CN104912212A - Composite vacuum thermal isolation heat preservation board and long-acting breathing mud thereof - Google Patents

Composite vacuum thermal isolation heat preservation board and long-acting breathing mud thereof Download PDF

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CN104912212A
CN104912212A CN201510315249.6A CN201510315249A CN104912212A CN 104912212 A CN104912212 A CN 104912212A CN 201510315249 A CN201510315249 A CN 201510315249A CN 104912212 A CN104912212 A CN 104912212A
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long
mud
acting breathing
breathing
acting
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CN104912212B (en
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翟传伟
李壮贤
何奕
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Qingdao Kerui new environmental protection materials Group Co. Ltd.
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Qingdao Creek New Environmental Materials Co Ltd
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Priority to CN201610525173.4A priority Critical patent/CN106242459B/en
Priority to CN201610525779.8A priority patent/CN106242460B/en
Priority to CN201510315249.6A priority patent/CN104912212B/en
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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/10Lime cements or magnesium oxide cements
    • C04B28/12Hydraulic lime
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00008Obtaining or using nanotechnology related materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00025Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20Resistance against chemical, physical or biological attack
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A30/00Adapting or protecting infrastructure or their operation
    • Y02A30/24Structural elements or technologies for improving thermal insulation
    • Y02A30/242Slab shaped vacuum insulation
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02BCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS
    • Y02B80/00Architectural or constructional elements improving the thermal performance of buildings
    • Y02B80/10Insulation, e.g. vacuum or aerogel insulation

Abstract

The invention discloses a composite vacuum thermal isolation heat preservation board and long-acting breathing mud of the board. The long-acting breathing mud is an indoor decoration material prepared through the manner that main raw materials of inorganic bond materials and kieselguhr are compounded with filling materials, function adding agents, water-retaining agents and construction adjusting agents through mechanical gravity-free mixing; the long-acting breathing mud is used in a whole room and has the functions of removing formaldehyde, purifying air, adjusting humidity, releasing negative oxygen ions, achieving fireproof and inflaming retarding aims, wall self-cleanness, disinfection and deodorization and the like; due to the fact that the long-acting breathing mud is healthy and environmentally friendly, the good decoration is achieved, functionality is achieved, and the mud is a new-generation indoor decoration material replacing wallpaper and emulsion varnish.

Description

A kind of composite evacuated heat insulating board and long-acting breathing mud thereof
Technical field
The present invention relates to a kind of vacuum heat-insulating plate, belong to the field of E04B building.
Background technology
Do not fire or difficult combustion although vacuum heat-insulating plate fire-protection rating common at present can be up to state standards, heat insulation effect is good.But they are easily scraped off in work progress, occur hollowing, gas leak phenomenon, utilization rate reduces greatly.
In addition the purification function of the interior decoration scavenging material of prior art is lower, and performance is not very stable, and purification efficiency is low.
Existing long-acting breathing mud like product mainly diatom ooze on the market, product quality disunity, testing conditions does not possess, and some businessman directly replaces diatom ooze with inner wall putty.Therefore can not reach good purification function, be unfavorable for the life health of people.
In prior art, the content of inorganic gel agent generally does and is mostly about 30%, therefore not strong with the adhesion stress of wall, if and increase the content of inorganic gel agent, then the functions such as other sterilizations can be caused to decline accordingly because other component ratios decline, long-acting breathing mud of the present invention, by increasing the content of inorganic gel agent, it is made to reach 45-50%, drastically increase the bonding of breathing mud and wall, simultaneously, by coordinating other composition, such as kieselguhr, packing material, functional additive, water-loss reducer, the composition of construction conditioning agent and quality proportion thereof, whole room is made to use long-acting breathing mud to have elimination formaldehyde, purify air, regulate humidity, releasing negative oxygen ion, fire protection flame retarding, metope is self-cleaning, the functions such as deodorization and sterilization.In addition because the increase of proportion of inorganic gel agent, other composition proportions are declined accordingly, also thus save holistic cost.
As preferably, described inorganic gel agent comprises at least one in gypsum, grey calcium, lime, white cement.
Be further used as preferably, described inorganic gel agent comprises gypsum, grey calcium, lime, white cement, and the mass ratio of described gypsum, grey calcium, lime, white cement is 1:(1-1.5): (2-2.45): (0.8-1.1).Found through experiments, in above-mentioned mass ratio situation, the adhesion stress of long-acting breathing mud and wall reaches best.
As preferably, diatomaceous particle diameter is between 10 ~ 325 orders.Described kieselguhr reaches different texture by the size grading of self, effectively raise kieselguhr content in the product, also just improve the absorptive capacity of the pernicious gases such as PARA FORMALDEHYDE PRILLS(91,95), improve indoor living environment greatly, and effectively can reduce the consumption of other packing materials, properties of product are improved.
Further preferably, diatomaceous particle diameter is between 120 ~ 205 orders.By preferred setting, can make, while the long-acting breathing mud performance of guarantee, to make the consumption of packing material reach less simultaneously, thus greatly saved material and cost.
As preferably, described packing material comprises at least one in quartz sand, iron oxide pigment, composite pigment, coarse whiting.Quartz sand can improve the intensity of product, has certain scratching function; Pigment can give long-acting breathing mud different color sensations, is suitable for the needs of multiple crowd, for indoor provide aesthetic feeling.
As preferably, packing material comprises quartz sand, iron oxide pigment, composite pigment, four kinds, coarse whiting stone, and mass ratio is wherein (10-15): (2-2.5): (1-1.45): (8-12).By above-mentioned ratio setting, can make long-acting breathing mud on the basis of the requirement of satisfied building, have ornamental very well, be the house decorative material of new generation of alternative wallpaper and emulsion paint.
As preferably, described functional additive is at least one in nano titanium oxide, nano-negative ion, ethylene urea methanal trapping agent.This product fills on diatomaceous absorption basis in biography and with the addition of functional additive, effectively can improve the absorption of the hazardous substancess such as long-acting breathing mud PARA FORMALDEHYDE PRILLS(91,95), capacity of decomposition, improve the permanence of product.By adding functional additive, the pernicious gases such as the formaldehyde in air, toluene, VOC can be decomposed, the effect purified air can be played.
As preferably, the mass ratio of nano titanium oxide, nano-negative ion, ethylene urea methanal trapping agent is (2-2.4): (2-2.45): (0.8-1.2).The present invention, by strengthening the ratio of nano titanium oxide, nano-negative ion, relative to prior art, increases the bactericidal action of sterilization ion, on the basis absorbed other hazardous substancess, makes the absorption drastically increasing PARA FORMALDEHYDE PRILLS(91,95), toluene.
As preferably, described water-loss reducer is at least one in hydroxypropyl methylcellulose, carboxymethyl cellulose, starch ether.The water conservation system adopting this composite, can improve the application property of product greatly, reduce the cost of product.Also save and economized raw-material consumption less, serve energy-conservation effect from energy consumption aspect.Added by water-loss reducer, the crackle avoided breathing mud and cause because of dry.
As preferably, the mass ratio of hydroxypropyl methylcellulose, carboxymethyl cellulose, starch ether is (0.3-0.4): (0.5-0.7): 1.By optimal design-aside, can make to breathe mud and newly can reach optimum.
As preferably, described construction conditioning agent is at least one in high efficiency water reducing agent, cement brighter, dry powder defoamer.Construction conditioning agent, while improving workability, turn improves the performance after products solidifying, improves the brightness of product, do not make this series products be confined to sub-body of light system.
After above-mentioned raw material accurate measurement, drop in agravic dry powder mortar mixing machine, pack through mechanical mixture discharging in 3 ~ 5 minutes.As long as after the water adding 0.6 ~ 0.8 of mass ratio in use stirs, by formative technology construction molding.
The film that long-acting breathing mud of the present invention is formed after using, can improve the quality of life of indoor living environment.Eliminate formaldehyde, purify air, regulate that humidity, releasing negative oxygen ion, fire protection flame retarding, metope are self-cleaning, deodorization and sterilization, be conducive to the physical and mental health of people.
Further illustrate below by specific embodiment.
Summary of the invention
The object of this invention is to provide a kind of vacuum thermal insulation plate, a kind of house decorative material of tool high-efficient purification function is provided simultaneously, except can purifying formaldehyde and other pernicious gases, can also humidity in conditioning chamber, improve the suitable Shu Du lived.Bacterium in decontamination chamber and peculiar smell.
Technical scheme of the present invention is:
The composite evacuated heat insulating board of a kind of long-acting breathing mud, is characterized in that: comprise vacuum heat-insulating plate and the long-acting breathing mud being coated on its periphery.
As preferably, composition and the quality proportioning thereof of long-acting breathing mud are: inorganic gel agent 45% ~ 50%, kieselguhr 30% ~ 40%, packing material 5% ~ 25%, functional additive 0.5% ~ 2%, water-loss reducer 0.5% ~ 2%, construction conditioning agent 0.5% ~ 2.0%.
As preferably, described inorganic gel agent comprises at least one in gypsum, grey calcium, lime, white cement.
As preferably, diatomaceous particle diameter is between 10 ~ 325 orders.
As preferably, described packing material comprises at least one in quartz sand, iron oxide pigment, composite pigment, coarse whiting, French chalk, kaolin.
As preferably, described functional additive is at least one in nano titanium oxide, nano-negative ion, ethylene urea methanal trapping agent.
As preferably, described water-loss reducer is at least one in hydroxypropyl methylcellulose, carboxymethyl cellulose, starch ether.
As preferably, described construction conditioning agent is at least one in high efficiency water reducing agent, cement brighter, dry powder defoamer.
The using method of long-acting breathing mud, after the water adding 0.6 ~ 0.8 of mass ratio in use stirs, by formative technology construction molding.
The invention has the beneficial effects as follows:
1) solve the problem of vacuum heat-insulating plate breakage gas leakage in work progress, construction install convenience, it has excellent heat insulating ability, water resistance, durability and frost resistance, and burning grade is not for firing or difficult combustion, and fireproof performance is excellent.
2) vacuum thermal insulation plate has and eliminates formaldehyde, purifies air, regulates that humidity, releasing negative oxygen ion, fire protection flame retarding, metope are self-cleaning, deodorization and sterilization, is conducive to the physical and mental health of people.
3) provide a kind of ornament materials-long-acting breathing mud with clean room's environment, this kind of long-acting breathing mud has better adhesion stress, and has higher compressive strength.
4) by the absorption of inorganic gel agent, kieselguhr, functional additive, decompose and remove indoor hazardous substances, reach the function purified air, then be equipped with titanium dioxide isoreactivity material breakdown formaldehyde, prevent bacteria breed.Improve indoor living environment, improve quality of the life, the health environment of Creating Green ecology.And this product can by different formula of executing gimmicks, decorate indoor is fitted up, is strengthened artistic gas part.
Detailed description of the invention
Describe the present invention below in conjunction with implementation process, the description of this part is only exemplary, does not do any restriction to protection scope of the present invention.
The composite evacuated heat insulating board of a kind of long-acting breathing mud, comprises vacuum heat-insulating plate and the long-acting breathing mud being coated on its periphery.
By technique scheme, solve the problem of vacuum heat-insulating plate breakage gas leakage in work progress, construction install convenience, it has excellent heat insulating ability, water resistance, durability and frost resistance, and burning grade is not for firing or difficult combustion, and fireproof performance is excellent.And vacuum thermal insulation plate has and eliminates formaldehyde, purifies air, regulates that humidity, releasing negative oxygen ion, fire protection flame retarding, metope are self-cleaning, deodorization and sterilization, be conducive to the physical and mental health of people.
A long-acting breathing mud for indoor decoration, its composition and quality proportioning thereof are: inorganic gel agent 45% ~ 50%, kieselguhr 30% ~ 40%, packing material 5% ~ 25%, functional additive 0.5% ~ 2%, water-loss reducer 0.5% ~ 2%, construction conditioning agent 0.5% ~ 2.0%.
Further preferably, inorganic gel agent 46% ~ 48%, kieselguhr 32% ~ 37%, packing material 10% ~ 15%, functional additive 0.8% ~ 1.6%, water-loss reducer 0.6% ~ 1.8%, construction conditioning agent 0.7% ~ 1.8%.
Further preferably, inorganic gel agent 47%, kieselguhr 33% ~ 35%, packing material 12% ~ 13%, functional additive 1% ~ 1.5%, water-loss reducer 1% ~ 1.5%, construction conditioning agent 1% ~ 1.5%.
As preferably, inorganic gel agent is 48.5%-50%, more preferably 48.5%-49.3%.
Further preferably, described packing material is 13%.
Further preferably, kieselguhr 35%-40%.
Further preferably, packing material 10%-20%, more preferably 10%-16.5%.
Further preferably, functional additive 1%-2%.
Further preferably, construction conditioning agent 1%-2.0%.
Further preferably, functional additive 1% ~ 2%.
Certainly, coated outside vacuum thermal insulation plate long-acting breathing mud is exactly long-acting breathing mud noted earlier.
Inorganic gel agent makes long-acting breathing mud firmly be attached to surface of wall.Meanwhile, these inorganic coagulation materials or meet water cure or meet water, curing, have certain regulatory function to the water capacity of room air, can also the growing of anti-bacteria.
Embodiment 1
A kind of architecture indoor decorating and renovating material, comprise the composition that quality proportioning is following respectively: inorganic gel agent is gypsum: 48.5%, kieselguhr: 30%, water-loss reducer hydroxypropyl methylcellulose: 0.5%, construction conditioning agent calcium sulphate retarder: 0.2%, construction conditioning agent redispersable latex powder: 0.3%, functional additive nano-negative ion: 0.5%, filler is particle diameter is 325 object coarse whitings: 20%
After above-mentioned raw material accurate measurement, drop in agravic dry powder mortar mixing machine, pack through mechanical mixture discharging in 3 ~ 5 minutes.As long as after the water adding 0.6 of mass ratio in use stirs, by formative technology construction molding.
Under this conditions of mixture ratios, the long-acting breathing mash layer PARA FORMALDEHYDE PRILLS(91,95) purifying property smearing 1mm thick is greater than 76.1%, clean-up effect persistence 65%, 37% is greater than to toluene purifying property, clean-up effect persistence 23%, radioactivity (category-A finishing material) External Exposure Index does not detect, and Outreach services is 0.1, Anti-mildew capability 2 grades, hygroscopic capacity 3h is 2.0 × 10 -2wa (1 × 10 -3kg/m 2), compressive strength is 9.2MPa.Effectively improve indoor living environment.
The improvement of embodiment 1, inorganic gel agent is 48.5%, and the mass ratio of wherein said gypsum, grey calcium, lime, white cement is 1:(1-1.5): (2-2.45): (0.8-1.1).
Under this conditions of mixture ratios, the long-acting breathing mash layer PARA FORMALDEHYDE PRILLS(91,95) purifying property smearing 1mm thick is greater than 80.1%, clean-up effect persistence 74%, 45% is greater than to toluene purifying property, clean-up effect persistence 30%, radioactivity (category-A finishing material) External Exposure Index does not detect, and Outreach services is 0.1, Anti-mildew capability 2 grades, hygroscopic capacity 3h is 2.2 × 10 -2wa (1 × 10 -3kg/m 2), compressive strength is 9.3MPa.Effectively improve indoor living environment.
Embodiment 2
A kind of architecture indoor decorating and renovating material, comprise the composition that quality proportioning is following respectively: inorganic gel agent gypsum: 45%, kieselguhr: 35%, water-loss reducer hydroxypropyl methylcellulose: 0.5%, water-loss reducer lignocellulosic: 0.5%, construction conditioning agent gypsum accelerating admixture: 0.2%, construction conditioning agent rubber powder: 1.8%, packing material coarse whiting 325 order: 11.5%, packing material quartz sand: 5%.Functional additive nano titanium oxide: 0.5%
After above-mentioned raw material accurate measurement, drop in agravic dry powder mortar mixing machine, pack through mechanical mixture discharging in 3 ~ 5 minutes.As long as after the water adding 0.6 of mass ratio in use stirs, by formative technology construction molding.
Under this conditions of mixture ratios, the long-acting breathing mash layer PARA FORMALDEHYDE PRILLS(91,95) purifying property smearing 1mm thick is greater than 76.1%, clean-up effect persistence 65%, 39% is greater than to toluene purifying property, clean-up effect persistence 24%, radioactivity (category-A finishing material) External Exposure Index does not detect, and Outreach services is 0.2, Anti-mildew capability 2 grades, hygroscopic capacity 3h is 1.5 × 10 -2wa (1 × 10 -3kg/m 2), compressive strength is 7.2MPa.Effectively improve indoor living environment.
As improvement, packing material is 20%, wherein quartz sand, iron oxide pigment, composite pigment, four kinds, coarse whiting stone, and mass ratio is wherein (10-15): (2-2.5): (1-1.45): (8-12).Through test, meeting under other conditions, compressive strength is 8.8MPa, and appearance color is fresh, has good decorate properties.
Embodiment 3
A kind of architecture indoor decorating and renovating material, comprise the composition that quality proportioning is following respectively: inorganic gel agent ash calcium: 50%, kieselguhr: 35.7%, water-loss reducer hydroxypropyl methylcellulose: 0.5%, water-loss reducer lignocellulosic: 0.5%, water-loss reducer starch ether: 0.3%, construction conditioning agent rubber powder: 2%, packing material quartz sand: 10%, functional additive ethylene urea: 1%.
After above-mentioned raw material accurate measurement, drop in agravic dry powder mortar mixing machine, pack through mechanical mixture discharging in 3 ~ 5 minutes.As long as after the water adding 0.75 of mass ratio in use stirs, by formative technology construction molding.
Under this conditions of mixture ratios, the long-acting breathing mash layer PARA FORMALDEHYDE PRILLS(91,95) purifying property smearing 1mm thick is greater than 83%, clean-up effect persistence 75%, and be greater than 40% to toluene purifying property, clean-up effect persistence 29.3%, Anti-mildew capability 1 grade, hygroscopic capacity 3h is 2.3 × 10 -2wa (1 × 10 -3kg/m 2), compressive strength is 9.1MPa.Effectively improve indoor living environment.
The further improvement of embodiment 3, water-loss reducer 0.3%, wherein the mass ratio of hydroxypropyl methylcellulose, carboxymethyl cellulose, starch ether is (0.3-0.4): (0.5-0.7): 1.By the setting of water-loss reducer, under making properties of product reach quality requirement situation, the cost of about 3-5% can also be reduced.
Embodiment 4
A kind of architecture indoor decorating and renovating material, comprise the composition that quality proportioning is following respectively: inorganic gel agent ash calcium: 49.3%, kieselguhr: 40%, water-loss reducer hydroxypropyl methylcellulose: 0.8%, water-loss reducer lignocellulosic: 0.5%, water-loss reducer starch ether: 0.4%, construction conditioning agent rubber powder: 2%, packing material quartz sand: 5%, functional additive nano titanium oxide: 0.5%, functional additive nano-negative ion: 1%, functional additive ethylene urea methanal trapping agent: 0.5%.
After above-mentioned raw material accurate measurement, drop in agravic dry powder mortar mixing machine, pack through mechanical mixture discharging in 3 ~ 5 minutes.As long as after the water adding 0.70 of mass ratio in use stirs, by formative technology construction molding.
Under this conditions of mixture ratios, the long-acting breathing mash layer PARA FORMALDEHYDE PRILLS(91,95) purifying property smearing 1mm thick is greater than 88%, clean-up effect persistence 80%, and be greater than 45% to toluene purifying property, clean-up effect persistence 36%, Anti-mildew capability 1 grade, hygroscopic capacity 3h is 2.1 × 10 -2wa (1 × 10 -3kg/m 2), compressive strength is 8.8MPa.Effectively improve indoor living environment.
As the improvement of above-described embodiment, functional additive 2.0%, wherein the mass ratio of nano titanium oxide, nano-negative ion, ethylene urea methanal trapping agent is (2-2.4): (2-2.45): (0.8-1.2).By above-mentioned setting, the long-acting breathing mash layer PARA FORMALDEHYDE PRILLS(91,95) purifying property smearing 1mm thick is greater than 94%, clean-up effect persistence 86%, is greater than 55%, clean-up effect persistence 47%, Anti-mildew capability 1 grade to toluene purifying property.
Above-mentioned four embodiments, the technique effect smearing the thick long-acting breathing mash layer of 1mm is as follows:
Be further used as preferably, inorganic gel agent 46% ~ 48%, kieselguhr 32% ~ 37%, packing material 10% ~ 15%, functional additive 0.8% ~ 1.6%, water-loss reducer 0.6% ~ 1.8%, construction conditioning agent 0.7% ~ 1.8%.By selecting above-mentioned number ratios, can make to breathe mud whole synthesis performance and improving about 5%-7%.So-called whole synthesis performance is exactly when each parameter of guarantee meets requirement of engineering, the ratio of the reference data of above-mentioned efficacy parameter relatively corresponding to each parameter, then all ratios are added obtain and.
Further preferably, inorganic gel agent 47%, kieselguhr 33% ~ 35%, packing material 12% ~ 13%, functional additive 1% ~ 1.5%, water-loss reducer 1% ~ 1.5%, construction conditioning agent 1% ~ 1.5%.By selecting above-mentioned number ratios, can make to breathe mud whole synthesis performance and improving about 7%.
In above-mentioned four embodiments, described inorganic gel agent comprises gypsum, grey calcium, lime, white cement, and the mass ratio of described gypsum, grey calcium, lime, white cement is 1:(1-1.5): (2-2.45): (0.8-1.1).Under this kind is preferably arranged, adhesive property can improve about 10%.
In above-mentioned four embodiments, functional additive selects the mass ratio of nano titanium oxide, nano-negative ion, ethylene urea methanal trapping agent to be (2-2.4): (2-2.45): (0.8-1.2).Improve the absorption more than 8% of PARA FORMALDEHYDE PRILLS(91,95), toluene.
In above-mentioned four embodiments, water-loss reducer chooses hydroxypropyl methylcellulose, carboxymethyl cellulose, starch ether, and its mass ratio is (0.3-0.4): (0.5-0.7): 1, by preferably, can improve water retention about 11%.
In above-mentioned four embodiments, packing material comprises quartz sand, iron oxide pigment, composite pigment, four kinds, coarse whiting stone, and mass ratio is wherein (10-15): (2-2.5): (1-1.45): (8-12).By above-mentioned ratio setting, long-acting breathing mud can be made to improve voltage endurance capability, can about 13% be improved.
Although the present invention discloses as above with preferred embodiment, the present invention is not defined in this.Any those skilled in the art, without departing from the spirit and scope of the present invention, all can make various changes or modifications, and therefore protection scope of the present invention should be as the criterion with claim limited range.

Claims (10)

1. the composite evacuated heat insulating board of long-acting breathing mud, is characterized in that: comprise vacuum heat-insulating plate and the long-acting breathing mud being coated on its periphery.
2. vacuum heat-insulating plate as claimed in claim 1, described long-acting breathing mud is long-acting breathing mud according to claim 3.
3. a long-acting breathing mud, its composition and quality proportioning thereof are: inorganic gel agent 45% ~ 50%, kieselguhr 30% ~ 40%, packing material 5% ~ 25%, functional additive 0.5% ~ 2.0%, water-loss reducer 0.5% ~ 2%, construction conditioning agent 0.5% ~ 2.0%.
4. long-acting breathing mud according to claim 3, is characterized in that, described inorganic gel agent comprises at least one in gypsum, grey calcium, lime, white cement.
5. long-acting breathing mud according to claim 3, it is characterized in that, diatomaceous particle diameter is between 10 ~ 325 orders.
6. long-acting breathing mud according to claim 3, is characterized in that, described packing material comprises at least one in quartz sand, iron oxide pigment, composite pigment, coarse whiting, French chalk, kaolin.
7. long-acting breathing mud according to claim 3, is characterized in that, described functional additive is at least one in nano titanium oxide, nano-negative ion, ethylene urea methanal trapping agent.
8. long-acting breathing mud according to claim 3, is characterized in that, described water-loss reducer is at least one in hydroxypropyl methylcellulose, carboxymethyl cellulose, starch ether.
9. long-acting breathing mud according to claim 3, is characterized in that, described construction conditioning agent is at least one in high efficiency water reducing agent, cement brighter, dry powder defoamer.
10. according to the using method of the long-acting breathing mud one of claim 3-9 Suo Shu, it is characterized in that, after the water adding 0.6 ~ 0.8 of mass ratio in use stirs, by formative technology construction molding.
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CN105255221A (en) * 2015-09-28 2016-01-20 广东嘉宝莉科技材料有限公司 Algae mud decorative wall material coating and preparation method and application thereof
CN105255221B (en) * 2015-09-28 2017-12-19 广东嘉宝莉科技材料有限公司 Algae clay decoration wall material coating and its preparation method and application
CN106082909A (en) * 2016-06-08 2016-11-09 刘高志 A kind of except formaldehyde environment friendly decorative material and preparation method thereof
CN107963861A (en) * 2017-11-27 2018-04-27 中华制漆(深圳)有限公司 Novel and multifunctional inorganic coating and its preparation method and application
CN107963861B (en) * 2017-11-27 2020-09-11 中华制漆(深圳)有限公司 Multifunctional inorganic coating and preparation method and application thereof
CN109503076A (en) * 2018-12-17 2019-03-22 北京未来空间美居科技有限公司 A kind of preparation method of ornament materials and its dalle with releasing negative oxygen ion environmental protection health-preserving function
CN112279608A (en) * 2020-09-28 2021-01-29 河南方众环保科技有限公司 Dry powder composition for preparing water-absorbing decorative material

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