CN103642191A - Antibacterial toughening modified polyphenyl ether alloy material - Google Patents
Antibacterial toughening modified polyphenyl ether alloy material Download PDFInfo
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- CN103642191A CN103642191A CN201310606226.1A CN201310606226A CN103642191A CN 103642191 A CN103642191 A CN 103642191A CN 201310606226 A CN201310606226 A CN 201310606226A CN 103642191 A CN103642191 A CN 103642191A
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- alloy material
- polyphenylene oxide
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- antibacterial
- toughening modifying
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Abstract
An antibacterial toughening modified polyphenyl ether alloy material belongs to the technical field of polymer materials. The alloy material is composed of the following raw materials by weight: 53.6-62.5 parts of polyphenyl ether resin, 11.2-17.8 parts of nylon resin, 6.3-11.2 parts of a toughening agent, 17-24 parts of a reinforced fiber, 0.05-0.3 part of an antibacterial agent, 0.2-0.7 part of an antioxidant, 0.5-1.1 parts of a lubricant and 0.9-2.1 parts of carbon black. Through tests, the antibacterial toughening modified polyphenyl ether alloy material is proved to have the following properties: tensile strength of 68-85 MPa, bending strength of 91-108 MPa, notched impact strength of 15-18 Kj / m<2> and have good effect in bacterial growth inhibition.
Description
Technical field
The invention belongs to technical field of polymer materials, be specifically related to a kind of antibacterial toughened polymer phenylate alloy material.
Background technology
Due to polyphenylene oxide, to have fusing point high, and crystallinity is strong, the feature such as corrosion-resistant and resistance to solvent, thereby be widely used in automobile, building, electrical equipment and office automation material.Polyphenyl ether material, property is crisp, when needing soft high impact material for some, due to brittle rupture easily occurring, thereby has limited its range of application.Polyphenyl ether material, after modification, can embody desired properties, and as processing temperature declines, melt viscosity reduction etc., to promote the using value of pure polyphenylene oxide resin.To this, the applicant does lasting and useful exploration, has finally formed technical scheme described below.
Summary of the invention
Task of the present invention is to provide a kind of and contributes to improve intensity, be conducive to promote impact resistance and be conducive to the antibacterial toughening modifying polyphenylene oxide alloy material of bacteria growing inhibiting.
Task of the present invention completes like this, a kind of antibacterial toughening modifying polyphenylene oxide alloy material, and its raw material by following parts by weight forms:
In one embodiment of the invention, described polyphenylene oxide resin is 2,6 dimethyl 1.4 polyphenylene oxide resins.
In another embodiment of the present invention, described nylon resin is NYLON610 resin.
In yet another embodiment of the present invention, described toughner is acrylonitrile-butadiene-styrene (ABS) tree multipolymer.
In another embodiment of the present invention, described fortifying fibre is the alkali free glass fibre of length 12mm.
Of the present invention, also have in an embodiment, described antiseptic-germicide is zinc pyrithione.
More of the present invention and in an embodiment, described oxidation inhibitor is the two dodecane esters of thio-2 acid.
In of the present invention and then an embodiment, described lubricant is amine hydroxybenzene.
Of the present invention, again more and in an embodiment, described carbon black is that carbonarius is female.
Antibacterial toughening modifying polyphenylene oxide alloy material provided by the invention has following performance index after tested: tensile strength 68～85MPa, and flexural strength 91～108MPa, notched Izod impact strength 15～18Kj/m2, bacteria growing inhibiting is effective.
Embodiment
Embodiment 1:
Embodiment 2:
Embodiment 3:
Embodiment 4:
The antibacterial toughening modifying polyphenylene oxide alloy material being obtained by above-described embodiment 1 to 4 has following technique effect after tested:
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 |
| Tensile strength MPa | 68 | 73 | 78 | 85 |
| Flexural strength MPa | 91 | 96 | 101 | 108 |
| Notched Izod impact strength Kj/m 2 | 15.2 | 16.3 | 17.0 | 17.8 |
Claims (9)
1. an antibacterial toughening modifying polyphenylene oxide alloy material, is characterized in that its raw material by following parts by weight forms:
53.6～62.5 parts of polyphenylene oxide resins;
11.2～17.8 parts of nylon resins;
6.3～11.2 parts of toughner;
17 ~ 24 parts of fortifying fibres;
0.05 ~ 0.3 part of antiseptic-germicide;
0.2 ~ 0.7 part, oxidation inhibitor;
0.5 ~ 1.1 part of lubricant;
0.9 ~ 2.1 part of carbon black.
2. antibacterial toughening modifying polyphenylene oxide alloy material according to claim 1, is characterized in that described polyphenylene oxide resin is 2,6 dimethyl 1.4 polyphenylene oxide resins.
3. antibacterial toughening modifying polyphenylene oxide alloy material according to claim 1, is characterized in that described nylon resin is NYLON610 resin.
4. antibacterial toughening modifying polyphenylene oxide alloy material according to claim 1, is characterized in that described toughner is acrylonitrile-butadiene-styrene (ABS) tree multipolymer.
5. antibacterial toughening modifying polyphenylene oxide alloy material according to claim 1, is characterized in that described fortifying fibre is the alkali free glass fibre of length 12mm.
6. antibacterial toughening modifying polyphenylene oxide alloy material according to claim 1, is characterized in that described antiseptic-germicide is zinc pyrithione.
7. antibacterial toughening modifying polyphenylene oxide alloy material according to claim 1, is characterized in that described oxidation inhibitor is the two dodecane esters of thio-2 acid.
8. antibacterial toughening modifying polyphenylene oxide alloy material according to claim 1, is characterized in that described lubricant is amine hydroxybenzene.
9. antibacterial toughening modifying polyphenylene oxide alloy material according to claim 1, is characterized in that described carbon black is that carbonarius is female.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310606226.1A CN103642191A (en) | 2013-11-25 | 2013-11-25 | Antibacterial toughening modified polyphenyl ether alloy material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310606226.1A CN103642191A (en) | 2013-11-25 | 2013-11-25 | Antibacterial toughening modified polyphenyl ether alloy material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103642191A true CN103642191A (en) | 2014-03-19 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310606226.1A Pending CN103642191A (en) | 2013-11-25 | 2013-11-25 | Antibacterial toughening modified polyphenyl ether alloy material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103642191A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1246499A (en) * | 1998-08-31 | 2000-03-08 | 中国科学院化学研究所 | High-toughness polyphenylether/polyamide composition and its preparing process |
| US20100210745A1 (en) * | 2002-09-09 | 2010-08-19 | Reactive Surfaces, Ltd. | Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes |
| CN102634205A (en) * | 2012-04-27 | 2012-08-15 | 常熟市发东塑业有限公司 | Antibacterial nylon composite material |
| US20120319055A1 (en) * | 2009-12-23 | 2012-12-20 | Cheil Industries Inc. | Multi-functional Resin Composite Material and Molded Product Using the Same |
| CN103254610A (en) * | 2013-05-31 | 2013-08-21 | 常熟市弘基无纺制品有限公司 | Flame-retardant glass fiber-reinforced polyphenylene ether composite material |
-
2013
- 2013-11-25 CN CN201310606226.1A patent/CN103642191A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1246499A (en) * | 1998-08-31 | 2000-03-08 | 中国科学院化学研究所 | High-toughness polyphenylether/polyamide composition and its preparing process |
| US20100210745A1 (en) * | 2002-09-09 | 2010-08-19 | Reactive Surfaces, Ltd. | Molecular Healing of Polymeric Materials, Coatings, Plastics, Elastomers, Composites, Laminates, Adhesives, and Sealants by Active Enzymes |
| US20120319055A1 (en) * | 2009-12-23 | 2012-12-20 | Cheil Industries Inc. | Multi-functional Resin Composite Material and Molded Product Using the Same |
| CN102634205A (en) * | 2012-04-27 | 2012-08-15 | 常熟市发东塑业有限公司 | Antibacterial nylon composite material |
| CN103254610A (en) * | 2013-05-31 | 2013-08-21 | 常熟市弘基无纺制品有限公司 | Flame-retardant glass fiber-reinforced polyphenylene ether composite material |
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| PB01 | Publication | ||
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Application publication date: 20140319 |