 25g; Graphite Powder 99: 0.6.
The preparation method is with embodiment 1.
The coating method of anti-corrosive anti-abrasion coating powder of the present invention and result of use: the in addition parts that the steel pipe inwall maybe need be sprayed are through surface degreasing dirt and sandblasting, require to make the apparent cleaning of steel according to GB Sa3 sandblast, with spraying or centrifugal blast cleaning, steel surface should not have dirt settlings such as visible grease, dirt, oxide skin, iron rust and paint coating, and this surface should show the even metal color and luster.
Reach 250 ℃ of design temperatures being heated to component table temperature, use the pipeline spraying equipment, implement dustless spraying, more than the thick 0.6mm of disposable spray.Then 180 ℃ of heat preservation solidification 45 minutes.
Coating flex resistance test shows, (amount of bow 5,7-6mm when coating is bent to the residual set amount greater than the maximum defluxion twice of steel pipe with matrix metal; Residual set amount 2,6-2,8mm), still remain intact.
The coating elongation test shows, is being under the yielding stress state coating strain that also meets with stresses together, and the feature that does not come off and do not crack., still remain intact greater than 0.2% at the unit elongation of stress (yield stress point is 457MPa) coating under 514-504MPa stress of hot-strip 27SiMn, do not have crackle and obscission.The coating current of anti-silt (sediment concentration 10kg/m 3, relative velocity 45m/s) wearing and tearing are more than 2 times of carbon steel.
The explanation of coating chemically-resistant soak test has excellent chemistry-resistant characteristic, stands the down-hole long term operation.
Soak medium The test specimen soak time Soak the result
Tap water 6 months Coating is smooth
Distilled water 6 months Coating is smooth
10%H 2SO 4 3 months Coating is smooth
20%HCL 36 days Coating is smooth
10%NaCL 3 months Coating is smooth
30%NaOH 6 months Coating is smooth
1%MDT 6 months Coating is smooth
The steel pipe of manufacturing again finished product after the spraying through analysis, is tested the tension resistance to impact shock of coating, and before the steel pipe body did not reach tension set, the coating of steel pipe can not damaged.The wearing test of coating under simulation downhole corrosion condition under the 35MPa pressure, anti-erosion performance satisfies the working life requirement more than 2 times of former steel pipe.
The present invention be directed to double antiseptic powder coating abrasion performance shortcoming, in wear-resistant filler, increase superfine silicon carbide, do toughness reinforcing and the enhancing acid resistance with ultrahigh molecular weight polyethylene(UHMWPE) (molecular weight 2,000,000), and increased self-lubricating structure, form pipeline behind the coating coated and make the anti scuffing characteristic again.
Make back coating mechanical property again
Project Cohesive strength MPa Shearing resistance MPa Shock strength kg-cm Sled stripping during water boil 24
Test value 61.7,64.8,58.2 (61.57) 36.2,35.1,36.4 (35.9) 50 The self-lubricating of coating light
During water boil 24 46.4,46.8,46.9 (46.7) 32.2,28.9,32.6 (31.2) 50 Sled can not shelled
In the bracket is mean value.
Make the coating mechanical property again and exceeded hydraulicefficiency machinery erosion resistant job requirement under water for a long time, the rod-pumped well operating mode is not as the hydraulicefficiency machinery complexity, and former in addition double antiseptic powder fundamental property is made coating again and met anticorrosion and wear-resistant requirement.
Pipeline of the present invention is made inwall anti scuffing compound resin coated powder again; use hot coating process; coated is on inner-walls of duct; make high moisture, Gao Hansha and high salinity in the mixed solution of oil reservoir extraction formed to recovering the oil or the heavy corrosion of transport pipe and the environment of wearing and tearing; unaffected or rare abrasion destroys, and inner-walls of duct is protected.Especially can be at the oil and water well oil pipe, strengthened and prolonged the life-cycle life cycle because of abrasion that sucker rod partial wear caused destroys the tube wall that makes oil pipe early failure.
In sum, content of the present invention is not limited in the above-described embodiment, and the knowledgeable people in the same area can propose other embodiment easily within technical director's thought of the present invention, but this embodiment comprises within the scope of the present invention.

Claims (10)

1, a kind of anti-corrosive anti-abrasion coating powder that is used for metallic conduit is characterized in that, the ratio of weight and number of this each component of powder is as follows:
Resins, epoxy E12 80-70
Phenol aldehyde modified Resins, epoxy 20-30
Dyhard RU 100 1.6-2.0
Sebacic dihydrazide 4.2-3.5
Polyvinyl butyral acetal 10-12
Ultrahigh molecular weight polyethylene(UHMWPE) 9-11
Glass-cermic powder 64-70
Silicon carbide 30-25
Graphite Powder 99 0.6-0.9
2, the anti-corrosive anti-abrasion coating powder that is used for metallic conduit according to claim 1 is characterized in that, the parts by weight of this each component of powder are Resins, epoxy E12:80 part; Phenol aldehyde modified Resins, epoxy: 20 parts; 11 parts of ultra high molecular polyethylenes; Polyvinyl butyral acetal: 10 parts; Dyhard RU 100: 2 parts; 3.5 parts of sebacic dihydrazides; Glass-cermic powder: 66 parts; 28 parts in silicon carbide; Graphite Powder 99: 0.8 part.
3, the anti-corrosive anti-abrasion coating powder that is used for metallic conduit according to claim 1 is characterized in that, the oxirane value 0.12-0.14 of described phenol aldehyde modified Resins, epoxy, softening temperature 105-112 ℃.
4, the anti-corrosive anti-abrasion coating powder that is used for metallic conduit according to claim 1 is characterized in that, the molecular weight of described ultrahigh molecular weight polyethylene(UHMWPE) is 150 ten thousand-250 ten thousand.
5, the anti-corrosive anti-abrasion coating powder that is used for metallic conduit according to claim 4 is characterized in that, the molecular weight of described ultrahigh molecular weight polyethylene(UHMWPE) is 2,000,000.
6, the anti-corrosive anti-abrasion coating powder that is used for metallic conduit according to claim 1 is characterized in that, described glass-cermic powder granularity is 300-500 orders.
7, the anti-corrosive anti-abrasion coating powder that is used for metallic conduit according to claim 6 is characterized in that, described glass-cermic powder granularity is 400 orders.
8, the anti-corrosive anti-abrasion coating powder that is used for metallic conduit according to claim 1 is characterized in that, described carborundum granularity is 300-500 purpose superfine silicon carbides.
9, the anti-corrosive anti-abrasion coating powder that is used for metallic conduit according to claim 8 is characterized in that, described carborundum granularity is 400 purpose superfine silicon carbides.
10, the anti-corrosive anti-abrasion coating powder that is used for metallic conduit according to claim 1 is characterized in that, the size range of the described powder that makes is the 80-400 order.
CNA2009100679740A 2009-02-27 2009-02-27 Anti-corrosive anti-abrasion coating powder for metal pipeline Pending CN101503593A (en)

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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102417785A (en) * 2011-12-01 2012-04-18 北京科美新防腐技术有限公司 Preparation method of epoxy anticorrosive paint for pipeline
CN103788830A (en) * 2014-01-20 2014-05-14 南通华新环保设备工程有限公司 Acid and alkali resistant coating for stirring equipment and preparation method thereof
US20150086711A1 (en) * 2012-06-13 2015-03-26 Valspar Sourcing, Inc. Low Application Temperature Powder Coating
CN105440882A (en) * 2015-11-30 2016-03-30 中国航空工业集团公司北京航空材料研究院 Nano-modification anti-corrosion and scouring-resistant paint and preparing method
CN107574366A (en) * 2017-09-03 2018-01-12 安徽天裕汽车零部件制造有限公司 A kind of automobile hydraulic support and its production method
CN107641378A (en) * 2017-11-13 2018-01-30 洛阳国润新材料科技股份有限公司 A kind of production technology of line plastic-steel tube modified ultra-high molecular weight polyethylene anticorrosive paint
CN108102505A (en) * 2017-12-05 2018-06-01 上海森琅建设工程有限公司 A kind of pipe internal coating, its preparation method and the application in underground pipe network
CN113045964A (en) * 2021-03-23 2021-06-29 吕学民 Special material for petroleum pipe eccentric wear-resistant cladding coating and preparation method thereof

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102417785A (en) * 2011-12-01 2012-04-18 北京科美新防腐技术有限公司 Preparation method of epoxy anticorrosive paint for pipeline
US20150086711A1 (en) * 2012-06-13 2015-03-26 Valspar Sourcing, Inc. Low Application Temperature Powder Coating
EP2861679A4 (en) * 2012-06-13 2016-03-23 Valspar Sourcing Inc Low application temperature powder coating
CN103788830A (en) * 2014-01-20 2014-05-14 南通华新环保设备工程有限公司 Acid and alkali resistant coating for stirring equipment and preparation method thereof
CN105440882A (en) * 2015-11-30 2016-03-30 中国航空工业集团公司北京航空材料研究院 Nano-modification anti-corrosion and scouring-resistant paint and preparing method
CN105440882B (en) * 2015-11-30 2017-08-15 中国航空工业集团公司北京航空材料研究院 A kind of nano modification anticorrosion resistance to erosion coating and preparation method
CN107574366A (en) * 2017-09-03 2018-01-12 安徽天裕汽车零部件制造有限公司 A kind of automobile hydraulic support and its production method
CN107641378A (en) * 2017-11-13 2018-01-30 洛阳国润新材料科技股份有限公司 A kind of production technology of line plastic-steel tube modified ultra-high molecular weight polyethylene anticorrosive paint
CN108102505A (en) * 2017-12-05 2018-06-01 上海森琅建设工程有限公司 A kind of pipe internal coating, its preparation method and the application in underground pipe network
CN113045964A (en) * 2021-03-23 2021-06-29 吕学民 Special material for petroleum pipe eccentric wear-resistant cladding coating and preparation method thereof

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Open date: 20090812