CN105352903B - Water body light absorbs and attenuation meter - Google Patents

Water body light absorbs and attenuation meter Download PDF

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CN105352903B
CN105352903B CN201510833317.8A CN201510833317A CN105352903B CN 105352903 B CN105352903 B CN 105352903B CN 201510833317 A CN201510833317 A CN 201510833317A CN 105352903 B CN105352903 B CN 105352903B
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window
water body
receiving channel
channel
decay
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CN105352903A (en
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许占堂
孙兆华
邹国旺
周雯
王桂芬
李彩
杨跃忠
曹文熙
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South China Sea Institute of Oceanology of CAS
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South China Sea Institute of Oceanology of CAS
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Abstract

The present invention provides a kind of water body light absorbs attenuation coefficient measuring instrument, and it is mainly made up of luminescence unit, sampling unit, probe unit and signal processing and analysis unit;Luminescence unit provides spectrum for water body parameter measurement and enriches the stable light source of performance;Sampling unit mainly realizes the sampling of water body example;Probe unit realizes the detection of optical radiation signal, and the parameter information of water body is carry in the signal;Signal processing and analysis unit can carry out spectrum analysis to the information detected, be that water body decay and absorption parameter calculate and provide underlying parameter data.The measuring instrument that the present invention is provided is capable of the measuring instrument of in site measurement water body light absorbs and decay, simplifies the measurement of water body light absorbs attenuation coefficient, and provides and reliably support for further analyzing water body Size Structure.

Description

Water body light absorbs and attenuation meter
Technical field
The present invention relates to a kind of optical measuring apparatus, and in particular to a kind of system of measurement water body optical absorption/attenuation coefficient.
Background technology
Water body optical absorption/attenuation coefficient characterizes absorption and attenuation of the water body to light, only with the material composition in water body It is relevant, it is two big inherent optics properties of water body independent of the geometry of water body light field.Light passes through medium, a part of quilt Absorb, another part deviates the former direction of propagation and scattered;The collective effect of absorption and scattering causes the decay of light.
The change of the absorption coefficient of light and light attenuation coefficient has close contact with water constituent.In addition to pure water, light Absorption coefficient is contributed from the absorption of coloured dissolved organic matters (CDOM), phytoplankton (ph) and non-admissible solutions (NAP); Suspended particulate substance is the main source for causing light scattering, and light-decay characteristic is determined together with the optical absorption characteristics of different component Variation characteristic.
(a, unit is m to the absorption coefficient of light of water body-1) a branch of directional light is defined as through a unlimited thin uniform dielectric, light Absorptivity (A) and the ratio of dielectric thickness (⊿ r), its definition can be represented with below equation:
A (λ)=2.303 × OD (λ)/r
Wherein, OD (λ) represents optical density (OD), and r represents light path.
In addition to pure water, water body absorption coefficient a (λ) can simply be divided into coloured dissolved organic matters, suspended particulate substance etc. The contribution of two major classes, is represented by:
A (λ)=aw(λ)+ap(λ)+aCDOM(λ), (1)
Right formula represents the tribute of full sea water (w), total particulate (p) and coloured dissolved organic matters (CDOM) to absorption respectively Offer, wherein total particulate absorb again can further decompose phytoplankton (ph), non-admissible solutions (NAP) absorption spectrum it With that is,
ap(λ)=aph(λ)+aNAP(λ)
(b, unit is m to the light scattering coefficient of water body-1) a branch of directional light is defined as through a unlimited thin uniform dielectric, light Scattered power (B) and dielectric thickness (⊿ r) ratio, i.e.,:
(c, unit is m to the light attenuation coefficient of water body-1) be water body absorption and scattering coefficienth sum, i.e.,:
C (λ)=a (λ)+b (λ)
In the prior art, for the measurement of water body light absorbs attenuation coefficient, usually using total reflection pipe or hypersorption pipe, need Enter trip temperature, salt correction and scatter correction;Or use spectrophotometer.It is multiple all to there is measurement operation in both approaches Miscellaneous, influence factor is more, the problems such as error is big.
The content of the invention
It is an object of the invention to provide it is a kind of can in site measurement water body light absorbs and decay measuring instrument, simplify water body The measurement of light absorbs attenuation coefficient, and provide reliable support for further analyzing water body Size Structure.
Realize that above-mentioned purpose concrete scheme of the present invention is as follows:
A kind of water body light absorbs and attenuation meter, it includes:Luminescence unit, sampling unit, probe unit and signal are adopted Set analysis unit, wherein:
The luminescence unit includes main channel and the three road subchannels that are divided into the rear end of main channel, the main channel and It is interconnected between subchannel, the light source assembly for producing optical signal is provided with the main channel, in main channel and subchannel Connectivity part is provided with the beam splitter for the optical signal to be divided into three beams, optical signal is divided into after three beams and respectively enters three tunnels Subchannel;In three road subchannels, wherein the terminal of the first subchannel and the second subchannel has the first window of closing With the second window;
The probe unit includes three tunnel receiving channels, wherein, the top point of the first receiving channel and the second receiving channel The 3rd window and the 4th window of closing are not provided with, and the 3rd receiving channel is connected with the second receiving channel;
The sampling unit is including for connecting the first water sample passage of first window and the 3rd window and for connecting Second water sample passage of the second window and the 4th window;
The signal processing and analysis unit is provided with spectroanalysis instrument;
The terminal of 3rd subchannel is connected by optical fiber with the terminal of the 3rd receiving channel, in the 3rd receiving channel and second The connectivity part of receiving channel installs a bundling device, and the bundling device is used to the optical signal in the 3rd subchannel receiving logical through the 3rd After the second receiving channel close with the optical signal in the second subchannel behind road and divide, be then resent to the second receiving channel Optical signal in terminal, first subchannel is sent to the terminal of the first receiving channel;The terminal of first receiving channel And second the terminal of receiving channel be connected by optical fiber with spectroanalysis instrument.
The first to three subchannel is absorbing path, attenuation path and reference channel, the first to three receiving channel Respectively absorb receiving channel, the receiving channel that decays and refer to receiving channel, first to fourth described window is respectively the first absorption Window, the first decay window, the second absorbing window and the second decay window.
The rear end of the main channel extends to form attenuation path, and the reference channel is directly connected with attenuation path, described Absorbing path is directly connected with main channel, and the beam splitter includes be arranged at absorbing path and the connectivity part of main channel first point Beam device and be arranged at reference channel and attenuation path connectivity part the second beam splitter.
First absorbing window, the first decay window, the second absorbing window and the second decay window are sustained height And direction, they are closed by sapphire;First absorbing path include with main channel it is vertical and connect it is vertical Absorbing path and aligned adsorbent passage that is vertical with the vertical absorbing path and connecting, in the vertical absorbing path with putting down The connectivity part of row absorbing path installs a right-angle prism.
The light source assembly includes the light source that spatially order is set gradually from the front end of main channel to its rear end, optically focused group Part, damping assemblies, diaphragm component and the first shutter assembly.The preferred high stable halogen tungsten lamp light source component of light source;Concentrating component is preferred Three glued achromatic lens concentrating components;Damping assemblies are attenuator;The preferred high power aperture diaphragm assembly of diaphragm component.
An opening is installed on towards in the snoot of concentrating component in the light source, it is electronic fast in the first beam splitter and first A collimation microscope group is also installed in light path between door.
In reference channel, bundling device and decay receiving channel terminal between decay receiving channel in and close beam The first convergence microscope group, the second convergence microscope group are separately installed with reference receiving channel between the terminal of device and reference receiving channel With the 3rd convergence microscope group;Homogenizer and energy harvester are installed, the homogenizer is located at second in the absorption receiving channel Absorbing window side.
In decay receiving channel between bundling device and the second decay window and the 3rd convergence microscope group away from bundling device The second shutter assembly and the 3rd shutter assembly are separately installed with the reference receiving channel of side.
First shutter assembly, the second shutter assembly and the 3rd shutter assembly are electronic shutter, the electronic shutter It is uniformly controlled with the switch of light source by external controller by controlling cable.
It is coated with the reflective coating of high reflectance on the inwall of the first water sample passage, it is described with the second water sample passage Inwall passes through blackening process, forms the absorbed layer with high-absorbility.
In water body light absorbs of the present invention and attenuation meter, it is rich that luminescence unit provides spectrum for water body parameter measurement The stable light source of rich performance;Sampling unit mainly realizes the sampling of water body example;Probe unit realizes the detection of optical radiation signal, The parameter information of water body is carry in the signal;Signal processing and analysis unit can carry out spectrum analysis to the information detected, Calculated for water body decay and absorption parameter and underlying parameter data are provided.
In currently preferred water body light absorbs and attenuation meter, in described luminescence unit, the preferred high stable of light source Halogen tungsten lamp light source component;The glued achromatic lens component of described concentrating component preferably three;The preferred Gao Gong of described diaphragm component Rate aperture diaphragm assembly.
In currently preferred water body light absorbs and attenuation meter, described the first water sample passage and the second water sample passage It is detachable pipeline.
Above-mentioned most preferred measuring instrument operation principle approximately as:The light radiation of the light source outgoing of high stable halogen tungsten lamp is passed through Snoot and concentrating component are imaged onto diaphragm component position, set damping assemblies to realize that light intensity is controllable in the optical path, are that system is obtained Obtain and provide regulated quantity compared with high s/n ratio.First shutter assembly realizes blocking for whole light path, and system dark noise measurement can be carried For means.Beam splitter (including having the first beam splitter and the second beam splitter of beam splitter prism formation) realizes that the path of light path four is set Meter, makes the optical signal separated respectively enter attenuation path, absorbing path and reference channel.The optical signal of attenuation path passes through first Decay window output enters the second water sample passage, and its inwall is the absorbing path through blackening process, can absorb the spuious of seawater Optical signal.The optical signal of absorbing path enters the first water sample passage by the output of the first absorbing window, and its inwall is plating high reflection The passage of film layer processing, can reflect the spuious optical signal of seawater.Reference channel optical signal is by the first convergence microscope group by optical fiber Probe unit is reached through cable passage.The power cable of light source, the controlling cable and power cable of shutter are led to by cable together Road is delivered to probe unit, and transfers to external controller to be uniformly controlled.Optical signal enters by the second decay window to be visited Unit is surveyed, the optical signal of the optical signal with reference to receiving channel and decay receiving channel can be combined into spectrum analysis by bundling device Instrument, the second shutter assembly and the 3rd shutter assembly are responsible for light path break-make, it is possible to achieve the measurement of decay receiving channel and reference are received The selective measurement of the optical signal of passage.Optical signal enters probe unit by the second absorbing window, and homogenizer can be by by inhaling The large angle incidence light for receiving passage is received, and after being collected through energy harvester, enters spectroanalysis instrument by optical fiber.
Compared with prior art, measuring instrument of the invention can quickly and conveniently realize in site measurement water body absorption spectrum, For the analysis of phytoplankton composition situation in water body, particularly seawater, using the teaching of the invention it is possible to provide the data of efficiently and accurately are supported.
Brief description of the drawings
Fig. 1 is the overall light channel structure schematic diagram of the water body light absorbs attenuation coefficient measuring instrument of the embodiment of the present invention 1.
Fig. 2 is the luminescence unit light channel structure schematic diagram of the water body light absorbs attenuation coefficient measuring instrument of the embodiment of the present invention 1.
Fig. 3 is the probe unit light channel structure schematic diagram of the water body light absorbs attenuation coefficient measuring instrument of the embodiment of the present invention 1.
Reference:
1st, luminescence unit;11st, main channel;111st, snoot;112nd, light source;113rd, concentrating component;114th, damping assemblies; 115th, diaphragm component;116th, the first shutter assembly;1171st, the first beam splitter;1172nd, the second beam splitter;118th, microscope group is collimated; 12nd, absorbing path;121st, right-angle prism;122nd, the first absorbing window;13rd, attenuation path;131st, the first decay window;14th, join Examine passage;
2nd, sampling unit;21st, the first water sample passage;22nd, the second water sample passage;23rd, cable passage;
3rd, probe unit;31st, receiving channel is absorbed;311st, the second absorbing window;312nd, homogenizer;313rd, collection of energy Device;32nd, decay receiving channel;321st, the second decay window;322nd, the second shutter assembly;323rd, bundling device;33rd, it is logical with reference to receiving Road;331st, the 3rd shutter assembly;
4th, signal processing and analysis unit;5th, optical fiber;61st, the first convergence microscope group;62nd, the second convergence microscope group;63rd, the 3rd convergence Microscope group.
Embodiment
In order to facilitate the understanding of the purposes, features and advantages of the present invention, below in conjunction with the accompanying drawings to the present invention Embodiment be described in detail.
Many details are elaborated in the following description to facilitate a thorough understanding of the present invention, still the present invention can be with It is different from other manner described here using other to implement, those skilled in the art can be without prejudice to intension of the present invention In the case of do similar popularization, therefore the present invention is not limited by following public specific embodiment.
Embodiment
A kind of water body light absorbs and attenuation parameter measuring instrument, as shown in figure 1, it is main by luminescence unit 1, sampling unit 2, Probe unit 3 and signal processing and analysis unit 4 are constituted;Luminescence unit 1 includes three that main channel 11 and the one end of main channel 11 are divided into Road subchannel, is respectively defined as absorbing path 12, attenuation path 13 and reference channel 14, and main channel 11 and absorbing path 12 are direct Connection, attenuation path 13 is directly connected with reference channel 14;
As shown in Fig. 2 being spatially sequentially sequentially provided with snoot 111, the light for high stable halogen tungsten lamp of sampling in main channel 11 Damping assemblies 114, the diaphragm in high power aperture that concentrating component 113, the attenuator of the glued achromatic lens in source 112, three are constituted Component 115, the first shutter assembly 116 and collimation microscope group 118;Main channel 11 and the connectivity part of absorbing path 12 (are distinguished the junction The referred to as top of the two, the other end is then referred to as terminal), attenuation path 13 and the connectivity part of reference channel 14 (distinguish the junction The referred to as top of the two, the other end is then referred to as terminal) two the first beam splitters 1171 formed by beam splitter prism are set respectively With the second beam splitter 1172, make optical signal by continuous beam splitting, be finally divided into after three beams and respectively enter three road subchannels;Three roads point are logical In road, absorbing path 12 is parallel with attenuation path 13 after right-angle turning, sets straight at the right-angle turning in absorbing path The terminal of angle prism 121, absorbing path 12 and attenuation path 13 sets the sapphire window in uniform height and direction respectively, respectively It is defined as setting first to converge microscope group 61 in the first absorbing window 122 and the first decay window 131, reference channel 14;
As shown in figure 3, probe unit 3 includes three tunnel receiving channels, it is respectively defined as absorbing receiving channel 31, decay reception Passage 32 and reference receiving channel 33;Absorb receiving channel 31 and decay receiving channel 32 has uniform height and direction Sapphire window, is respectively defined as the second absorbing window 311 and the second decay window 321, (is referred to as with reference to the one end of receiving channel 33 Terminal) it is connected with the reference channel of luminescence unit 1 by optical fiber 5, the other end (being referred to as top) is communicated to decay receiving channel 32 It is internal;Absorb in receiving channel 31 and be additionally provided with homogenizer 312 and energy harvester 313;In the receiving channel 32 that decays, close to the One end of two decay windows 321 sets the second shutter assembly 322, and bundling device 323 is being set with the reference connectivity part of receiving channel 33, The second convergence microscope group 62 is additionally provided with one end away from the second decay window;The is set with reference to the optical fiber joint end of receiving channel 33 Three shutter assemblies 331, the 3rd convergence microscope group 63 is additionally provided with along optical path direction;
Sampling unit 2 includes the first water sample passage 21 and the second water sample passage 22, and the both ends open of the first water sample passage 21 is divided The first absorbing window 122 and the second absorbing window 311 are not connected, and the both ends open of the second water sample passage 22 connects first and declined respectively Subtract the decay window 321 of window 131 and second, two water sample passages are provided with water sample import and export;The inwall of first water sample passage 21 Through plating the processing of high reflection film layer, the inwall top layer of the second water sample passage 22 is through blackening process;First water sample passage 21 and the second water sample Passage 22 is detachable pipeline, and end is connected with each windows active;
Signal processing and analysis unit 4 is connect by the absorption of optical fiber 5 and probe unit 3 respectively provided with two spectroanalysis instruments Receive passage 31 and decay receiving channel 32 is connected;
The rear portion of probe unit 3 passes interface equipped with power interface, automatically controlled and number.Electronic shutter and light source switch are by external Controller is uniformly controlled by controlling cable, and sampling unit 2 is additionally provided with cable passage 23 in addition, and cable passage 23 is responsible for protection and supplied Various cables are transferred to probe unit 3 by electric wire cable, optical fiber and controlling cable by luminescence unit 1.
In water body light absorbs of the present invention and attenuation tester, luminescence unit provides spectrum for water body parameter measurement and enriches performance Stable light source;Sampling unit mainly realizes the sampling of water body example;Probe unit realizes the detection of optical radiation signal, the signal In carry the parameter information of water body;Signal processing and analysis unit can carry out spectrum analysis to the information detected, be water body Decay and absorption parameter, which are calculated, provides underlying parameter data.
The present embodiment measuring instrument in use, above-mentioned most preferred measuring instrument operation principle approximately as:High stable halogen tungsten lamp The light radiation of the outgoing of light source 112 be imaged onto the position of diaphragm component 115 by snoot 111 and concentrating component 113, in the optical path Set damping assemblies 114 to realize that light intensity is controllable, obtained for system and provide regulated quantity compared with high s/n ratio.First shutter assembly 116 is real Now whole light path is blocked, and can measure offer means to system dark noise.Beam splitter (including formed by beam splitter prism One beam splitter 1171 and the second beam splitter 1172) realize that the path of light path four is designed, the optical signal separated is respectively enterd decay logical Road 13, absorbing path 12 and reference channel 14.The optical signal of attenuation path 13 enters second by the output of the first decay window 131 Water sample passage 22, its inwall is the absorbing path through blackening process, can absorb the spuious optical signal of seawater.Absorbing path 12 Optical signal enters the first water sample passage 21 by the output of the first absorbing window 122, and its inwall is logical for the film layer processing of plating high reflection Road, can reflect the spuious optical signal of seawater.The optical signal of reference channel 14 is led to by the first convergence microscope group 61 by optical fiber 5 through cable Road 23 reaches probe unit 3.The power cable of light source 112, the controlling cable and power cable of shutter are together by cable passage 23 are delivered to probe unit 3, and transfer to external controller to be uniformly controlled.Optical signal enters by the second decay window 321 Enter probe unit 3, bundling device 323 can merge the optical signal of the optical signal with reference to receiving channel 33 and decay receiving channel 32 Into spectroanalysis instrument, the second shutter assembly 322 and the 3rd shutter assembly 331 are responsible for light path break-make, it is possible to achieve decay is received Passage 32 measure and optical signal with reference to receiving channel 33 selective measurement.Optical signal enters by the second absorbing window 311 Probe unit 3, homogenizer 312 will can be received by the large angle incidence light of absorbing path, be collected through energy harvester 313 Afterwards, spectroanalysis instrument is entered by optical fiber 5.
Above-listed detailed description is illustrating for possible embodiments of the present invention, and the embodiment simultaneously is not used to limit this hair Bright the scope of the claims, all equivalence enforcements or change without departing from carried out by the present invention are intended to be limited solely by the scope of the claims of this case.

Claims (10)

1. a kind of water body light absorbs and attenuation meter, it is characterised in that it includes:Luminescence unit (1), sampling unit (2), spy Unit (3) and signal processing and analysis unit (4) are surveyed, wherein:
The luminescence unit (1) includes main channel (11) and three road subchannels being divided into the rear end of main channel (11), described Main channel (11) is interconnected between subchannel, and the light source assembly for producing optical signal is provided with the main channel (11), The connectivity part of main channel (11) and subchannel is provided with the beam splitter for the optical signal to be divided into three beams, is divided optical signal Three road subchannels are respectively enterd after into three beams;In three road subchannels, wherein the terminal of the first subchannel and the second subchannel point The first window and the second window of closing are not provided with;
The probe unit (3) includes three tunnel receiving channels, wherein, the top difference of the first receiving channel and the second receiving channel The 3rd window and the 4th window of closing are provided with, the 3rd receiving channel is connected with the second receiving channel;
The sampling unit (2) is including for connecting the first water sample passage (21) of first window and the 3rd window and for even Connect the second water sample passage (22) of the second window and the 4th window;
The signal processing and analysis unit (4) is provided with spectroanalysis instrument;
The terminal of 3rd subchannel is connected by optical fiber with the terminal of the 3rd receiving channel, is received in the 3rd receiving channel with second The connectivity part of passage installs a bundling device (323), and the bundling device (323) is used for the optical signal in the 3rd subchannel through the 3rd After the second receiving channel close with the optical signal in the second subchannel after receiving channel and divide, be then resent to the second reception Optical signal in the terminal of passage, first subchannel is sent to the terminal of the first receiving channel;First receiving channel Terminal and the terminal of the second receiving channel be connected by optical fiber with spectroanalysis instrument.
2. water body light absorbs according to claim 1 and attenuation meter, it is characterised in that the first to three subchannel For absorbing path (12), attenuation path (13) and reference channel (14), the first to three receiving channel is respectively to absorb to receive Passage (31), decay receiving channel (32) and reference receiving channel (33), first to fourth described window is respectively the first absorption window Mouth (122), the first decay window (131), the second absorbing window (311) and the second decay window (321).
3. water body light absorbs according to claim 2 and attenuation meter, it is characterised in that after the main channel (11) End extension forms attenuation path (13), and the reference channel (14) directly connects with attenuation path (13), the absorbing path (12) directly connected with main channel (11), the beam splitter includes being arranged at absorbing path (12) and the connectivity part of main channel (11) The first beam splitter (1171) and be arranged at reference channel (14) and attenuation path (13) connectivity part the second beam splitter (1172)。
4. water body light absorbs according to claim 3 and attenuation meter, it is characterised in that first absorbing window (122), the first decay window (131), the second absorbing window (311) and the second decay window (321) are sustained height and side To they are closed by sapphire;First absorbing path include with main channel (11) it is vertical and connect it is vertical Absorbing path and aligned adsorbent passage that is vertical with the vertical absorbing path and connecting, in the vertical absorbing path with putting down The connectivity part of row absorbing path installs a right-angle prism (121).
5. water body light absorbs according to claim 3 and attenuation meter, it is characterised in that the light source assembly includes pressing Light source (112) that spatial order is set gradually from front end to its rear end of main channel (11), concentrating component (113), damping assemblies (114), diaphragm component (115) and the first shutter assembly (116).
6. water body light absorbs according to claim 5 and attenuation meter, it is characterised in that in the light source (112) peace It is open loaded on one towards in the snoot (111) of concentrating component (113), in the first beam splitter (1171) and the first shutter assembly (116) a collimation microscope group (118) is also installed in the light path between.
7. water body light absorbs according to claim 5 and attenuation meter, it is characterised in that in reference channel (14), Bundling device (323) and decay receiving channel (32) terminal between decay receiving channel (32) in and bundling device (323) with With reference to receiving channel (33) terminal between reference receiving channel (33) in be separately installed with the first convergence microscope group (61), second Converge microscope group (62) and the 3rd convergence microscope group (63);Homogenizer (312) and energy are installed in the absorption receiving channel (31) Collector (313), the homogenizer (312) is located at the second absorbing window (311) side.
8. water body light absorbs according to claim 7 and attenuation meter, it is characterised in that in bundling device (323) and the In decay receiving channel (32) between two decay windows (321) and the 3rd convergence microscope group (63) is away from bundling device (323) one The second shutter assembly (322) and the 3rd shutter assembly (331) are separately installed with the reference receiving channel (33) of side.
9. water body light absorbs according to claim 8 and attenuation meter, it is characterised in that first shutter assembly (116), the second shutter assembly (322) and the 3rd shutter assembly (331) are electronic shutter, the electronic shutter and light source (112) switch is uniformly controlled by external controller by controlling cable.
10. water body light absorbs according to claim 2 and attenuation meter, it is characterised in that the first water sample passage (21) reflective coating is coated with inwall, the inwall with the second water sample passage (22) passes through blackening process.
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