CN105315570A - Painted pottery clay and preparation method of same - Google Patents
Painted pottery clay and preparation method of same Download PDFInfo
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- CN105315570A CN105315570A CN201410277489.7A CN201410277489A CN105315570A CN 105315570 A CN105315570 A CN 105315570A CN 201410277489 A CN201410277489 A CN 201410277489A CN 105315570 A CN105315570 A CN 105315570A
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Abstract
The invention provides painted pottery clay and a preparation method of same. The painted pottery clay is composed of the following components, by weight: 25-35% of a plasticizing agent, 5-15% of polyvinyl chloride paste resin, 50-60% of an inorganic filling material, 8-15% of a lubricant, 0.1-3% of a coloring agent and 0.02-3% of a color fixing agent. The painted pottery clay is soft and is good in plasticity which is 2.5 times than plasticine. The painted pottery clay can be used for producing painted pottery products through steaming, boiling, baking, microwave heating and the like heating methods, is simple in production process, is low in cost, is convenient to use and is beneficial to popularization and application.
Description
Technical field
The present invention relates to a kind of ancient painted pottery field, particularly relate to a kind of ancient painted pottery mud and preparation method thereof
Background technology
Ancient painted pottery is a kind of polymerizability potter's clay, and this material color enriches, and snappiness is good, be a kind of features such as potter's clay, paper clay, sculpture greasy filth, plasticine that collect is handicraft creation material all over the body.Audient is wide for this material, manually person's sculpture, creative making shaping after, after heat, can become that color is beautiful, pattern is ever-changing, the hard exquisite ornaments as pottery and artwork.
But at present ancient painted pottery mud plasticity-is not good, to heating tool and conditional request also relatively stricter, be unfavorable for that product promotion uses.Therefore utilize the ancient painted pottery raw material resources of China's abundant to develop a kind of plasticity-is good, color beautiful lasting, by the ancient painted pottery mud of the mode hot briquettings such as boiling, baking, microwave, there is very important production practice meaning.
Summary of the invention
The object of the invention is to overcome weak point in prior art, a kind of ancient painted pottery mud and preparation method thereof is provided.
For solving the problems of the technologies described above, the present invention proposes following technical scheme:
A kind of ancient painted pottery mud, be made up of softening agent, pvc resin paste grade, inorganic fillings, lubricant, tinting material, laking agent, by its weight percent meter, softening agent 25-35%, pvc resin paste grade 5-15%, inorganic fillings 50%-60%, lubricant 8%-15%, tinting material 0.1%-3%, laking agent 0.02%-3%.
Preferably, above-mentioned ancient painted pottery mud, softening agent is made up of trioctyl lemon acid, tri-n-butyl citrate, epoxy soybean oil, by its mass ratio range, and trioctyl lemon acid: tri-n-butyl citrate: epoxy soybean oil ratio is respectively 0.9 ~ 1.1:0.9 ~ 1.1:0.2 ~ 0.3.
Preferably, above-mentioned ancient painted pottery mud, inorganic fillings is any one or arbitrary combination in diatomite, calcium carbonate, zinc sulfate and mixture of calcium sulfate.
Preferably, above-mentioned ancient painted pottery mud, lubricant is any one in ceramics industry in acceptable mineral oil, silicone oil.
Preferably, above-mentioned ancient painted pottery mud, laking agent is acrylic resin modified.
Preferably, above-mentioned ancient painted pottery mud, tinting material is mineral dye.
Preferably, above-mentioned ancient painted pottery mud, by its weight percent meter, trioctyl lemon acid 11.3%, tri-n-butyl citrate 11.4%, epoxy soybean oil 2.3%, pvc resin paste grade 15%, diatomite 50%, acceptable mineral oil 8% in ceramics industry, red iron oxide 1%, acrylic resin modified 1%.
Preferably, ancient painted pottery mud preparation technology, concrete steps are as follows:
(1) softening agent be made up of trioctyl lemon acid, tri-n-butyl citrate, epoxy soybean oil is mixed, obtain mixture A.
(2) mixture A, polyvinyl chloride (PVC) RESINS, inorganic fillings are mixed in proportion and are stirred, stir 40 minutes, cooling is placed, and obtains mixture B.
(3) lubricant is put into mixture B in proportion, dropwise instill while stirring, stir 30 minutes, take out to be cooled, obtain mixture C.
(4) mixture C is put into stirrer or hand rubs 20 minutes, take out to be cooled, obtain mixture D.
(5) toner be mixed into mixture D in proportion and stir, to be cooled, obtain mixture E.
(6) laking agent injected mixture E in proportion and stir, with hand or stirrer kneading 40 minutes, obtaining mixture F.
(7) with extrusion machine extruding mixture F repeatedly, cut out and make standard ancient painted pottery mud, make the ancient painted pottery mud of thick about 0.5-1cm.
The invention has the beneficial effects as follows:
Compared to existing technology, the present invention is by improving ancient painted pottery mud formula and preparation method, its plasticity-is 2.5 times of common plasticine product, color is lastingly true to nature, both can pass through oven cooking cycle, microwave heating, also achieve by high temperature type of heating such as boilings hard as pottery, reach long-term effect of placing, not because of time, water, fire and modification.
Embodiment
Below in conjunction with specific embodiment, technical scheme of the present invention is further described.
Embodiment 1
1, starting material mixing
(1) trioctyl lemon acid 11.3kg is got, tri-n-butyl citrate 11.4kg, epoxy soybean oil 2.3kg, pvc resin paste grade 15kg, diatomite 50kg, acceptable mineral oil 8kg, red iron oxide 1kg in ceramics industry, acrylic resin modified 1kg.
(2) by trioctyl lemon acid, tri-n-butyl citrate, epoxy soybean oil fully mixes in proportion, obtains mixture A.
(3) mixture A, pvc resin paste grade, diatomite are fully mixed, stir 40 minutes, cooling is placed, and obtains mixture B.
(3) added by mineral oil in mixture B, feed postition is: add mineral oil while stirring, stir about 25 minutes, and mixture C is placed to obtain in cooling.
(4) mixture C is put into stirrer stir or hand rub, about 20 minutes, take out cooling, obtain mixture D.
(5) red iron oxide is put into mixture D, stir, take out cooling, obtain mixture E.
(6) by acrylic resin modified instillation mixture E, stir, with hand or stirrer kneading 40 minutes, obtain mixture F.2, compression moulding
Mixture E extrusion machine is extruded repeatedly, cuts out and make standard ancient painted pottery mud, thick about 0.8cm.
After above-mentioned ancient painted pottery mud is made ancient painted pottery ornaments according to art shapes, insert in steamer and steam, after 45 minutes, the ancient painted pottery ornaments of a set of color light tone.
Embodiment 2
1, starting material mixing
(1) trioctyl lemon acid 15.2kg is got, tri-n-butyl citrate 15.2kg, epoxy soybean oil 4.6kg, pvc resin paste grade 5kg, calcium carbonate 51kg, acceptable mineral oil 8kg, carbon black 0.5kg, acrylic resin modified 0.5kg in ceramics industry.
(2) by trioctyl lemon acid, tri-n-butyl citrate, epoxy soybean oil fully mixes in proportion, obtains mixture A.
(3) mixture A, pvc resin paste grade, diatomite are fully mixed, stir 40 minutes, cooling is placed, and obtains mixture B.
(3) added by mineral oil in mixture B, feed postition is: add mineral oil while stirring, stir about 25 minutes, and mixture C is placed to obtain in cooling.
(4) mixture C is put into stirrer stir or hand rub, about 20 minutes, take out cooling, obtain mixture D.
(5) carbon black is put into mixture D, stir, take out cooling, obtain mixture E.
(6) by acrylic resin modified instillation mixture E, stir, with hand or stirrer kneading 40 minutes, obtain mixture F.
2, compression moulding
Repeatedly extrude with extrusion machine, cut out and make standard ancient painted pottery, thick about 0.9cm.
After above-mentioned ancient painted pottery mud is made ancient painted pottery ornaments according to art shapes, after wrapping with preservative film, insert boiling in 15% salt solution, boil rear constant temperature boiling after about 50 minutes, the ancient painted pottery ornaments of a set of color light tone.
Embodiment 3
1, starting material mixing
(1) trioctyl lemon acid 11.3kg is got, tri-n-butyl citrate 11.4kg, epoxy soybean oil 2.3kg, pvc resin paste grade 5kg, calcium carbonate 60kg, acceptable silicone oil 9kg, cadmium yellow 0.8kg in ceramics industry, acrylic resin modified 0.2kg.
(2) by trioctyl lemon acid, tri-n-butyl citrate, epoxy soybean oil fully mixes in proportion, obtains mixture A.
(3) mixture A, pvc resin paste grade, diatomite are fully mixed, stir 40 minutes, cooling is placed, and obtains mixture B.
(3) added by mineral oil in mixture B, feed postition is: add mineral oil while stirring, stir about 25 minutes, and mixture C is placed to obtain in cooling.
(4) mixture C is put into stirrer stir or hand rub, about 20 minutes, take out cooling, obtain mixture D.
(5) cadmium yellow is put into mixture D, stir, take out cooling, obtain mixture E.
(6) by acrylic resin modified instillation mixture E, stir, with hand or stirrer kneading 40 minutes, obtain mixture F.
2, compression moulding
Repeatedly extrude with extrusion machine, cut out and make standard ancient painted pottery earth, thick about 1cm.
After above-mentioned ancient painted pottery mud is made ancient painted pottery ornaments according to art shapes, insert in steamer and steam, after 45 minutes, the ancient painted pottery ornaments of a set of color light tone.
Embodiment 4
1, starting material mixing
(1) trioctyl lemon acid 11.1kg is got, tri-n-butyl citrate 11.1kg, epoxy soybean oil 2.8kg, pvc resin paste grade 5kg, calcium carbonate 50kg, acceptable silicone oil 15kg, iron oxide yellow 2kg, acrylic resin modified 3kg in ceramics industry.
(2) by trioctyl lemon acid, tri-n-butyl citrate, epoxy soybean oil fully mixes in proportion, obtains mixture A.
(3) mixture A, pvc resin paste grade, diatomite are fully mixed, stir 40 minutes, cooling is placed, and obtains mixture B.
(3) added by mineral oil in mixture B, feed postition is: add mineral oil while stirring, stir about 25 minutes, and mixture C is placed to obtain in cooling.
(4) mixture C is put into stirrer stir or hand rub, about 20 minutes, take out cooling, obtain mixture D.
(5) iron oxide yellow is put into mixture D, stir, take out cooling, obtain mixture E.
(6) by acrylic resin modified instillation mixture E, stir, with hand or stirrer kneading 40 minutes, obtain mixture F.
2, compression moulding
Repeatedly extrude with extrusion machine, cut out and make standard ancient painted pottery mud, thick about 0.8cm.
After above-mentioned ancient painted pottery mud is made ancient painted pottery artwork according to art shapes, insert with moderate heat heating in microwave oven, after 10 minutes, the ancient painted pottery artwork of a set of color light tone.
Embodiment 5
1, starting material mixing
(1) trioctyl lemon acid 11.6kg is got, tri-n-butyl citrate 11.7kg, epoxy soybean oil 3.5kg, pvc resin paste grade 10kg, zinc sulfate and barium sulfate 53kg, acceptable silicone oil 10kg in ceramics industry, laterite 0.1kg, acrylic resin modified 0.1kg.
(2) by trioctyl lemon acid, tri-n-butyl citrate, epoxy soybean oil fully mixes in proportion, obtains mixture A.
(3) mixture A, pvc resin paste grade, diatomite are fully mixed, stir 40 minutes, cooling is placed, and obtains mixture B.
(3) added by mineral oil in mixture B, feed postition is: add mineral oil while stirring, stir about 25 minutes, and mixture C is placed to obtain in cooling.
(4) mixture C is put into stirrer stir or hand rub, about 20 minutes, take out cooling, obtain mixture D.
(5) laterite is put into mixture D, stir, take out cooling, obtain mixture E.
(6) by acrylic resin modified instillation mixture E, stir, with hand or stirrer kneading 40 minutes, obtain mixture F.
2, compression moulding
Repeatedly extrude with extrusion machine, cut out and make standard ancient painted pottery mud, thick about 0.8cm.
After above-mentioned ancient painted pottery mud is made ancient painted pottery ornaments according to art shapes, insert in steamer and steam, after 45 minutes, the ancient painted pottery ornaments of a set of color light tone.
Embodiment 6
1, starting material mixing
(1) trioctyl lemon acid 13.7kg is got, tri-n-butyl citrate 13.6kg, epoxy soybean oil 2.7kg, pvc resin paste grade 8kg, diatomite 50kg, acceptable mineral oil 11kg, cinnabar 0.98kg, acrylic resin modified 0.02kg in ceramics industry.
(2) by trioctyl lemon acid, tri-n-butyl citrate, epoxy soybean oil fully mixes in proportion, obtains mixture A.
(3) mixture A, pvc resin paste grade, diatomite are fully mixed, stir 40 minutes, cooling is placed, and obtains mixture B.
(3) added by mineral oil in mixture B, feed postition is: add mineral oil while stirring, stir about 25 minutes, and mixture C is placed to obtain in cooling.
(4) mixture C is put into stirrer stir or hand rub, about 20 minutes, take out cooling, obtain mixture D.
(5) cinnabar is put into mixture D, stir, take out cooling, obtain mixture E.
(6) by acrylic resin modified instillation mixture E, stir, with hand or stirrer kneading 40 minutes, obtain mixture F.
2, compression moulding
Repeatedly extrude with extrusion machine, cut out and make standard ancient painted pottery mud, thick about 0.7cm.
After above-mentioned ancient painted pottery mud is made ancient painted pottery ornaments according to art shapes, insert in baking oven and toast, after 30 minutes, the ancient painted pottery ornaments of a set of color light tone.
Embodiment 7
1, starting material mixing
(1) trioctyl lemon acid 5.8kg is got, tri-n-butyl citrate 5.8kg, epoxy soybean oil 1.2kg, pvc resin paste grade 2.5kg, diatomite 27.5kg, acceptable mineral oil 6kg, barba hispanica 0.5kg in ceramics industry, acrylic resin modified 0.5kg.
(2) by trioctyl lemon acid, tri-n-butyl citrate, epoxy soybean oil fully mixes in proportion, obtains mixture A.
(3) mixture A, pvc resin paste grade, diatomite are fully mixed, stir 40 minutes, cooling is placed, and obtains mixture B.
(3) added by mineral oil in mixture B, feed postition is: add mineral oil while stirring, stir about 25 minutes, and mixture C is placed to obtain in cooling.
(4) mixture C is put into stirrer stir or hand rub, about 20 minutes, take out cooling, obtain mixture D.
(5) barba hispanica is put into mixture D, stir, take out cooling, obtain mixture E.
(6) by acrylic resin modified instillation mixture E, stir, with hand or stirrer kneading 40 minutes, obtain mixture F.
2, compression moulding
Repeatedly extrude with extrusion machine, cut out and make standard ancient painted pottery mud, thick about 0.7cm.
After above-mentioned ancient painted pottery mud is made ancient painted pottery ornaments according to art shapes, insert in baking oven and toast, after 30 minutes, the ancient painted pottery ornaments of a set of color light tone.
Application test example
Experiment one: ancient painted pottery mud in embodiment 1 and plasticine are carried out plasticity-simultaneous test:
1, experimental instrument and equipment
Precision 0.01mm compression plastometer.
2, test conditions
A. envrionment temperature: (25 ± 2) DEG C
B. ambient relative humidity: (55-75) %
C. specimen size: Φ 28 × 38 right cylinder
D. displacement range: 0-25mm, displacement accuracy≤1%
E. pressure range: 0-500N, pressure precision≤1%
3 test methods and procedures
3.1 sample preparations
White oil coated by upper and lower pressing plate, makes it have good anti-adhesion performance.The manual height be kneaded into is greater than 40mm, upper and lower surface is smooth, length and width are all greater than 40mm sample blocks puts on stainless steel, firmly mould is vertically depressed, pug is made to be full of mould completely, then unnecessary pug is prescinded with cutting mud device, by doctor blade, be finally slightly less than the plastic cylinder of mould internal diameter with a diameter.
Release in sample from mould gently, put on stainless steel.
Sample is carefully moved to press table central authorities, avoids in moving process deforming.
3.2 determination step
Pressure F10 and F50 that bear when recording sample compression 10% and 50% with precision 0.01mm compression plastometer, and obtain plasticity number according to formulae discovery below.
R is plasticity number, and instrument can automatically calculate and show
A is the constant for Φ 28 × 38 cylindrical specimens, and this value is 1.80.
Same sample must carry out 6 parallel tests, and each plasticity index measured value relative deviation should not be greater than 15%, if the measured value having to be greater than 15% should be left out, test result gets its mean value, calculates and is accurate to 2 significant digits number.If have the relative deviation of two measured values more than 15%, then resurvey.After being completed, removing the detritus on instrument, wipe absolute oil mark.
4, experimental result
Table one ancient painted pottery mud, plasticine plasticity-experimental result
Unit: kg.cm
| Project | 1 | 2 | 3 | 4 | 5 | Average |
| Ancient painted pottery mud | 2.12 | 2.02 | 2.16 | 2.10 | 2.04 | 2.088 |
| Plasticine | 0.82 | 0.83 | 0.81 | 0.82 | 0.81 | 0.820 |
Experimental result shows, in embodiment 1, ancient painted pottery mud plasticity-is better than plasticine, and is 2.5 times of commercially available plasticine.
Experiment two: the ancient painted pottery mud that ancient painted pottery mud in embodiment 1 and two kinds of different ingredients are made is carried out plasticity-simultaneous test:
1, experiment material
Contrast ancient painted pottery mud 1 is filled a prescription: get trioctyl lemon acid 18.5kg, epoxy soybean oil 9.5kg, pvc resin paste grade 15kg, diatomite 50kg, acceptable mineral oil 8kg, red iron oxide 1kg in ceramics industry, acrylic resin modified 1kg.
Contrast ancient painted pottery mud 2 is filled a prescription: get tri-n-butyl citrate 17.1kg, trioctyl lemon acid 7.9kg, pvc resin paste grade 15kg, diatomite 50kg, acceptable mineral oil 8kg, red iron oxide 1kg in ceramics industry, acrylic resin modified 1kg.
Both making methods are with manufacture method in embodiment 1.
2, test method is with " experiment one, 3 "
3, experimental result
Table two different ingredients ancient painted pottery mud plasticity-experimental result
Unit: kg.cm
| Project | 1 | 2 | 3 | 4 | 5 | Average |
| Ancient painted pottery mud | 2.12 | 2.02 | 2.16 | 2.10 | 2.04 | 2.088 |
| Ancient painted pottery mud 1 | 1.91 | 1.84 | 1.89 | 1.92 | 1.99 | 1.910 |
| Ancient painted pottery mud 2 | 1.12 | 1.15 | 1.20 | 1.18 | 1.23 | 1.176 |
Experimental result shows, in embodiment 1, ancient painted pottery mud plasticity-is better than contrast two kinds of ancient painted pottery mud.
Above-mentioned detailed description of this kind of ancient painted pottery mud and preparation method thereof being carried out with reference to embodiment; illustrative instead of determinate; several embodiments can be listed according to institute's limited range; therefore in the change do not departed under general plotting of the present invention and amendment, should belong within protection scope of the present invention.
Claims (9)
1. an ancient painted pottery mud, it is characterized in that: be made up of softening agent, pvc resin paste grade, inorganic fillings, lubricant, tinting material, laking agent, by its weight percent meter, softening agent 25-35%, pvc resin paste grade 5-15%, inorganic fillings 50%-60%, lubricant 8%-15%, tinting material 0.1%-3%, laking agent 0.02%-3%.
2. ancient painted pottery mud as claimed in claim 1, it is characterized in that: softening agent is made up of trioctyl lemon acid, tri-n-butyl citrate, epoxy soybean oil, by its mass ratio range, trioctyl lemon acid: tri-n-butyl citrate: epoxy soybean oil ratio is respectively 0.9 ~ 1.1:0.9 ~ 1.1:0.2 ~ 0.3.
3. ancient painted pottery mud as claimed in claim 1, is characterized in that: inorganic fillings is any one or arbitrary combination in diatomite, calcium carbonate, zinc sulfate and mixture of calcium sulfate.
4. as according to ancient painted pottery mud according to claim 1, it is characterized in that: lubricant is any one in ceramics industry in acceptable mineral oil, silicone oil.
5. ancient painted pottery mud as claimed in claim 1, is characterized in that: laking agent is acrylic resin modified.
6. ancient painted pottery mud as claimed in claim 1, is characterized in that: tinting material is mineral dye.
7. ancient painted pottery mud as claimed in claim 1, it is characterized in that: by its weight percent meter, trioctyl lemon acid 11.3%, tri-n-butyl citrate 11.4%, epoxy soybean oil 2.3%, pvc resin paste grade 15%, diatomite 50%, acceptable mineral oil 8% in ceramics industry, red iron oxide 1%, acrylic resin modified 1%.
8. ancient painted pottery mud as claimed in claim 1, is characterized in that: obtained by following method:
(1) softening agent be made up of trioctyl lemon acid, tri-n-butyl citrate, epoxy soybean oil is mixed, obtain mixture A.
(2) mixture A, polyvinyl chloride (PVC) RESINS, inorganic fillings are mixed in proportion and are stirred, stir 40 minutes, cooling is placed, and obtains mixture B.
(3) lubricant is put into mixture B in proportion, dropwise instill while stirring, stir 30 minutes, take out to be cooled, obtain mixture C.
(4) mixture C is put into stirrer or hand rubs 20 minutes, take out to be cooled, obtain mixture D.
(5) toner be mixed into mixture D in proportion and stir, to be cooled, obtain mixture E.
(6) laking agent injected mixture E in proportion and stir, with hand or stirrer kneading 40 minutes, obtaining mixture F.
(7) with extrusion machine extruding mixture F repeatedly, cut out and make standard ancient painted pottery mud, make the ancient painted pottery mud of thick about 0.5-1cm.
9. the ancient painted pottery mud as described in claim 1 or 8, is characterized in that: its plasticity-is 2.5 times of plasticine.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201410277489.7A CN105315570B (en) | 2014-06-20 | 2014-06-20 | A kind of ancient painted pottery mud and preparation method thereof |
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| CN201410277489.7A CN105315570B (en) | 2014-06-20 | 2014-06-20 | A kind of ancient painted pottery mud and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106751143A (en) * | 2016-11-29 | 2017-05-31 | 金华博科彩泥技术研发有限公司 | Make clay of erasing rubber and preparation method thereof by oneself |
| CN107828153A (en) * | 2017-11-23 | 2018-03-23 | 珠海库摩饰品有限公司 | A kind of soft ceramic mud and its manufacture craft |
| CN108102243A (en) * | 2017-11-27 | 2018-06-01 | 广德粤华塑业制品有限公司 | A kind of PVC environmental protection color |
| CN108976821A (en) * | 2018-06-19 | 2018-12-11 | 润亚科技（深圳）有限公司 | A kind of macromolecule ebonite mud |
| CN109053030A (en) * | 2018-10-16 | 2018-12-21 | 得时宝(广州)科技有限公司 | A kind of pottery mud and preparation method thereof |
| CN111423209A (en) * | 2020-05-14 | 2020-07-17 | 界首市卢氏刻花彩陶有限公司 | Preparation method of painted pottery pug |
| CN111777827A (en) * | 2020-06-16 | 2020-10-16 | 佛山市顺德区怡德塑料制品有限公司 | Modified PVC material and preparation method thereof |
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| JPS60155252A (en) * | 1984-01-24 | 1985-08-15 | Sanyuu Shoji Kk | Workpiece material for craftwork |
| CN1778839A (en) * | 2004-11-24 | 2006-05-31 | 于淼 | Formula of plastic rubber |
| CN101186736A (en) * | 2007-12-18 | 2008-05-28 | 东莞市汇欣工贸有限公司 | Soft ceramic mud and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JPS60155252A (en) * | 1984-01-24 | 1985-08-15 | Sanyuu Shoji Kk | Workpiece material for craftwork |
| CN1778839A (en) * | 2004-11-24 | 2006-05-31 | 于淼 | Formula of plastic rubber |
| CN101186736A (en) * | 2007-12-18 | 2008-05-28 | 东莞市汇欣工贸有限公司 | Soft ceramic mud and preparation method thereof |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106751143A (en) * | 2016-11-29 | 2017-05-31 | 金华博科彩泥技术研发有限公司 | Make clay of erasing rubber and preparation method thereof by oneself |
| CN107828153A (en) * | 2017-11-23 | 2018-03-23 | 珠海库摩饰品有限公司 | A kind of soft ceramic mud and its manufacture craft |
| CN108102243A (en) * | 2017-11-27 | 2018-06-01 | 广德粤华塑业制品有限公司 | A kind of PVC environmental protection color |
| CN108976821A (en) * | 2018-06-19 | 2018-12-11 | 润亚科技（深圳）有限公司 | A kind of macromolecule ebonite mud |
| CN109053030A (en) * | 2018-10-16 | 2018-12-21 | 得时宝(广州)科技有限公司 | A kind of pottery mud and preparation method thereof |
| CN111423209A (en) * | 2020-05-14 | 2020-07-17 | 界首市卢氏刻花彩陶有限公司 | Preparation method of painted pottery pug |
| CN111777827A (en) * | 2020-06-16 | 2020-10-16 | 佛山市顺德区怡德塑料制品有限公司 | Modified PVC material and preparation method thereof |
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| CN105315570B (en) | 2017-09-26 |
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