CN105273474A - Mildew-proof antibacterial putty powder and using method - Google Patents
Mildew-proof antibacterial putty powder and using method Download PDFInfo
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- CN105273474A CN105273474A CN201510502996.0A CN201510502996A CN105273474A CN 105273474 A CN105273474 A CN 105273474A CN 201510502996 A CN201510502996 A CN 201510502996A CN 105273474 A CN105273474 A CN 105273474A
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Abstract
The present invention discloses mildew-proof antibacterial putty powder including a main body material, an adhesive material and a mildew-proof antibacterial material, the main body material, the adhesive material and the mildew-proof antibacterial material are respectively individually packaged in a putty powder large package, before the package, the main body material, the adhesive material and the mildew-proof antibacterial material are respectively individually pulverized, the powder putty basic level crack is 0.48mm-0.51mm, the adhesive strength is 0.80MPa-1.1MPa, the bond strength after 5 times of freeze-thaw cycle is 0.51MPa-0.54MPa, the water absorbing amount is 1.0g / 10min-1.3g / 10min, and the fineness is 50mum-80mum. The putty powder prepared by the invention is not easy to mildew, good in water resistance, and high in bond strength, has the advantages of no dusting, no peeling, no cracking, no mildewing, easy construction, and good antibacterial effect.
Description
Technical field
The invention belongs to and building material technical field, particularly relate to a kind of antimildew and antibacterial putty powder and using method thereof.
Background technology
Along with people are to the attention of building coating operating technique, putty is also developed accordingly as important supplementary material, and each manufacturer domestic develops the putty of different purposes, variform in succession.The significantly development of Coating Market; putty material; especially exterior wall putty material becomes the main products of many dry-mixed mortar manufacturers; this is because from the practical situations of domestic construction coating; frequent existence is bubbled, decortication, the disadvantage such as mouldy, really had a strong impact on coating to the protection of buildings and decorate properties.Use at China's wet area (Jiangsu and Zhejiang Provinces, Shanghai, Hubei, Guangdong, Fujian, Sichuan, Chongqing, Hunan, Hainan, Guangxi etc.) especially severe that goes mouldy, cause interior wall revision rate high especially, general 1-2 interior wall body of wall will renovate, and cause financial loss huge especially.
Chinese patent CN201310254640.0 discloses a kind of Environmentally-frieinterior interior wall putty powder, this putty powder is made up of following component with parts by weight: white cement 15-18 part, sierozem power 3-5 part, cassava pasted starch 6-8 part,-320 order heavy calcium carbonate 22-26 parts,-200 order pearlstone 3-5 parts, 3-5mm polypropylene fibre 1.5-2.5 part, polyvinyl alcohol 2-4 part, carboxymethyl cellulose 2-3 part, three grades of flyash 2.5-3.5 parts, sodium bentonite 5-7 part, Sodium Silicofluoride 1-2 part, dispersion agent 2-4 part, defoamer 0.4-0.6 part, mould inhibitor 0.2-0.4 part.But this putty powder easily produces Signs of Mould after using, situation about using in south is more serious, and work-ing life is not long.
Chinese patent CN201310427199.1 discloses a kind of Environment-friendlyhigh-strength high-strength mildew-proof putty powder, comprise the component of following weight percent: water-ground limestone 70-99%, grey calcium 0-30%, starch alkenyl succinate ester 0.5-10%, Vltra tears 0.2-5%, treated starch 0.5-10%, the weight percent sum of above-mentioned each component is 100%.But the water tolerance of this putty powder and bonding strength poor, result of use is poor, is not suitable with market-oriented demand.
Therefore a kind of unsuitable mouldy, putty powder that water-tolerant, cohesive strength are large is badly in need of, to meet the needs in market.
Summary of the invention
The present invention is directed to the problems referred to above, a kind of antibacterial and mouldproof putty powder and using method thereof are provided.
The present invention's adopted technical scheme that solves the problem is: a kind of antimildew and antibacterial putty powder, comprises material of main part, jointing material and antimildew and antibacterial material, material of main part, jointing material and antimildew and antibacterial material are independently packed in the large packaging of putty powder, material of main part, jointing material and antimildew and antibacterial material are independently pulverized before packing, basic unit's crackle of putty powder is 0.48mm ~ 0.51mm, the cohesive strength of putty powder is 0.80MPa ~ 1.1MPa, cohesive strength after putty powder freeze-thaw cycle 5 times is 0.51MPa ~ 0.54MPa, the water regain of putty powder is 1.0g/10min ~ 1.3g/10min, the fineness of putty powder is 50 μm ~ 80 μm, and material of main part is: zine fluosilicate, quartz sand, terra alba, talcum powder, kaolin, piezoelectric ceramic powder, marble flour, iron dravite, terbium oxide, be oxidized ten dicalcium 14 aluminium, the weight part of material of main part consists of: zine fluosilicate 1 part ~ 3 parts, quartz sand 20 parts ~ 30 parts, terra alba 1 part ~ 7 parts, talcum powder 1 part ~ 3 parts, kaolin 10 parts ~ 20 parts, piezoelectric ceramic powder 1 part ~ 3 parts, marble flour 10 parts ~ 30 parts, iron dravite 1 part ~ 5 parts, terbium oxide 1 part ~ 5 parts, be oxidized 1 part ~ 5 parts, ten dicalcium 14 aluminium.Material of main part, jointing material efficient combination, the amount of slurry absorption working fluid in the course of processing can be reduced, cut the waste, the interpolation of antimildew and antibacterial material simultaneously, can antibacterially eliminate the unusual smell, purify air, have that bonding strength is high, water-retentivity is good, environmental protection, stationary phase long, the strong quality better of bounding force feature.
Further, terbium oxide is terbium sesquioxide or terbium peroxide.The premium properties of terbium oxide can make putty powder have special gloss.
Further, when terbium oxide is terbium sesquioxide, the weight part of material of main part consists of: zine fluosilicate 1 part ~ 3 parts, quartz sand 20 parts ~ 25 parts, terra alba 1 part ~ 4 parts, talcum powder 1 part ~ 3 parts, kaolin 10 parts ~ 15 parts, piezoelectric ceramic powder 1 part ~ 3 parts, marble flour 10 parts ~ 20 parts, iron dravite 1 part ~ 3 parts, terbium sesquioxide 1 part ~ 3 parts, be oxidized 1 part ~ 3 parts, ten dicalcium 14 aluminium.
Further, when terbium oxide is terbium peroxide, the weight part of material of main part consists of: zine fluosilicate 1 part ~ 3 parts, quartz sand 25 parts ~ 30 parts, terra alba 4 parts ~ 7 parts, talcum powder 1 part ~ 3 parts, kaolin 15 parts ~ 20 parts, piezoelectric ceramic powder 1 part ~ 3 parts, marble flour 20 parts ~ 30 parts, iron dravite 3 parts ~ 5 parts, terbium peroxide 3 parts ~ 5 parts, be oxidized 3 parts ~ 5 parts, ten dicalcium 14 aluminium.
Further, jointing material is the mixture of tripoly phosphate sodium STPP, Natvosol, polypropylene fibre, starch ethers, white cement, methyl cellulose ether.
Further, the weight part of jointing material consists of: tripoly phosphate sodium STPP 1 part ~ 3 parts, Natvosol 3 parts ~ 5 parts, polypropylene fibre 3 parts ~ 5 parts, starch ethers 4 parts ~ 6 parts, white cement 3 parts ~ 5 parts, methyl cellulose ether 3 parts ~ 5 parts.
Further, antimildew and antibacterial material is TiO
2, ZnO, CdS, WO
3, sodium Diacetate, SnO
2and Fe
2o
3mixture.The anti-biotic material added is photocatalysis antibacterial material, under irradiate light, just can kill the microorganism be in contact with it completely, instant effect, durable, non-secondary pollution in the short period of time.
Further, the weight part of antimildew and antibacterial material consists of: TiO
21 part ~ 3 parts, ZnO1 part ~ 3 part, CdS1 part ~ 3 part, WO
31 part ~ 3 parts, SnO
21 part ~ 3 parts, sodium Diacetate 1 part ~ 3 parts, Fe
2o
31 part ~ 3 parts.Mould inhibitor is sodium Diacetate, have anti-mold effect that is efficient, wide spectrum, especially have stronger restraining effect to flavacin, it is by infiltration microorganism wall, the generation of various enzyme system in interference cell, efficiently can suppress growing and spreading of more than ten kind of Mycinomycin II and various bacteria.
Further, the weight ratio of putty powder is, material of main part: jointing material: antimildew and antibacterial material=3:1:1.
According to another object of the present invention, be the using method that a kind of antimildew and antibacterial putty powder is provided, be specially: the packaging of material of main part, antimildew and antibacterial material is taken apart, mix, then add the clear water of material of main part, antimildew and antibacterial material gross weight 2 times, after stirring, add jointing material, limit edged stirs, even to all material mixing, do not play pimple, can use.Putty powder water-tolerant of the present invention, cohesive strength are large, have not dry linting, non-scale, do not chap, do not play mould advantage, and easy construction, can directly use by trowelling, also can support the use with high-grade emulsion paint, be applicable to southern wet area, and kitchen, toilet, the easy mouldy place such as vault, and this putty powder is not containing toxic organic solvents and harmful composition, meets the requirement of environmental type.
Advantage of the present invention is:
1. putty powder water-tolerant, the cohesive strength prepared of the present invention is large, has not dry linting, non-scale, does not chap, do not play mould advantage, and easy construction;
2. the anti-biotic material that the present invention adds is photocatalysis antibacterial material, under irradiate light, just can kill the microorganism be in contact with it completely, instant effect, durable, non-secondary pollution in the short period of time;
3. the mould inhibitor that the present invention adds is sodium Diacetate, there is anti-mold effect that is efficient, wide spectrum, especially to flavacin, there is stronger restraining effect, it is by infiltration microorganism wall, the generation of various enzyme system in interference cell, efficiently can suppress growing and spreading of more than ten kind of Mycinomycin II and various bacteria;
4. putty powder of the present invention can directly use by trowelling, also can support the use with high-grade emulsion paint, be applicable to southern wet area, and kitchen, toilet, the easy mouldy place such as vault, and this putty powder is not containing toxic organic solvents and harmful composition, meets the requirement of environmental type.
Except object described above, feature and advantage, the present invention also has other object, feature and advantage.Below with reference to embodiment, the present invention is further detailed explanation.
Embodiment
Below in conjunction with embodiment, the present invention is described in detail, but the multitude of different ways that the present invention can be defined by the claims and cover is implemented.
Embodiment 1
A kind of antimildew and antibacterial putty powder and using method thereof
Antimildew and antibacterial putty powder forms:
Material of main part: zine fluosilicate 1kg, quartz sand 20kg, terra alba 1kg, talcum powder 1kg, kaolin 10kg, piezoelectric ceramic powder 1kg, marble flour 10kg, iron dravite 1kg, terbium sesquioxide 3kg, be oxidized ten dicalcium 14 aluminium 3kg.
Jointing material: tripoly phosphate sodium STPP 1kg, Natvosol 3kg, polypropylene fibre 3kg, starch ethers 4kg, white cement 3kg, methyl cellulose ether 3kg.
Antimildew and antibacterial material: TiO
21kg, ZnO1kg, CdS3kg, WO
33kg, SnO
23kg, sodium Diacetate 3kg, Fe
2o
33kg.
Method of preparation and use:
By material of main part, jointing material and antimildew and antibacterial material, independently pulverize before packing, fineness is 50 μm, and independently packs in the large packaging of putty powder, during use, the packaging of material of main part, antimildew and antibacterial material is taken apart, mix, then add the clear water of material of main part, antimildew and antibacterial material gross weight 2 times, after stirring, add jointing material, limit edged stirs, even to all material mixing, do not play pimple, can use.
Embodiment 2
A kind of antimildew and antibacterial putty powder and using method thereof
Antimildew and antibacterial putty powder forms:
Material of main part: zine fluosilicate 3kg, quartz sand 25kg, terra alba 4kg, talcum powder 3kg, kaolin 15kg, piezoelectric ceramic powder 3kg, marble flour 20kg, iron dravite 3kg, terbium sesquioxide 1kg, be oxidized ten dicalcium 14 aluminium 1kg.
Jointing material: tripoly phosphate sodium STPP 3kg, Natvosol 3kg, polypropylene fibre 5kg, starch ethers 5kg, white cement 5kg, methyl cellulose ether 5kg.
Antimildew and antibacterial material: TiO
26kg, ZnO6kg, CdS2.8kg, WO
32.8kg, SnO
22.8kg, sodium Diacetate 2.8kg, Fe
2o
32.8kg.
Method of preparation and use:
By material of main part, jointing material and antimildew and antibacterial material, independently pulverize before packing, fineness is 60 μm, and independently packs in the large packaging of putty powder, during use, the packaging of material of main part, antimildew and antibacterial material is taken apart, mix, then add the clear water of material of main part, antimildew and antibacterial material gross weight 2 times, after stirring, add jointing material, limit edged stirs, even to all material mixing, do not play pimple, can use.
Embodiment 3
A kind of antimildew and antibacterial putty powder and using method thereof
Antimildew and antibacterial putty powder forms:
Material of main part: zine fluosilicate 1kg, quartz sand 25kg, terra alba 4kg, talcum powder 1kg, kaolin 15kg, piezoelectric ceramic powder 1kg, marble flour 20kg, iron dravite 3kg, terbium peroxide 3kg, be oxidized ten dicalcium 14 aluminium 5kg.
Jointing material: tripoly phosphate sodium STPP 2kg, Natvosol 4kg, polypropylene fibre 4kg, starch ethers 6kg, white cement 5kg, methyl cellulose ether 5kg.
Antimildew and antibacterial material: TiO
23kg, ZnO3kg, CdS3kg, WO
33kg, SnO
23kg, sodium Diacetate 3kg, Fe
2o
38kg.
Method of preparation and use:
By material of main part, jointing material and antimildew and antibacterial material, independently pulverize before packing, fineness is 70 μm, and independently packs in the large packaging of putty powder, during use, the packaging of material of main part, antimildew and antibacterial material is taken apart, mix, then add the clear water of material of main part, antimildew and antibacterial material gross weight 2 times, after stirring, add jointing material, limit edged stirs, even to all material mixing, do not play pimple, can use.
Embodiment 4
A kind of antimildew and antibacterial putty powder and using method thereof
Antimildew and antibacterial putty powder forms:
Material of main part: zine fluosilicate 2kg, quartz sand 30kg, terra alba 7kg, talcum powder 3kg, kaolin 20kg, piezoelectric ceramic powder 3kg, marble flour 30kg, iron dravite 5kg, terbium peroxide 5kg, be oxidized ten dicalcium 14 aluminium 3kg.
Jointing material: tripoly phosphate sodium STPP 4kg, Natvosol 6kg, polypropylene fibre 6kg, starch ethers 8kg, white cement 6kg, methyl cellulose ether 6kg.
Antimildew and antibacterial material: TiO
25kg, ZnO5kg, CdS5kg, WO
35kg, SnO
25kg, sodium Diacetate 6kg, Fe
2o
35kg.
Method of preparation and use:
By material of main part, jointing material and antimildew and antibacterial material, independently pulverize before packing, fineness is 80 μm, and independently packs in the large packaging of putty powder, during use, the packaging of material of main part, antimildew and antibacterial material is taken apart, mix, then add the clear water of material of main part, antimildew and antibacterial material gross weight 2 times, after stirring, add jointing material, limit edged stirs, even to all material mixing, do not play pimple, can use.
Experimental example
In this experimental example, test the performance of putty powder prepared by the present invention 1 ~ 4 by experiment.
1. test materials
Experimental group: putty powder prepared by the embodiment of the present invention 1 ~ 4;
Control group: common putty powder.
2. test method
The indices performance of the test embodiment of the present invention 1 ~ 4 putty powder, common putty powder.
3. test-results
Analyze after the indices performance test of the embodiment of the present invention 1 ~ 4 putty powder, common putty powder, experimental result is in table 1.
Table 1. test result
Experimental result shows, compared with common putty powder, the embodiment of the present invention 1 ~ 4 prepare the antimildew and antibacterial of putty powder under square one, cohesive strength, cohesive strength after freeze thawing (circulate 5 times after) results of property mensuration be better than common putty powder, basic unit's crackle, water regain are lower than common putty powder, preparation method is applicable to promoting, and quality product is better.
These are only the preferred embodiments of the present invention and experimental example, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., within the protection domain that all should be included in invention.
Claims (10)
1. an antimildew and antibacterial putty powder, comprises material of main part, jointing material and antimildew and antibacterial material, described material of main part, jointing material and antimildew and antibacterial material are independently packed in the large packaging of putty powder, described material of main part, jointing material and antimildew and antibacterial material are independently pulverized before packing, it is characterized in that, basic unit's crackle of described putty powder is 0.48mm ~ 0.51mm, the cohesive strength of described putty powder is 0.80MPa ~ 1.1MPa, cohesive strength after described putty powder freeze-thaw cycle 5 times is 0.51MPa ~ 0.54MPa, the water regain of described putty powder is 1.0g/10min ~ 1.3g/10min, and the fineness of described putty powder is 50 μm ~ 80 μm, and described material of main part is: zine fluosilicate, quartz sand, terra alba, talcum powder, kaolin, piezoelectric ceramic powder, marble flour, iron dravite, terbium oxide, be oxidized ten dicalcium 14 aluminium, the weight part of described material of main part consists of: zine fluosilicate 1 part ~ 3 parts, quartz sand 20 parts ~ 30 parts, terra alba 1 part ~ 7 parts, talcum powder 1 part ~ 3 parts, kaolin 10 parts ~ 20 parts, piezoelectric ceramic powder 1 part ~ 3 parts, marble flour 10 parts ~ 30 parts, iron dravite 1 part ~ 5 parts, terbium oxide 1 part ~ 5 parts, be oxidized 1 part ~ 5 parts, ten dicalcium 14 aluminium.
2. putty powder according to claim 1, is characterized in that, described terbium oxide is terbium sesquioxide or terbium peroxide.
3. putty powder according to claim 2, it is characterized in that, when described terbium oxide is terbium sesquioxide, the weight part of described material of main part consists of: zine fluosilicate 1 part ~ 3 parts, quartz sand 20 parts ~ 25 parts, terra alba 1 part ~ 4 parts, talcum powder 1 part ~ 3 parts, kaolin 10 parts ~ 15 parts, piezoelectric ceramic powder 1 part ~ 3 parts, marble flour 10 parts ~ 20 parts, iron dravite 1 part ~ 3 parts, terbium sesquioxide 1 part ~ 3 parts, be oxidized 1 part ~ 3 parts, ten dicalcium 14 aluminium.
4. putty powder according to claim 2, it is characterized in that, when described terbium oxide is terbium peroxide, the weight part of described material of main part consists of: zine fluosilicate 1 part ~ 3 parts, quartz sand 25 parts ~ 30 parts, terra alba 4 parts ~ 7 parts, talcum powder 1 part ~ 3 parts, kaolin 15 parts ~ 20 parts, piezoelectric ceramic powder 1 part ~ 3 parts, marble flour 20 parts ~ 30 parts, iron dravite 3 parts ~ 5 parts, terbium peroxide 3 parts ~ 5 parts, be oxidized 3 parts ~ 5 parts, ten dicalcium 14 aluminium.
5. putty powder according to claim 1, is characterized in that, described jointing material is the mixture of tripoly phosphate sodium STPP, Natvosol, polypropylene fibre, starch ethers, white cement, methyl cellulose ether.
6. putty powder according to claim 5, it is characterized in that, the weight part of described jointing material consists of: tripoly phosphate sodium STPP 1 part ~ 3 parts, Natvosol 3 parts ~ 5 parts, polypropylene fibre 3 parts ~ 5 parts, starch ethers 4 parts ~ 6 parts, white cement 3 parts ~ 5 parts, methyl cellulose ether 3 parts ~ 5 parts.
7. putty powder according to claim 1, is characterized in that, described antimildew and antibacterial material is TiO
2, ZnO, CdS, WO3, sodium Diacetate, SnO
2and Fe
2o
3mixture.
8. putty powder according to claim 7, is characterized in that, the weight part of described antimildew and antibacterial material consists of: TiO
21 part ~ 3 parts, ZnO1 part ~ 3 part, CdS1 part ~ 3 part, WO
31 part ~ 3 parts, SnO
21 part ~ 3 parts, sodium Diacetate 1 part ~ 3 parts, Fe
2o
31 part ~ 3 parts.
9. putty powder according to claim 1, is characterized in that, the weight ratio of described putty powder is, material of main part: jointing material: antimildew and antibacterial material=3:1:1.
10. the using method of an antimildew and antibacterial putty powder as claimed in claim 1, it is characterized in that, described using method is: the packaging of material of main part, antimildew and antibacterial material taken apart, mix, then add the clear water of material of main part, antimildew and antibacterial material gross weight 2 times, after stirring, add jointing material, limit edged stirs, even to all material mixing, do not play pimple, can use.
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Cited By (4)
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CN106433279A (en) * | 2016-11-29 | 2017-02-22 | 中山摩尔化学工业有限公司 | Inner wall putty with antibacterial and odor removing effects and preparation method thereof |
CN110387192A (en) * | 2019-07-16 | 2019-10-29 | 佛山欧神诺陶瓷有限公司 | A kind of ceramic polishing liquid and preparation method thereof that can generate anion |
CN112680015A (en) * | 2021-03-12 | 2021-04-20 | 广东博智林机器人有限公司 | Putty material |
CN114213894A (en) * | 2022-02-07 | 2022-03-22 | 浙江建工新材料有限公司 | Moistureproof and mildewproof putty suitable for humid environment |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106433279A (en) * | 2016-11-29 | 2017-02-22 | 中山摩尔化学工业有限公司 | Inner wall putty with antibacterial and odor removing effects and preparation method thereof |
CN110387192A (en) * | 2019-07-16 | 2019-10-29 | 佛山欧神诺陶瓷有限公司 | A kind of ceramic polishing liquid and preparation method thereof that can generate anion |
CN112680015A (en) * | 2021-03-12 | 2021-04-20 | 广东博智林机器人有限公司 | Putty material |
CN114213894A (en) * | 2022-02-07 | 2022-03-22 | 浙江建工新材料有限公司 | Moistureproof and mildewproof putty suitable for humid environment |
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