CN105234555B - A kind of ultrasonic assistant transition liquid-phase connection method - Google Patents

A kind of ultrasonic assistant transition liquid-phase connection method Download PDF

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Publication number
CN105234555B
CN105234555B CN201510779986.1A CN201510779986A CN105234555B CN 105234555 B CN105234555 B CN 105234555B CN 201510779986 A CN201510779986 A CN 201510779986A CN 105234555 B CN105234555 B CN 105234555B
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welded
mother metal
ultrasonic
connection method
phase connection
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CN105234555A (en
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陈晓光
李大成
刘丽娟
彭炤宇
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Hebei Yutian Material Technology Co ltd
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Harbin Puruisi Material Technology Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/24Preliminary treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K20/00Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
    • B23K20/10Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating making use of vibrations, e.g. ultrasonic welding

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Pressure Welding/Diffusion-Bonding (AREA)

Abstract

A kind of ultrasonic assistant transition liquid-phase connection method, the present invention relates to a kind of ultrasonic assistant transition liquid-phase connection method.The problem of the present invention is to solve existing transition liquid-phase Joining Technology to need to complete in a vacuum or inert atmosphere, and time-consuming, method is:First, mother metal to be welded is subjected to mechanical grinding and cleaning, then assembles component to be welded;2nd, ultrasonic tool head is applied orthogonal on component to be welded, applies pressure, then heat, then apply ultrasonic activation, complete isothermal solidification;Three:If the isothermal solidification time is more than 10min, continue to heat up, then apply ultrasonic activation again, complete isothermal solidification;4th, cool to room temperature with the furnace, that is, complete.The present invention realizes abolishing for interface oxidation film by the sound plastic effect of ultrasonic wave in solids, shortens weld interval, weld seam filling rate is up to more than 95%.The present invention is applied to soldering field.

Description

A kind of ultrasonic assistant transition liquid-phase connection method
Technical field
The present invention relates to a kind of ultrasonic assistant transition liquid-phase connection method.
Background technology
With the development of science and technology, in particular with the fast development of Aero-Space, space technology, sophisticated manufacturing, So that interconnection technique is also evolving and perfect.Partial transient liquid technology is since being developed in strengthened dispersion alloy, fibre It is widely used in the connection of dimension enhancing composite, dissimilar metal and new material.Partial transient liquid is due to deflection Small, it is easy to remove surface film oxide during connection, it is connected better than diffusion;Linker chemistry composition, the tissue of partial transient liquid Structure can make it be better than soldering again with mother metal uniformity.The advantages of technological synthesis diffusion welding and soldering, can Excellent microstructure and properties of joint is obtained, causes a large amount of concerns of domestic and international numerous areas in recent years, and obtain more and more wider General application.
The principle of partial transient liquid adds intermediate layer between mother metal, is incubated at a temperature of less than mother metal fusing point, Using intermediate layer fuse itself or eutectic reaction occur with mother metal form a number of liquid phase on linkage interface, while by Accelerate diffusion in the effect of liquid phase, in liquid phase reduce fusing point element rapidly to matrix spread so that combination interface chemistry into Clearly demarcated aobvious to change, the liquid phase in balancing each other is reduced, and is caused to be incubated a period of time combination interface at a certain temperature and is realized that isothermal coagulates Gu.Homogenized by isothermal solidification, solid-phase component, finally obtain the joint consistent with mother metal chemical composition and even tissue and obtain Obtain and continuously engage covering weave.Duvail D S propose the concept and mechanism of partial transient liquid first within 1974.It is domestic It is called transition liquid-phase weldering or diffusion brazing.Partial transient liquid as a kind of new accurate interconnection technique, have deform it is small, The advantages that temperature is low, residual stress is small, strength of joint is high is connected, the material of melting welding, particularly high temperature are difficult to available for connection and is closed Gold, marmem, intermetallic compound and composite etc..
Up to this point, many scholars various transition liquid-phase connection methods at exploitation, such as active transient liquid phase connect Connect, PTLP bonding, nonmetal oxide intermediate layer partial transient liquid, non-interlayer partial transient liquid, temperature ladder Spend partial transient liquid, two-step heating partial transient liquid, non axial constant-pressure partial transient liquid etc., most of welding sides Method is needed in a vacuum or inert atmosphere to complete welding process.Soaking time required in other welding process generally compared with It is long, it is even longer to generally require dozens of minutes.
The content of the invention
The invention aims to solve the shearing strength of joint difference of existing liquid phase connecting method welding and weld seam filling A kind of the problem of the problem of rate is low connects with transition liquid-phase needs vacuum environment, the Connection Time is long, there is provided ultrasonic assistant transition Liquid phase connecting method.
A kind of ultrasonic assistant transition liquid-phase connection method of the present invention is as follows:First, by mother metal to be welded carry out mechanical grinding and Cleaning, then by " mother metal-intermediate materials to be welded-mother metal to be welded " order assemble, obtain component to be welded, wherein mother metal to be welded with Intermediate layer material has low melting eutecticses;2nd, ultrasonic tool head is applied orthogonal on component to be welded, apply pressure be 0.02~ 5kN, then heat, then apply ultrasonic activation 1s~10min, complete isothermal solidification;Three:If the isothermal solidification time is more than 10min, then continue to heat up, then apply ultrasonic activation 1s~10min again, complete isothermal solidification;4th, in step 2 or step After three complete isothermal solidification, cool to room temperature with the furnace, that is, complete.
Ultrasonic assistant transition liquid-phase connection method proposed by the invention, can be completed in atmospheric conditions, and being capable of pole Greatly shorten the time formed required for solid solution joint.With normal ultrasound waves assistant brazings (by ultrasonic wave in a liquid Cavitation effect is completed oxide-film and abolished) to compare, this method realizes interface oxygen by ultrasonic wave in sound plastic effect in solids Change abolishing for film, ultrasonic activation can promote substantial amounts of liquid to extrude, and be imitated in cavitation effect, acoustic streaming effect and sound plasticity Accelerate solid solution diffusion behavior under the comprehensive function answered, shorten weld interval, weld seam filling rate is up to more than 95%.
Brief description of the drawings
Fig. 1 is 1 connection procedure schematic diagram of experiment;
Fig. 2 is Mg-Zn-Mg microstructures prepared by 1 control group of experiment;
Fig. 3 is Mg-Zn-Mg microstructures prepared by 1 test group of experiment.
Embodiment
Embodiment one:A kind of ultrasonic assistant transition liquid-phase connection method of present embodiment is as follows:First, will be to be welded Mother metal carries out mechanical grinding and cleaning, then assembles, obtains to be welded by the order of " mother metal-intermediate materials to be welded-mother metal to be welded " Component, wherein mother metal to be welded has low melting eutecticses with intermediate layer material;2nd, ultrasonic tool head is applied orthogonal to component to be welded On, application pressure is 0.02~5kN, is then heated, then applies ultrasonic activation 1s~10min, completes isothermal solidification;Three:If The isothermal solidification time is more than 10min, then continues to heat up, and then applies ultrasonic activation 1s~10min again, completes isothermal solidification; 4th, after step 2 or step 3 complete isothermal solidification, cool to room temperature with the furnace, that is, complete.
The ultrasonic assistant transition liquid-phase connection method that present embodiment is proposed, can be completed in atmospheric conditions, and energy It is enough greatly to shorten the time formed required for solid solution joint.With normal ultrasound waves assistant brazing (by ultrasonic wave in liquid In cavitation effect complete oxide-film abolish) compare, this method realizes boundary by ultrasonic wave in sound plastic effect in solids Surface oxidation film is abolished, and ultrasonic activation can promote substantial amounts of liquid to extrude, and is moulded in cavitation effect, acoustic streaming effect and sound Property effect comprehensive function under accelerate solid solution diffusion behavior, shorten weld interval, weld seam filling rate is up to more than 95%.
Embodiment two:Present embodiment is unlike embodiment one:If mother metal to be welded is magnesium alloy Or magnesium-based composite material, then intermediate layer material is Zn, Cu, Al, Ag or yellow gold;Answered if mother metal to be welded is aluminium alloy or aluminium base Condensation material, then intermediate layer material is Zn, Cu, Mg, Ag or yellow gold;If mother metal to be welded is copper alloy or Cu-base composites, Then intermediate layer material is Zn, Al, Mg or Ag.It is other identical with embodiment one.
Embodiment three:Present embodiment is unlike embodiment one or two:In described in step 1 Between mother metal using evaporation or sputtering by the way of be preset in mother metal surface to be welded.It is other identical with embodiment one or two.
Embodiment four:Unlike one of present embodiment and embodiment one to three:Described in step 1 Intermediate materials be placed in using paillon foil between the mother metal to be welded of both sides.It is other identical with one of embodiment one to three.
Embodiment five:Described in step 2 unlike one of present embodiment and embodiment one to four The heating rate of heating is 5~10 DEG C/min.It is other identical with one of embodiment one to four.
Embodiment six:Unlike one of present embodiment and embodiment one to five:Described in step 2 Heating temperature higher than the low melting eutecticses of mother metal to be welded and intermediate layer material temperature, and less than the fusing point of intermediate layer material. It is other identical with one of embodiment one to five.
Embodiment seven:Unlike one of present embodiment and embodiment one to six:Step 2 or step Ultrasonic frequency is 16~45KHz in rapid three, and amplitude is 5~25 μm.It is other identical with one of embodiment one to six.
Embodiment eight:Unlike one of present embodiment and embodiment one to seven:Step 3 heats up Temperature be not higher than 0.9 times of mother metal fusing point.It is other identical with one of embodiment one to seven.
Beneficial effects of the present invention are verified by tests below:
Experiment 1:Test group ultrasonic assistant transition liquid-phase connection method is as follows:First, by magnesium alloy carry out mechanical grinding and Cleaning, then assembled by the order of " magnesium alloy-Zn paper tinsels-magnesium alloy ", wherein Zn paper tinsels are 0.05mm pure Zn paper tinsels, obtain to be welded group Part;2nd, ultrasonic tool head is applied orthogonal on component to be welded, application pressure is 0.03kN, is then added using resistance radiation Hot method, under conditions of firing rate is 5~10 DEG C/min, component to be welded is heated to 370 DEG C, then apply ultrasonic activation 2min, isothermal solidification is completed, room temperature is then cooled to the furnace, that is, completes.
Contrast test is:First, magnesium alloy is subjected to mechanical grinding and cleaning, then by " magnesium alloy-Zn paper tinsels-magnesium alloy " Order assembles, and wherein Zn paper tinsels are 0.05mm pure Zn paper tinsels, obtain component to be welded;2nd, ultrasonic tool head is applied orthogonal to treat Weld on component, application pressure is 0.03kN, is 5~10 DEG C/min's in firing rate then using resistance radiation heating methods Under the conditions of, component to be welded is heated to 370 DEG C, then apply ultrasonic activation 3s, isothermal solidification is completed, then cools to room with the furnace Temperature, that is, complete.
The magnesium alloy of this experiment is AZ31B, and this experiment connection procedure schematic diagram is as shown in Figure 1.
As shown in Fig. 2 as seen from Figure 2, original Zn layers disappear Mg-Zn-Mg microstructures prepared by control group, Chemical reaction occurs in joint and forms Mg-Zn compound tissues.
As shown in figure 3, as seen from Figure 3, original Zn layers disappear Mg-Zn-Mg microstructures prepared by test group, Mg-Zn compounds are not formed, but Zn elements are solid-solution in Mg matrixes completely, are formed and the close tissue of Mg substrates.By Fig. 2 and Fig. 3 contrast understand, in joint the presence of continuous compound certainly will influence joint performance, Fig. 2 center taps shear strength is 55MPa, And Fig. 3 center taps shear strength is 106MPa, reach the intensity of mother metal.Test group weld seam filling rate reaches 98%
Experiment 2, this experiment ultrasonic assistant transition liquid-phase connection method are as follows:First, by magnesium alloy carry out mechanical grinding and Cleaning, then assembled by the order of " aluminum matrix composite-Zn paper tinsels-aluminum matrix composite ", wherein Zn paper tinsels are 0.05mm pure Zn Paper tinsel, obtain component to be welded;2nd, ultrasonic tool head is applied orthogonal on component to be welded, application pressure is 0.05kN, is then adopted With resistance radiation heating methods, under conditions of firing rate is 5~10 DEG C/min, component to be welded is heated to 390 DEG C, then apply Add ultrasonic activation 10s, then heat to 480 DEG C, apply ultrasonic activation 20s, complete isothermal solidification, then cool to room with the furnace Temperature, that is, complete.
The aluminum matrix composite of this experiment is 55% volume fraction SiC particle-reinforced Al matrix composite, and weld seam is filled Rate reaches 96%.
From above-mentioned experiment, the present invention realizes interface oxidation film by ultrasonic wave in sound plastic effect in solids To abolish, ultrasonic activation can promote substantial amounts of liquid to extrude, and in the comprehensive of cavitation effect, acoustic streaming effect and sound plastic effect The lower acceleration solid solution diffusion behavior of cooperation, shortens weld interval, weld seam filling rate is up to more than 95%.

Claims (7)

1. a kind of ultrasonic assistant transition liquid-phase connection method, it is characterised in that this method is as follows:First, mother metal to be welded is subjected to machine Tool is polished and cleaning, is then assembled by the order of " mother metal-intermediate materials to be welded-mother metal to be welded ", component to be welded is obtained, wherein treating Weldering mother metal has low melting eutecticses with intermediate layer material;2nd, ultrasonic tool head is applied orthogonal on component to be welded, applies pressure For 0.02~5kN, then heat, then apply ultrasonic activation 1s~10min, complete isothermal solidification;Three:If the isothermal solidification time More than 10min, then continue to heat up, then apply ultrasonic activation 1s~10min again, complete isothermal solidification;4th, in step 2 or After step 3 completes isothermal solidification, cool to room temperature with the furnace, that is, complete;Ultrasonic frequency is 16 wherein in step 2 and step 3 ~45KHz, amplitude are 5~25 μm.
2. a kind of ultrasonic assistant transition liquid-phase connection method according to claim 1, it is characterised in that if mother metal to be welded For magnesium alloy or magnesium-based composite material, then intermediate layer material is Zn, Cu, Al, Ag or yellow gold;If mother metal to be welded is aluminium alloy Or aluminum matrix composite, then intermediate layer material is Zn, Cu, Mg, Ag or yellow gold;If mother metal to be welded is copper alloy or copper-based multiple Condensation material, then intermediate layer material is Zn, Al, Mg or Ag.
3. a kind of ultrasonic assistant transition liquid-phase connection method according to claim 1, it is characterised in that described in step 1 Intermediate materials using evaporation or sputtering by the way of be preset in mother metal surface to be welded.
4. a kind of ultrasonic assistant transition liquid-phase connection method according to claim 1, it is characterised in that described in step 1 Intermediate materials be placed in using paillon foil between the mother metal to be welded of both sides.
5. a kind of ultrasonic assistant transition liquid-phase connection method according to claim 1, it is characterised in that described in step 2 The heating rate of heating be 5~10 DEG C/min.
6. a kind of ultrasonic assistant transition liquid-phase connection method according to claim 1, it is characterised in that described in step 2 Heating temperature higher than the low melting eutecticses of mother metal to be welded and intermediate layer material temperature, and less than the fusing point of intermediate layer material.
7. a kind of ultrasonic assistant transition liquid-phase connection method according to claim 1, it is characterised in that step 3 heats up Temperature be not higher than 0.9 times of mother metal fusing point.
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CN106735672A (en) * 2016-12-06 2017-05-31 上海航天设备制造总厂 The room temperature supersonically preparation method of intermetallic compound joint
CN106735833A (en) * 2016-12-26 2017-05-31 天津理工大学 Sound based on eutectic reaction causes instant liquid-phase diffusion welding welding method
CN108927608A (en) * 2017-05-27 2018-12-04 天津理工大学 Sound based on monotectic reaction causes transient liquid phase welding method and its application
CN108637451A (en) * 2018-05-28 2018-10-12 东莞市新玛博创超声波科技有限公司 A kind of method of low temperature ultrasonic auxiliary magnesium alloy welding
CN109365983A (en) * 2018-12-14 2019-02-22 东莞市新玛博创超声波科技有限公司 A kind of ultrasonic wave added welding method of the magnesium alloy of 72Cu-28Zn alloy as intermediate reaction material layer
CN109365990B (en) * 2018-12-14 2020-10-27 东莞市新玛博创超声波科技有限公司 Ultrasonic-assisted aluminum alloy welding method for obtaining full solid solution joint in short time
CN109648185B (en) * 2019-01-08 2021-04-09 青岛理工大学 Ultrasonic-assisted transient liquid phase diffusion connection method for high-strength corrosion-resistant Mg/Al connection joint
CN111604579A (en) * 2019-02-25 2020-09-01 邢台职业技术学院 Method for welding functional material and application thereof
CN110026672B (en) * 2019-04-01 2021-11-26 天津大学 Ultrasonic cavitation welding method
CN112059397A (en) * 2019-06-10 2020-12-11 天津理工大学 Method for ultrasonic-assisted welding of high-temperature material under atmosphere protection
CN112872528A (en) * 2021-03-25 2021-06-01 吉林大学 Dissimilar metal ultrasonic-assisted eutectic reaction brazing method

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