CN105228579A - Cosmetic composition - Google Patents
Cosmetic composition Download PDFInfo
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- CN105228579A CN105228579A CN201480027111.XA CN201480027111A CN105228579A CN 105228579 A CN105228579 A CN 105228579A CN 201480027111 A CN201480027111 A CN 201480027111A CN 105228579 A CN105228579 A CN 105228579A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
- A61Q1/02—Preparations containing skin colorants, e.g. pigments
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/044—Suspensions
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Abstract
The present invention relates to a kind of cosmetic composition, it comprises: (a) powder phase; (b) aqueous phase, wherein the viscosity of said composition is 2,500mPas or lower, preferably 1,000mPas or lower and more preferably 800mPas or lower; This powder comprises at least one powder with the amount of gross weight more than 1 % by weight relative to said composition, and described powder is selected from perlite, aluminium chlorohydrate, porous silica, amorphous hollow silica, silylanizing Silicon stone and magnesium carbonate.Cosmetic composition of the present invention can be uniform hydrous powdery dispersion in use, and the salubrious sensation that can simultaneously realize when using and lasting dressing effect.
Description
Technical field
The present invention relates to the cosmetic composition comprising powder phase and aqueous phase, wherein this powder comprises mutually and can be uniformly distributed powder in the composition by such as shake said composition.
Background technology
Up to now, various types of cosmetic composition is for modifying skin, particularly facial.Such as, the foundation cream of W/O or O/W emulsion form has been used.The foundation cream of W/O emulsion form can provide good lasting effects, but can not provide salubrious sensation.On the other hand, the foundation cream of O/W emulsion form can provide salubrious sensation, but can not provide good lasting effects.Therefore, the cosmetic composition of emulsion form is difficult to not only set up good lasting effects but also produce salubrious sensation in use.
Conventionally, comprise the another kind of cosmetic composition of the hydrous powdery dispersion of powder and water, as being called as that of " Mizu-Oshiroi " in Japan, for modifying skin, particularly face.When not in use, such cosmetic composition is separated into the biphase of aqueous phase and powder phase.When deployed, this cosmetic composition can such as shake to be distributed to equably in aqueous phase mutually by this powder with hand.Because the hydrous powdery dispersion formed thus comprises the continuous aqueous phase comprising water, it in use provides salubrious sensation to skin.
But, this hydrous powdery dispersion does not usually comprise or only comprises a small amount of oil, and be therefore sometimes difficult to give skin lasting dressing effect, lasting color make-up effect particularly on face, especially for having the skin (Combination or oily skin) of sebum secretion of raising and the skin that is exposed under extreme temperature and/or damp condition by day, as when ASEAN.A kind of probability improving lasting effects adds oil in this hydrous powdery dispersion.But adding oil can give oil reservoir to this cosmetic composition.When not in use, this oil reservoir may weaken the aesthetic appearance of the cosmetic composition of the bilayer formation of aqueous phase and powder phase.In addition, if this cosmetic composition contains oil, it may in use be difficult to form uniform powder dispersion, even if by this cosmetic composition of thorough shake.Add surfactant this oil can be contributed to evenly spread in this hydrous powdery dispersion.But this will cause forming O/W emulsion, therefore, cannot realize providing lasting dressing effect to skin (particularly face).In addition, add surfactant and can cause unacceptable stimulation to skin.
Disclosure of the invention content
An object of the present invention is to provide a kind of substantially by the cosmetic composition of aqueous phase and powder phase composition, it can be hydrous powdery dispersion, and the salubrious sensation that can simultaneously realize in use procedure and lasting dressing effect, as matt effect and the oily effect of control, even if under the extreme condition of temperature and/or humidity, though this cosmetic composition not containing or only containing a small amount of oil or surfactant.
Here, " substantially " refers to compositions of the present invention and contains the aqueous phase and the powder phase that total over 98 % by weight, preferably greater than 99 % by weight, and more preferably contains aqueous phase and the powder phase of total 100 % by weight.
Above-mentioned purpose of the present invention can be realized by cosmetic composition, and described cosmetic composition comprises:
(a) powder phase; With
(b) aqueous phase,
Wherein
The viscosity of said composition is 2,500mPas or lower, preferably 1,000mPas or lower and more preferably 800mPas or lower, and
This powder comprises at least one powder with the amount of gross weight more than 1 % by weight relative to said composition, and described powder is selected from perlite, aluminium chlorohydrate, porous silica, amorphous hollow silica, silylanizing Silicon stone and magnesium carbonate.
In a preferred embodiment, this powder comprises perlite mutually.In a further preferred embodiment, this powder comprises perlite and silylanizing Silicon stone mutually.
Preferably, this powder have make the median particle of this powder be less than 30 microns, be preferably less than 25 microns, be more preferably less than 20 microns and be even more preferably less than the particle size distribution of 15 microns.
Further preferably, this powder has and makes 90% of this powder particle to be less than 55 microns, is preferably less than 50 microns and be more preferably less than the particle size distribution of 45 microns.
The amount of this powder can be relative to said composition gross weight 2 % by weight or higher, preferably 3 % by weight or higher, more preferably 5 % by weight or higher, even more preferably 10 % by weight or higher and most preferably 15 % by weight or higher.
Powder in cosmetic composition of the present invention can comprise at least one additional filler and/or pigment mutually.
Additional filler can be selected from Talcum, Kaolin, Muscovitum, solid silica, sericite, calcination of talc, calcining Muscovitum, calcining sericite, synthetic mica, Bismuth Oxychloride, barium sulfate, boron nitride, calcium carbonate, magnesium bicarbonate and hydroxyapatite.In a preferred embodiment, this additional filler is calcium carbonate.
This pigment can be selected from titanium dioxide, zirconium oxide, cerium oxide, zinc oxide, ferrum oxide (black, yellow or redness), chromium oxide, manganese violet, ultramarine, chromic oxide gel, barba hispanica and metal dust, is preferably selected from titanium oxide, ferrum oxide and composition thereof.
In cosmetic composition of the present invention, the amount of powder phase can be 3 to 40 % by weight, preferably 5 to 35 % by weight and more preferably 10 to 30 % by weight relative to said composition gross weight.
Aqueous phase in cosmetic composition of the present invention can comprise at least one hydrophilic organic solvent.
In cosmetic composition of the present invention, the amount of aqueous phase can be 30 to 97 % by weight, preferably 35 to 85 % by weight and more preferably 40 to 75 % by weight relative to said composition gross weight.
Cosmetic composition of the present invention can comprise at least one oil with the amount being less than 1 % by weight relative to said composition gross weight.In a preferred embodiment, said composition is not containing any oil.
Cosmetic composition of the present invention can comprise at least one surfactant or gellant with the amount being less than 1 % by weight relative to said composition gross weight.In a preferred embodiment, said composition is not containing any surfactant.
The invention still further relates to for color make-up, especially for skin delustring or the cosmetic method reducing skin glossy (as shinny), comprising:
Apply cosmetic composition of the present invention.
Said composition can face use before in a reservoir shake with this powder of Eddy diffusion.
Implement best mode of the present invention
After extensive studies it, inventor has been found that by providing the cosmetic composition being particularly useful for skin particularly facial likely to realize above-mentioned purpose, described cosmetic composition is substantially by aqueous phase and powder phase composition, it can be hydrous powdery dispersion in use, and can by powder mutually in introduce particular powder selected by least one and realize salubrious sensation when using and lasting dressing effect, even if under the extreme condition of temperature and/or humidity, though this cosmetic composition not containing or only containing a small amount of oil or surfactant.
Thus, the present invention relates to cosmetic composition, it comprises:
(a) powder phase; With
(b) aqueous phase,
Wherein
The viscosity of said composition is 2,500mPas or lower, preferably 1,000mPas or lower and more preferably 800mPas or lower,
This powder comprises at least one powder with the amount of gross weight more than 1 % by weight relative to said composition, and described powder is selected from perlite, aluminium chlorohydrate, porous silica, amorphous hollow silica, silylanizing Silicon stone and magnesium carbonate.
Cosmetic composition of the present invention can provide salubrious sensation (water due in this aqueous phase) and lasting dressing effect as matt effect simultaneously, though under the extreme condition of temperature and/or humidity (due to powder mutually in selected particular powder (one or more)).
Below, cosmetic composition of the present invention is explained in more detailed manner.
[cosmetic composition]
Cosmetic composition of the present invention comprises:
(a) powder phase; With
(b) aqueous phase.
When not in use, the powder phase in cosmetic composition of the present invention and aqueous phase form two different phases, and usually form two-layer, and wherein powder phase layer is deposited in below aqueous layer.
When deployed, cosmetic composition of the present invention such as can form hydrous powdery dispersion with hand shaking, and it is preferably powder and is containing the homogeneous dispersion in water continuous phase.
In a preferred embodiment, before being applied on skin by cosmetic composition of the present invention, hydrous powdery dispersion is formed with hand shaking.
Powder in cosmetic composition of the present invention comprises the powder that at least one is selected from perlite, aluminium chlorohydrate, porous silica, amorphous hollow silica, silylanizing Silicon stone and magnesium carbonate mutually.The combination of selected powder can be used.In a preferred embodiment, this cosmetic composition is at least containing perlite.
As porous silica or amorphous hollow silica, can mention:
-porous silica microsphere, especially AsahiGlass company equal 3.70 mls/g with Sunsphere H53 and Sunsphere H33(oil absorption) run after fame; Kobo company with MSS-500-3H run after fame sell those;
The amorphous silica microsphere of-polydimethylsiloxane coating, especially runs after fame with SASunsphere H33 those (oil absorption equals 2.43 mls/g) of selling,
-silylanizing silica powder, especially DowCorning company run after fame with DowCorningVM-2270AerogelFineParticles those (oil absorption equals 10.40 mls/g) of selling;
-amorphous hollow silica particle, especially Kobo company run after fame those (oil absorption equals 5.50 mls/g) of selling with SilicaShells, and
-with the surface-treated precipitated silica powders of mineral tallow, as the precipitated silica with Tissuemat E process, especially Evonik-Degussa company runs after fame with AcemattOR412 those (oil absorption equals 3.98 mls/g) of selling.
As magnesium carbonate, can mention:
-Buschle & Lepper company with TipoCarbomagel run after fame sell product (oil absorption equals 2.14 mls/g).
Preferably to be included in this powder mutually in powder be perlite.Perlite particle used in the present invention can comprise can with trade name Optimat2550OR, 2040OR and 1430OR those (oil absorption equals 2.4 mls/g) purchased from WORLDMINERALS company.
In a particular, this cosmetic composition is at least containing perlite and silylanizing silica powder.
The particle of the particular powder selected above can have the structure of porous or hollow, and therefore, it can absorb water or oily mater effectively as sebum.Therefore, the particular powder selected above can provide lasting dressing effect, particularly lasting color make-up effect as matt effect, to water resistant if perspiration and oily mater are as sebum.
Sensation when considering use etc., the particular powder preferably selected above has relatively little granularity.Therefore, preferably this powder have make the median particle of this powder be less than 30 microns, be preferably less than 25 microns, be more preferably less than 20 microns and be even more preferably less than the particle size distribution of 15 microns.Here, " median particle of this powder is for being less than 25 microns " refer to 50% of this powder particle there is the granularity being less than 25 microns.This granularity can be recorded by laser diffractometry, and this granularity is based on volume diameter.
Sensation when considering use etc., the particular powder further preferably selected above has the particle size distribution of relative narrowness.Therefore, preferably this powder has and makes 90% of this powder particle to be less than 55 microns, is preferably less than 50 microns and be more preferably less than the particle size distribution of 45 microns.
This powder mutually in the amount of particular powder selected above have no particular limits.The amount of this powder can be relative to said composition gross weight 2 % by weight or higher, preferably 3 % by weight or higher, more preferably 5 % by weight or higher, even more preferably 10 % by weight or higher and most preferably 15 % by weight or higher.When the amount of the particular powder selected above improves, likely provide better dressing effect, particularly more lasting color make-up effect is as more lasting matt effect.In addition, likely cosmetic composition of the present invention is applied to skin particularly on face after immediately rapid steaming flood, therefore, use the time needed for the cosmetic process of cosmetic composition of the present invention to shorten.But, the touch perception provided by the particular powder selected above is provided, the amount of the particular powder preferably selected above be relative to cosmetic composition gross weight of the present invention more than 1.0 % by weight to 25 % by weight, more preferably 2 % by weight to 20 % by weight and even more preferably 5 % by weight to 15 % by weight.
Except the particular powder selected above, the powder in cosmetic composition of the present invention can comprise at least one additional filler and/or at least one pigment mutually.
Term " filler " is interpreted as referring to colourless or white, inorganic or compound particle, and they are insoluble to liquid component possible in cosmetic composition of the present invention, regardless of temperature when manufacturing said composition.
This additional filler (one or more) can be inorganic or organic, and can have spherical or elliptical shape, regardless of crystal formation (such as lamellar, cube, six sides, tiltedly side etc.).Talcum, Kaolin, Muscovitum, solid silica, sericite, calcination of talc, calcining Muscovitum, calcining sericite, synthetic mica, Bismuth Oxychloride, barium sulfate, boron nitride, calcium carbonate, magnesium bicarbonate and hydroxyapatite can be mentioned without limitation, the powder formed with polyethylene that polyamide (Nylon) is formed, poly-Beta-alanine is formed, the powder that polyurethane is formed, the powder that tetrafluoro ethylene polymer (Teflon) is formed, lauroyl lysine, starch, polymeric hollow microsphere, as those of poly-(vinylidene chloride)/acrylonitrile, such as Expancel (NobelIndustrie), or those of acrylic copolymer, organic siliconresin microballon (such as from the Tospearls of Toshiba), particle is formed by polysiloxane elastomer, or derived from having 8 to 22 carbon atoms, as the metal soap of the organic carboxyl acid of 12 to 18 carbon atoms, such as zinc stearate, magnesium stearate, lithium stearate, Dodecanoic acid, zinc salt or magnesium myristate.
As polyamide powder, can mention UBEIndustries company with Pomp610 run after fame sell product (oil absorption equals 2.02 mls/g).
As polymeric hollow microsphere, can also mention:
-CardinalHealthTechnologies company with Microsponge5640 run after fame sell porous polymethyl acrylic acid methyl ester ./ethylene glycol dimethacrylate ball (oil absorption equals 1.55 mls/g); With
-ethylene glycol dimethacrylate/lauryl methacrylate copolymer powder, especially DowCorning company run after fame with Polytrap 6603 those (oil absorption equals 6.56 mls/g) of selling.
Preferably this additional filler is inorganic filler.Thus, this additional filler can be selected from Talcum, Kaolin, Muscovitum, solid silica, sericite, calcination of talc, calcining Muscovitum, calcining sericite, synthetic mica, Bismuth Oxychloride, barium sulfate, boron nitride, calcium carbonate, magnesium carbonate and hydroxyapatite.Muscovitum and/or calcium carbonate is used to be preferred as this additional filler (one or more).
Preferably this powder is mutually containing perlite and this additional filler is calcium carbonate.
Being suitable for additional filler of the present invention can be that such as its particle mean size is less than 100 microns and is especially the filler of 1 to 50 micron, such as 4 to 20 microns.This average (intermediate value) granularity can be recorded by laser diffractometry, and this granularity is based on volume diameter.
This additional filler can with the amount of 1 % by weight to 30 % by weight of the gross weight relative to cosmetic composition of the present invention be present in this powder mutually in.In one embodiment, this additional filler can with relative to said composition gross weight 3 % by weight to 20 % by weight amount exist.In further embodiment of the present invention, this additional filler can with relative to said composition gross weight 5 % by weight to 10 % by weight amount exist.
Term " pigment " is interpreted as referring to and is insoluble to Physiological Medium and is intended to the white with arbitrary shape of painted said composition or coloured, inorganic or organic filler.
According in the operable inorganic pigment of the present invention, can mention titanium dioxide (optionally surface-treated), zirconium oxide or cerium oxide and zinc oxide, (black, yellow or redness) ferrum oxide or chromium oxide, manganese violet, ultramarine, chromic oxide gel and barba hispanica without limitation, or metal dust is as aluminium powder or copper powder.In a preferred embodiment, said composition comprises titanium oxide, ferrum oxide or its mixture.
According in the operable organic pigment of the present invention, can mention without limitation in addition white carbon black, D & C type pigment and based on alkermes and the color lake based on barium, strontium, calcium or aluminum.
Also likely use at least one angle heterochromatosis pigment.This pigment according to the observation angle measuring gauge reveals relatively large color change.
This angle heterochromatosis pigment can be selected from the pigment and liquid crystal pigment such as with multi-coated interference structure.
In the case of the multi-layer structure, this structure can comprise such as at least two-layer, and each layer is independent of other layer (one or more layers) or be otherwise made up of at least one material being such as selected from following material: MgF
2, CeF
3, ZnS, ZnSe, Si, SiO
2, Ge, Te, Fe
2o
3, Pt, Va, Al
2o
3, MgO, Y
2o
3, S
2o
3, SiO, HfO
2, ZrO
2, CeO
2, Nb
2o
5, Ta
2o
5, TiO
2, Ag, Al, Au, Cu, Rb, Ti, Ta, W, Zn, MoS
2, cryolite, alloy and polymer.
The multiple structure that can be used for this angle heterochromatosis pigment is such as following structure: Al/SiO
2/ Al/SiO
2/ Al; Cr/MgF
2/ Al/MgF
2/ Al; MoS
2/ SiO
2/ Al/SiO
2/ MoS
2; Fe
2o
3/ SiO
2/ Al/SiO
2/ Fe
2o
3; Fe
2o
3/ SiO
2/ Fe
2o
3/ SiO
2/ Fe
2o
3; MoS
2/ SiO
2/ Muscovitum-oxide/SiO
2/ MoS
2; And Fe
2o
3/ SiO
2/ Muscovitum-oxide/SiO
2/ Fe
2o
3.Thickness according to each layer can obtain different colors.Thus, structure Fe is adopted
2o
3/ SiO
2/ Al/SiO
2/ Fe
2o
3, for the SiO of 320 to 350 nanometers
2layer, color becomes redness-Lycoperdon polymorphum Vitt from green-gold; For the SiO of 380 to 400 nanometers
2layer, color becomes gold from redness; For the SiO of 410 to 420 nanometers
2layer, color from purple becomes green; And for the SiO of 430 to 440 nanometers
2layer, color becomes redness from coppery.
Therefore, this multiple structure can be inorganic or organic.Different colors is obtained according to the thickness of each different layers.
The angle heterochromatosis pigment with multi-coated interference structure disclosed herein is those that such as describe in the following documents: USP-3438796, EP-A-227423, USP-5135812, EP-A-170439, EP-A-341002, USP-4930866, USP-5641719, EP-A-472371, EP-A-395410, EP-A-753545, EP-A-768343, EP-A-571836, EP-A-708154, EP-A-579091, USP-5411586, USP-5364467, WO97/39066, DE-A-4225031, WO95/17479, DE-A-19614637 and combination thereof.They can be the sheet form with metallization color.
In one embodiment, the angle heterochromatosis pigment with multi-coated interference structure can be selected from following commercially available angle heterochromatosis pigment: from the InfiniteColors of Shiseido company, from the SicopearlFantastico of BASF, from Colorstream, Xirallic or Xirona of Merck, and from the Colorglitter of Flex.
As the angle heterochromatosis pigment of multiple structure, can mention with " Sicopearl " run after fame sell those.
Also likely use at least one liquid crystal pigment, it is such as described in patent application EP-A-1046692.
Operable liquid crystal particle comprise such as with CTFA title Polyacrylate-4 and by Wacker company with " Helicone HCSapphire ", " Helicone HCScarabeus ", " Helicone HCJade ", " Helicone HCMaple ", " Helicone HCXLSapphire ", " Helicone HCXLScarabeus ", " Helicone HCXLJade " and " Helicone HCXLMaple " run after fame sell those.
Also likely use at least one pearlescent pigment.Term " pearlescent pigment " is interpreted as referring to any shape, such as, produce in the shell of some shellfish, or the iris particle of synthesis.
Pearlescent pigment (one or more) is optional from white pearlescent pigment, as scribbled titanium or scribbling the Muscovitum of Bismuth Oxychloride; Colored pearlescent pigments, as scribble ferrum oxide odenite, scribble such as barba hispanica or scribble the odenite of chromium oxide, scribble the odenite of the organic pigment of the above-mentioned type, and based on the pearlescent pigment of Bismuth Oxychloride.
This pigment can with relative to cosmetic composition gross weight of the present invention 1 % by weight to 30 % by weight amount be present in powder in said composition mutually in.In one embodiment, this pigment can with relative to said composition gross weight 3 % by weight to 20 % by weight amount exist.In another embodiment, this pigment can with relative to said composition gross weight 5 % by weight to 10 % by weight amount exist.
Preferably, at least one additional filler in cosmetic composition of the present invention and/or at least one pigment preferred hydrophilic or lyophobic dust surface-treated.
In cosmetic composition of the present invention, the amount of powder phase is be greater than 1 % by weight relative to said composition gross weight, and can be 3 to 40 % by weight, preferably 5 to 35 % by weight and more preferably 10 to 30 % by weight relative to said composition gross weight.
Aqueous phase in cosmetic composition of the present invention can comprise at least one hydrophilic organic solvent.
This hydrophilic organic solvent is preferably water miscibility.As hydrophilic organic solvent, such as C can be mentioned
1-C
4alkanol, as ethanol and isopropyl alcohol; Polyhydric alcohol and polyol ethers, as glycerol, butoxy ethanol, propylene glycol, propylene glycol monomethyl ether, diethylene glycol monoethyl ether and monomethyl ether; And aromatic alcohol is as benzylalcohol and phenyl phenol; Similar product; And composition thereof.
This organic solvent can with relative to cosmetic composition gross weight of the present invention 1 to 40 % by weight, preferably 5 to 30 % by weight and more preferably 10 to 20 % by weight amount exist.
The water yield in aqueous phase in cosmetic composition of the present invention can be relative to said composition gross weight 30 to 65 % by weight, preferably 35 to 60 % by weight and more preferably 40 to 55 % by weight.
The pH of the water in the aqueous phase in cosmetic composition of the present invention does not limit, but can be preferably 4.0 to 8.0, more preferably 5.0 to 7.5 and even more preferably 6.0 to 7.0.
The amount of the aqueous phase in cosmetic composition of the present invention can be relative to said composition gross weight 30 to 97 % by weight, preferably 35 to 80 % by weight and more preferably 40 to 75 % by weight.
Cosmetic composition of the present invention have 2,500mPas or lower, preferably 1,000mPas or lower, the viscosity of more preferably 800mPas or lower, more preferably 600mPas or lower, more preferably 400mPas or lower and even more preferably 200mPas or lower.
Cosmetic composition of the present invention can have the viscosity of 0.8mPas or higher, preferred 1.0mPas or higher, more preferably 1.5mPas or higher, more preferably 2.0mPas or higher, more preferably 3.0mPas or higher and even more preferably 5.0mPas or higher.
This viscosity can use Routine Viscometer, the RheomatRM180 viscometer (being sold by ProReo) that such as No. 2 axles are such as housed just mix cosmetic composition of the present invention with after forming uniform hydrous powdery dispersion such as 1-10 minute after record at 25 DEG C.
The low viscosity of cosmetic composition of the present invention means that cosmetic composition of the present invention does not comprise or only comprises a small amount of oil, surfactant or gellant.
In one embodiment of the invention, cosmetic composition of the present invention can with relative to said composition gross weight be less than 1 % by weight, be preferably less than 0.1 % by weight and the amount that is more preferably less than 0.01 % by weight comprise at least one oil.Most preferably cosmetic composition of the present invention is not containing any oil.
Term " oil " refers to be the fatty material of liquid form at ambient pressure at 25 DEG C here.
If present, this oil can be selected from oil, mineral oil, the artificial oil in animal or plant source, as the ester oil except animal or plant oil and artificial triglyceride, silicone oil and hydro carbons, particularly aliphatic hydrocarbon.These oil can be volatile or nonvolatile.Two or more oil can combinationally use.Therefore, the combination of the oil of single type or dissimilar oil can be used.
In another embodiment of the present invention, cosmetic composition of the present invention can be less than 1 % by weight relative to said composition gross weight, be preferably less than 0.1 % by weight and the amount that is more preferably less than 0.01 % by weight comprise at least one surfactant or at least one gellant.Most preferably cosmetic composition of the present invention is not containing any surfactant or gellant.
If present, the surfactant used in the present invention can be selected from anionic surfactant, amphoteric surfactant, cationic surface active agent and nonionic surfactant.Two or more surfactants can combinationally use.Thus, the combination of the surfactant of single type or dissimilar surfactant can be used.Preferably, according to the present invention, " surfactant " foam should can be formed when not having additive with water.
In cosmetic composition of the present invention, there is gellant causes the viscosity of said composition to improve, and due to the aqueous phase that comprises water mobility and tend to provide so not salubrious sensation.Therefore, preferred cosmetic composition of the present invention does not comprise or only comprises a small amount of gellant.
But if present, the gellant used in the present invention can be selected from hydrophilic gellant.Two or more gellant can combinationally use.Thus, the combination of the hydrophilic gellant of single type or dissimilar hydrophilic gellant can be used.This hydrophilic gellant can make the aqueous phase thickening of cosmetic composition of the present invention.
This hydrophilic gellant can be selected from such as:
(i) CVP Carbopol ETD2050;
(ii) the polymer of the 2-acrylamide-2-methylpro panesulfonic acid of polyacrylamide and optional crosslinked and/or neutralization and copolymer;
(iii) polysaccharide, as xanthan gum, guar gum, alginate or cellulosic polymer; With
(iv) inorganic compound.
Cosmetic composition of the present invention can comprise other conventional cosmetic ingredients any, its can be selected from such as antioxidant, spice, antiseptic, nertralizer, opacifier, vitamin, wetting agent, from tanned compound and antiwrinkle active principle.
Certainly, this for selection or that these are optional supplementary element (one or more) and/or its are measured, with the adverse effect making the beneficial property of cosmetic composition of the present invention or substantially can not can not be subject to contemplated interpolation by those skilled in the art.
Cosmetic composition of the present invention can by such as mixing the composition (particular powder selected, additional filler, additional pigment etc.) of this powder phase above and being prepared by the composition (one or more) under agitation adding aqueous phase subsequently, and this mixture pours in container subsequently in case of need.
[cosmetic method]
Another aspect of the present invention is for color make-up, especially for skin delustring or the cosmetic method reducing skin glossy (as shinny), comprising:
Apply cosmetic composition of the present invention.
For how cosmetic composition of the present invention being applied to the skin, particularly face of user less than limiting.Cosmetic composition of the present invention is applied preferably by the suitable applicator applicator as explained above of use.
Drying steps can be imposed to the cosmetic composition of the present invention be applied on skin.
The dry skin being applied to user for how, particularly the cosmetic composition of the present invention of face does not also limit.Likely use the exsiccator producing hot blast or cool breeze, or fan.Certainly, likely after spreading, cosmetic composition of the present invention is stayed on skin, because according to the amount of the cosmetic composition of the present invention be applied on skin, body temperature is enough to the aqueous phase of dry cosmetic composition of the present invention.
Cosmetic method of the present invention can be used for by being applied to for modifying skin on skin by cosmetic composition of the present invention as above, particularly face.According to cosmetic method of the present invention, salubrious sensation and lasting dressing effect can be provided to user, as lasting color make-up effect.Thus, the sub-light outward appearance of skin, the good appearance particularly with the glossy face of minimizing can continue a period of time grown very much.
Embodiment
In more detailed manner the present invention will be described by embodiment.But they should not be construed as and limit the scope of the invention.
Embodiment 1-3
[preparation]
In table 1, the chemical cosmetic compositions of the embodiment 1-3 of display is prepared by component shown in mixture table 1.The numerical value of the group component shown in this table is all based on " % by weight " of active raw material.
[evaluation]
(viscosity)
The compositions viscosity separately of embodiment 1-3 uses the RheomatRM180 viscometer (being sold by ProReo) No. 2 axles being housed according to this viscosity to record at 25 DEG C.This measurement is carried out after axle rotates 10 minutes with the shear rate of 200rpm in the composition.The actual viscosity measured value display of the compositions of embodiment 1-3 in Table 1.
(sensory evaluation)
The compositions prepared in five professional expert group Evaluation operation example 1-3, gives salubrious sensation marking when using according to following standard.
1: very greasy
2: greasy
3: between greasy and salubrious between
4: salubrious
5: very salubrious
Expert group shows in Table 1 embodiment 1-3 average score separately.
(matt effect)
The compositions of embodiment 1-3 is applied to the face of panel member separately.The clean glossiness (reflected light) on face is measured by polarization camera immediately after each compositions is applied to face.
30 minutes after the application, again measure clean glossiness on face in the same manner as above to determine the glossiness on face.
At once clean glossiness (T after the application
0) and the applying clean glossiness (T of latter 30 minutes
30) between difference be defined as sub-light value (T
30-T
0).Respectively said process is carried out to 12 professional expert groups, and calculate the meansigma methods of this sub-light value.Result display in Table 1.
Lower sub-light value shows that this cosmetic composition has more lasting matt effect.The sub-light value being less than 9.5 is preferred, is more preferably less than 9.0 and be preferably less than 8.0 further.
[result]
Find surprisingly, embodiment 1-3 provide not only good lasting matt effect, additionally provides salubrious sensation during use.
Table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Titanium oxide | 7.0770 | 7.4000 | 7.4000 |
| Ferrum oxide | 1.3272 | 1.4000 | 1.4000 |
| Perlite | 2.8800 | 10.000 | 15.000 |
| Muscovitum | 4.0000 | 4.0000 | 4.0000 |
| Aluminium chlorohydrate | 1.0000 | - | - |
| Kaolin | 3.0000 | - | - |
| Phenyl phenol | In right amount | In right amount | In right amount |
| Glycerol | 20.0000 | 20.0000 | 20.0000 |
| Ethanol | 10.0000 | 10.0000 | 10.0000 |
| Water | q.s. 100 | q.s. 100 | q.s. 100 |
| Viscosity (mPas) | 28 | 111 | 63 |
| Sensory evaluation (clearly feeling) | 5 | 4.8 | 4.4 |
| Sub-light value (T 30-T 0) | 9.71 | 7.00 | 6.39 |
Comparative example
Compare under extreme condition (37 DEG C and 60% humidity) it is said containing water, butanediol, glycerol, titanium oxide, Kaolin, ferrum oxide, camomile extract and methyl parahydroxybenzoate with HahagikuMizu-oshiroi run after fame sell product (being distributed by IshizawaLaboratories) and embodiment 3(comprise 15% perlite) as above to embodiment 1 to 3 explanation matt effect.Result is presented at hereinafter.
| Comparative example | Embodiment 3 (15% perlite) | |
| Sub-light value (T 30-T 0) | 9.9 | 6.39 |
Can be concluded by this result, with powder mutually in containing compared with kaolinic HahagikuMizu-oshiroi, in matt effect, demonstrate better performance containing perlitic compositions of the present invention, even if under extreme conditions (temperature and/or humidity).
Embodiment 4-7
[preparation]
In table 2, the following compositions of the embodiment 4-7 of display is prepared by component shown in mixture table 2.The numerical value of the group component shown in this table is all based on " % by weight " of active raw material.
[evaluation]
Each compositions (embodiment 4-7) is applied to the face (cheek) of panel member, and checks matt effect by two panel member.Finding that said composition has can effect compared with the compositions of embodiment 1.
Table 2
| Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | |
| Titanium oxide | 7.4000 | 7.4000 | 7.4000 | 7.4000 |
| Ferrum oxide | 1.4000 | 1.4000 | 1.4000 | 1.4000 |
| Silylanizing Silicon stone (DOW CORNING VM-2270 AEROGEL FINE PARTICLES) | 0.5000 | - | - | - |
| Amorphous hollow silica | - | 3.0000 | - | - |
| Magnesium carbonate | - | - | 3.0000 | - |
| Muscovitum | - | 4.0000 | 4.0000 | 4.0000 |
| Perlite | 15.000 | - | - | 3.0000 |
| Phenyl phenol | In right amount | In right amount | In right amount | In right amount |
| Glycerol | - | - | - | 20.0000 |
| Ethanol | - | - | - | 10.0000 |
| Water | q.s. 100 | q.s. 100 | q.s. 100 | q.s. 100 |
| The result of matt effect assessment | Can compared with embodiment 1 | Can compared with embodiment 1 | Can compared with embodiment 1 | Can compared with embodiment 1 |
The matt effect aspect that is combined in that example 5 shows perlite and silylanizing Silicon stone provides even better performance.Embodiment 6 and 7 shows good result by amorphous hollow silica and magnesium carbonate respectively.
Claims (11)
1. cosmetic composition, comprises:
(a) powder phase; With
(b) aqueous phase,
Wherein
The viscosity of described compositions is 2,500mPas or lower, preferably 1,000mPas or lower and more preferably 800mPas or lower,
Described powder comprises at least one powder with the amount of gross weight more than 1 % by weight relative to described compositions, and described powder is selected from perlite, aluminium chlorohydrate, porous silica, amorphous hollow silica, silylanizing Silicon stone and magnesium carbonate.
2. cosmetic composition as claimed in claim 1, wherein said powder is perlite.
3. cosmetic composition as claimed in claim 1 or 2, wherein said powder have make the median particle of this powder be less than 30 microns, be preferably less than 25 microns, be more preferably less than 20 microns and be even more preferably less than the particle size distribution of 15 microns.
4. the cosmetic composition as described in claims 1 to 3, wherein said powder has and makes 90% of this powder particle to be less than 55 microns, is preferably less than 50 microns and be more preferably less than the particle size distribution of 45 microns.
5. the cosmetic composition as described in any one of Claims 1-4, the amount of wherein said powder be relative to described composition total weight 2 % by weight or higher, preferably 3 % by weight or higher, more preferably 5 % by weight or higher, even more preferably 10% or higher and most preferably 15% or higher.
6. the cosmetic composition as described in any one of claim 1 to 5, wherein said powder comprises at least one additional filler and/or pigment mutually.
7. cosmetic composition as claimed in claim 6, wherein said additional filler is selected from Talcum, Kaolin, Muscovitum, solid silica, sericite, calcination of talc, calcining Muscovitum, calcining sericite, synthetic mica, Bismuth Oxychloride, barium sulfate, boron nitride, calcium carbonate and hydroxyapatite, preferred calcium carbonate.
8. cosmetic composition as claimed in claim 6, wherein said pigment is selected from titanium dioxide, zirconium oxide, cerium oxide, zinc oxide, ferrum oxide (black, yellow or redness), chromium oxide, manganese violet, ultramarine, chromic oxide gel, barba hispanica and metal dust, is preferably selected from titanium oxide, ferrum oxide and composition thereof.
9. the cosmetic composition as described in any one of claim 1 to 8, the amount of wherein said powder phase is relative to described composition total weight 3 to 40 % by weight, preferably 5 to 35 % by weight and more preferably 10 to 30 % by weight.
10. the cosmetic composition as described in any one of claim 1 to 9, the amount of wherein said aqueous phase is relative to described composition total weight 30 to 97 % by weight, preferably 35 to 85 % by weight and more preferably 40 to 75 % by weight.
11. for color make-up, especially for skin delustring or reduce the glossy cosmetic method of skin, comprising:
On skin as described in cosmetic composition as described in any one of claim 1 to 10 is applied to.
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|---|---|---|---|
| JP2013102127 | 2013-05-14 | ||
| JP2013-102127 | 2013-05-14 | ||
| PCT/JP2014/063133 WO2014185539A1 (en) | 2013-05-14 | 2014-05-09 | Cosmetic composition |
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| CN105228579A true CN105228579A (en) | 2016-01-06 |
| CN105228579B CN105228579B (en) | 2019-05-21 |
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| JP (1) | JP6543575B2 (en) |
| KR (1) | KR102190042B1 (en) |
| CN (1) | CN105228579B (en) |
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| JP6532646B2 (en) * | 2013-12-06 | 2019-06-19 | ロレアル | Powdery cosmetic composition |
| US20180369095A1 (en) * | 2015-12-21 | 2018-12-27 | L'oreal | Cosmetic composition comprising a specific filler combination and a film-forming polymer to increase long-lasting effects |
| KR20190108819A (en) | 2018-03-15 | 2019-09-25 | 주식회사 은호 | Cosmetic composition containing nephrite nano emulsion and manufacture method the same |
| JP2021102559A (en) * | 2019-12-24 | 2021-07-15 | ロレアル | Spherical hydrophobic silica aerogel, and cosmetic composition comprising composite silica particle and/or hollow silica particle |
| US20210196589A1 (en) * | 2019-12-26 | 2021-07-01 | L'oreal | Compositions, dispensing systems and methods for providing sensorial and aesthetic benefits to acne prone skin |
| KR102320833B1 (en) * | 2021-03-04 | 2021-11-02 | 한국콜마주식회사 | Solid or semisolid type cosmetic composition comprising sodium stearate and thickner, and its manufacturing method |
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| FR2881643A1 (en) * | 2005-02-04 | 2006-08-11 | Oreal | Non-rinsing composition, for topical application on the skin for matifying skin and/or for reducing brightness of skin, comprises an aqueous phase and pearlite particles |
| WO2012081132A2 (en) * | 2010-12-17 | 2012-06-21 | L'oreal | Cosmetic composition |
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| JPS6019281B2 (en) * | 1976-07-28 | 1985-05-15 | ポ−ラ化成工業株式会社 | cosmetics |
| JPS61207318A (en) * | 1985-03-12 | 1986-09-13 | Shiseido Co Ltd | Makeup cosmetic |
| GB9726227D0 (en) * | 1997-12-12 | 1998-02-11 | Crosfield Joseph & Sons | Particle agglomerates |
| JP3751888B2 (en) * | 2002-02-04 | 2006-03-01 | 日本メナード化粧品株式会社 | Liquid makeup cosmetics |
| DE20207329U1 (en) * | 2002-05-10 | 2002-10-24 | Schwan-Stabilo Cosmetics GmbH & Co., 90562 Heroldsberg | preparation |
| JP4907071B2 (en) * | 2004-10-12 | 2012-03-28 | 株式会社日本色材工業研究所 | Cosmetic for salmon |
| US9278866B2 (en) * | 2005-08-10 | 2016-03-08 | The Procter & Gamble Company | Hollow silica particles, compositions comprising them, and methods for making same |
| FR2964871B1 (en) * | 2010-09-17 | 2012-10-19 | Oreal | SOLID COSMETIC COMPOSITION OF MAKE-UP |
| JP5701819B2 (en) * | 2011-06-13 | 2015-04-15 | 富士フイルム株式会社 | Emulsified base makeup cosmetic and method for producing the same |
| FR2980108B1 (en) * | 2011-09-21 | 2013-08-30 | Oreal | SOLID COSMETIC COMPOSITION IN THE FORM OF COMPACT POWDER |
| FR2992203B1 (en) * | 2012-06-21 | 2014-10-24 | Oreal | COSMETIC COMPOSITION FOR SKIN MAKE-UP |
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2014
- 2014-05-09 WO PCT/JP2014/063133 patent/WO2014185539A1/en active Application Filing
- 2014-05-09 JP JP2015555880A patent/JP6543575B2/en active Active
- 2014-05-09 CN CN201480027111.XA patent/CN105228579B/en active Active
- 2014-05-09 KR KR1020157033352A patent/KR102190042B1/en active IP Right Grant
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| US4732754A (en) * | 1984-03-21 | 1988-03-22 | American Cyanamid Company | Method for the preparation of antiperspirant compositions having enhanced efficacy |
| FR2881643A1 (en) * | 2005-02-04 | 2006-08-11 | Oreal | Non-rinsing composition, for topical application on the skin for matifying skin and/or for reducing brightness of skin, comprises an aqueous phase and pearlite particles |
| WO2012081132A2 (en) * | 2010-12-17 | 2012-06-21 | L'oreal | Cosmetic composition |
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| Publication number | Publication date |
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| JP6543575B2 (en) | 2019-07-10 |
| WO2014185539A1 (en) | 2014-11-20 |
| KR20160006712A (en) | 2016-01-19 |
| KR102190042B1 (en) | 2020-12-11 |
| JP2016518307A (en) | 2016-06-23 |
| CN105228579B (en) | 2019-05-21 |
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