CN105274580A - 电解锰生产中水和锰渣综合利用的方法 - Google Patents
电解锰生产中水和锰渣综合利用的方法 Download PDFInfo
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- CN105274580A CN105274580A CN201510781313.XA CN201510781313A CN105274580A CN 105274580 A CN105274580 A CN 105274580A CN 201510781313 A CN201510781313 A CN 201510781313A CN 105274580 A CN105274580 A CN 105274580A
- Authority
- CN
- China
- Prior art keywords
- slag
- water
- manganese
- slurry
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011572 manganese Substances 0.000 title claims abstract description 93
- 239000002893 slag Substances 0.000 title claims abstract description 92
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 title claims abstract description 75
- 229910052748 manganese Inorganic materials 0.000 title claims abstract description 73
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 61
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 21
- 238000000034 method Methods 0.000 title claims abstract description 19
- 239000002002 slurry Substances 0.000 claims abstract description 48
- 239000007788 liquid Substances 0.000 claims abstract description 39
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 22
- 238000005406 washing Methods 0.000 claims abstract description 16
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 11
- 239000004568 cement Substances 0.000 claims abstract description 9
- 238000001914 filtration Methods 0.000 claims description 26
- 239000012065 filter cake Substances 0.000 claims description 23
- 238000005868 electrolysis reaction Methods 0.000 claims description 16
- 239000000706 filtrate Substances 0.000 claims description 16
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 12
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 12
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 12
- 239000000126 substance Substances 0.000 claims description 12
- 238000011084 recovery Methods 0.000 claims description 11
- 238000006073 displacement reaction Methods 0.000 claims description 9
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 9
- 230000007935 neutral effect Effects 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 6
- 239000002351 wastewater Substances 0.000 claims description 6
- 239000011449 brick Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000013505 freshwater Substances 0.000 claims description 5
- 239000006210 lotion Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000005086 pumping Methods 0.000 claims description 5
- 229920002472 Starch Polymers 0.000 claims description 4
- 230000008859 change Effects 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 4
- 238000012216 screening Methods 0.000 claims description 4
- 235000019698 starch Nutrition 0.000 claims description 4
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 3
- LZMCUTZPLPUFMB-UHFFFAOYSA-L dihydroxy(oxo)manganese Chemical class O[Mn](O)=O LZMCUTZPLPUFMB-UHFFFAOYSA-L 0.000 claims description 3
- 238000002386 leaching Methods 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 claims description 3
- 239000002244 precipitate Substances 0.000 claims description 3
- 239000010865 sewage Substances 0.000 claims description 3
- 239000008107 starch Substances 0.000 claims description 3
- 101000601610 Drosophila melanogaster Heparan sulfate N-sulfotransferase Proteins 0.000 claims description 2
- 238000009991 scouring Methods 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 5
- 238000004064 recycling Methods 0.000 abstract description 3
- 150000003863 ammonium salts Chemical class 0.000 abstract description 2
- 159000000003 magnesium salts Chemical class 0.000 abstract description 2
- 239000000463 material Substances 0.000 abstract description 2
- 239000012528 membrane Substances 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract 1
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- 150000003839 salts Chemical class 0.000 description 4
- 238000006477 desulfuration reaction Methods 0.000 description 2
- 230000023556 desulfurization Effects 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- NWUYHJFMYQTDRP-UHFFFAOYSA-N 1,2-bis(ethenyl)benzene;1-ethenyl-2-ethylbenzene;styrene Chemical compound C=CC1=CC=CC=C1.CCC1=CC=CC=C1C=C.C=CC1=CC=CC=C1C=C NWUYHJFMYQTDRP-UHFFFAOYSA-N 0.000 description 1
- AQGDXJQRVOCUQX-UHFFFAOYSA-N N.[S] Chemical compound N.[S] AQGDXJQRVOCUQX-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000011469 building brick Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000009615 deamination Effects 0.000 description 1
- 238000006481 deamination reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000008676 import Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000003456 ion exchange resin Substances 0.000 description 1
- 229920003303 ion-exchange polymer Polymers 0.000 description 1
- XMWCXZJXESXBBY-UHFFFAOYSA-L manganese(ii) carbonate Chemical compound [Mn+2].[O-]C([O-])=O XMWCXZJXESXBBY-UHFFFAOYSA-L 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000001471 micro-filtration Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 238000000108 ultra-filtration Methods 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Abstract
Description
Claims (5)
Priority Applications (1)
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CN201510781313.XA CN105274580B (zh) | 2015-11-15 | 2015-11-15 | 电解锰生产中水和锰渣综合利用的方法 |
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CN201510781313.XA CN105274580B (zh) | 2015-11-15 | 2015-11-15 | 电解锰生产中水和锰渣综合利用的方法 |
Publications (2)
Publication Number | Publication Date |
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CN105274580A true CN105274580A (zh) | 2016-01-27 |
CN105274580B CN105274580B (zh) | 2018-01-12 |
Family
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Family Applications (1)
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CN201510781313.XA Active CN105274580B (zh) | 2015-11-15 | 2015-11-15 | 电解锰生产中水和锰渣综合利用的方法 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106399701A (zh) * | 2016-08-31 | 2017-02-15 | 中信大锰矿业有限责任公司 | 一种电解锰渣中可溶锰的回收方法 |
CN108507899A (zh) * | 2018-04-04 | 2018-09-07 | 青海盐湖工业股份有限公司 | 一种电解金属镁槽渣分析方法 |
CN108689671A (zh) * | 2018-06-07 | 2018-10-23 | 广西壮族自治区环境保护科学研究院 | 电解锰渣中锰和硫酸铵处理回收方法 |
CN110551898A (zh) * | 2019-09-16 | 2019-12-10 | 中信大锰矿业有限责任公司 | 一种电解锰渣的处理方法 |
CN110735153A (zh) * | 2018-09-27 | 2020-01-31 | 庞炼红 | 电解金属锰产出的阳极泥的循环再利用方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5625939A (en) * | 1979-08-07 | 1981-03-12 | Nippon Steel Corp | Manufacture of metallic manganese |
CN101260471A (zh) * | 2008-04-28 | 2008-09-10 | 中国环境科学研究院 | 一种采用阳极液提取锰渣中可溶性锰的成套清洁生产工艺 |
CN101629250A (zh) * | 2008-07-16 | 2010-01-20 | 保靖友丰锰业有限责任公司 | 从电解金属锰压滤渣中回收可溶锰的方法 |
CN104357662A (zh) * | 2014-11-04 | 2015-02-18 | 中国环境科学研究院 | 一种电解锰渣的无害化处理工艺 |
CN104480314A (zh) * | 2014-12-17 | 2015-04-01 | 赵阳臣 | 锰业生产废渣回收利用的方法 |
-
2015
- 2015-11-15 CN CN201510781313.XA patent/CN105274580B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5625939A (en) * | 1979-08-07 | 1981-03-12 | Nippon Steel Corp | Manufacture of metallic manganese |
CN101260471A (zh) * | 2008-04-28 | 2008-09-10 | 中国环境科学研究院 | 一种采用阳极液提取锰渣中可溶性锰的成套清洁生产工艺 |
CN101629250A (zh) * | 2008-07-16 | 2010-01-20 | 保靖友丰锰业有限责任公司 | 从电解金属锰压滤渣中回收可溶锰的方法 |
CN104357662A (zh) * | 2014-11-04 | 2015-02-18 | 中国环境科学研究院 | 一种电解锰渣的无害化处理工艺 |
CN104480314A (zh) * | 2014-12-17 | 2015-04-01 | 赵阳臣 | 锰业生产废渣回收利用的方法 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106399701A (zh) * | 2016-08-31 | 2017-02-15 | 中信大锰矿业有限责任公司 | 一种电解锰渣中可溶锰的回收方法 |
CN108507899A (zh) * | 2018-04-04 | 2018-09-07 | 青海盐湖工业股份有限公司 | 一种电解金属镁槽渣分析方法 |
CN108689671A (zh) * | 2018-06-07 | 2018-10-23 | 广西壮族自治区环境保护科学研究院 | 电解锰渣中锰和硫酸铵处理回收方法 |
CN110735153A (zh) * | 2018-09-27 | 2020-01-31 | 庞炼红 | 电解金属锰产出的阳极泥的循环再利用方法 |
CN110551898A (zh) * | 2019-09-16 | 2019-12-10 | 中信大锰矿业有限责任公司 | 一种电解锰渣的处理方法 |
Also Published As
Publication number | Publication date |
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CN105274580B (zh) | 2018-01-12 |
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Legal Events
Date | Code | Title | Description |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210714 Address after: 425000 zaobei village, Zhushan Town, Lingling District, Yongzhou City, Hunan Province Patentee after: Yongzhou Xincheng Manganese Industry Co.,Ltd. Address before: 416400 Public Security Village No. 51, Huayuan Town, Huayuan County, Tujia and Miao Autonomous Prefecture, Western Hunan Province Patentee before: Wang Zhaobing |
|
TR01 | Transfer of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A method for comprehensive utilization of water and manganese slag in electrolytic manganese production Granted publication date: 20180112 Pledgee: Agricultural Bank of China Limited Yongzhou Lingling sub branch Pledgor: Yongzhou Xincheng Manganese Industry Co.,Ltd. Registration number: Y2024980008611 |