CN102746649A - Fragrant nylon/polyethylene alloy material - Google Patents
Fragrant nylon/polyethylene alloy material Download PDFInfo
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- CN102746649A CN102746649A CN2012101980101A CN201210198010A CN102746649A CN 102746649 A CN102746649 A CN 102746649A CN 2012101980101 A CN2012101980101 A CN 2012101980101A CN 201210198010 A CN201210198010 A CN 201210198010A CN 102746649 A CN102746649 A CN 102746649A
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Abstract
Belonging to the technical field of high polymer materials, the invention provides a fragrant nylon/polyethylene alloy material, which is composed of the following raw materials by weight: 100-130 parts of nylon 1010 resin; 40-55 parts of nylon 6 resin; 20-30 parts of polyethylene; 1.2-2.1 parts of a coupling agent; 50-68 parts of a filling material; 2-4 parts of a fragrant masterbatch; 1.3-1.9 parts of an antioxidant; and 48-63 parts of a reinforced fiber. The fragrant nylon/polyethylene alloy material provided in the invention has tensile strength of more than 155MPa, bending strength of more than 220MPa, izod notched impact strength of more than 24kj/m<2>, as well as a melt index of greater than 27g/10min, has low hygroscopicity, and can avoid generating the effect of an unpleasant odor.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of fragrance type nylon/polyethylene alloy material
Background technology
nylon is a kind of broad-spectrum material, and is main but be not limited to be used for fields such as automobile, building, electric, packing and living utensil.Because the easy moisture absorption of nylon component, thereby cause the complex process of fabricated product.And polyvinyl resin is inertia to moisture content, is difficult in the course of processing moisture absorption takes place, and can not cause that product properties reduces.Therefore, exploitation nylon/polyethylene alloy material has active operation significance
Summary of the invention
task of the present invention is to provide a kind of and helps to ensure the favorable mechanical physical strength, helps reducing water absorbability and be of value to fragrance type nylon/polyethylene alloy material of avoiding tedious peculiar smell.
Task of the present invention is accomplished like this, a kind of fragrance type nylon/polyethylene alloy material, and its raw material by following parts by weight is formed:
100~130 parts of nylon 1010 resins;
40~55 parts of Nylon 6s;
20~30 parts of Vilaterm;
1.2~2.1 parts of coupling agents;
50~68 parts of fillers;
2~4 parts of aroma agglomerates;
1.3~1.9 parts in oxidation inhibitor;
48~63 parts of
fortifying fibres.
in one embodiment of the invention, described nylon 1010 resin is a fusing point at 210 ℃ resin.
in another embodiment of the present invention, described Nylon 6 is a fusing point at 220 ℃ resin.
in yet another embodiment of the present invention, described Vilaterm is a new LDPE (film grade).
in another embodiment of the present invention, described coupling agent is the sec.-propyl triethoxyl silane.
also have among the embodiment of the present invention, and described filler is the Marinco H through activation treatment.
more of the present invention and among embodiment, and described aroma agglomerate is the mixture of white carbon black of essence and the mass percent 70% of mass percent 30%.
in of the present invention and then embodiment, described oxidation inhibitor is three [2,4 di-tert-butyl-phenyl] phosphorous acid ester.
of the present invention again more and among embodiment, described fortifying fibre is the alkali-free short glass fiber of length 3mm.
The tensile strength of fragrance type nylon/polyethylene alloy material provided by the invention is greater than 155MPa, and flexural strength is greater than 220MPa, and the socle girder notched Izod impact strength is greater than 24kj/m
2
, melting index is greater than 27g/10min, has agent of low hygroscopicity and can avoid producing the effect of unpleasant peculiar smell.
Embodiment
Embodiment 1:
fusing point is 100 parts of nylon 1010 resins at 210 ℃ resin; Fusing point is 50 parts of Nylon 6s at 220 ℃ resin; 20 parts of new LDPE (film grade)s; Coupling agent is 1.6 parts of sec.-propyl triethoxyl silanes, and filler promptly passes through 50 parts of the Marinco Hs of activation treatment, is that 30% essence and mass percent are 2 parts of the aroma agglomerates filled the post of of the mixture of 70% white carbon black by mass percent; Oxidation inhibitor i.e. 1.5 parts of three [2,4 di-tert-butyl-phenyl] phosphorous acid esters and length is 48 parts of the alkali-free short glass fibers of 3mm.
Embodiment 2:
fusing point is 105 parts of nylon 1010 resins at 210 ℃ resin; Fusing point is 40 parts of Nylon 6s at 220 ℃ resin; 25 parts of new LDPE (film grade)s; Coupling agent is 1.2 parts of sec.-propyl triethoxyl silanes, and filler promptly passes through 55 parts of the Marinco Hs of activation treatment, is that 30% essence and mass percent are 2.5 parts of the aroma agglomerates filled the post of of the mixture of 70% white carbon black by mass percent; Oxidation inhibitor i.e. 1.3 parts of three [2,4 di-tert-butyl-phenyl] phosphorous acid esters and length is 63 parts of the alkali-free short glass fibers of 3mm.
Embodiment 3:
fusing point is 115 parts of nylon 1010 resins at 210 ℃ resin; Fusing point is 45 parts of Nylon 6s at 220 ℃ resin; 30 parts of new LDPE (film grade)s; Coupling agent is 1.8 parts of sec.-propyl triethoxyl silanes, and filler promptly passes through 60 parts of the Marinco Hs of activation treatment, is that 30% essence and mass percent are 3 parts of the aroma agglomerates filled the post of of the mixture of 70% white carbon black by mass percent; Oxidation inhibitor i.e. 1.6 parts of three [2,4 di-tert-butyl-phenyl] phosphorous acid esters and length is 54 parts of the alkali-free short glass fibers of 3mm.
Embodiment 4:
fusing point is 130 parts of nylon 1010 resins at 210 ℃ resin; Fusing point is 55 parts of Nylon 6s at 220 ℃ resin; 26 parts of new LDPE (film grade)s; Coupling agent is 2.1 parts of sec.-propyl triethoxyl silanes, and filler promptly passes through 68 parts of the Marinco Hs of activation treatment, is that 30% essence and mass percent are 4 parts of the aroma agglomerates filled the post of of the mixture of 70% white carbon black by mass percent; Oxidation inhibitor i.e. 1.9 parts of three [2,4 di-tert-butyl-phenyl] phosphorous acid esters and length is 60 parts of the alkali-free short glass fibers of 3mm.
Type nylon/the polyethylene alloy material of the fragrance that is obtained by the foregoing description 1 to 4 has the technique effect shown in the following table through test:
Claims (9)
1.
A kind of fragrance type nylon/polyethylene alloy material is characterized in that its raw material by following parts by weight forms:
100~130 parts of nylon 1010 resins;
40~55 parts of Nylon 6s;
20~30 parts of Vilaterm;
1.2~2.1 parts of coupling agents;
50~68 parts of fillers;
2~4 parts of aroma agglomerates;
1.3~1.9 parts in oxidation inhibitor;
48~63 parts of
fortifying fibres.
2.
fragrance type nylon/polyethylene alloy material according to claim 1 is characterized in that described nylon 1010 resin is a fusing point at 210 ℃ resin.
3.
fragrance type nylon/polyethylene alloy material according to claim 1 is characterized in that described Nylon 6 is a fusing point at 220 ℃ resin.
4.
fragrance type nylon/polyethylene alloy material according to claim 1 is characterized in that described Vilaterm is a new LDPE (film grade).
5.
fragrance type nylon/polyethylene alloy material according to claim 1 is characterized in that described coupling agent is the sec.-propyl triethoxyl silane.
6.
fragrance type nylon/polyethylene alloy material according to claim 1 is characterized in that described filler is the Marinco H through activation treatment.
7.
fragrance type nylon/polyethylene alloy material according to claim 1 is characterized in that described aroma agglomerate is the mixture of white carbon black of essence and the mass percent 70% of mass percent 30%.
8.
fragrance type nylon/polyethylene alloy material according to claim 1 is characterized in that described oxidation inhibitor is three [2,4 di-tert-butyl-phenyl] phosphorous acid ester.
9.
Fragrance type nylon/polyethylene alloy material according to claim 1 is characterized in that described fortifying fibre is the alkali-free short glass fiber of length 3mm
Priority Applications (1)
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CN2012101980101A CN102746649A (en) | 2012-06-15 | 2012-06-15 | Fragrant nylon/polyethylene alloy material |
Applications Claiming Priority (1)
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CN2012101980101A CN102746649A (en) | 2012-06-15 | 2012-06-15 | Fragrant nylon/polyethylene alloy material |
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CN102746649A true CN102746649A (en) | 2012-10-24 |
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CN2012101980101A Pending CN102746649A (en) | 2012-06-15 | 2012-06-15 | Fragrant nylon/polyethylene alloy material |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105350110A (en) * | 2015-12-03 | 2016-02-24 | 苏州宝力塑胶材料有限公司 | Production method of nylon fuzz for flocking |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102276899A (en) * | 2011-07-18 | 2011-12-14 | 武汉钢铁(集团)公司 | Magnesium hydroxide flame-retardant composite material and preparation method thereof |
CN102417725A (en) * | 2011-11-22 | 2012-04-18 | 广州合成材料研究院有限公司 | Material utilized specially for blades of industrial evaporative cold air blower and cooling ventilator |
-
2012
- 2012-06-15 CN CN2012101980101A patent/CN102746649A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102276899A (en) * | 2011-07-18 | 2011-12-14 | 武汉钢铁(集团)公司 | Magnesium hydroxide flame-retardant composite material and preparation method thereof |
CN102417725A (en) * | 2011-11-22 | 2012-04-18 | 广州合成材料研究院有限公司 | Material utilized specially for blades of industrial evaporative cold air blower and cooling ventilator |
Non-Patent Citations (2)
Title |
---|
《中国科技博览》 20090131 王玫瑰等 一种新型功能产品--香味塑料 68-69 1-9 , 第1期 * |
王玫瑰等: "一种新型功能产品——香味塑料", 《中国科技博览》 * |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105350110A (en) * | 2015-12-03 | 2016-02-24 | 苏州宝力塑胶材料有限公司 | Production method of nylon fuzz for flocking |
CN105350110B (en) * | 2015-12-03 | 2017-11-28 | 苏州宝力塑胶材料有限公司 | The production method of flocking nylon fine hair |
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Application publication date: 20121024 |