CN105339411B - 用作蜂窝状小室的填料的环氧树脂基组合物 - Google Patents

用作蜂窝状小室的填料的环氧树脂基组合物 Download PDF

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Publication number
CN105339411B
CN105339411B CN201480036569.1A CN201480036569A CN105339411B CN 105339411 B CN105339411 B CN 105339411B CN 201480036569 A CN201480036569 A CN 201480036569A CN 105339411 B CN105339411 B CN 105339411B
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curable compositions
epoxy
composition
epoxy resin
filler
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Chinese (zh)
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CN105339411A (zh
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苏海勃·埃尔吉姆阿维
弗兰克·纳鲁斯
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3M Innovative Properties Co
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3M Innovative Properties Co
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C44/00—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles
    • B29C44/02—Shaping by internal pressure generated in the material, e.g. swelling or foaming ; Producing porous or cellular expanded plastics articles for articles of definite length, i.e. discrete articles
    • B29C44/12—Incorporating or moulding on preformed parts, e.g. inserts or reinforcements
    • B29C44/18—Filling preformed cavities
    • B29C44/186—Filling multiple cavities
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/58—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres
    • B29C70/66—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising fillers only, e.g. particles, powder, beads, flakes, spheres the filler comprising hollow constituents, e.g. syntactic foam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/10—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material
    • B32B3/12—Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a discontinuous layer, i.e. formed of separate pieces of material characterised by a layer of regularly- arranged cells, e.g. a honeycomb structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32—Epoxy compounds containing three or more epoxy groups
    • C08G59/38—Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/42—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof
    • C08G59/4238—Polycarboxylic acids; Anhydrides, halides or low molecular weight esters thereof heterocyclic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50—Amines
    • C08G59/5046—Amines heterocyclic
    • C08G59/5053—Amines heterocyclic containing only nitrogen as a heteroatom
    • C08G59/508—Amines heterocyclic containing only nitrogen as a heteroatom having three nitrogen atoms in the ring
    • C08G59/5086—Triazines; Melamines; Guanamines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2419/00—Buildings or parts thereof
    • B32B2419/04—Tiles for floors or walls
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/003—Interior finishings
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2605/00—Vehicles
    • B32B2605/18—Aircraft
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T50/00—Aeronautics or air transport
    • Y02T50/40—Weight reduction

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Composite Materials (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Laminated Bodies (AREA)
  • Panels For Use In Building Construction (AREA)
  • Aviation & Aerospace Engineering (AREA)
CN201480036569.1A 2013-06-28 2014-06-26 用作蜂窝状小室的填料的环氧树脂基组合物 Active CN105339411B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13174347.8A EP2818490B1 (en) 2013-06-28 2013-06-28 Use of an epoxy resin-based composition as a filler honeycomb cells
EP13174347.8 2013-06-28
PCT/US2014/044307 WO2014210292A1 (en) 2013-06-28 2014-06-26 Epoxy resin-based composition as a filler honeycomb cells

Publications (2)

Publication Number Publication Date
CN105339411A CN105339411A (zh) 2016-02-17
CN105339411B true CN105339411B (zh) 2019-04-23

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CN201480036569.1A Active CN105339411B (zh) 2013-06-28 2014-06-26 用作蜂窝状小室的填料的环氧树脂基组合物

Country Status (8)

Country Link
US (1) US9765215B2 (https=)
EP (1) EP2818490B1 (https=)
JP (1) JP6429868B2 (https=)
KR (1) KR20160026995A (https=)
CN (1) CN105339411B (https=)
BR (1) BR112015032696A2 (https=)
CA (1) CA2917012A1 (https=)
WO (1) WO2014210292A1 (https=)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20150190981A1 (en) * 2014-01-08 2015-07-09 E I Du Pont De Nemours And Company Metallic core having a high compression strength and articles made from same
US20160016381A1 (en) * 2014-07-17 2016-01-21 Jorge Enrique Celis Marin Fire Restrictive Material
BR112017016240A2 (pt) 2015-01-30 2018-03-27 Zephyros Inc composição
CN107873046A (zh) * 2015-06-02 2018-04-03 泽菲罗斯有限公司 高强度面板粘合剂
EP3239207B1 (en) * 2016-04-27 2021-07-28 3M Innovative Properties Company Curable epoxy compositions
EP3333211B1 (en) * 2016-12-09 2020-10-14 3M Innovative Properties Company Composite article comprising a honeycomb structure comprising hot/wet resistant low density epoxy compositions
EP3489271B1 (en) * 2017-11-22 2020-05-27 3M Innovative Properties Company Thermal cycling resistant low density composition
WO2019170747A1 (en) 2018-03-08 2019-09-12 Zephyros, Inc. Honeycomb core splice adhesive with improved fire retardancy
EP3569629B1 (de) * 2018-05-17 2022-07-06 Evonik Operations GmbH Schnell härtende epoxysysteme
EP3666812B1 (en) 2018-12-13 2021-10-13 3M Innovative Properties Company Room temperature stable one-part void filler
CN110654098B (zh) * 2019-09-12 2022-05-24 重庆泛锐科技有限公司 一种利用静电喷涂法制备复合夹心板材用夹芯层的方法
CN114981386A (zh) 2019-11-13 2022-08-30 泽费罗斯股份有限公司 蜂窝增强用封装膏
US20230092362A1 (en) 2020-02-18 2023-03-23 Zephyros, Inc. Low Density Flame Retardant Two-Component Composition for Structural Void Filling
CN112232233B (zh) * 2020-10-20 2024-02-09 广东星唯信息技术有限公司 一种防止驾驶培训计时作弊的方法
GB2611297B (en) * 2021-09-27 2024-09-18 Isaksen Guttorm A light aircraft with a dual wedge fuselage
KR102809188B1 (ko) * 2023-03-31 2025-05-19 주식회사 디시시랩 스토퍼형 전기 자동차 충전 장치 및 이를 이용한 시스템

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3351574A (en) * 1965-02-24 1967-11-07 Celanese Coatings Co Castor oil polyglycidyl ether

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BE756055A (fr) * 1969-09-12 1971-03-11 Procter & Gamble Resines epoxydiques assouplies
JPH04353553A (ja) 1991-05-31 1992-12-08 Sanyo Chem Ind Ltd フェノ−ル樹脂改質剤
JPH05239317A (ja) * 1992-03-02 1993-09-17 Toray Ind Inc エポキシ樹脂組成物、プリプレグおよびプリプレグの製造法
JPH09296024A (ja) * 1996-05-02 1997-11-18 Yokohama Rubber Co Ltd:The エポキシ樹脂組成物
JP3201262B2 (ja) 1996-05-30 2001-08-20 株式会社日立製作所 熱硬化性樹脂組成物，電機絶縁線輪，回転電機及びその製造方法
IL142339A0 (en) * 1998-10-23 2002-03-10 Vantico Ag Method for filling and reinforcing honeycomb sandwich panels
EP1674518A1 (en) * 2004-12-23 2006-06-28 3M Innovative Properties Company Fire-retardant low-density epoxy composition
NO20075120L (no) * 2007-05-23 2008-11-24 Mi Llc Anvendelse av direkte epoksyemulsjoner for borehullstabilisering
KR101368986B1 (ko) 2007-12-28 2014-02-28 에스케이케미칼주식회사 엘시디 구동소자용 에폭시 수지 조성물
EP2403892B1 (en) * 2009-03-04 2014-06-18 Dow Global Technologies LLC Thermosettable composition containing a glycidylether based on trimethylolpropane octadecaethoxilate
GB0905362D0 (en) * 2009-03-30 2009-05-13 3M Innovative Properties Co Fire resistant epoxy resin based core filler material developing low exothermic heat
EP2653486B1 (en) 2012-04-20 2014-12-03 3M Innovative Properties Company Low density epoxy composition with low water uptake

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3351574A (en) * 1965-02-24 1967-11-07 Celanese Coatings Co Castor oil polyglycidyl ether

Also Published As

Publication number Publication date
JP2016531969A (ja) 2016-10-13
WO2014210292A1 (en) 2014-12-31
CA2917012A1 (en) 2014-12-31
EP2818490A1 (en) 2014-12-31
BR112015032696A2 (pt) 2017-07-25
KR20160026995A (ko) 2016-03-09
JP6429868B2 (ja) 2018-11-28
US9765215B2 (en) 2017-09-19
US20160160039A1 (en) 2016-06-09
CN105339411A (zh) 2016-02-17
EP2818490B1 (en) 2019-04-10

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