CN105246985B - 交联聚(乙烯醇)和二氧化硅纳米颗粒多层涂层以及方法 - Google Patents
交联聚(乙烯醇)和二氧化硅纳米颗粒多层涂层以及方法 Download PDFInfo
- Publication number
- CN105246985B CN105246985B CN201480030468.3A CN201480030468A CN105246985B CN 105246985 B CN105246985 B CN 105246985B CN 201480030468 A CN201480030468 A CN 201480030468A CN 105246985 B CN105246985 B CN 105246985B
- Authority
- CN
- China
- Prior art keywords
- layer
- pva
- silica
- substrate
- silica nanoparticles
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/046—Forming abrasion-resistant coatings; Forming surface-hardening coatings
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
- C03C17/42—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions at least one coating of an organic material and at least one non-metal coating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
- C08J7/0423—Coating with two or more layers, where at least one layer of a composition contains a polymer binder with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/043—Improving the adhesiveness of the coatings per se, e.g. forming primers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/054—Forming anti-misting or drip-proofing coatings
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D129/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Coating compositions based on hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Coating compositions based on derivatives of such polymers
- C09D129/02—Homopolymers or copolymers of unsaturated alcohols
- C09D129/04—Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1606—Antifouling paints; Underwater paints characterised by the anti-fouling agent
- C09D5/1612—Non-macromolecular compounds
- C09D5/1618—Non-macromolecular compounds inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1693—Antifouling paints; Underwater paints as part of a multilayer system
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2201/00—Polymeric substrate or laminate
- B05D2201/02—Polymeric substrate
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2507/00—Polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D2518/00—Other type of polymers
- B05D2518/10—Silicon-containing polymers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/46—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase
- C03C2217/47—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the dispersed phase consisting of a specific material
- C03C2217/475—Inorganic materials
- C03C2217/478—Silica
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
- Laminated Bodies (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361828836P | 2013-05-30 | 2013-05-30 | |
| US61/828,836 | 2013-05-30 | ||
| PCT/US2014/035450 WO2014193573A1 (en) | 2013-05-30 | 2014-04-25 | Crosslinked poly(vinyl alcohol) and silica nanoparticle multilayer coatings and methods |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105246985A CN105246985A (zh) | 2016-01-13 |
| CN105246985B true CN105246985B (zh) | 2017-11-03 |
Family
ID=50842354
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480030468.3A Expired - Fee Related CN105246985B (zh) | 2013-05-30 | 2014-04-25 | 交联聚(乙烯醇)和二氧化硅纳米颗粒多层涂层以及方法 |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US9925560B2 (enExample) |
| EP (1) | EP3004258A1 (enExample) |
| JP (1) | JP2016525963A (enExample) |
| CN (1) | CN105246985B (enExample) |
| WO (1) | WO2014193573A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014193571A1 (en) | 2013-05-30 | 2014-12-04 | 3M Innovative Properties Company | Poly(vinyl alcohol)-containing and silica nanoparticle multilayer coatings and methods |
| CN105246984A (zh) | 2013-05-30 | 2016-01-13 | 3M创新有限公司 | 聚(乙烯醇)和二氧化硅纳米粒子多层涂层及方法 |
| JP6677649B2 (ja) * | 2014-04-11 | 2020-04-08 | スリーエム イノベイティブ プロパティズ カンパニー | 酸焼結相互接続シリカナノ粒子の3次元多孔質ネットワークを有するミクロ多孔質物品及びその製造方法 |
| KR102443092B1 (ko) | 2015-09-01 | 2022-09-14 | 삼성전자주식회사 | 공기조화장치에 사용되는 부품 및 이를 구비한 공기조화장치 |
| EP3323864A1 (en) * | 2016-11-22 | 2018-05-23 | BASF Coatings GmbH | Optical coating having a low refractive index |
| CN111433242B (zh) * | 2017-12-11 | 2023-07-25 | 住友电气工业株式会社 | 树脂组合物及光纤 |
| KR102316018B1 (ko) * | 2018-11-23 | 2021-10-22 | 주식회사 엘지화학 | 광학 적층체 |
| WO2020255569A1 (ja) * | 2019-06-18 | 2020-12-24 | 住友電気工業株式会社 | 光ファイバ |
| EP3988515B1 (en) * | 2019-06-19 | 2025-01-01 | Sumitomo Electric Industries, Ltd. | Optical fiber |
| WO2021019648A1 (ja) * | 2019-07-29 | 2021-02-04 | 凸版印刷株式会社 | ガスバリア積層体及びこれを用いた包装材 |
| KR102862216B1 (ko) * | 2020-03-19 | 2025-09-19 | 삼성디스플레이 주식회사 | 커버 윈도우 및 이를 포함하는 표시 장치 |
| DE102020213101A1 (de) * | 2020-10-16 | 2022-04-21 | Mitsubishi Polyester Film Gmbh | Ein- oder mehrschichtige Polyesterfolie mit einer permanenten Antifog-Beschichtung und einer Transparenz von mindestens 92% |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0437902A1 (en) * | 1988-07-07 | 1991-07-24 | Toray Industries, Inc. | Anti-fogging film |
| EP0770658A2 (en) * | 1995-10-27 | 1997-05-02 | Sumitomo Chemical Company, Limited | Antifog film |
| CN101579672A (zh) * | 2008-05-16 | 2009-11-18 | 3M创新有限公司 | 用于提高亲水性/透射率的二氧化硅涂层 |
| WO2011137005A1 (en) * | 2010-04-28 | 2011-11-03 | 3M Innovative Properties Company | Articles including nanosilica-based primers for polymer coatings and methods |
| WO2012173803A1 (en) * | 2011-06-15 | 2012-12-20 | 3M Innovative Properties Company | Hydrophobic hydrocarbon coatings |
Family Cites Families (31)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA557259A (en) | 1955-02-23 | 1958-05-13 | Canadian Kodak Co. Limited | Multiple layer hopper for multiply coating a web |
| US3692725A (en) | 1970-10-28 | 1972-09-19 | Kimberly Clark Co | Stabilized binder for water-flushable non-woven webs |
| US4127682A (en) * | 1975-05-19 | 1978-11-28 | American Optical Corporation | Abrasion and antifog-resistant optical element |
| US4478909A (en) * | 1980-10-24 | 1984-10-23 | Toray Industries, Inc. | Anti-fogging coating film |
| US4567221A (en) | 1983-03-31 | 1986-01-28 | Kuraray Co., Ltd. | Water resistant compositions |
| JPH0688455B2 (ja) | 1985-09-02 | 1994-11-09 | 富士写真フイルム株式会社 | 感熱記録材料 |
| US4859717A (en) | 1987-09-04 | 1989-08-22 | Mobil Oil Corporation | Cross-linked polyvinyl alcohols and oil reservoir permeability control therewith |
| US5221497A (en) | 1988-03-16 | 1993-06-22 | Nissan Chemical Industries, Ltd. | Elongated-shaped silica sol and method for preparing the same |
| US5134021A (en) | 1990-01-04 | 1992-07-28 | Toray Industries, Inc. | Anti-fogging film |
| DE4007668A1 (de) | 1990-03-10 | 1991-09-12 | Beiersdorf Ag | Hydrogelschaeume und verfahren zu deren herstellung |
| US5262475A (en) * | 1992-05-12 | 1993-11-16 | Film Specialties, Inc. | Hydrophilic compositions which are fog-resistant |
| US5412016A (en) | 1992-09-28 | 1995-05-02 | E. I. Du Pont De Nemours And Company | Process for making polymeric inorganic-organic compositions |
| US5677050A (en) | 1995-05-19 | 1997-10-14 | Minnesota Mining And Manufacturing Company | Retroreflective sheeting having an abrasion resistant ceramer coating |
| US6040053A (en) | 1996-07-19 | 2000-03-21 | Minnesota Mining And Manufacturing Company | Coating composition having anti-reflective and anti-fogging properties |
| US5861195A (en) | 1997-01-21 | 1999-01-19 | Minnesota Mining And Manufacturing Company | Method for coating a plurality of fluid layers onto a substrate |
| KR100580351B1 (ko) | 1997-04-17 | 2006-05-16 | 가부시끼가이샤 구레하 | 방습 필름 및 전기 발광 소자 |
| EP1293488A1 (en) | 2001-09-12 | 2003-03-19 | Toyo Gosei Kogyo Co., Ltd. | Coating solution and method for forming transparent coating film |
| GB2431659A (en) | 2005-10-28 | 2007-05-02 | Sun Chemical Ltd | Gas barrier coating having high thermal resistance |
| GB2431660A (en) | 2005-10-28 | 2007-05-02 | Sun Chemical Ltd | Thermally resistant gas barrier lamella |
| DE102005054913A1 (de) | 2005-11-17 | 2007-05-24 | Wacker Polymer Systems Gmbh & Co. Kg | Silan-modifizierte Polyvinylalkohole |
| US20130224478A1 (en) | 2008-08-07 | 2013-08-29 | 3M Innovative Properties Company | Acicular silica coating for enhanced hydrophilicity/transmittivity |
| US20100035039A1 (en) * | 2008-08-07 | 2010-02-11 | 3M Innovative Properties Company | Acicular silica coating for enhanced hydrophilicity/transmittivity |
| US8633263B2 (en) | 2009-03-31 | 2014-01-21 | 3M Innovative Properties Company | Coating composition and method of making and using the same |
| WO2010114698A1 (en) | 2009-03-31 | 2010-10-07 | 3M Innovative Properties Company | Aqueous coating composition comprising spherical silica particles and method of making and using the same |
| US9340683B2 (en) | 2009-12-17 | 2016-05-17 | 3M Innovative Properties Company | Sulfonate-functional coatings and methods |
| EP2563848B1 (en) | 2010-04-28 | 2020-08-26 | 3M Innovative Properties Company | Silicone-based material |
| US8709582B2 (en) | 2010-07-30 | 2014-04-29 | Essilor International | Optical article including an antireflecting coating having antifog properties and process for making same |
| KR20130139959A (ko) | 2010-10-06 | 2013-12-23 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 나노실리카계 코팅을 갖는 반사방지 물품 |
| CN103201331B (zh) | 2010-11-10 | 2014-12-17 | 3M创新有限公司 | 疏水性氟化涂层 |
| WO2014193571A1 (en) | 2013-05-30 | 2014-12-04 | 3M Innovative Properties Company | Poly(vinyl alcohol)-containing and silica nanoparticle multilayer coatings and methods |
| CN105246984A (zh) | 2013-05-30 | 2016-01-13 | 3M创新有限公司 | 聚(乙烯醇)和二氧化硅纳米粒子多层涂层及方法 |
-
2014
- 2014-04-25 WO PCT/US2014/035450 patent/WO2014193573A1/en not_active Ceased
- 2014-04-25 US US14/893,248 patent/US9925560B2/en not_active Expired - Fee Related
- 2014-04-25 EP EP14727309.8A patent/EP3004258A1/en not_active Withdrawn
- 2014-04-25 CN CN201480030468.3A patent/CN105246985B/zh not_active Expired - Fee Related
- 2014-04-25 JP JP2016516660A patent/JP2016525963A/ja not_active Withdrawn
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0437902A1 (en) * | 1988-07-07 | 1991-07-24 | Toray Industries, Inc. | Anti-fogging film |
| EP0770658A2 (en) * | 1995-10-27 | 1997-05-02 | Sumitomo Chemical Company, Limited | Antifog film |
| CN101579672A (zh) * | 2008-05-16 | 2009-11-18 | 3M创新有限公司 | 用于提高亲水性/透射率的二氧化硅涂层 |
| WO2009140482A1 (en) * | 2008-05-16 | 2009-11-19 | 3M Innovative Properties Company | Silica coating for enhanced hydrophilicity/transmittivity |
| WO2011137005A1 (en) * | 2010-04-28 | 2011-11-03 | 3M Innovative Properties Company | Articles including nanosilica-based primers for polymer coatings and methods |
| WO2012173803A1 (en) * | 2011-06-15 | 2012-12-20 | 3M Innovative Properties Company | Hydrophobic hydrocarbon coatings |
Also Published As
| Publication number | Publication date |
|---|---|
| EP3004258A1 (en) | 2016-04-13 |
| WO2014193573A1 (en) | 2014-12-04 |
| CN105246985A (zh) | 2016-01-13 |
| US9925560B2 (en) | 2018-03-27 |
| JP2016525963A (ja) | 2016-09-01 |
| US20160121365A1 (en) | 2016-05-05 |
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| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20171103 Termination date: 20180425 |
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| CF01 | Termination of patent right due to non-payment of annual fee |