CN103273713B - Four layers of look synthetic resin block and preparation method thereof - Google Patents
Four layers of look synthetic resin block and preparation method thereof Download PDFInfo
- Publication number
- CN103273713B CN103273713B CN201310233678.XA CN201310233678A CN103273713B CN 103273713 B CN103273713 B CN 103273713B CN 201310233678 A CN201310233678 A CN 201310233678A CN 103273713 B CN103273713 B CN 103273713B
- Authority
- CN
- China
- Prior art keywords
- iron oxide
- layers
- layer
- synthetic resin
- polymethyl methacrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Landscapes
- Cosmetics (AREA)
- Laminated Bodies (AREA)
- Casting Or Compression Moulding Of Plastics Or The Like (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of four layers of look synthetic resin block and preparation method thereof, these four layers of look synthetic resin blocks are made up of successively four-layer structure, and every Rotating fields includes component: polymethyl methacrylate, iron oxide red, iron oxide black, iron oxide yellow, titanium white, methyl methacrylate and GDMA.This preparation method is: polymethyl methacrylate powder is dry at 80 ~ 90 DEG C; Prepare four layers of materials respectively according to proportioning, every layer of materials all will mix, and pugging mullering, to dough period, forms plastic dough product; Combine hot-forming for four layers of plastic dough product in order in mould, hot pressing temperature 110 ~ 130 DEG C, hot pressing time 10 ~ 20min; By four layers of look synthetic resin block heat treatment 10 ~ 12h at 80 ~ 90 DEG C after hot-forming, obtain four layers of look synthetic resin block finished product.The dental models processed by the present invention or crown and bridge colour developing nature, true to nature, and preparation of the present invention is simple.
Description
Technical field
The present invention relates to synthetic resin block technical field, more particularly, relate to a kind of four layers of look synthetic resin block and preparation method thereof.
Background technology
Synthetic resin block may be used for skilled worker room by processing and fabricating dental models or crown and bridge.Take polymethyl methacrylate as the plastic tooth of main component, in the history of the existing many decades of clinical oral application, it is made up through so-called " powder/liquid polymerization technique " of the mixture of methyl methacrylate monomer and polymethylmethacrylate powder.
At present, existing synthetic resin block majority is monochromatic, the dental models be made or crown and bridge color single, the needs in market cannot be met, therefore, for reaching effect more true to nature, usual needs carry out post-processed to the dental models completed or crown and bridge, but, can workload be added like this, improve production cost.
Summary of the invention
The object of the invention is to overcome above-mentioned defect of the prior art, a kind of four layers of look synthetic resin block are provided.
Another object of the present invention is to overcome above-mentioned defect of the prior art, a kind of preparation method of four layers of look synthetic resin block is provided.
For achieving the above object, technical scheme provided by the invention is as follows: a kind of four layers of look synthetic resin block, are made up of successively four-layer structure, wherein,
Ground floor is made up of following component by mass percentage: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.01%, iron black: 0% ~ 0.005%, iron oxide yellow: 0% ~ 0.02%, titanium white: 0% ~ 0.2%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
The second layer is made up of following component by mass percentage: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.004%, iron black: 0% ~ 0.003%, iron oxide yellow: 0% ~ 0.01%, titanium white: 0% ~ 0.15%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
Third layer is made up of following component by mass percentage: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.004%, iron black: 0% ~ 0.003%, iron oxide yellow: 0% ~ 0.007%, titanium white: 0% ~ 0.15%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
4th layer is made up of following component by mass percentage: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.01%, iron black: 0% ~ 0.01%, iron oxide yellow: 0% ~ 0.005%, titanium white: 0% ~ 0.1%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%.
The preparation method of four layers of look synthetic resin block of the present invention, comprises the following steps:
(1) raw material drying: polymethyl methacrylate powder is dry at 80 ~ 90 DEG C;
(2) match colors mixing: prepare four layers of materials respectively according to proportioning, every layer of materials all will mix, and pugging mullering, to dough period, forms plastic dough product;
(3) hot-forming: to combine hot-forming for four layers of plastic dough product in order in mould, hot pressing temperature 110 ~ 130 DEG C, hot pressing time 10 ~ 20min;
(4) heat treatment: by four layers of look synthetic resin block heat treatment 10 ~ 12h at 80 ~ 90 DEG C after hot-forming, obtain four layers of look synthetic resin block finished product;
Wherein, each constituent mass percentage of four layers of materials is respectively:
Ground floor: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.01%, iron black: 0% ~ 0.005%, iron oxide yellow: 0% ~ 0.02%, titanium white: 0% ~ 0.2%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
The second layer: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.004%, iron black: 0% ~ 0.003%, iron oxide yellow: 0% ~ 0.01%, titanium white: 0% ~ 0.15%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
Third layer: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.004%, iron black: 0% ~ 0.003%, iron oxide yellow: 0% ~ 0.007%, titanium white: 0% ~ 0.15%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
4th layer: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.01%, iron black: 0% ~ 0.01%, iron oxide yellow: 0% ~ 0.005%, titanium white: 0% ~ 0.1%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%.
Furthermore, in technique scheme, described die size is ground floor thickness: 4 ~ 9mm, second layer thickness: 3 ~ 5mm, third layer thickness: 3 ~ 5mm, the 4th layer thickness: 4 ~ 6mm.
The present invention has following advantage and effect relative to prior art:
1, four layers of look synthetic resin block of the present invention have excellent processing characteristics, and dimensional stability is high, can be used for making multilayer color developing effect dental models or crown and bridge.
2, the dental models processed by four layers of look synthetic resin block of the present invention or crown and bridge colour developing nature, true to nature, and preparation of the present invention is simple, and simplify operating process, production cost is low.
Detailed description of the invention
Below in conjunction with embodiment, the present invention is described in further detail, but embodiments of the present invention are not limited thereto.
Embodiment 1
(1) raw material drying: polymethyl methacrylate powder is dry at 80 DEG C.
(2) match colors mixing: prepare four layers of materials respectively according to proportioning, every layer of materials all will mix, and pugging mullering, to dough period, forms plastic dough product;
(3) hot-forming: to combine hot-forming for four layers of plastic dough product in order in mould, hot pressing temperature 110 DEG C, hot pressing time 10min.Wherein, die size is ground floor thickness: 4mm, second layer thickness: 3mm, third layer thickness: 3mm, the 4th layer thickness: 4mm, appearance and size Φ 98.5*14mm.
(4) heat treatment: by four layers of look synthetic resin block heat treatment 10h at 80 DEG C after hot-forming, obtain four layers of look synthetic resin block finished product.
Wherein, each constituent mass percentage of four layers of materials is respectively:
Ground floor: polymethyl methacrylate: 67%, iron oxide red: 0.003%, iron black: 0.003%, iron oxide yellow: 0.012%, titanium white: 0.08%, methyl methacrylate: 31.712%, GDMA: 1.19%;
The second layer: polymethyl methacrylate: 67%, iron oxide red: 0.002%, iron black: 0.002%, iron oxide yellow: 0.007%, titanium white: 0.08%, methyl methacrylate: 31.719%, GDMA: 1.19%;
Third layer: polymethyl methacrylate: 67%, iron oxide red: 0.003%, iron black: 0.001%, iron oxide yellow: 0.005%, titanium white: 0.08%, methyl methacrylate: 31.721%, GDMA: 1.19%;
4th layer: polymethyl methacrylate: 67%, iron oxide red: 0.002%, iron black: 0.002%, iron oxide yellow: 0.004%, titanium white: 0.07%, methyl methacrylate: 31.73%, GDMA: 1.192%;
Embodiment 2
(1) raw material drying: polymethyl methacrylate powder is dry at 85 DEG C.
(2) match colors mixing: prepare four layers of materials respectively according to proportioning, every layer of materials all will mix, and pugging mullering, to dough period, forms plastic dough product;
(3) hot-forming: to combine hot-forming for four layers of plastic dough product in order in mould, hot pressing temperature 110 DEG C, hot pressing time 15min.Wherein, die size is ground floor thickness: 5mm, second layer thickness: 4mm, third layer thickness: 4mm, the 4th layer thickness: 5mm, appearance and size Φ 98.5*18mm.
(4) heat treatment: by four layers of look synthetic resin block heat treatment 12h at 85 DEG C after hot-forming, obtain four layers of look synthetic resin block finished product.
Wherein, each constituent mass percentage of four layers of materials is respectively:
Ground floor: polymethyl methacrylate: 70%, iron oxide red: 0.004%, iron black: 0.002%, iron oxide yellow: 0.01%, titanium white: 0.1%, methyl methacrylate: 28.689%, GDMA: 1.195%;
The second layer: polymethyl methacrylate: 70%, iron oxide red: 0.002%, iron black: 0.002%, iron oxide yellow: 0.007%, titanium white: 0.1%, methyl methacrylate: 28.694%, GDMA: 1.195%;
Third layer: polymethyl methacrylate: 70%, iron oxide red: 0.003%, iron black: 0.001%, iron oxide yellow: 0.005%, titanium white: 0.1%, methyl methacrylate: 28.696%, GDMA: 1.195%;
4th layer: polymethyl methacrylate: 70%, iron oxide red: 0.002%, iron black: 0.002%, iron oxide yellow: 0.003%, titanium white: 0.07%, methyl methacrylate: 28.726%, GDMA: 1.197%.
Embodiment 3
(1) raw material drying: polymethyl methacrylate powder is dry at 90 DEG C.
(2) match colors mixing: prepare four layers of materials respectively according to proportioning, every layer of materials all will mix, and pugging mullering, to dough period, forms plastic dough product;
(3) hot-forming: to combine hot-forming for four layers of plastic dough product in order in mould, hot pressing temperature 125 DEG C, hot pressing time 20min.Wherein, die size is ground floor thickness: 6mm, second layer thickness: 4mm, third layer thickness: 4mm, the 4th layer thickness: 6mm, appearance and size Φ 98.5*20mm.
(4) heat treatment: by four layers of look synthetic resin block heat treatment 12h at 90 DEG C after hot-forming, obtain four layers of look synthetic resin block finished product.
Wherein, each constituent mass percentage of four layers of materials is respectively:
Ground floor: polymethyl methacrylate: 72%, iron oxide red: 0.008%, iron black: 0.005%, iron oxide yellow: 0.02%, titanium white: 0.18%, methyl methacrylate: 25.787%, GDMA: 2%;
The second layer: polymethyl methacrylate: 72%, iron oxide red: 0.004%, iron black: 0.003%, iron oxide yellow: 0.007%, titanium white: 0.15%, methyl methacrylate: 25.836%, GDMA: 2%;
Third layer: polymethyl methacrylate: 72%, iron oxide red: 0.004%, iron black: 0.002%, iron oxide yellow: 0.006%, titanium white: 0.15%, methyl methacrylate: 25.838%, GDMA: 2%;
4th layer: polymethyl methacrylate: 72%, iron oxide red: 0.008%, iron black: 0.002%, iron oxide yellow: 0.005%, titanium white: 0.08%, methyl methacrylate: 25.905%, GDMA: 2%.
In sum, each layer color of the present invention can be regulated and controled by formula, to reach best color developing effect, the dental models processed by the present invention or crown and bridge colour developing nature, true to nature, and preparation of the present invention is simple, simplify operating process, production cost is low.
Above-described embodiment is the present invention's preferably embodiment; but embodiments of the present invention are not restricted to the described embodiments; change, the modification done under other any does not deviate from Spirit Essence of the present invention and principle, substitute, combine, simplify; all should be the substitute mode of equivalence, be included in protection scope of the present invention.
Claims (3)
1. four layers of look synthetic resin block, are applied in dental models or crown and bridge, it is characterized in that, be made up of successively four-layer structure, wherein,
Ground floor is made up of following component by mass percentage: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.01%, iron black: 0% ~ 0.005%, iron oxide yellow: 0% ~ 0.02%, titanium white: 0% ~ 0.2%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
The second layer is made up of following component by mass percentage: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.004%, iron black: 0% ~ 0.003%, iron oxide yellow: 0% ~ 0.01%, titanium white: 0% ~ 0.15%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
Third layer is made up of following component by mass percentage: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.004%, iron black: 0% ~ 0.003%, iron oxide yellow: 0% ~ 0.007%, titanium white: 0% ~ 0.15%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
4th layer is made up of following component by mass percentage: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.01%, iron black: 0% ~ 0.01%, iron oxide yellow: 0% ~ 0.005%, titanium white: 0% ~ 0.1%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%.
2. the preparation method of four layers of look synthetic resin block according to claim 1, it is characterized in that, this preparation method comprises the following steps:
(1) raw material drying: polymethyl methacrylate powder is dry at 80 ~ 90 DEG C;
(2) match colors mixing: prepare four layers of materials respectively according to proportioning, every layer of materials all will mix, and pugging mullering, to dough period, forms plastic dough product;
(3) hot-forming: to combine hot-forming for four layers of plastic dough product in order in mould, hot pressing temperature 110 ~ 130 DEG C, hot pressing time 10 ~ 20min;
(4) heat treatment: by four layers of look synthetic resin block heat treatment 10 ~ 12h at 80 ~ 90 DEG C after hot-forming, obtain four layers of look synthetic resin block finished product;
Wherein, each constituent mass percentage of four layers of materials is respectively:
Ground floor: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.01% is iron black: 0% ~ 0.005%, iron oxide yellow: 0% ~ 0.02%, titanium white: 0% ~ 0.2%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
The second layer: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.004% is iron black: 0% ~ 0.003%, iron oxide yellow: 0% ~ 0.01%, titanium white: 0% ~ 0.15%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
Third layer: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.004% is iron black: 0% ~ 0.003%, iron oxide yellow: 0% ~ 0.007%, titanium white: 0% ~ 0.15%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%;
4th layer: polymethyl methacrylate: 62% ~ 74%, iron oxide red: 0% ~ 0.01% is iron black: 0% ~ 0.01%, iron oxide yellow: 0% ~ 0.005%, titanium white: 0% ~ 0.1%, methyl methacrylate: 25% ~ 36%, GDMA: 1% ~ 2%.
3. the preparation method of four layers of look synthetic resin block according to claim 2, is characterized in that, described die size is ground floor thickness: 4 ~ 9mm, second layer thickness: 3 ~ 5mm, third layer thickness: 3 ~ 5mm, the 4th layer thickness: 4 ~ 6mm.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310233678.XA CN103273713B (en) | 2013-06-13 | 2013-06-13 | Four layers of look synthetic resin block and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201310233678.XA CN103273713B (en) | 2013-06-13 | 2013-06-13 | Four layers of look synthetic resin block and preparation method thereof |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103273713A CN103273713A (en) | 2013-09-04 |
CN103273713B true CN103273713B (en) | 2015-12-09 |
Family
ID=49056382
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201310233678.XA Active CN103273713B (en) | 2013-06-13 | 2013-06-13 | Four layers of look synthetic resin block and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103273713B (en) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103654981A (en) * | 2013-12-23 | 2014-03-26 | 上海医疗器械股份有限公司 | Multi-layer-color denture and base integrated carving block as well as manufacturing and use methods thereof |
CN104013473B (en) * | 2014-06-23 | 2016-01-20 | 上海医疗器械股份有限公司 | Dimensional metal mesh and the one-body molded carviag block of base and manufacture thereof, using method |
JP6865564B2 (en) * | 2015-11-30 | 2021-04-28 | 株式会社松風 | Resin material for multi-layer dental cutting |
DE102015121858A1 (en) * | 2015-12-15 | 2017-06-22 | Heraeus Kulzer Gmbh | Process for producing large polymerized dental material blocks |
EP3108849B1 (en) | 2016-04-25 | 2019-04-24 | 3M Innovative Properties Company | Multi-layered zirconia dental mill blank and process of production |
CN108078789B (en) * | 2017-12-19 | 2020-12-18 | 上海沪亮生物医药科技有限公司 | Preparation method of multicolor integrated dental repair material |
CN109637316A (en) * | 2018-12-17 | 2019-04-16 | 北京大学口腔医学院 | Double-layer resin tooth for the training of oral cavity tooth preparation |
CN116137807B (en) * | 2020-07-29 | 2024-05-28 | 舒万诺知识产权公司 | Method for manufacturing dental mill blocks with uniform color and/or translucency gradient |
CN112206170B (en) * | 2020-09-30 | 2021-10-15 | 爱迪特(秦皇岛)科技股份有限公司 | Gradient resin and preparation method and application thereof |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN85101839A (en) * | 1985-04-01 | 1987-01-10 | 拜尔公司 | Inorganic-organic filler, its preparation method and the application in polymeric composition thereof |
CN1484582A (en) * | 2000-12-28 | 2004-03-24 | 3M | Multi-layered article comprising a first lager of a thermoset polyurethane |
EP1413259A1 (en) * | 2002-10-23 | 2004-04-28 | Heraeus Kulzer GmbH & Co.KG | Dental moulded part, preferably artificial tooth |
FR2872032A1 (en) * | 2004-06-24 | 2005-12-30 | Oreal | Composition, useful as e.g. make-up foundation and anti dark circle product, comprises solid particles of a material, a liquid binder, and at least a dye to confer a color on the composition |
CN101670694A (en) * | 2009-06-19 | 2010-03-17 | 常州博双塑料有限公司 | Five-layer co-extrusion laminated board for sanitary ware and preparation method thereof |
CN101670696A (en) * | 2009-06-19 | 2010-03-17 | 常州博双塑料有限公司 | Extruded acryl composite foam board and preparation method thereof |
CN102501530A (en) * | 2011-11-03 | 2012-06-20 | 东莞市雄林新材料科技有限公司 | Multilayer TPU attached film and production technology thereof |
-
2013
- 2013-06-13 CN CN201310233678.XA patent/CN103273713B/en active Active
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN85101839A (en) * | 1985-04-01 | 1987-01-10 | 拜尔公司 | Inorganic-organic filler, its preparation method and the application in polymeric composition thereof |
CN1484582A (en) * | 2000-12-28 | 2004-03-24 | 3M | Multi-layered article comprising a first lager of a thermoset polyurethane |
EP1413259A1 (en) * | 2002-10-23 | 2004-04-28 | Heraeus Kulzer GmbH & Co.KG | Dental moulded part, preferably artificial tooth |
FR2872032A1 (en) * | 2004-06-24 | 2005-12-30 | Oreal | Composition, useful as e.g. make-up foundation and anti dark circle product, comprises solid particles of a material, a liquid binder, and at least a dye to confer a color on the composition |
CN101670694A (en) * | 2009-06-19 | 2010-03-17 | 常州博双塑料有限公司 | Five-layer co-extrusion laminated board for sanitary ware and preparation method thereof |
CN101670696A (en) * | 2009-06-19 | 2010-03-17 | 常州博双塑料有限公司 | Extruded acryl composite foam board and preparation method thereof |
CN102501530A (en) * | 2011-11-03 | 2012-06-20 | 东莞市雄林新材料科技有限公司 | Multilayer TPU attached film and production technology thereof |
Also Published As
Publication number | Publication date |
---|---|
CN103273713A (en) | 2013-09-04 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103273713B (en) | Four layers of look synthetic resin block and preparation method thereof | |
CN103654981A (en) | Multi-layer-color denture and base integrated carving block as well as manufacturing and use methods thereof | |
JP2018514245A (en) | Method for producing zirconia multilayer block for artificial teeth | |
CN105879240A (en) | Far-infrared negative ion health care pad | |
CN103467047A (en) | Floor tile and producing method thereof | |
CN101537655B (en) | Manufacture method for artificial marble | |
CN102320779B (en) | Celik dark beige artificial granite and preparation method thereof | |
KR101221026B1 (en) | Method for preparing material for dental restoration and material for dental restoration prepared by the same | |
TW201219126A (en) | Forming mold with dual structure and method of manufacturing exterior panel for household electric appliance using the forming mold | |
KR101410662B1 (en) | Artificial Pearl Necleus | |
CN113461421B (en) | Laminated zirconia dental ceramic material and preparation method thereof | |
KR101717255B1 (en) | Recycled zirconia block and method for preparing the same | |
CN109016078A (en) | A kind of fiber ceramics powder pressing forming technique | |
CN103897399A (en) | Architectural modeling surface mold | |
CN102408946B (en) | High temperature resistant essence | |
CN110756728A (en) | Silica gel model manufacturing method | |
KR20160025819A (en) | Forming method of artificial teeth using zirconia and artificial teeth | |
JPH0363134A (en) | Interior material and manufacture thereof | |
CN109159608A (en) | A kind of imitative shellwork and manufacturing process | |
CN204863923U (en) | Imitative sun utensil discolours | |
TWI523764B (en) | Method of manufacturing three - dimensional sound - absorbing panel | |
CN108250826A (en) | A kind of wood-based plate rapid condensation repairing putty paste | |
CN105564116A (en) | Sand sculpture handicraft and making technology thereof | |
TW201533008A (en) | Manufacturing method of artificial stone | |
PH22018001490Y1 (en) | Process of producing lightweight cement-based composite from bakong (hanguana malayana) stem and the product produced thereof |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
CB02 | Change of applicant information |
Address after: 276800 Shandong Province, Rizhao City Donggang District Shanhaiguan Road No. 68 Applicant after: Shandong Hu Ge oral cavity material limited company Address before: 276800 No. 68, Shanhai Road, Shandong, Rizhao City Applicant before: Rizhao Huge Dental Material Industry Co., Ltd. |
|
COR | Change of bibliographic data | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |