CN105385225A - Special colorless printing ink for high-temperature protection of water-washing aluminum and preparation method of special colorless printing ink - Google Patents
Special colorless printing ink for high-temperature protection of water-washing aluminum and preparation method of special colorless printing ink Download PDFInfo
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- CN105385225A CN105385225A CN201510827040.8A CN201510827040A CN105385225A CN 105385225 A CN105385225 A CN 105385225A CN 201510827040 A CN201510827040 A CN 201510827040A CN 105385225 A CN105385225 A CN 105385225A
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Abstract
The invention discloses a special colorless printing ink for high-temperature protection of water-washing aluminum. The special colorless printing ink is prepared from the following raw materials in parts by weight: 45 to 55 parts of alcohol ester soluble polyurethane resin liquid, 12 to 22 parts of ester soluble ternary chloride-acetate resin liquid, 20 to 32 parts of an alcohol and ester mixed solvent and 1 to 2 parts of heat-resisted addition agent liquid. The special colorless printing ink is prepared by selecting environment-friendly film-forming main resin, auxiliary resin, an environment-friendly solvent and a special addition agent and stirring at a high speed. The product has the characteristics of good solvent releasing property, flexibility, high temperature resistance and the like; the printing ink can be effectively prevented from being corroded by aluminum steam in an evaporation process, and the printing ink has no color change and has a very strong metal luster effect. The special colorless printing ink has relatively good affinity with a printing ink film-forming surface and relatively good interface compatibility with an aluminum layer; the one-time stripping force of an aluminum washing composite bag produced by the special colorless printing ink is about 1.5N/15mm and the product has stable quality and huge market value.
Description
Technical field
The invention belongs to printing-ink technical field, be specifically related to special colorless ink of a kind of washing aluminium high temperature protection and preparation method thereof.
Background technology
Along with Flexible Package Market constantly innovation and development, a kind of novel package one is washed aluminium packaging and is arisen at the historic moment, this type of packaging is domestic and even print request is the highest in the world at present, one of packaging that design effect is the most exquisite, improve grade most, be widely used in the outer packaging in the fields such as food, tobacco bale, gift, daily-use chemical industry, electronics, medicine, makeup, apply more in the world, domestic existing minority scale color printing enterprise applies this new production line.
What is called washes aluminium packaging, its technique be by print after color film carry out full version and aluminize, wash off by the aluminium lamination clear water of design requirements by subregion again, and then with other base material compounds, general product structure is VMPET//BOPA//LDPE, PET//BOPA//LDPE or other structures.Compared with common packaging of aluminizing, there is obvious superiority: the common whole bag surface of packaging of aluminizing has aluminium lamination to hide, content cannot be shown very well, wash aluminium packaging and then in the region needing to set off with aluminium lamination printed patterns gloss, luster effect can be reached, also can design transparent visual effect region, therefore, wash aluminium packaging to make through special technique, have outstanding outward appearance and necessarily false proof double effects, market application widely.
The mode of washing aluminium is more, but the most applicable enterprise batch production and the higher mode of production efficiency is that clear water washes aluminium method.The concrete production technique of washing aluminium packaging is as follows: print (printing environment-friendly polyurethane ink, the special colorless ink of inked areas printing washing aluminium high temperature protection, part inked areas or void region printing water-based wash aluminium dumb light ink), aluminize, wash aluminium, compound, slaking, bag.
Due to the singularity of its production technique, fed back by market survey, at present, there is following limitation in the high temperature protection gloss oil that domestic several ink enterprises produce:
(1) do not mate with printing-ink above, add the production cost of color printing enterprise and reduce production efficiency.Require during printing to add a certain amount of solidifying agent in each color ink, and the amount of printing surface larger interpolation solidifying agent is larger, finishes printing the color film of rear requirement and just can aluminize after the curing chamber of 35 ~ 45 DEG C arranges 24 ~ 46h.
(2) be not easy to accurate chromatography, version printing have to be expired, and easily play printing wire-drawing.
(3) ink is corroded in evaporate process.Color film is after vacuum aluminum-coated, and ink layer is destroyed blackening, does not have metalluster.
(4) with ink film forming face affinity and poor with aluminium lamination interface compatibility, after causing compound, sack peeling force is low, generally≤0.4N/15mm (GB/T10004-2008 " composite packing film, bag dry laminating, extrude compound " standard-required >=0.6N/15mm), the easy aliquation of sack, condemnation factor is very high.
(5) have in document and mention the water-based that ink company invented and wash aluminium protection gloss oil; its water-base resin used requires ability complete drying under 150 DEG C of conditions; existing printing equipment and printed substrate all can not meet, and therefore it does not have general applicability.
Summary of the invention
In order to solve problems of the prior art, the invention provides special colorless ink of a kind of washing aluminium high temperature protection and preparation method thereof.
The technical solution used in the present invention is:
The special colorless ink of a kind of washing aluminium high temperature protection, comprises the raw material of following parts by weight:
Alcohol ester soluble polyurethane resin liquid 45 ~ 55 parts
The molten ternary chlorine vinegar resin liquid of ester 12 ~ 22 parts
Ester, alcohol mixed solvent 20 ~ 32 parts
Heat resistance accessory liquid 1 ~ 2 part.
Further, described ester, alcohol mixed solvent are specially the mixed solvent of ethyl acetate and ethanol, and wherein the weight ratio of ethyl acetate and ethanol is 1: 1.
Further, described heat resistance accessory liquid selects silane coupling agent or titanate coupling agent to be prepared from.
Further, the heat resistance accessory liquid that described silane coupling agent or titanate coupling agent are made is prepared as follows: by weight, 50 parts of ethyl acetate, alcohol mixed solvent are dropped into PP Pipe Compound cylinder, wherein the weight ratio of ethyl acetate and ethanol is 1: 1, slowly drop into 50 parts of silane coupling agents or titanate coupling agent again, open dispersion machine, speed governing to 500 ~ 600r/min, obtained after stirring 5 ~ 10min.
The present invention washes the preparation method of the special colorless ink of aluminium high temperature protection, comprises the following steps:
45 ~ 55 parts of alcohol ester soluble polyurethane resin liquid are dropped into dispersion machine, speed governing to 300 ~ 400r/min, drops into 12 ~ 22 parts of molten ternary chlorine vinegar resin liquid of ester, then calls in 10 ~ 15 parts of esters, alcohol mixed solvent, speed governing to 1000 ~ 1200r/min, stir 15 ~ 20min, until there is vitreous state in liquid, speed governing to 300 ~ 400r/min, add remaining 12 ~ 17 parts of esters, alcohol mixed solvent and 1 ~ 2 part of heat resistance accessory liquid, speed governing to 800 ~ 1000r/min, stirs 5 ~ 10min, obtained finished product.
Alcohol ester soluble polyurethane resin liquid of the present invention is prepared by following method:
By weight, 50 parts of esters, alcohol mixed solvent are dropped into PP Pipe Compound cylinder, dispersion machine speed governing to 300 ~ 400r/min, the block resin of slow input 32 parts of esters, alcohol-soluble polyurethane, speed governing to 1200 ~ 1500r/min, sealing stirring 90 ~ 120min, adds remaining 28 parts of esters, alcohol mixed solvents, speed governing to 800 ~ 1000r/min, stir 5 ~ 10min, metering, accurately, send QC, resin liquid fineness, viscosity, transparency are tested, drops into special storage tank by corresponding pipeline after qualified for subsequent use.
Ester of the present invention molten ternary chlorine vinegar resin liquid is prepared by following method:
By weight, 50 parts of esters, alcohol mixed solvent are dropped into PP Pipe Compound cylinder, dispersion machine speed governing to 300 ~ 400r/min, the molten ternary chlorine vinegar powdex of slow input 20 parts of esters, speed governing to 1200 ~ 1500r/min, sealing stirring 40 ~ 60min, adds remaining 30 parts of esters, alcohol mixed solvents, be adjusted to 800 ~ 1000r/min, stir 5 ~ 10min, metering, accurately, send QC, resin liquid fineness, viscosity, transparency are tested, drops into special storage tank by corresponding pipeline after qualified for subsequent use.
The present invention washes aluminium high temperature protection special colorless ink Product checking data as following table:
Name of product: the special colorless ink of washing aluminium high temperature protection
Product operative norm: People's Republic of China (PRC) light industry standard QB/T2024-2012 " intaglio plate plastics film compound oil ink "
The washing aluminium packing bag detection data that application the present invention washes the production of aluminium high temperature protection special colorless ink are as follows:
Packing bag title: wash aluminium laminated bag
Packing bag operative norm: National Standard of the People's Republic of China GB/T10004-2008 " composite packing film, bag dry laminating, extrude compound "
Beneficial effect of the present invention:
(1) production technique of the present invention is simple, and critical control point is few, and quality more can ensure well.
(2) the present invention and ink reactionless, molten phenomenon again can not be produced to ink.
(3) ink of the present invention and printing-ink compatibleness and release property good, during printing, do not need to add solidifying agent in printing-ink, finishing printing does not need slaking to place just can to enter operation of aluminizing immediately, greatly increase work efficiency and reduce production cost.
(4) due to excellent with printing-ink compatibleness, during printed book invention ink, few white ink is wherein added, just can accurately chromatography, main portions and secondary position overprint error≤0.2mm, word, pattern there will not be incompleteness, the phenomenon such as imperfect, avoids printing or scraps after washing aluminium.
(5) ink of the present invention has good high temperature protection effect, can available protecting ink in evaporate process not by aluminium steam corrosion (aluminium temperature of fusion is 1200 DEG C ~ 1400 DEG C), ink nondiscoloration and there is very strong metalluster effect.
(6) the present invention and ink film forming face have good affinity, good interface compatibility is had with aluminium lamination, what application the present invention produced washes aluminium bag one deck peeling force and can reach about 1.5N/15mm, higher than GB/T10004-2008 " composite packing film, bag dry laminating, extrude compound " standard-required.
Embodiment
Below in conjunction with the specific embodiment of the invention, be clearly and completely described technical scheme of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
The special colorless ink of a kind of washing aluminium high temperature protection, comprises the raw material of following parts by weight:
Alcohol ester soluble polyurethane resin liquid 45 parts
The molten ternary chlorine vinegar resin liquid of ester 22 parts
Ester, alcohol mixed solvent 32 parts
Heat resistance accessory liquid 1 part;
Described ester, alcohol mixed solvent are specially the mixed solvent of ethyl acetate and ethanol, and wherein the weight ratio of ethyl acetate and Virahol is 1: 1;
Described heat resistance accessory liquid selects silane coupling agent or titanate coupling agent to be prepared from;
The heat resistance accessory liquid that described silane coupling agent or titanate coupling agent are made is prepared as follows: by weight, 50 parts of ethyl acetate, alcohol mixed solvent are dropped into PP Pipe Compound cylinder, wherein the weight ratio of ethyl acetate and ethanol is 1: 1, slowly drop into 50 parts of silane coupling agents or titanate coupling agent again, open dispersion machine, speed governing to 500 ~ 600r/min, obtained finished product after stirring 5 ~ 10min;
Described alcohol ester soluble polyurethane resin liquid is prepared by following method: by weight, 50 parts of esters, alcohol mixed solvent are dropped into PP Pipe Compound cylinder, dispersion machine speed governing to 300 ~ 400r/min, the block resin of slow input 32 parts of esters, alcohol-soluble polyurethane, speed governing to 1200 ~ 1500r/min, sealing stirring 90 ~ 120min, add remaining 28 parts of esters, alcohol mixed solvents, speed governing to 800 ~ 1000r/min, stir 5 ~ 10min, metering, accurately, send QC, resin liquid fineness, viscosity, transparency are tested, drops into special storage tank by corresponding pipeline after qualified for subsequent use;
Described ester molten ternary chlorine vinegar resin liquid is prepared by following method: by weight, 50 parts of esters, alcohol mixed solvent are dropped into PP Pipe Compound cylinder, dispersion machine speed governing to 300 ~ 400r/min, the molten ternary chlorine vinegar powdex of slow input 20 parts of esters, speed governing to 1200 ~ 1500r/min, sealing stirring 40 ~ 60min, add remaining 30 parts of esters, alcohol mixed solvents, be adjusted to 800 ~ 1000r/min, stir 5 ~ 10min, metering, accurately, send QC, resin liquid fineness, viscosity, transparency are tested, drops into special storage tank by corresponding pipeline after qualified for subsequent use;
The present invention wash aluminium high temperature protection specially and colorless ink prepared by following method:
According to the above ratio, alcohol ester soluble polyurethane resin liquid is dropped into dispersion machine, speed governing to 300 ~ 400r/min, drop into the molten ternary chlorine vinegar resin liquid of ester, then call in part part ester, alcohol mixed solvent, speed governing to 1000 ~ 1200r/min, stir 15 ~ 20min, until there is vitreous state in liquid, speed governing to 300 ~ 400r/min, adds remaining part ester, alcohol mixed solvent and heat resistance accessory liquid, speed governing to 800 ~ 1000r/min, stir 5 ~ 10min, obtained finished product.
Embodiment 2
The special colorless ink of a kind of washing aluminium high temperature protection, comprises the raw material of following parts by weight:
Alcohol ester soluble polyurethane resin liquid 48.7 parts
The molten ternary chlorine vinegar resin liquid of ester 20 parts
Ester, alcohol mixed solvent 30 parts
Heat resistance accessory liquid 1.3 parts;
The other the same as in Example 1.
Embodiment 3
The special colorless ink of a kind of washing aluminium high temperature protection, comprises the raw material of following parts by weight:
Alcohol ester soluble polyurethane resin liquid 50 parts
The molten ternary chlorine vinegar resin liquid of ester 21 parts
Ester, alcohol mixed solvent 27.5 parts
Heat resistance accessory liquid 1.5 parts;
The other the same as in Example 1.
Embodiment 4
The special colorless ink of a kind of washing aluminium high temperature protection, comprises the raw material of following parts by weight:
Alcohol ester soluble polyurethane resin liquid 54 parts
The molten ternary chlorine vinegar resin liquid of ester 18 parts
Ester, alcohol mixed solvent 26 parts
Heat resistance accessory liquid 2 parts;
The other the same as in Example 1.
Embodiment 5
The special colorless ink of a kind of washing aluminium high temperature protection, comprises the raw material of following parts by weight:
Alcohol ester soluble polyurethane resin liquid 55 parts
The molten ternary chlorine vinegar resin liquid of ester 21.2 parts
Ester, alcohol mixed solvent 22 parts
Heat resistance accessory liquid 1.8 parts;
The other the same as in Example 1.
Embodiment 6
The special colorless ink of a kind of washing aluminium high temperature protection, comprises the raw material of following parts by weight:
Alcohol ester soluble polyurethane resin liquid 53 parts
The molten ternary chlorine vinegar resin liquid of ester 17 parts
Ester, alcohol mixed solvent 28.8 parts
Heat resistance accessory liquid 1.2 parts;
The other the same as in Example 1.
During ink printing of the present invention, chromatography is accurate, do not need to add solidifying agent in printing-ink, finish printing and do not need slaking placement just can aluminize immediately, with ink affinity and good with aluminium lamination interface compatibility, the ink metal bright light effect that aluminium lamination sets off clearly, sack stripping strength reaches 1.5N/15mm, higher than GB/T10004-2008 " composite packing film, bag dry laminating, extrude compound " standard-required, other physical indexs also can meet respective standard requirement, exquisite appearance, marketable value is huge.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (5)
1. wash the special colorless ink of aluminium high temperature protection, it is characterized in that, comprise the raw material of following parts by weight:
Alcohol ester soluble polyurethane resin liquid 45 ~ 55 parts
The molten ternary chlorine vinegar resin liquid of ester 12 ~ 22 parts
Ester, alcohol mixed solvent 20 ~ 32 parts
Heat resistance accessory liquid 1 ~ 2 part.
2. the special colorless ink of washing aluminium high temperature protection according to claim 1, is characterized in that, described ester, alcohol mixed solvent are specially the mixed solvent of ethyl acetate and ethanol, and wherein the weight ratio of ethyl acetate and ethanol is 1: 1.
3. the special colorless ink of washing aluminium high temperature protection according to claim 1, is characterized in that, described heat resistance accessory liquid selects silane coupling agent or titanate coupling agent to be prepared from.
4. the preparation method of the special colorless ink of washing aluminium high temperature protection according to claim 3; it is characterized in that: the heat resistance accessory liquid that described silane coupling agent or titanate coupling agent are made is prepared as follows: by weight; 50 parts of ethyl acetate, alcohol mixed solvent are dropped into PP Pipe Compound cylinder; wherein the weight ratio of ethyl acetate and ethanol is 1: 1; slowly drop into 50 parts of silane coupling agents or titanate coupling agent again; open dispersion machine; speed governing to 500 ~ 600r/min, obtained after stirring 5 ~ 10min.
5. the preparation method of the special colorless ink of washing aluminium high temperature protection described in any one of Claims 1 to 4, is characterized in that, comprise the following steps:
45 ~ 55 parts of alcohol ester soluble polyurethane resin liquid are dropped into dispersion machine, speed governing to 300 ~ 400r/min, drops into 12 ~ 22 parts of molten ternary chlorine vinegar resin liquid of ester, then calls in 10 ~ 15 parts of esters, alcohol mixed solvent, speed governing to 1000 ~ 1200r/min, stir 15 ~ 20min, until there is vitreous state in liquid, speed governing to 300 ~ 400r/min, add remaining 12 ~ 17 parts of esters, alcohol mixed solvent and 1 ~ 2 part of heat resistance accessory liquid, speed governing to 800 ~ 1000r/min, stirs 5 ~ 10min, obtained finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510827040.8A CN105385225B (en) | 2015-11-24 | 2015-11-24 | Dedicated colorless ink of a kind of washing aluminium high temperature protection and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510827040.8A CN105385225B (en) | 2015-11-24 | 2015-11-24 | Dedicated colorless ink of a kind of washing aluminium high temperature protection and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105385225A true CN105385225A (en) | 2016-03-09 |
| CN105385225B CN105385225B (en) | 2019-02-15 |
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| CN201510827040.8A Active CN105385225B (en) | 2015-11-24 | 2015-11-24 | Dedicated colorless ink of a kind of washing aluminium high temperature protection and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106380942A (en) * | 2016-08-25 | 2017-02-08 | 惠州兴鑫涂料化工有限公司 | Transparent gloss oil for food packaging films |
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| CN102618117A (en) * | 2012-03-25 | 2012-08-01 | 重庆宏图油墨有限公司 | Single-liquid environment-friendly universal compound printing ink and preparation method for same |
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| JP2013059974A (en) * | 2011-09-15 | 2013-04-04 | Seiko Epson Corp | Transfer medium, method of manufacturing the same, and transfer product |
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2015
- 2015-11-24 CN CN201510827040.8A patent/CN105385225B/en active Active
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| JP2013059974A (en) * | 2011-09-15 | 2013-04-04 | Seiko Epson Corp | Transfer medium, method of manufacturing the same, and transfer product |
| CN102618117A (en) * | 2012-03-25 | 2012-08-01 | 重庆宏图油墨有限公司 | Single-liquid environment-friendly universal compound printing ink and preparation method for same |
| CN102675981A (en) * | 2012-06-01 | 2012-09-19 | 黄山新力油墨科技有限公司 | White ink suitable for solvent-free glue compositing and preparation method thereof |
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Cited By (1)
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| CN106380942A (en) * | 2016-08-25 | 2017-02-08 | 惠州兴鑫涂料化工有限公司 | Transparent gloss oil for food packaging films |
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| CN105385225B (en) | 2019-02-15 |
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Address after: 408102 Group 7 of Da'e Village, Lidu Street Office, Fuling District, Chongqing Patentee after: Chongqing Hongtu New Materials Technology Co., Ltd. Address before: 408102 Group 7 of Da'e Village, Lidu Street Office, Fuling District, Chongqing Patentee before: CHONGQING HONGTU INK CO., LTD. |
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Denomination of invention: Special colorless printing ink for high-temperature protection of water-washing aluminum and preparation method of special colorless printing ink Effective date of registration: 20200421 Granted publication date: 20190215 Pledgee: Chongqing Fuling Branch of Bank of China Limited Pledgor: Chongqing Hongtu New Materials Technology Co.,Ltd. Registration number: Y2020500000004 |
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Date of cancellation: 20210623 Granted publication date: 20190215 Pledgee: Chongqing Fuling Branch of Bank of China Ltd. Pledgor: Chongqing Hongtu New Materials Technology Co.,Ltd. Registration number: Y2020500000004 |