CN103497479A - Imitation wood grain color master batch, preparation method, and applications thereof - Google Patents
Imitation wood grain color master batch, preparation method, and applications thereof Download PDFInfo
- Publication number
- CN103497479A CN103497479A CN201310369460.7A CN201310369460A CN103497479A CN 103497479 A CN103497479 A CN 103497479A CN 201310369460 A CN201310369460 A CN 201310369460A CN 103497479 A CN103497479 A CN 103497479A
- Authority
- CN
- China
- Prior art keywords
- wood grain
- pigment
- imitative wood
- masterbatch
- imitation wood
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/88—Thermal treatment of the stream of extruded material, e.g. cooling
- B29C48/911—Cooling
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Extrusion Moulding Of Plastics Or The Like (AREA)
Abstract
The invention discloses an imitation wood grain color master batch, which comprises the following components in percentage by weight: 60 to 95% of carrier resin, 1 to 20% of pigment, 1 to 15% of dispersant, and 0 to 5% of other auxiliary agents; wherein the carrier resin is a mixture of PC and ABS, the PC accounts for 0 to 80% of the total weight of the carrier resin, and the ABS accounts for 20 to 100% of the total weight of the carrier resin. The preparation method comprises the following steps: (a) adding the components according to the ratios mentioned above into a high-speed mixer, and evenly mixing the components at the normal temperature and under the normal pressure; (b) melting, mixing and extruding the mixed materials mentioned above in a double-screw extruder, and at the same time subjecting the extruded materials to processes of water cooling, cutting, and wind drying so as to obtain the imitation wood grain color master batch. The imitation wood grain color master batch has the advantages of little color powder usage amount, good temperature toleration ability, and excellent dispersing ability; is easy to operate and control when the color master batch is applied to prepare imitation wood grain composite material of wood and plastic; has a good compatibility with PVC base basic materials and a high imitation wood appearance, thus the formed grains are natural and clear, the surface color is bright and beautiful, and the imitation wood grain effect is good.
Description
Technical field
The present invention relates to the painted field of imitative wood grain profiled material, be specifically related to a kind of imitative wood grain Masterbatch and preparation method thereof and application in imitative wood grain wood plastic composite.
Background technology
Wood plastic composite is as a kind of novel environment friendly material, and, protection against corrosion good with its light weight, sense of touch, protection against the tide, Anti-moth-eating, the advantage such as fire-retardant cause people's broad interest.In order to make it that better imitative wood and ornamental be arranged, improve the quality of wood plastic composite, extrude with the Wood-like composite material of wood grain shape and pursue the psychological needs of natural timber to meet to greatest extent people, become the domestic and international competitively focus of research at present.The imitative wood grain composite wood of PVC base has the processing characteristic that timber can be followed closely, can saw, can dig, and can substitute in a large number natural timber, in all trades and professions, is widely used, and has a extensive future.
At present hard PVC mainly adopts toner painted, and the painted characteristics of toner are directly used toner (pigment or dyestuff) to add appropriate powdery auxiliary agent plastic pellet is carried out to painted method, and its advantage is that cost is low, but the short run operation.But its disadvantage is pigment can fly upward in transportation, storage, weighing, mixed process, produces and pollutes, and has a strong impact on Working environment.Disclosed a kind of production method of Weather resistant wood-grain imitating PVC plastic profiled bar in patent CN101492987, but the method is to adopt dry mixed powder to be extruded, toners etc. easily fly away in workshop, cause the pollution of environmental unit, serious threat HUMAN HEALTH, and the dry mixed powder hopper easy cleaning not of extruding rear forcing machine.
Patent CN1386623 has disclosed on twin screw plastic profile extrusion machine production line, at twin screw extruder vacuum vent holes place, adopts special metering equipment to add the method for the wood grain mill base of having debugged to produce imitative wood grain profiled material.But the method has higher requirement to the production plant temperature, the too low input difficulty that will cause mill base of workshop temperature; The wood grain that color paste deployment bothered and imitated wood grain profiled material goods is difficult to control, and there will be the problems such as wood grain great Hua, thereby causes imitative wood grain effect poor.
Masterbatch requires selected resin to have good wet and dissemination to tinting material, and be colored material and there is good consistency.In patent CN101885885, adopt Acrylnitrile-Butadiene-Styrene (ABS), polystyrene (PS), styrene-butadiene copolymer (K glue), acrylonitritrile-styrene resin (AS), styrene-ethylene butylene-styrene multipolymer (SEBS) to prepare a kind of color master batch for hard PVC as the carrier of Masterbatch, but form mechanism and effect according to the wood grain of imitative wood grain profile, this Masterbatch also is not suitable for use in imitative wood grain Masterbatch, and its resistance to elevated temperatures poor, disperse inhomogeneous.
Summary of the invention
The shortcomings and deficiencies that exist for prior art, primary and foremost purpose of the present invention is to provide a kind of toner consumption few, the imitative wood grain Masterbatch of Heat stability is good, dispersing property excellence.
Another object of the present invention is to provide the preparation method of above-mentioned imitative wood grain Masterbatch.
A further object of the present invention is to provide the good wood plastic composite of imitative wood grain effect prepared with above-mentioned imitative wood grain Masterbatch.
The present invention is achieved by the following technical solutions:
A kind of imitative wood grain Masterbatch by weight percentage, comprising:
Vector resin 60～95%;
Pigment 1～20%;
Dispersion agent 1～15%;
Other auxiliary agent 0 ~ 5%;
Described vector resin is PC, ABS blend, and wherein to account for the weight percent of vector resin total amount be that the weight percent that 0 ~ 80%, ABS accounts for the vector resin total amount is 20 ~ 100% to PC.
Preferably, in described PC, ABS blend PC to account for weight percent be that to account for weight percent be 30 ~ 100% to 0～70%, ABS.
Described imitative wood grain Masterbatch is 200 ℃ in temperature, and pressure is that the melting index of measuring under the 10KG condition is 4～11g/l0min.
Described pigment is mineral dye and/or pigment dyestuff; Described mineral dye is selected from one or more mixtures of titanium dioxide, carbon black, zinc sulfide white, red iron oxide, lead-chrome yellow (lead chromate), zinc-chrome yellow (zinc chromate), cadmium yellow (Cadmium Sulfide), iron oxide yellow (hydrous iron oxide), chromoxide green, barba hispanica, cobalt blue, ultramarine; Described pigment dyestuff is selected from one or more mixtures of azo pigment, heterocycle pigment, miscellany pigment.
Described dispersion agent is selected from one or more mixtures of polyamide wax, white mineral oil, Poly Propylene Wax, polyethylene wax, EVA wax, polyethylene glycol adipate, calcium stearate, Zinic stearas.
Described other auxiliary agent is selected from one or more mixtures of oxidation inhibitor, processing aid, filler.
A kind of preparation method of imitative wood grain Masterbatch, comprise the steps:
A) each component is joined in high-speed mixer by proportioning, mix under normal temperature and pressure conditions;
B) use twin screw extruder at 140 ~ 250 ℃ in the said mixture material, screw speed is to carry out melt blending under 380 ~ 420r/min condition to extrude, by the shearing of screw rod, the mixing pigment that makes, in vector resin, be uniformly dispersed, use water cooling, pelletizing, air-dry simultaneously, obtain imitative wood grain Masterbatch.
The described water-cooled cooling temperature of step b) is 15 ℃～80 ℃.
A kind of imitative wood grain wood plastic composite, permillage meter by weight comprises:
PVC base base-material 987～999 ‰;
Above-mentioned imitative wood grain Masterbatch 1～13 ‰.
The present invention compared with prior art, has following beneficial effect:
1) the toner consumption of imitative wood grain Masterbatch of the present invention is few, and temperature tolerance is good, dispersing property is excellent.
2) imitative wood grain Masterbatch of the present invention environmental protection, pollution-free, can overcome the painted pollution of toner and common PVC Masterbatch colour-change problem while being applied to hard PVC goods painted.
When 3) imitative wood grain Masterbatch of the present invention is used in the imitative wood grain wood plastic composite of preparation, easy handling is good and have a highly solid wood outward appearance of emulation with control, Masterbatch and PVC base base-material consistency, the lines formed is naturally clear, surface color is beautiful, imitative wood grain effect is good, is a kind of desirable imitative wooden wood-plastic products.
Embodiment
Further illustrate the present invention below by embodiment, following examples are preferably embodiment of the present invention, but embodiments of the present invention are not subject to the restriction of following embodiment.
The testing method of properties:
The fluidity determining method of the imitative wood grain Masterbatch of gained: adopt XNR-400AM type Melt Flow Rate Measurer.At first parameter is set, be respectively: 200 ℃ of experimental temperatures, warm up time 4min, pelletizing interval time is that 30S, pelletizing number are 5.After temperature rises to design temperature constant temperature, reinforced 5g left and right, start to measure.By setting the counterweight of different temperature and placement different mass, thus the MI of specimen.
The thermal stability determination method of the imitative wood grain Masterbatch of gained: adopt German NETZSH 209 F3 type thermal gravimetric analyzers; sample is tested from the calorific loss rate of 40 ℃ to 750 ℃; 20 ℃/min of temperature rise rate; example weight is 7 ~ 10mg; heat-processed is carried out under nitrogen protection, and test result be take the temperature of rate of weight loss as 5% time and meaned herein.
The imitative wood grain effect relative evaluation method of the imitative wood grain wood plastic composite of gained: imitative wood grain effect is by a scoring group (60 people), comprise that professional and non-specialised staff are marked to it, thereby comprehensive everybody suggestion, show that obtained product imitates good Yu a bad referential evaluation number of wood grain effect, in addition to the description of the actual wood grain effect of goods, thereby reflected preferably to a certain extent the imitative wood grain effect of obtained goods.It is 1 ~ 5 grade that imitative wood grain effect evaluation is divided into, and is respectively 1 grade (0.1 ~ 0.5), 2 grades (0.6 ~ 1.5), 3 grades (1.6 ~ 2.5), 4 grades (2.6 ~ 3.5), 5 grades (3.6 ~ 4.5), and wherein the score value scope is 0 ~ 5.1 grade of relativity representative is the poorest, and 5 grades of relativity representatives are best, i.e. the imitative wood grain effect of the higher representative of numerical value is better, and the imitative wood grain effect of the lower representative of numerical value is poorer.
Calculation formula:
embodiment 1 ~ 7 and Comparative Examples 1 ~ 3: the preparation of imitative wood grain Masterbatch
Under normal temperature and pressure, vector resin, pigment, dispersion agent and/or other auxiliary agent in embodiment 1 ~ 7 and Comparative Examples 1 ~ 3 are carried out to high-speed mixing 600s in high-speed mixer, after mixed material, adopt twin screw extruder to carry out melt blending, the temperature controlled scope of forcing machine warm area is at 120 ~ 250 ℃, screw speed is 400r/min, by the shearing of screw rod, the mixing pigment that makes, in vector resin, be uniformly dispersed, with water cooling (30 ℃ of water cooling temperatures), pelletizing (the Masterbatch outward appearance is cylindric), air-dry, make imitative wood grain Masterbatch of the present invention.
Pigment red in embodiment and Comparative Examples is elected as: one or more mixtures of red iron oxide 101, red iron oxide 110, red iron oxide 130, red iron oxide 190, pigment red 122.
The pigment that can substitute Pigment red in embodiment and Comparative Examples is selected from: Pigment Yellow 73 001, Pigment Yellow 73 042, Pigment Yellow 73 109, Pigment Yellow 73 110, Pigment Yellow 73 119, pigment Yellow 12 8, pigment yellow 13, pigment yellow 13 8, pigment Yellow 14, pigment yellow 147, Pigment Yellow 73 151, pigment yellow 154, Pigment Yellow 73 168, Pigment Yellow 73 180, Pigment Yellow 73 181, Pigment Yellow 73 183, Pigment Yellow 73 191:1, Pigment Yellow 73 215, Pigment Yellow 73 42, Pigment Yellow 73 53, Pigment Yellow 73 62, Pigment Yellow 73 65, Pigment Yellow 73 74, pigment yellow 83, Pigment Yellow 73 93, Pigment Yellow 73 95, pigment Blue 15, pigment Blue 15: 1, pigment blue 16, Pigment blue 2, Pigment blue 28, Pigment blue 29, Pigment blue 36, pigment blue 60, Pigment blue 72, Pigment green 17, pigment green 36, Pigment green 50, pigment Green 7 adds Phthalocyanine Green G, pigment violet 19, pigment violet 2, pigment Violet 23 adds permanent violet RL, pigment violet 29, pigment violet 37, pigment brown 23, pigment brown 24, pigment brown 6, pigment Orange 13, pigment orange 16, pigment orange 43, pigment orange 61, pigment orange 64, pigment orange 71, Pigment black 011, Pigment black 23, Pigment black 28, Pigment black 7, Pigment red 101 adds ferric oxide, Pigment Red 112, Pigment red 144, pigment red 146, pigment red 149, Pigment red 166, Pigment red 170, Pigment red 177, Pigment red 178, pigment red179, Pigment red 181, Pigment red 187, Pigment red 202, Pigment Red 207, Pigment red 208, Pigment red 209, pigment red 21 4, Pigment red 220, Pigment red 221, Pigment red 247, Pigment red 254, Pigment red 264, Pigment red 272, pigment red 4 8:2, pigment red 4 9:2, Pigment red 5, Pigment red 52:2, Pigment red 57:1, Pigment red 68 etc.
Concrete proportioning (wt%) and the test performance result thereof of table 1 embodiment 1 ~ 7 and Comparative Examples 1 ~ 3
Annotate: in embodiment, PVC-800 is mean polymerisation degree at 720 ~ 860 polyvinyl chloride resin.
embodiment 8 ~ 14 and Comparative Examples 4 ~ 8: the preparation of imitative wood grain wood plastic composite:
The imitative wood grain Masterbatch of embodiment 1 ~ 7 and Comparative Examples 1 ~ 3 gained is mixed by weight ratio in table 2 with PVC base base-material at 120 ~ 190 ℃, then extruded in single screw extrusion machine that (screw speed is 15.6r/min), vacuum water are cold formed, traction, cutting make imitative wood grain wood plastic composite, its performance is tested in sample preparation, records result referring to table 2:
PVC base base-material described in the embodiment of the present invention can make according to ordinary method, in patent 102336989A: 30 parts of wood powders that take are added in high speed mixing smelting machine, baking 8-10 minute under 110 ~ 120 ℃, add again 1.0 parts of coupling agents to activate this wood powder 5 minutes, enter cold mixing and be cooled to room temperature, discharge cold mixed rear standby, start high mixed, 100 parts of the universal polyvinyl chloride (PVC) RESINS that take (polyvinyl chloride (PVC) RESINS herein is to adopt to produce the PVC sill PVC that mean polymerisation degree commonly used is 680 ~ 860 in the industry while moulding profiled material in the present invention) and 5 parts of one package stabilizers are dropped into to high mixing by feeding system, high-speed stirring is warming up to after 90 ℃ material by 30 parts of activated wood powders, 10 parts of light calcium carbonates and 6 parts of frothing aids add simultaneously and highly mixedly add 1.0 parts of composite foamable agents after continuing to be mixed to 110 ℃, continuing to be mixed to 115 ~ 125 ℃ enters cold mixed, after compound enters cold mixing, while fully being cooled to below 40 ℃ through stirring, but enter truck and become foam mixture, but described foam mixture is dropped in the conical double screw extruder hopper, by main feed system, add and extrude in forcing machine and get final product, wherein, Heating temperature is 165 ~ 180 ℃, melt pressure 12 ~ 15Mpa, 165 ~ 170 ℃ of melt temperatures, engine speed 10 ~ 15r/min.
The concrete proportioning of table 2 embodiment 8 ~ 14 and Comparative Examples 4 ~ 8 and test performance result thereof
Claims (9)
1. an imitative wood grain Masterbatch by weight percentage, comprising:
Vector resin 60～95%;
Pigment 1～20%;
Dispersion agent 1～15%;
Other auxiliary agent 0 ~ 5%;
Described vector resin is PC, ABS blend, and wherein to account for the weight percent of vector resin total amount be that the weight percent that 0 ~ 80%, ABS accounts for the vector resin total amount is 20 ~ 100% to PC.
2. imitative wood grain Masterbatch according to claim 1, is characterized in that, in described PC, ABS blend, PC accounts for weight percent and is preferably 0～70%, ABS and accounts for weight percent and be preferably 30 ~ 100%.
3. according to the described imitative wood grain Masterbatch of claim 1, it is characterized in that, described imitative wood grain Masterbatch is 200 ℃ in temperature, and pressure is that the melting index of measuring under the 10KG condition is 4～11g/l0min.
4. according to the described imitative wood grain Masterbatch of claim 1, it is characterized in that, described pigment is mineral dye and/or pigment dyestuff; Described mineral dye is selected from one or more mixtures of titanium dioxide, carbon black, zinc sulfide white, red iron oxide, lead chromate, zinc chromate, Cadmium Sulfide, hydrous iron oxide, chromoxide green, barba hispanica, cobalt blue, ultramarine; Described pigment dyestuff is selected from one or more mixtures of azo pigment, heterocycle pigment, miscellany pigment.
5. according to the described imitative wood grain Masterbatch of claim 1, it is characterized in that, described dispersion agent is selected from one or more mixtures of polyamide wax, white mineral oil, Poly Propylene Wax, polyethylene wax, EVA wax, polyethylene glycol adipate, calcium stearate, Zinic stearas.
6. according to the described imitative wood grain Masterbatch of claim 1, it is characterized in that, described other auxiliary agent is selected from one or more mixtures of oxidation inhibitor, processing aid, filler.
7. the preparation method of imitative wood grain Masterbatch as described as claim 1 ~ 6, comprise the steps:
A) each component is joined in high-speed mixer by proportioning, mix under normal temperature and pressure conditions;
B) use twin screw extruder at 140 ~ 250 ℃ in the said mixture material, screw speed is to carry out melt blending under 380 ~ 420r/min condition to extrude, by the shearing of screw rod, the mixing pigment that makes, in vector resin, be uniformly dispersed, use water cooling, pelletizing, air-dry simultaneously, obtain imitative wood grain Masterbatch.
8. the preparation method of imitative wood grain Masterbatch according to claim 7, is characterized in that, the described water-cooled cooling temperature of step b) is 15 ℃～80 ℃.
9. an imitative wood grain wood plastic composite, permillage meter by weight comprises:
PVC base base-material 987～999 ‰;
The described imitative wood grain Masterbatch 1 of claim 1～6～13 ‰.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310369460.7A CN103497479B (en) | 2013-08-22 | 2013-08-22 | A kind of imitative wood grain color master batch and preparation method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310369460.7A CN103497479B (en) | 2013-08-22 | 2013-08-22 | A kind of imitative wood grain color master batch and preparation method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103497479A true CN103497479A (en) | 2014-01-08 |
| CN103497479B CN103497479B (en) | 2016-08-10 |
Family
ID=49862745
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310369460.7A Active CN103497479B (en) | 2013-08-22 | 2013-08-22 | A kind of imitative wood grain color master batch and preparation method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103497479B (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104072913A (en) * | 2014-07-09 | 2014-10-01 | 苏州亨利通信材料有限公司 | Tarnish-resisting master batch and preparation method thereof |
| CN104356526A (en) * | 2014-11-28 | 2015-02-18 | 北京东方昊炅科技发展有限公司 | Hardwood external wall decorative plate imitated big leaf sandalwood grain material and preparation method thereof |
| CN104761858A (en) * | 2015-03-19 | 2015-07-08 | 宁波色母粒有限公司 | Solid-color PC color master batch with toughening effect, and preparation method thereof |
| CN105199201A (en) * | 2015-10-14 | 2015-12-30 | 裴秀琴 | Polyethylene composite material with straw fibers and preparation method thereof |
| CN105350110A (en) * | 2015-12-03 | 2016-02-24 | 苏州宝力塑胶材料有限公司 | Production method of nylon fuzz for flocking |
| CN106003748A (en) * | 2016-05-24 | 2016-10-12 | 浙江天博新材料有限公司 | Preparation method of color-mixed and hot-pressed plastic-wood composite profile |
| CN106147082A (en) * | 2016-08-17 | 2016-11-23 | 林炳祥 | A kind of PVC color masterbatch |
| WO2016197914A1 (en) * | 2015-06-08 | 2016-12-15 | 金发科技股份有限公司 | Polycarbonate composition and preparation method therefor |
| CN111057333A (en) * | 2019-12-26 | 2020-04-24 | 金发科技股份有限公司 | Wood-grain-like flame-retardant plasticized soft polyvinyl chloride composite material and preparation method thereof |
| CN112778753A (en) * | 2020-12-31 | 2021-05-11 | 上海聚威新材料股份有限公司 | PA6/PA56 silver flow pattern apparent material and preparation method thereof |
| CN112776304A (en) * | 2021-02-01 | 2021-05-11 | 佛山中科吉港科技有限公司 | Wood-grain-like profile extrusion method and extruder |
| CN113372641A (en) * | 2021-06-25 | 2021-09-10 | 苏州润步新材料有限公司 | High-light-fastness outdoor wood-plastic master batch and preparation method thereof |
| CN114393758A (en) * | 2022-01-18 | 2022-04-26 | 北京华夏理想证章有限公司 | Preparation method of die-cast simulated emerald texture cap emblem |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1557870A (en) * | 2004-02-11 | 2004-12-29 | 广东盛恒昌化学工业有限公司 | Natural-like multifunctional color batch and use thereof |
| WO2007121044A1 (en) * | 2006-04-14 | 2007-10-25 | Polyone Corporation | Liquid color concentrate |
| CN103131119A (en) * | 2013-01-31 | 2013-06-05 | 杜县南 | Color master batch and manufacturing method thereof |
-
2013
- 2013-08-22 CN CN201310369460.7A patent/CN103497479B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1557870A (en) * | 2004-02-11 | 2004-12-29 | 广东盛恒昌化学工业有限公司 | Natural-like multifunctional color batch and use thereof |
| WO2007121044A1 (en) * | 2006-04-14 | 2007-10-25 | Polyone Corporation | Liquid color concentrate |
| CN103131119A (en) * | 2013-01-31 | 2013-06-05 | 杜县南 | Color master batch and manufacturing method thereof |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104072913A (en) * | 2014-07-09 | 2014-10-01 | 苏州亨利通信材料有限公司 | Tarnish-resisting master batch and preparation method thereof |
| CN104072913B (en) * | 2014-07-09 | 2016-08-24 | 苏州亨利通信材料有限公司 | A kind of fastness master batch and manufacture method thereof |
| CN104356526A (en) * | 2014-11-28 | 2015-02-18 | 北京东方昊炅科技发展有限公司 | Hardwood external wall decorative plate imitated big leaf sandalwood grain material and preparation method thereof |
| CN104761858A (en) * | 2015-03-19 | 2015-07-08 | 宁波色母粒有限公司 | Solid-color PC color master batch with toughening effect, and preparation method thereof |
| CN104761858B (en) * | 2015-03-19 | 2017-11-07 | 宁波色母粒有限公司 | Real color PC Masterbatch with toughening effect and preparation method thereof |
| WO2016197914A1 (en) * | 2015-06-08 | 2016-12-15 | 金发科技股份有限公司 | Polycarbonate composition and preparation method therefor |
| CN105199201A (en) * | 2015-10-14 | 2015-12-30 | 裴秀琴 | Polyethylene composite material with straw fibers and preparation method thereof |
| CN105350110A (en) * | 2015-12-03 | 2016-02-24 | 苏州宝力塑胶材料有限公司 | Production method of nylon fuzz for flocking |
| CN105350110B (en) * | 2015-12-03 | 2017-11-28 | 苏州宝力塑胶材料有限公司 | The production method of flocking nylon fine hair |
| CN106003748A (en) * | 2016-05-24 | 2016-10-12 | 浙江天博新材料有限公司 | Preparation method of color-mixed and hot-pressed plastic-wood composite profile |
| CN106147082A (en) * | 2016-08-17 | 2016-11-23 | 林炳祥 | A kind of PVC color masterbatch |
| CN111057333A (en) * | 2019-12-26 | 2020-04-24 | 金发科技股份有限公司 | Wood-grain-like flame-retardant plasticized soft polyvinyl chloride composite material and preparation method thereof |
| CN112778753A (en) * | 2020-12-31 | 2021-05-11 | 上海聚威新材料股份有限公司 | PA6/PA56 silver flow pattern apparent material and preparation method thereof |
| CN112776304A (en) * | 2021-02-01 | 2021-05-11 | 佛山中科吉港科技有限公司 | Wood-grain-like profile extrusion method and extruder |
| CN113372641A (en) * | 2021-06-25 | 2021-09-10 | 苏州润步新材料有限公司 | High-light-fastness outdoor wood-plastic master batch and preparation method thereof |
| CN114393758A (en) * | 2022-01-18 | 2022-04-26 | 北京华夏理想证章有限公司 | Preparation method of die-cast simulated emerald texture cap emblem |
| CN114393758B (en) * | 2022-01-18 | 2024-01-26 | 北京华夏理想证章有限公司 | Preparation method of die-casting simulated emerald grain cap badge |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103497479B (en) | 2016-08-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103497479A (en) | Imitation wood grain color master batch, preparation method, and applications thereof | |
| CN103483717B (en) | A kind of imitative wood grain Masterbatch and preparation method thereof and application | |
| CN101885885B (en) | Color master batch for hard PVC and preparation method thereof | |
| CN102746559B (en) | Acid-resistant anti-aging flame-retardant color masterbatch and preparation method thereof | |
| CN108485245B (en) | Universal black master batch and preparation method thereof | |
| CN103897295B (en) | A kind of biomass PVC composite and preparation method thereof | |
| CN102796470B (en) | High-temperature-resistant EVA (ethylene-vinyl acetate) hot-melt adhesive for woodwork coating and preparation method thereof | |
| CN104230289A (en) | 3D printing composition as well as preparation method and applications thereof | |
| CN101319068A (en) | White master batch applied for polyolefin film and preparation method thereof | |
| CN101392078A (en) | Universal white master batch and preparation method thereof | |
| CN106750740B (en) | A kind of preparation method of low temperature resistant modified plastics | |
| CN103254546A (en) | ABS color master batch and preparation process thereof | |
| CN102952326A (en) | Modified linear polyethylene resin and preparation method thereof | |
| CN104497406A (en) | Filling master batch for transparent film and preparation method of filling master batch | |
| CN107619544A (en) | Blue phase black agglomerate for AS or ABS and preparation method thereof | |
| CN108976602A (en) | A kind of marbling master batch suitable for PP | |
| CN105542380B (en) | A kind of ABS noctilucence master batch and preparation method thereof | |
| CN108047666A (en) | A kind of tensile strength environmentally-friendly plastic Masterbatch macromolecule carrier and its manufacturing method | |
| AU2008274913B2 (en) | Masterbatch preparation process | |
| CN108977123A (en) | A kind of low temperature resistant books and periodicals glue and preparation method thereof | |
| CN105802740B (en) | A kind of candle pigment and its production technology | |
| CN104861312B (en) | Micro- cross-linking low-smoke halogen-free high fire-retardance flexible cable material of thermoplasticity and preparation method thereof | |
| CN106519629A (en) | Extra-dark PC/ABS alloy material and preparation method thereof | |
| WO2012088871A1 (en) | Colourized pen with high elasticity and plasticity and manufacturing process thereof | |
| CN104592771B (en) | A kind of anti-rut agent for asphalt pavements and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB03 | Change of inventor or designer information |
Inventor after: Huang Xianbo Inventor after: Chen Dahua Inventor after: Xiong Shaoyan Inventor after: Liu Jianzhong Inventor after: Feng Yulin Inventor after: Song Wei Inventor after: Zhang Fan Inventor after: Liang Jiedong Inventor after: Xiao Yan Inventor before: Xiong Shaoyan Inventor before: Liu Jianzhong Inventor before: Feng Yulin Inventor before: Chen Dahua Inventor before: Song Wei Inventor before: Zhang Fan Inventor before: Liang Jiedong Inventor before: Xiao Yan |
|
| COR | Change of bibliographic data | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170608 Address after: Ke Feng Lu Science City high tech Industrial Development Zone of Guangzhou City, Guangdong Province, No. 33 510663 Co-patentee after: GUANGDONG JINFA TECHNOLOGY CO., LTD. Patentee after: Kingfa Technology Co., Ltd. Co-patentee after: GUANGZHOU KINGFA CARBON FIBER NEW MATERIAL DEVELOPMENT CO., LTD. Address before: Ke Feng Lu Science City high tech Industrial Development Zone of Guangzhou City, Guangdong Province, No. 33 510663 Co-patentee before: Guangzhou Lesco-Kingfa WPC Technology Co., Ltd. Patentee before: Kingfa Technology Co., Ltd. Co-patentee before: GUANGZHOU KINGFA CARBON FIBER NEW MATERIAL DEVELOPMENT CO., LTD. |