CN105350110B - The production method of flocking nylon fine hair - Google Patents
The production method of flocking nylon fine hair Download PDFInfo
- Publication number
- CN105350110B CN105350110B CN201510872209.1A CN201510872209A CN105350110B CN 105350110 B CN105350110 B CN 105350110B CN 201510872209 A CN201510872209 A CN 201510872209A CN 105350110 B CN105350110 B CN 105350110B
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- China
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- parts
- weight
- black
- fine hair
- production method
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Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/04—Pigments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
A kind of production method the invention discloses flocking with nylon fine hair, by 5~8 parts by weight PA black masterbatch and 92~95 parts by weight PA6 section blend spinnings, the black tow of PA are made, are then cut into black fine hair；By weight, the PA black masterbatch is composed of the following components：30~40 parts by weight of carbon black per, 3~5 parts by weight auxiliary agents, 67~55 parts by weight PA6.The production method of flocking of the present invention nylon fine hair, it uses specific PA black masterbatch, coloured before spinning, original poststaining process can be substituted, can also solve the problems, such as existing PA black masterbatch spinnability, reduces fault, improve fiber blackness, extend the filament spinning component cycle, extend fibre cutter service life, final obtained black fine hair is available for electrostatic spinning to use.
Description
Technical field
Production method the present invention relates to flocking with nylon fine hair.
Background technology
The production of flocking nylon fine hair, it is that fine hair, then dyed, rinsing, conduction are first cut into using PA essential color fibers
Arrange, dry, black fine hair is made in screening.Wherein the technology of dyeing is limited by increasingly tighter environmental requirement, and adds
Work cost is high.And some PA black masterbatch of the prior art, when spinning PA black fibres, spinnability is poor, and fault is more, fiber blackness
Deficiency, the filament spinning component cycle is too short, changes frequently, the fibre cutter replacement cycle is short.
The content of the invention
A kind of production method it is an object of the invention to provide flocking with nylon fine hair, it uses the black mothers of specific PA
Grain, coloured before spinning, original poststaining process can be substituted, existing PA black masterbatch spinnability can also be solved the problems, such as, subtract
Few fault, improves fiber blackness, extends the filament spinning component cycle, extends fibre cutter service life, final obtained black fine hair can
Used for electrostatic spinning.
To achieve the above object, the technical scheme is that a kind of production method of flocking nylon fine hair is designed, by 5
~8 parts by weight PA black masterbatch and 92~95 parts by weight PA6 section blend spinnings, are made the black tow of PA, are then cut into black fine hair；
By weight, the PA black masterbatch is composed of the following components：
30~40 parts by weight of carbon black per,
3~5 parts by weight auxiliary agents,
67~55 parts by weight PA6.
Preferably, the carbon black is high-carbon black pigment.
Preferably, the auxiliary agent includes dispersant, silane coupler, polyamide wax, antioxidant.
Preferably, by weight, the auxiliary agent is composed of the following components：
1.2 parts of β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid isooctanol ester,
4.2 parts of polyamide waxes,
1.3 parts of γ-(methacryloxypropyl) propyl trimethoxy silicane,
2.1 parts of γ-glycidyl ether trimethoxy silanes,
1.4 parts of phenyl silicone oils,
0.9 part of polyvinylpyrrolidone,
1.2 parts of calgons,
3.1 parts of vinyltrimethoxy silanes,
2.3 parts of maleic anhydride modified polyethylene,
1.1 parts of Aluminates,
0.9 part of four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] pentaerythritol ester.
The advantages of the present invention are：A kind of production method of flocking nylon fine hair is provided, it uses special
Fixed PA black masterbatch, coloured before spinning, original poststaining process can be substituted, can also solve existing PA black masterbatch can spin
Sex chromosome mosaicism, fault is reduced, improve fiber blackness, extend the filament spinning component cycle, extend fibre cutter service life, it is final obtained
Black fine hair is available for electrostatic spinning to use.
The key point of the present invention is the preferred feedstock and formula of special PA black masterbatch.It is preferred that go out suitable high-carbon black pigment
And auxiliary agent, solve the spinning technique problem of scattering problem and rear road client of the high-carbon black pigment in master batch is produced, Ji Nengda
To the blackness of flocking fine hair, and can ensures spinning, cuts smoothly completing for whole processes such as suede.Obtained fine hair is not required to dye again
Requirement of the downstream client to fine hair product can be reached, be available for electrostatic spinning to use.
Flocking of the present invention nylon fine hair production method, coloured before being spun using special PA black masterbatch, can be in production PA silks
Just there is the color of high color fastness during beam, then cut into flocking fine hair, direct colour flocking.So save the system of dyeing and finishing etc. one
The process of row, energy consumption is reduced, is more beneficial for environmental protection.Employ master batch made from preferred feedstock of the invention and formula, fine hair system
The filament spinning component cycle during work is original 3 times, and fault is largely reduced, and blackness significantly improves, and the fibre cutter cycle is former
First 2 times.
Embodiment
With reference to embodiment, the embodiment of the present invention is further described.Following examples are only used for more
Add and clearly demonstrate technical scheme, and can not be limited the scope of the invention with this.
The technical scheme that the present invention is embodied is：
A kind of production method of flocking nylon fine hair, 5~8 parts by weight PA black masterbatch and 92~95 parts by weight PA6 are cut
Piece blend spinning, the black tow of PA are made, are then cut into black fine hair；
By weight, the PA black masterbatch is composed of the following components：
30~40 parts by weight of carbon black per,
3~5 parts by weight auxiliary agents,
67~55 parts by weight PA6.
The carbon black is high-carbon black pigment.
The auxiliary agent includes dispersant, silane coupler, polyamide wax, antioxidant.
By weight, the auxiliary agent is composed of the following components：
1.2 parts of β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid isooctanol ester,
4.2 parts of polyamide waxes,
1.3 parts of γ-(methacryloxypropyl) propyl trimethoxy silicane,
2.1 parts of γ-glycidyl ether trimethoxy silanes,
1.4 parts of phenyl silicone oils,
0.9 part of polyvinylpyrrolidone,
1.2 parts of calgons,
3.1 parts of vinyltrimethoxy silanes,
2.3 parts of maleic anhydride modified polyethylene,
1.1 parts of Aluminates,
0.9 part of four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] pentaerythritol ester.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, some improvements and modifications can also be made, these improvements and modifications
Also it should be regarded as protection scope of the present invention.
Claims (1)
1. the flocking production method of nylon fine hair, it is characterised in that：
By 5~8 parts by weight PA black masterbatch and 92~95 parts by weight PA6 section blend spinnings, the black tow of PA are made, are then cut into black
Fine hair；
By weight, the PA black masterbatch is composed of the following components：
30~40 parts by weight of carbon black per,
3~5 parts by weight auxiliary agents,
67~55 parts by weight PA6；
The carbon black is high-carbon black pigment；
By weight, the auxiliary agent is composed of the following components：
1.2 parts of β-(3,5- di-tert-butyl-hydroxy phenyl) propionic acid isooctanol ester,
4.2 parts of polyamide waxes,
1.3 parts of γ-(methacryloxypropyl) propyl trimethoxy silicane,
2.1 parts of γ-glycidyl ether trimethoxy silanes,
1.4 parts of phenyl silicone oils,
0.9 part of polyvinylpyrrolidone,
1.2 parts of calgons,
3.1 parts of vinyltrimethoxy silanes,
2.3 parts of maleic anhydride modified polyethylene,
1.1 parts of Aluminates,
0.9 part of four [β-(3,5- di-tert-butyl-hydroxy phenyls) propionic acid] pentaerythritol ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510872209.1A CN105350110B (en) | 2015-12-03 | 2015-12-03 | The production method of flocking nylon fine hair |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510872209.1A CN105350110B (en) | 2015-12-03 | 2015-12-03 | The production method of flocking nylon fine hair |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105350110A CN105350110A (en) | 2016-02-24 |
| CN105350110B true CN105350110B (en) | 2017-11-28 |
Family
ID=55326166
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510872209.1A Active CN105350110B (en) | 2015-12-03 | 2015-12-03 | The production method of flocking nylon fine hair |
Country Status (1)
| Country | Link |
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| CN (1) | CN105350110B (en) |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1657568A (en) * | 2004-12-07 | 2005-08-24 | 青岛科技大学 | Super-toughness fire resistant nylon alloy |
| CN102746649A (en) * | 2012-06-15 | 2012-10-24 | 苏州宇度医疗器械有限责任公司 | Fragrant nylon/polyethylene alloy material |
| CN102786793A (en) * | 2012-07-25 | 2012-11-21 | 金发科技股份有限公司 | Modified nylon material and its preparation method |
| CN103243414A (en) * | 2013-03-25 | 2013-08-14 | 辽阳市和源化纤有限公司 | Method for preparing nylon 66 colored and low-denier industrial yarns |
| CN103497479A (en) * | 2013-08-22 | 2014-01-08 | 金发科技股份有限公司 | Imitation wood grain color master batch, preparation method, and applications thereof |
| CN104630927A (en) * | 2013-11-12 | 2015-05-20 | 嵇春霞 | Melt blending spinning black high strength nylon filament and production method thereof |
| CN105001601A (en) * | 2015-06-19 | 2015-10-28 | 周焕民 | Spinning conductive masterbatch containing graphene and preparation method thereof |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005226020A (en) * | 2004-02-16 | 2005-08-25 | Toray Ind Inc | Masterbatch resin composition for coloring polyoxymethylene resin and colored polyoxymethylene resin composition |
| JP2005298545A (en) * | 2004-04-06 | 2005-10-27 | Asahi Kasei Chemicals Corp | Method for producing electroconductive resin composition |
-
2015
- 2015-12-03 CN CN201510872209.1A patent/CN105350110B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1657568A (en) * | 2004-12-07 | 2005-08-24 | 青岛科技大学 | Super-toughness fire resistant nylon alloy |
| CN102746649A (en) * | 2012-06-15 | 2012-10-24 | 苏州宇度医疗器械有限责任公司 | Fragrant nylon/polyethylene alloy material |
| CN102786793A (en) * | 2012-07-25 | 2012-11-21 | 金发科技股份有限公司 | Modified nylon material and its preparation method |
| CN103243414A (en) * | 2013-03-25 | 2013-08-14 | 辽阳市和源化纤有限公司 | Method for preparing nylon 66 colored and low-denier industrial yarns |
| CN103497479A (en) * | 2013-08-22 | 2014-01-08 | 金发科技股份有限公司 | Imitation wood grain color master batch, preparation method, and applications thereof |
| CN104630927A (en) * | 2013-11-12 | 2015-05-20 | 嵇春霞 | Melt blending spinning black high strength nylon filament and production method thereof |
| CN105001601A (en) * | 2015-06-19 | 2015-10-28 | 周焕民 | Spinning conductive masterbatch containing graphene and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN105350110A (en) | 2016-02-24 |
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Address after: 215000 Shiyuan Road, Shiqiao village, Xiangcheng District Beiqiao street, Suzhou, Jiangsu Patentee after: Suzhou Baoli Di material Polytron Technologies Inc Address before: 215000 Shiyuan Road, Shiqiao village, Xiangcheng District Beiqiao street, Suzhou, Jiangsu Patentee before: POLY PLASTIC MASTERBATCH (SUZHOU) CO., LTD. |