CN105219131A - A kind of electric power network outdoor case is with driving graphene-based coating of bird and preparation method thereof - Google Patents
A kind of electric power network outdoor case is with driving graphene-based coating of bird and preparation method thereof Download PDFInfo
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- CN105219131A CN105219131A CN201510699132.2A CN201510699132A CN105219131A CN 105219131 A CN105219131 A CN 105219131A CN 201510699132 A CN201510699132 A CN 201510699132A CN 105219131 A CN105219131 A CN 105219131A
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Abstract
The invention discloses a kind of electric power network outdoor case with driving graphene-based coating of bird and preparation method thereof, with Graphene, phenoxy group hybrid resin, aluminium nitride, organosilicon crylic acid latex, Shawinigan black, eucalyptus oil, maleic anhydride, 2, 4, 6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, acrylic acid hybridisation resin, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, tarragon, the stem or leaf of cattail, Moschus, iron powder and silicon sol are raw material, through the method for substep mixing, prepare a kind of corrosion-resistant, wear-resisting, the electric power network outdoor case that can absorb heat is with driving the graphene-based coating of bird.
Description
Technical field
The invention belongs to and drive the graphene-based paint field of bird, particularly a kind of electric power network outdoor case is with driving graphene-based coating of bird and preparation method thereof.
Background technology
Power equipment (powersystem) mainly comprises with generating set and the large class of power-supply unit two, generating set is station boiler, steam turbine, internal combustion turbine, water turbine, generator, transformer etc. mainly, the transmitting line, mutual inductor, contactor etc. of power-supply unit mainly various voltage range.
Along with industrial expansion, in electric power network outdoor case, drive the graphene-based coating of bird for main coating can play anticorrosion, wear-resisting, acid and alkali-resistance effect is more and more important, at present, the common graphene-based coating of bird that drives easily is corroded with aging, can not play automatically cleaning, acid and alkali-resistance effect.
Summary of the invention
The object of the invention is for the problems referred to above, develop a kind of corrosion-resistant, wear-resisting, the electric power network outdoor case that can absorb heat is with driving graphene-based coating of bird and preparation method thereof.
A kind of electric power network outdoor case is with driving the graphene-based coating of bird, and described casing is environment real-time monitoring system casing, is outdoor mechanism case, is provided with humidity sensor, humidity regulator, temperature sensor, temperature regulator in casing, well heater and power supply:
This electric power network outdoor case is made up of following weight part material with driving the graphene-based coating of bird:
Graphene 20-54 part;
Phenoxy group hybrid resin 20-54 part;
Aluminium nitride 20-54 part;
Organosilicon crylic acid latex 20-54 part;
Shawinigan black 20-54 part;
Eucalyptus oil 20-54 part;
Maleic anhydride 1-14 part;
2,4,6-tri(dimethylaminomethyl)phenol 1-14 part;
Dibutyl tin laurate 1-14 part;
Acrylic acid hybridisation resin 1-14 part;
Tripoly phosphate sodium STPP 1-14 part;
Gas phase aluminium sesquioxide 1-14 part;
Aluminum silicate fiber 1-14 part;
ISOPROPYL PHENYL DIPHENYL PHOSPHATE 1-14 part;
Volatile salt 1-14 part;
Titanium dioxide 1-14 part;
Tarragon 1-14 part;
Stem or leaf of cattail 1-14 part;
Moschus 1-14 part;
Iron powder 1-14 part;
Silicon sol 1-14 part.
As preferably, this electric power network outdoor case is made up of following weight part material with driving the graphene-based coating of bird:
Graphene 34 parts;
Phenoxy group hybrid resin 34 parts;
Aluminium nitride 34 parts;
Organosilicon crylic acid latex 34 parts;
Shawinigan black 34 parts;
Eucalyptus oil 34 parts;
Maleic anhydride 4 parts;
2,4,6-tri(dimethylaminomethyl)phenol 4 parts;
Dibutyl tin laurate 4 parts;
Acrylic acid hybridisation resin 4 parts;
Tripoly phosphate sodium STPP 4 parts;
Gas phase aluminium sesquioxide 4 parts;
Aluminum silicate fiber 4 parts;
ISOPROPYL PHENYL DIPHENYL PHOSPHATE 4 parts;
Volatile salt 4 parts;
Titanium dioxide 4 parts;
Tarragon 4 parts;
The stem or leaf of cattail 4 parts;
4 parts, Moschus;
Iron powder 4 parts;
Silicon sol 4 parts.
As preferably, the particle diameter of described Graphene is 20-60nm.
Prepare an electric power network outdoor case method of driving the graphene-based coating of bird described above, comprise the steps:
(1) prepare burden according to driving the graphene-based system component of bird;
(2) first add Graphene, phenoxy group hybrid resin, aluminium nitride, organosilicon crylic acid latex and Shawinigan black according to formula ratio, shredder ground and mixed 3min, adds eucalyptus oil subsequently again, stirs 20min with homogenizer;
(3) at 45 DEG C, maleic anhydride, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, acrylic acid hybridisation resin, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, tarragon, the stem or leaf of cattail, Moschus, iron powder and silicon sol, and stir 40min, obtain electric power network outdoor case with driving the graphene-based coating of bird.
Beneficial effect of the present invention:
(1) adopt Graphene, phenoxy group hybrid resin, aluminium nitride, organosilicon crylic acid latex, Shawinigan black and eucalyptus oil as the main component of driving the graphene-based coating of bird, Graphene is as the main component of coating, electroconductibility or salt spray resistance can not only be improved, coat-thickness can also be reduced further simultaneously, increase the sticking power to base material, promote the wear resistance of coating, and the compound use of resin and Shawinigan black, greatly will strengthen the performance of driving the wear-resisting, corrosion-resistant of the graphene-based coating of bird and acid and alkali-resistance; And inorganic materials aluminium nitride and novel nano-material organosilicon crylic acid latex, because self is for the reinforced effects of coating, as main component, the wear resistance of coating is strengthened greatly; The compound use of eucalyptus oil and other several raw materials, can not only play the effect of driving bird, also by the compatible crossing effect with resin, organosilicon crylic acid latex and Shawinigan black, promotes the synergy of each raw material.
(2) in order to optimize the performance of driving the graphene-based coating of bird further, have selected maleic anhydride, 2, 4, 6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, acrylic acid hybridisation resin, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, tarragon, the stem or leaf of cattail, Moschus, iron powder and silicon sol are ancillary component, this is not only made to drive the wear-resisting of the graphene-based coating of bird, corrosion-resistant, acid-proof alkaline is improved, or this must drive the graphene-based coating of bird there is good hydrophobic performance, and owing to the addition of solar selectively absorptive function iron powder and silicon sol combination, make this drive the graphene-based coating of bird and can be used in the relevant electric power network outdoor case of sun power.
(3) the present invention is selecting tarragon, the stem or leaf of cattail, Moschus and eucalyptus oil as driving the graphene-based coating of bird, said composition is common material, nontoxic, and it is cheap, efficient effect on driving birds can be played simultaneously, simultaneously eucalyptus oil or the main component of said composition, has important promoter action for wear-resisting, the lubrication of said composition and cleaning effect.
(4) this drives the graphene-based Paint preparation technology of bird simply, is easy to industrialization, and raw material sources are extensive, are applicable to very much being applied to production.
Embodiment
Below in conjunction with specific embodiment, and comparable data describes in further detail the present invention.Should be understood that these embodiments just in order to demonstrate the invention, but not limit the scope of the invention by any way.
Embodiment 1:
A kind of electric power network outdoor case is with driving the graphene-based coating of bird, described casing is environment real-time monitoring system casing, for outdoor mechanism case, humidity sensor, humidity regulator, temperature sensor, temperature regulator are installed, well heater and power supply in casing: this electric power network outdoor case is made up of following weight part material with driving the graphene-based coating of bird:
Graphene 34 parts;
Phenoxy group hybrid resin 34 parts;
Aluminium nitride 34 parts;
Organosilicon crylic acid latex 34 parts;
Shawinigan black 34 parts;
Eucalyptus oil 34 parts;
Maleic anhydride 4 parts;
2,4,6-tri(dimethylaminomethyl)phenol 4 parts;
Dibutyl tin laurate 4 parts;
Acrylic acid hybridisation resin 4 parts;
Tripoly phosphate sodium STPP 4 parts;
Gas phase aluminium sesquioxide 4 parts;
Aluminum silicate fiber 4 parts;
ISOPROPYL PHENYL DIPHENYL PHOSPHATE 4 parts;
Volatile salt 4 parts;
Titanium dioxide 4 parts;
Tarragon 4 parts;
The stem or leaf of cattail 4 parts;
4 parts, Moschus;
Iron powder 4 parts;
Silicon sol 4 parts;
The particle diameter of described Graphene is 30nm.
Prepare an electric power network outdoor case method of driving the graphene-based coating of bird described above, comprise the steps:
(1) prepare burden according to driving the graphene-based system component of bird;
(2) first add Graphene, phenoxy group hybrid resin, aluminium nitride, organosilicon crylic acid latex and Shawinigan black according to formula ratio, shredder ground and mixed 3min, adds eucalyptus oil subsequently again, stirs 20min with homogenizer;
(3) at 45 DEG C, maleic anhydride, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, acrylic acid hybridisation resin, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, tarragon, the stem or leaf of cattail, Moschus, iron powder and silicon sol, and stir 40min, obtain electric power network outdoor case with driving the graphene-based coating of bird.
Embodiment 2:
A kind of electric power network outdoor case is with driving the graphene-based coating of bird, described casing is environment real-time monitoring system casing, for outdoor mechanism case, humidity sensor, humidity regulator, temperature sensor, temperature regulator are installed, well heater and power supply in casing: this electric power network outdoor case is made up of following weight part material with driving the graphene-based coating of bird:
Graphene 46 parts;
Phenoxy group hybrid resin 46 parts;
Aluminium nitride 46 parts;
Organosilicon crylic acid latex 46 parts;
Shawinigan black 46 parts;
Eucalyptus oil 46 parts;
Maleic anhydride 6 parts;
2,4,6-tri(dimethylaminomethyl)phenol 6 parts;
Dibutyl tin laurate 6 parts;
Acrylic acid hybridisation resin 6 parts;
Tripoly phosphate sodium STPP 6 parts;
Gas phase aluminium sesquioxide 6 parts;
Aluminum silicate fiber 6 parts;
ISOPROPYL PHENYL DIPHENYL PHOSPHATE 6 parts;
Volatile salt 6 parts;
Titanium dioxide 6 parts;
Tarragon 6 parts;
The stem or leaf of cattail 6 parts;
6 parts, Moschus;
Iron powder 6 parts;
Silicon sol 6 parts;
The particle diameter of described Graphene is 30nm.
Prepare an electric power network outdoor case method of driving the graphene-based coating of bird described above, comprise the steps:
(1) prepare burden according to driving the graphene-based system component of bird;
(2) first add Graphene, phenoxy group hybrid resin, aluminium nitride, organosilicon crylic acid latex and Shawinigan black according to formula ratio, shredder ground and mixed 3min, adds eucalyptus oil subsequently again, stirs 20min with homogenizer;
(3) at 45 DEG C, maleic anhydride, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, acrylic acid hybridisation resin, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, tarragon, the stem or leaf of cattail, Moschus, iron powder and silicon sol, and stir 40min, obtain electric power network outdoor case with driving the graphene-based coating of bird.
Embodiment 3:
A kind of electric power network outdoor case is with driving the graphene-based coating of bird, described casing is environment real-time monitoring system casing, for outdoor mechanism case, humidity sensor, humidity regulator, temperature sensor, temperature regulator are installed, well heater and power supply in casing: this electric power network outdoor case is made up of following weight part material with driving the graphene-based coating of bird:
Graphene 30 parts;
Phenoxy group hybrid resin 30 parts;
Aluminium nitride 30 parts;
Organosilicon crylic acid latex 30 parts;
Shawinigan black 30 parts;
Eucalyptus oil 30 parts;
Maleic anhydride 1 part;
2,4,6-tri(dimethylaminomethyl)phenol 1 part;
Dibutyl tin laurate 1 part;
Acrylic acid hybridisation resin 1 part;
Tripoly phosphate sodium STPP 1 part;
Gas phase aluminium sesquioxide 1 part;
Aluminum silicate fiber 1 part;
ISOPROPYL PHENYL DIPHENYL PHOSPHATE 1 part;
Volatile salt 1 part;
Titanium dioxide 1 part;
Tarragon 1 part;
The stem or leaf of cattail 1 part;
1 part, Moschus;
Iron powder 1 part;
Silicon sol 1 part;
The particle diameter of described Graphene is 40nm.
Prepare an electric power network outdoor case method of driving the graphene-based coating of bird described above, comprise the steps:
(1) prepare burden according to driving the graphene-based system component of bird;
(2) first add Graphene, phenoxy group hybrid resin, aluminium nitride, organosilicon crylic acid latex and Shawinigan black according to formula ratio, shredder ground and mixed 3min, adds eucalyptus oil subsequently again, stirs 20min with homogenizer;
(3) at 45 DEG C, maleic anhydride, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, acrylic acid hybridisation resin, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, tarragon, the stem or leaf of cattail, Moschus, iron powder and silicon sol, and stir 40min, obtain electric power network outdoor case with driving the graphene-based coating of bird.
Embodiment 4:
A kind of electric power network outdoor case is with driving the graphene-based coating of bird, described casing is environment real-time monitoring system casing, for outdoor mechanism case, humidity sensor, humidity regulator, temperature sensor, temperature regulator are installed, well heater and power supply in casing: this electric power network outdoor case is made up of following weight part material with driving the graphene-based coating of bird:
Graphene 20 parts;
Phenoxy group hybrid resin 20 parts;
Aluminium nitride 20 parts;
Organosilicon crylic acid latex 20 parts;
Shawinigan black 20 parts;
Eucalyptus oil 20 parts;
Maleic anhydride 14 parts;
2,4,6-tri(dimethylaminomethyl)phenol 14 parts;
Dibutyl tin laurate 14 parts;
Acrylic acid hybridisation resin 14 parts;
Tripoly phosphate sodium STPP 14 parts;
Gas phase aluminium sesquioxide 14 parts;
Aluminum silicate fiber 14 parts;
ISOPROPYL PHENYL DIPHENYL PHOSPHATE 14 parts;
Volatile salt 14 parts;
Titanium dioxide 14 parts;
Tarragon 14 parts;
The stem or leaf of cattail 14 parts;
14 parts, Moschus;
Iron powder 14 parts;
Silicon sol 14 parts;
The particle diameter of described Graphene is 40nm.
Prepare an electric power network outdoor case method of driving the graphene-based coating of bird described above, comprise the steps:
(1) prepare burden according to driving the graphene-based system component of bird;
(2) first add Graphene, phenoxy group hybrid resin, aluminium nitride, organosilicon crylic acid latex and Shawinigan black according to formula ratio, shredder ground and mixed 3min, adds eucalyptus oil subsequently again, stirs 20min with homogenizer;
(3) at 45 DEG C, maleic anhydride, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, acrylic acid hybridisation resin, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, tarragon, the stem or leaf of cattail, Moschus, iron powder and silicon sol, and stir 40min, obtain electric power network outdoor case with driving the graphene-based coating of bird.
Carry out salt-fog test to the electric power network outdoor case of driving the graphene-based paint of bird prepared by embodiment 1-4 and scratch results of property, result is as follows:
| Erosion resistance (salt-fog test) | Scratch resistant | |
| Embodiment 1 | 630 hours | 0 |
| Embodiment 2 | 631 hours | 0 |
| Embodiment 3 | 631 hours | 0 |
| Embodiment 4 | 632 hours | 0 |
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.
Claims (4)
1. electric power network outdoor case is with driving the graphene-based coating of bird, it is characterized in that:
Described casing is environment real-time monitoring system casing, is outdoor mechanism case, is provided with humidity sensor, humidity regulator, temperature sensor, temperature regulator in casing, well heater and power supply:
This electric power network outdoor case is made up of following weight part material with driving the graphene-based coating of bird:
Graphene 20-54 part;
Phenoxy group hybrid resin 20-54 part;
Aluminium nitride 20-54 part;
Organosilicon crylic acid latex 20-54 part;
Shawinigan black 20-54 part;
Eucalyptus oil 20-54 part;
Maleic anhydride 1-14 part;
2,4,6-tri(dimethylaminomethyl)phenol 1-14 part;
Dibutyl tin laurate 1-14 part;
Acrylic acid hybridisation resin 1-14 part;
Tripoly phosphate sodium STPP 1-14 part;
Gas phase aluminium sesquioxide 1-14 part;
Aluminum silicate fiber 1-14 part;
ISOPROPYL PHENYL DIPHENYL PHOSPHATE 1-14 part;
Volatile salt 1-14 part;
Titanium dioxide 1-14 part;
Tarragon 1-14 part;
Stem or leaf of cattail 1-14 part;
Moschus 1-14 part;
Iron powder 1-14 part;
Silicon sol 1-14 part.
2. electric power network outdoor case as claimed in claim 2 is with driving the graphene-based coating of bird, it is characterized in that:
This electric power network outdoor case is made up of following weight part material with driving the graphene-based coating of bird:
Graphene 34 parts;
Phenoxy group hybrid resin 34 parts;
Aluminium nitride 34 parts;
Organosilicon crylic acid latex 34 parts;
Shawinigan black 34 parts;
Eucalyptus oil 34 parts;
Maleic anhydride 4 parts;
2,4,6-tri(dimethylaminomethyl)phenol 4 parts;
Dibutyl tin laurate 4 parts;
Acrylic acid hybridisation resin 4 parts;
Tripoly phosphate sodium STPP 4 parts;
Gas phase aluminium sesquioxide 4 parts;
Aluminum silicate fiber 4 parts;
ISOPROPYL PHENYL DIPHENYL PHOSPHATE 4 parts;
Volatile salt 4 parts;
Titanium dioxide 4 parts;
Tarragon 4 parts;
The stem or leaf of cattail 4 parts;
4 parts, Moschus;
Iron powder 4 parts;
Silicon sol 4 parts.
3. electric power network outdoor case as claimed in claim 1 or 2 is with driving the graphene-based coating of bird, it is characterized in that: the particle diameter of described Graphene is 20-60nm.
4. prepare an electric power network outdoor case method of driving the graphene-based coating of bird as claimed in claim 1, it is characterized in that: comprise the steps:
(1) prepare burden according to driving the graphene-based system component of bird;
(2) first add Graphene, phenoxy group hybrid resin, aluminium nitride, organosilicon crylic acid latex and Shawinigan black according to formula ratio, shredder ground and mixed 3min, adds eucalyptus oil subsequently again, stirs 20min with homogenizer;
(3) at 45 DEG C, maleic anhydride, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, acrylic acid hybridisation resin, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, tarragon, the stem or leaf of cattail, Moschus, iron powder and silicon sol, and stir 40min, obtain electric power network outdoor case with driving the graphene-based coating of bird.
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| CN201510699132.2A CN105219131A (en) | 2015-10-26 | 2015-10-26 | A kind of electric power network outdoor case is with driving graphene-based coating of bird and preparation method thereof |
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|---|---|---|---|
| CN201510699132.2A CN105219131A (en) | 2015-10-26 | 2015-10-26 | A kind of electric power network outdoor case is with driving graphene-based coating of bird and preparation method thereof |
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Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613548A (en) * | 2009-08-07 | 2009-12-30 | 河南省阳光防腐涂装有限公司 | Multifunctional bird nesting resistance anticorrosion coating |
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2015
- 2015-10-26 CN CN201510699132.2A patent/CN105219131A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101613548A (en) * | 2009-08-07 | 2009-12-30 | 河南省阳光防腐涂装有限公司 | Multifunctional bird nesting resistance anticorrosion coating |
Non-Patent Citations (2)
| Title |
|---|
| 中国塑料加工工业协会主编: "《中国塑料工业年鉴.2013》", 31 January 2014, 中国石化出版社 * |
| 刘栋 等: "《建筑涂料配方设计与制造技术》", 30 April 2008, 中国石化出版社 * |
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Application publication date: 20160106 |