CN102634205A - Antibacterial nylon composite material - Google Patents
Antibacterial nylon composite material Download PDFInfo
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- CN102634205A CN102634205A CN2012101285057A CN201210128505A CN102634205A CN 102634205 A CN102634205 A CN 102634205A CN 2012101285057 A CN2012101285057 A CN 2012101285057A CN 201210128505 A CN201210128505 A CN 201210128505A CN 102634205 A CN102634205 A CN 102634205A
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- nylon
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- antimicrobial
- nylon composite
- composite materials
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Abstract
The invention relates to an antibacterial nylon composite material, belonging to the technical field of high molecular materials. The antibacterial nylon composite material comprises the following materials by weight of 30-50 parts of nylon 1010 resin, 20-25 parts of nylon 6 resin, 0.6-1.2 parts of coupling agent, 15-25 parts of filler, 0.8-1.7 parts of antibacterial agent, 0.3-0.8 part of antioxidant and 25-30 parts of chopped glass fiber. The antibacterial nylon composite material has the advantages that the performance indexes are as follows: the tensile strength is greater than 135 MPa, the bending strength is greater than 205 MPa, the notched impact strength of a cantilever beam is greater than 22 kj/m<2>, and the melt index is greater than 21g/10min, and the antibacterial nylon composite material resists bacterial corrosion.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of antimicrobial nylon composite materials.
Background technology
Along with nylon products is widely used in the household electrical appliances, and the Along with people's growth in the living standard, various household electrical appliance get into ordinary citizen's family.After date was corroded by mould easily when but mostly nylon products used one section, had a strong impact on outward appearance and influenced people's health.Therefore, the nylon material that exploitation has excellent antibacterial effect has positive effect, and the technical scheme that will introduce below is based on producing under this prerequisite.
Summary of the invention
Task of the present invention is to provide a kind of to be had excellent antibacterial effect and uses and avoid by mould erosive antimicrobial nylon composite materials.
Task of the present invention is accomplished like this, a kind of antimicrobial nylon composite materials, and its raw material by following parts by weight is formed:
30～35 parts of nylon 1010 resins;
20～25 parts of Nylon 6s;
0.6～1.2 part of coupling agent;
15～25 parts of fillers;
0.8～1.7 part of antiseptic-germicide;
0.3～0.8 part in oxidation inhibitor;
25～30 parts of short glass fibers.
In a concrete embodiment of the present invention, described nylon 1010 resin be fusing point more than 220 ℃ and viscosity index be 2.4 nylon resin.
In another concrete embodiment of the present invention, described Nylon 6 be melting point resin more than 230 ℃ and viscosity index be 2.5 nylon resin.
In another concrete embodiment of the present invention, described coupling agent is a vinyltrimethoxy silane.
In another concrete embodiment of the present invention, described filler is a lime carbonate.
Also have among the concrete embodiment of the present invention, described antiseptic-germicide is the plastic antimicrobial agent of carrying silver ion.
more of the present invention and among concrete embodiment, described oxidation inhibitor is tricresyl phosphite (2,4 di-tert-butyl-phenyl) ester.
In of the present invention and then concrete embodiment, described short glass fiber is the alkali-free short glass fiber of length 3mm.
Antimicrobial nylon composite materials provided by the invention has following performance index through test: tensile strength is greater than 135MPa, and flexural strength is greater than 205MPa, and the socle girder notched Izod impact strength is greater than 22kj/m
2, melting index is greater than 21g/10min, and bacterium corrodes in opposing.
Embodiment
Embodiment 1:
Take by weighing by weight fusing point more than 220 ℃ and viscosity index be 2.4 nylon resin be 30.5 parts of nylon 1010 resins, fusing point more than 230 ℃ and viscosity index be that 2.5 nylon resin is that 20.3 parts of Nylon 6s, coupling agent are that 0.6 part of vinyltrimethoxy silane, filler are that 15.2 parts in lime carbonate, antiseptic-germicide are that 0.8 part of plastic antimicrobial agent, the oxidation inhibitor of carrying silver ion is 0.3 part of tricresyl phosphite (2,4 di-tert-butyl-phenyl) ester and length is 25.3 parts of the alkali-free short glass fibers of 3mm.
Embodiment 2:
Take by weighing by weight fusing point more than 220 ℃ and viscosity index be 2.4 nylon resin be 32.4 parts of nylon 1010 resins, fusing point more than 230 ℃ and viscosity index be that 2.5 nylon resin is that 23.5 parts of Nylon 6s, coupling agent are that 0.8 part of vinyltrimethoxy silane, filler are that 19.7 parts in lime carbonate, antiseptic-germicide are that 1.3 parts of plastic antimicrobial agents, the oxidation inhibitor of carrying silver ion is 0.5 part of tricresyl phosphite (2,4 di-tert-butyl-phenyl) ester and length is 27.8 parts of the alkali-free short glass fibers of 3mm.
Embodiment 3:
Take by weighing by weight fusing point more than 220 ℃ and viscosity index be 2.4 nylon resin be 33.2 parts of nylon 1010 resins, fusing point more than 230 ℃ and viscosity index be that 2.5 nylon resin is that 21.7 parts of Nylon 6s, coupling agent are that 1.0 parts of vinyltrimethoxy silanes, filler are that 21.4 parts in lime carbonate, antiseptic-germicide are that 1.5 parts of plastic antimicrobial agents, the oxidation inhibitor of carrying silver ion is 0.7 part of tricresyl phosphite (2,4 di-tert-butyl-phenyl) ester and length is 28.9 parts of the alkali-free short glass fibers of 3mm.
Embodiment 4:
Take by weighing by weight fusing point more than 220 ℃ and viscosity index be 2.4 nylon resin be 34.8 parts of nylon 1010 resins, fusing point more than 230 ℃ and viscosity index be that 2.5 nylon resin is that 24.9 parts of Nylon 6s, coupling agent are that 1.2 parts of vinyltrimethoxy silanes, filler are that 24.5 parts in lime carbonate, antiseptic-germicide are that 1.7 parts of plastic antimicrobial agents, the oxidation inhibitor of carrying silver ion is 0.8 part of tricresyl phosphite (2,4 di-tert-butyl-phenyl) ester and length is 29.7 parts of the alkali-free short glass fibers of 3mm.
The antimicrobial nylon composite materials that is obtained by the foregoing description 1 to 4 has the technique effect shown in the following table through test.
Claims (8)
1.
A kind of antimicrobial nylon composite materials is characterized in that its raw material by following parts by weight forms:
30～35 parts of nylon 1010 resins;
20～25 parts of Nylon 6s;
0.6～1.2 part of coupling agent;
15～25 parts of fillers;
0.8～1.7 part of antiseptic-germicide;
0.3～0.8 part in oxidation inhibitor;
25～30 parts of
short glass fibers.
2.
antimicrobial nylon composite materials according to claim 1, it is characterized in that described nylon 1010 resin be fusing point more than 220 ℃ and viscosity index be 2.4 nylon resin.
3.
antimicrobial nylon composite materials according to claim 1, it is characterized in that described Nylon 6 be melting point resin more than 230 ℃ and viscosity index be 2.5 nylon resin.
4.
antimicrobial nylon composite materials according to claim 1 is characterized in that described coupling agent is a vinyltrimethoxy silane.
5.
antimicrobial nylon composite materials according to claim 1 is characterized in that described filler is a lime carbonate.
6.
antimicrobial nylon composite materials according to claim 1 is characterized in that described antiseptic-germicide is the plastic antimicrobial agent of carrying silver ion.
7.
antimicrobial nylon composite materials according to claim 1 is characterized in that described oxidation inhibitor is tricresyl phosphite (2,4 di-tert-butyl-phenyl) ester.
8.
Antimicrobial nylon composite materials according to claim 1 is characterized in that described short glass fiber is the alkali-free short glass fiber of length 3 ㎜
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101285057A CN102634205A (en) | 2012-04-27 | 2012-04-27 | Antibacterial nylon composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2012101285057A CN102634205A (en) | 2012-04-27 | 2012-04-27 | Antibacterial nylon composite material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102634205A true CN102634205A (en) | 2012-08-15 |
Family
ID=46618789
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2012101285057A Pending CN102634205A (en) | 2012-04-27 | 2012-04-27 | Antibacterial nylon composite material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102634205A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103642191A (en) * | 2013-11-25 | 2014-03-19 | 常熟市蓝天新材料科技有限公司 | Antibacterial toughening modified polyphenyl ether alloy material |
| CN103788645A (en) * | 2014-02-24 | 2014-05-14 | 齐齐哈尔北坤合成高分子材料有限公司 | Antibacterial reinforced nylon material and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970631A (en) * | 2006-11-15 | 2007-05-30 | 广州擎天新材料研究开发有限公司 | Antibacterial nylon plastic material and its preparation method |
| CN101440213A (en) * | 2007-11-19 | 2009-05-27 | 上海日之升新技术发展有限公司 | Nylon 6 composition for automobile rear-view mirror holder |
| US20110263777A1 (en) * | 2009-01-29 | 2011-10-27 | Tomohide Nakagawa | Polyamide resin composition reinforced with glass fiber |
| CN102241883A (en) * | 2010-09-25 | 2011-11-16 | 深圳市科聚新材料有限公司 | Antimicrobial polyamide material and preparation method thereof |
-
2012
- 2012-04-27 CN CN2012101285057A patent/CN102634205A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1970631A (en) * | 2006-11-15 | 2007-05-30 | 广州擎天新材料研究开发有限公司 | Antibacterial nylon plastic material and its preparation method |
| CN101440213A (en) * | 2007-11-19 | 2009-05-27 | 上海日之升新技术发展有限公司 | Nylon 6 composition for automobile rear-view mirror holder |
| US20110263777A1 (en) * | 2009-01-29 | 2011-10-27 | Tomohide Nakagawa | Polyamide resin composition reinforced with glass fiber |
| CN102241883A (en) * | 2010-09-25 | 2011-11-16 | 深圳市科聚新材料有限公司 | Antimicrobial polyamide material and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 《包装工程》 20100930 刘文涛等 "抗菌尼龙610 /蛭石复合材料的制备与性能研究" 44-46 1-8 第31卷, 第17期 * |
| 刘文涛等: ""抗菌尼龙610 /蛭石复合材料的制备与性能研究"", 《包装工程》 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103642191A (en) * | 2013-11-25 | 2014-03-19 | 常熟市蓝天新材料科技有限公司 | Antibacterial toughening modified polyphenyl ether alloy material |
| CN103788645A (en) * | 2014-02-24 | 2014-05-14 | 齐齐哈尔北坤合成高分子材料有限公司 | Antibacterial reinforced nylon material and preparation method thereof |
| CN103788645B (en) * | 2014-02-24 | 2016-06-15 | 齐齐哈尔北坤合成高分子材料有限公司 | A kind of antibacterial enhancing nylon material and preparation method thereof |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20120815 |