CN105131664A - Anticorrosive paint for electric power grid outdoor box and preparing method of anticorrosive paint - Google Patents
Anticorrosive paint for electric power grid outdoor box and preparing method of anticorrosive paint Download PDFInfo
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- CN105131664A CN105131664A CN201510701673.4A CN201510701673A CN105131664A CN 105131664 A CN105131664 A CN 105131664A CN 201510701673 A CN201510701673 A CN 201510701673A CN 105131664 A CN105131664 A CN 105131664A
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Abstract
The invention discloses anticorrosive paint for an electric power grid outdoor box and a preparing method of the anticorrosive paint. The anticorrosive paint comprises the raw materials of graphene, polyimide, mesocarbon microbeads, hexafluorobutyl methacrylate-acrylate copolymer emulsion, organosilicone modification fluorocarbon resin, eucalyptus oil, crylic acid, 2,4,6-tri(dimethyl aminomethyl)phenol, dibutyltin dilaurate, phenolic resin, sodium tripolyphosphate, gas phase aluminum oxide, alumina silicate fibers, isopropyl phenyl diphenyl phosphate, ammonium carbonate, titanium dioxide, polyving akohol, coagulant, diluent, iron powder and silica sol. The anticorrosive paint which is resistant to corrosion and abrasion and capable of absorbing heat is prepared through a step-by-step mixing method, and the anticorrosive paint is suitable for the power grid outdoor box.
Description
Technical field
The invention belongs to wear-resistant paint field, particularly a kind of electric power network outdoor case wear-resistant paint and preparation method thereof.
Background technology
Power equipment (powersystem) mainly comprises with generating set and the large class of power-supply unit two, generating set is station boiler, steam turbine, internal combustion turbine, water turbine, generator, transformer etc. mainly, the transmitting line, mutual inductor, contactor etc. of power-supply unit mainly various voltage range.
Along with industrial expansion, in electric power network outdoor case, wear-resistant paint for main coating can play anticorrosion, wear-resisting, acid and alkali-resistance effect is more and more important, at present, common wear-resistant paint is easily corroded with aging, can not play automatically cleaning, acid and alkali-resistance effect.
Summary of the invention
The object of the invention is for the problems referred to above, develop a kind of wear-resisting, corrosion-resistant, electric power network outdoor case wear-resistant paint that can absorb heat and preparation method thereof.
A kind of electric power network outdoor case wear-resistant paint, described casing is environment real-time monitoring system casing, for outdoor mechanism case, humidity sensor, humidity regulator, temperature sensor, temperature regulator are installed in casing, well heater and power supply: described casing is environment real-time monitoring system casing, for outdoor mechanism case, humidity sensor, humidity regulator, temperature sensor, temperature regulator are installed in casing, well heater and power supply; This wear-resistant paint is made up of following weight part material: Graphene 25-56 part; Polyimide 25-56 part; Carbonaceous mesophase spherules 25-56 part; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 25-56 part; Organic-silicon-modified fluorocarbon resin 25-56 part; Eucalyptus oil 25-56 part; Vinylformic acid 1-16 part; 2,4,6-tri(dimethylaminomethyl)phenol 1-16 part; Dibutyl tin laurate 1-16 part; Resol 1-16 part; Tripoly phosphate sodium STPP 1-16 part; Gas phase aluminium sesquioxide 1-16 part; Aluminum silicate fiber 1-16 part; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 1-16 part;
Volatile salt 1-16 part; Titanium dioxide 1-16 part; Polyvinyl alcohol 1-16 part; Peptizer 1-16 part; Thinner 1-16 part; Iron powder 1-16 part; Silicon sol 1-16 part.
As preferred version of the present invention, this wear-resistant paint is made up of following weight part material: Graphene 36 parts; Polyimide 36 parts; Carbonaceous mesophase spherules 36 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 36 parts; Organic-silicon-modified fluorocarbon resin 36 parts; Eucalyptus oil 36 parts; 6 parts, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 6 parts; Dibutyl tin laurate 6 parts; 6 parts, resol; Tripoly phosphate sodium STPP 6 parts; Gas phase aluminium sesquioxide 6 parts; Aluminum silicate fiber 6 parts; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 6 parts; Volatile salt 6 parts; Titanium dioxide 6 parts; Polyvinyl alcohol 6 parts; 6 parts, peptizer; Thinner 6 parts; Iron powder 6 parts; Silicon sol 6 parts.
As preferred version of the present invention, the particle diameter of described Graphene is 25-60nm.
Present invention also offers a kind of method preparing above-mentioned wear-resistant paint, comprise the steps:
(1), prepare burden according to the composition of graphene-based wear-resistant paint;
(2), Graphene, polyimide, carbonaceous mesophase spherules, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add eucalyptus oil more subsequently, stir 25min with homogenizer;
(3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, resol, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, polyvinyl alcohol, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain wear-resistant paint.
By the application of above-mentioned technique means, the present invention has following beneficial effect:
(1), adopt Graphene, polyimide, carbonaceous mesophase spherules, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate, organic-silicon-modified fluorocarbon resin and eucalyptus oil as the main component of wear-resistant paint, Graphene is as the main component of coating, electroconductibility or salt spray resistance can not only be improved, coat-thickness can also be reduced further simultaneously, increase the sticking power to base material, promote the wear resistance of coating, and the compound use of resin and organic-silicon-modified fluorocarbon resin, greatly will strengthen the performance of the wear-resisting, corrosion-resistant of wear-resistant paint and acid and alkali-resistance; And inorganic materials carbonaceous mesophase spherules and Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate, because self has reinforced effects for coating, as main component, the wear resistance of this wear-resistant paint is strengthened greatly; The compound use of eucalyptus oil and other several raw materials, the effect of driving bird can not only be played, also by the compatible crossing effect with resin, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin, promote the synergy of each raw material.
(2), select vinylformic acid, 2, 4, 6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, resol, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, polyvinyl alcohol, peptizer, thinner, iron powder and silicon sol are ancillary component, not only make the wear-resisting of this wear-resistant paint, corrosion-resistant, acid-proof alkaline is improved, still this wear-resistant paint is made to have good hydrophobic performance, and owing to the addition of solar selectively absorptive function iron powder and silicon sol combination, this wear-resistant paint is made to can be used in the relevant electric power network outdoor case of sun power.
(3), this wear-resistant paint preparation technology is simple, and be easy to industrialization, raw material sources are extensive, are applicable to very much being applied to production.
Embodiment
Below in conjunction with specific embodiment, and comparable data describes in further detail the present invention.Should be understood that these embodiments just in order to demonstrate the invention, but not limit the scope of the invention by any way.
Embodiment 1
The wear-resistant paint that the present embodiment provides is made up of following weight part material: Graphene 36 parts; Polyimide 36 parts; Carbonaceous mesophase spherules 36 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 36 parts; Organic-silicon-modified fluorocarbon resin 36 parts; Eucalyptus oil 36 parts; 6 parts, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 6 parts; Dibutyl tin laurate 6 parts; 6 parts, resol; Tripoly phosphate sodium STPP 6 parts; Gas phase aluminium sesquioxide 6 parts; Aluminum silicate fiber 6 parts; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 6 parts; Volatile salt 6 parts; Titanium dioxide 6 parts; Polyvinyl alcohol 6 parts; 6 parts, peptizer; Thinner 6 parts; Iron powder 6 parts; Silicon sol 6 parts.The particle diameter of wherein said Graphene is 30nm.
The preparation method of the wear-resistant paint of the present embodiment, comprises the steps: (1), prepares burden according to the composition of wear-resistant paint; (2), Graphene, polyimide, carbonaceous mesophase spherules, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add eucalyptus oil more subsequently, stir 25min with homogenizer; (3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, resol, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, polyvinyl alcohol, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain wear-resistant paint.
Embodiment 2
The wear-resistant paint that the present embodiment provides is made up of following weight part material: Graphene 46 parts; Polyimide 46 parts; Carbonaceous mesophase spherules 46 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 46 parts; Organic-silicon-modified fluorocarbon resin 46 parts; Eucalyptus oil 46 parts; 6 parts, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 6 parts; Dibutyl tin laurate 6 parts; 6 parts, resol; Tripoly phosphate sodium STPP 6 parts; Gas phase aluminium sesquioxide 6 parts; Aluminum silicate fiber 6 parts; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 6 parts; Volatile salt 6 parts; Titanium dioxide 6 parts; Polyvinyl alcohol 6 parts; 6 parts, peptizer; Thinner 6 parts; Iron powder 6 parts; Silicon sol 6 parts.The particle diameter of wherein said Graphene is 30nm.
The preparation method of the wear-resistant paint of the present embodiment, comprises the steps: (1), prepares burden according to the composition of wear-resistant paint; (2), Graphene, polyimide, carbonaceous mesophase spherules, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add eucalyptus oil more subsequently, stir 25min with homogenizer; (3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, resol, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, polyvinyl alcohol, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain wear-resistant paint.
Embodiment 3
The wear-resistant paint that the present embodiment provides is made up of following weight part material: Graphene 30 parts; Polyimide 30 parts; Carbonaceous mesophase spherules 30 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 30 parts; Organic-silicon-modified fluorocarbon resin 30 parts; Eucalyptus oil 30 parts; 1 part, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 1 part; Dibutyl tin laurate 1 part; 1 part, resol; Tripoly phosphate sodium STPP 1 part; Gas phase aluminium sesquioxide 1 part; Aluminum silicate fiber 1 part; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 1 part; Volatile salt 1 part; Titanium dioxide 1 part; Polyvinyl alcohol 1 part; 1 part, peptizer; Thinner 1 part; Iron powder 1 part; Silicon sol 1 part.The particle diameter of wherein said Graphene is 40nm.
The preparation method of the wear-resistant paint of the present embodiment, comprises the steps: (1), prepares burden according to the composition of wear-resistant paint; (2), Graphene, polyimide, carbonaceous mesophase spherules, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add eucalyptus oil more subsequently, stir 25min with homogenizer; (3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, resol, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, polyvinyl alcohol, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain wear-resistant paint.
Embodiment 4
The wear-resistant paint that the present embodiment provides is made up of following weight part material: Graphene 26 parts; Polyimide 26 parts; Carbonaceous mesophase spherules 26 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 26 parts; Organic-silicon-modified fluorocarbon resin 26 parts; Eucalyptus oil 26 parts; 16 parts, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 16 parts; Dibutyl tin laurate 16 parts; 16 parts, resol; Tripoly phosphate sodium STPP 16 parts; Gas phase aluminium sesquioxide 16 parts; Aluminum silicate fiber 16 parts; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 16 parts; Volatile salt 16 parts; Titanium dioxide 16 parts; Polyvinyl alcohol 16 parts; 16 parts, peptizer; Thinner 16 parts; Iron powder 16 parts; Silicon sol 16 parts.The particle diameter of wherein said Graphene is 40nm.
The preparation method of the wear-resistant paint of the present embodiment, comprises the steps: (1), prepares burden according to the composition of wear-resistant paint; (2), Graphene, polyimide, carbonaceous mesophase spherules, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add eucalyptus oil more subsequently, stir 25min with homogenizer; (3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, resol, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, polyvinyl alcohol, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain wear-resistant paint.
The electric power network outdoor case of the wear-resistant paint coating prepared by embodiment 1-4 is carried out to salt-fog test and scratched results of property, and result is as follows:
| Erosion resistance (salt-fog test) | Scratch resistant | |
| Embodiment 1 | 675 hours | 0 |
| Embodiment 2 | 674 hours | 0 |
| Embodiment 3 | 676 hours | 0 |
| Embodiment 4 | 671 hours | 0 |
To those skilled in the art, obviously the invention is not restricted to the details of above-mentioned one exemplary embodiment, and when not deviating from spirit of the present invention or essential characteristic, the present invention can be realized in other specific forms.Therefore, no matter from which point, all should embodiment be regarded as exemplary, and be nonrestrictive, scope of the present invention is limited by claims instead of above-mentioned explanation, and all changes be therefore intended in the implication of the equivalency by dropping on claim and scope are included in the present invention.
In addition, be to be understood that, although this specification sheets is described according to embodiment, but not each embodiment only comprises an independently technical scheme, this narrating mode of specification sheets is only for clarity sake, those skilled in the art should by specification sheets integrally, and the technical scheme in each embodiment also through appropriately combined, can form other embodiments that it will be appreciated by those skilled in the art that.
Claims (4)
1. an electric power network outdoor case wear-resistant paint, described casing is environment real-time monitoring system casing, for outdoor mechanism case, humidity sensor, humidity regulator, temperature sensor, temperature regulator are installed in casing, well heater and power supply: described casing is environment real-time monitoring system casing, for outdoor mechanism case, humidity sensor, humidity regulator, temperature sensor, temperature regulator are installed in casing, well heater and power supply; It is characterized in that: this wear-resistant paint is made up of following weight part material: Graphene 25-56 part; Polyimide 25-56 part; Carbonaceous mesophase spherules 25-56 part; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 25-56 part; Organic-silicon-modified fluorocarbon resin 25-56 part; Eucalyptus oil 25-56 part; Vinylformic acid 1-16 part; 2,4,6-tri(dimethylaminomethyl)phenol 1-16 part; Dibutyl tin laurate 1-16 part; Resol 1-16 part; Tripoly phosphate sodium STPP 1-16 part; Gas phase aluminium sesquioxide 1-16 part; Aluminum silicate fiber 1-16 part; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 1-16 part; Volatile salt 1-16 part; Titanium dioxide 1-16 part; Polyvinyl alcohol 1-16 part; Peptizer 1-16 part; Thinner 1-16 part; Iron powder 1-16 part; Silicon sol 1-16 part.
2. electric power network outdoor case wear-resistant paint according to claim 1, is characterized in that: this wear-resistant paint is made up of following weight part material: Graphene 36 parts; Polyimide 36 parts; Carbonaceous mesophase spherules 36 parts; Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate 36 parts; Organic-silicon-modified fluorocarbon resin 36 parts; Eucalyptus oil 36 parts; 6 parts, vinylformic acid; 2,4,6-tri(dimethylaminomethyl)phenol 6 parts; Dibutyl tin laurate 6 parts; 6 parts, resol; Tripoly phosphate sodium STPP 6 parts; Gas phase aluminium sesquioxide 6 parts; Aluminum silicate fiber 6 parts; ISOPROPYL PHENYL DIPHENYL PHOSPHATE 6 parts; Volatile salt 6 parts; Titanium dioxide 6 parts; Polyvinyl alcohol 6 parts; 6 parts, peptizer; Thinner 6 parts; Iron powder 6 parts; Silicon sol 6 parts.
3. electric power network outdoor case wear-resistant paint according to claim 1 and 2, is characterized in that: the particle diameter of described Graphene is 25-60nm.
4. prepare a method for the wear-resistant paint described in the claims, it is characterized in that: comprise the steps:
(1), prepare burden according to the composition of graphene-based wear-resistant paint;
(2), Graphene, polyimide, carbonaceous mesophase spherules, Copolymer Emulsion of Hexafluorobutyl Methacrylate-Acrylate and organic-silicon-modified fluorocarbon resin is first added according to formula ratio, shredder ground and mixed 3min, add eucalyptus oil more subsequently, stir 25min with homogenizer;
(3), at 45 DEG C, vinylformic acid, 2 is added again, 4,6-tri(dimethylaminomethyl)phenol, dibutyl tin laurate, resol, tripoly phosphate sodium STPP, gas phase aluminium sesquioxide, aluminum silicate fiber, ISOPROPYL PHENYL DIPHENYL PHOSPHATE, volatile salt, titanium dioxide, polyvinyl alcohol, peptizer, thinner, iron powder and silicon sol, and stir 40min, obtain wear-resistant paint.
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|---|---|---|---|
| CN201510701673.4A CN105131664A (en) | 2015-10-26 | 2015-10-26 | Anticorrosive paint for electric power grid outdoor box and preparing method of anticorrosive paint |
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| CN201510701673.4A CN105131664A (en) | 2015-10-26 | 2015-10-26 | Anticorrosive paint for electric power grid outdoor box and preparing method of anticorrosive paint |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110862743A (en) * | 2019-11-21 | 2020-03-06 | 安徽新大陆特种涂料有限责任公司 | Iron oxide red epoxy anticorrosive paint for engineering machinery |
| CN111514517A (en) * | 2020-06-12 | 2020-08-11 | 鄢文玲 | Outdoor exercise strolling machine |
-
2015
- 2015-10-26 CN CN201510701673.4A patent/CN105131664A/en active Pending
Non-Patent Citations (1)
| Title |
|---|
| 刘永泉主编: "《农药新品种实用手册》", 31 May 2012 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110862743A (en) * | 2019-11-21 | 2020-03-06 | 安徽新大陆特种涂料有限责任公司 | Iron oxide red epoxy anticorrosive paint for engineering machinery |
| CN111514517A (en) * | 2020-06-12 | 2020-08-11 | 鄢文玲 | Outdoor exercise strolling machine |
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Application publication date: 20151209 |