CN105199580A - Anticorrosive environment-friendly spray paint formula - Google Patents

Anticorrosive environment-friendly spray paint formula Download PDF

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Publication number
CN105199580A
CN105199580A CN201510692638.0A CN201510692638A CN105199580A CN 105199580 A CN105199580 A CN 105199580A CN 201510692638 A CN201510692638 A CN 201510692638A CN 105199580 A CN105199580 A CN 105199580A
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parts
spray paint
environmental protection
paint formula
mixture
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CN201510692638.0A
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王海平
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Abstract

The invention discloses an anticorrosive environment-friendly spray paint formula, and relates to the field of chemical industries. The anticorrosive environment-friendly spray paint formula comprises the following components in parts by weight: 28 to 35 parts of glacial acetic acid, 3 to 7 parts of organic fluorine epoxy resin, 7 to 12 parts of epoxy modified organic silicon resin, 2 to 6 parts of glycol monomethyl ether, 6 to 9 parts of dimethyl sulfoxide, 8 to 13 parts of zinc phosphate, 8 to 13 parts of barium chromate, 1 to 4 parts of ethanol, 2 to 7 parts of polyacrylate, 1 to 4 parts of alcohol soluble resin, 7 to 13 parts of diacetone alcohol, 6 to 9 parts of zinc oxide, 8 to 13 parts of toluene diisocynate, 3 to 7 parts of n-butyl acetate, 12 to 16 parts of benzophenone, 9 to 13 parts of triethanolamine and 3 to 7 parts of diphenyl polysiloxane. The paint is bright in color and good in air-curing resisting effect, can substitute medium chrome yellow in inorganic pigment, is applicable to the outer wall paint, and has no harm of heavy metals, no harmful substances, good environment protection effect, little odor, no peculiar smell after being smeared on the wall, good mechanical performance, excellent electric insulation performance, dampness and water resistance, rust and cold resistance and ozone aging resistance.

Description

A kind of spray paint formula of anticorrosion environmental protection
Technical field
The present invention relates to chemical field, be specifically related to a kind of spray paint formula of anticorrosion environmental protection.
Background technology
The outdoor long-lasting protection coating general requirement coating protection life-span reaches more than 10a, belongs to long-lasting protection coating system, can apply under harsh applied environment and have long-acting work-ing life.At present, the heavy mechanical equipment of heavy mechanical equipment length duration of service or open work is after wind and weather, and equipment corrosion is serious, easily causes hidden danger, also reduction of service life.The over-all propertieies such as traditional paint sun-proof, heat-resisting, resistance to migration are relatively poor.Be mainly used in the plays such as the gas dried lacquer, emulsion paint, printing-ink, coating etc. of general quality be low.Photostabilization can not be used for and require higher occasion, in existing oil paint, a lot of paint has used benzene class, ketone and ester class equal solvent in process of production, these solvent highly volatiles, understand environment in production and use procedure, also can cause harm in various degree to the health of the spraying workman of working-yard.At present, paint on the market after a procedure taste is very large, generally all just can will move in about point ventilative two weeks, contains the air painting taste harmful.And after part drying varniss, in paint film, still remain solvent, directly can have influence on the health of user.Therefore, select environment and the minimum alcoholic solvent of harm, the Environment-friendlyplastic plastic shellac varnish developing a set of ethanol-soluble type is necessary.
Summary of the invention
Problem to be solved by this invention is to provide a kind of protection against corrosion, energy-conserving and environment-protective, the paint that can spray.
To achieve these goals, the technical scheme that the present invention takes is: the component proportioning (mass fraction) of the spray paint formula of described anticorrosion environmental protection comprises Glacial acetic acid 28-35 part, organic fluorine epoxy resin 3-7 part, epoxy modified silicone resin liquid 7-12 part, ethylene glycol monomethyl ether 2-6 part, dimethyl sulfoxide (DMSO) 6-9 part, zinc phosphate 8-13 part, baryta yellow 8-13 part, ethanol 1-4 part, polyacrylic ester 2-7 part, spirit-soluble resin 1-4 part, diacetone alcohol 7-13 part, zinc oxide 6-9 part, tolylene diisocyanate 8-13 part, N-BUTYL ACETATE 3-7 part, benzophenone 12-16 part, trolamine 9-13 part and diphenylpolysiloxane 3-7 part.
Preferably, the component proportioning (mass fraction) of the spray paint formula of described anticorrosion environmental protection comprises 28 parts, Glacial acetic acid, organic fluorine epoxy resin 3 parts, epoxy modified silicone resin liquid 7 parts, ethylene glycol monomethyl ether 2 parts, dimethyl sulfoxide (DMSO) 6 parts, zinc phosphate 8 parts, baryta yellow 8 parts, ethanol 1 part, polyacrylic ester 2 parts, spirit-soluble resin 1 part, diacetone alcohol 7 parts, 6 parts, zinc oxide, tolylene diisocyanate 8 parts, N-BUTYL ACETATE 3 parts, benzophenone 12 parts, trolamine 9 parts and diphenylpolysiloxane 3 parts.
Preferably, the preparation technology of the spray paint of described anticorrosion environmental protection carries out according to following steps,
(1) preparation of mixture A: get a heatable container, to pour into Glacial acetic acid and epoxy modified silicone resin liquid according to the dosage of formula and wherein mixes and heat, obtained mixture A.
(2) preparation of mixture B: under the condition stirred, then by organic fluorine epoxy resin, ethylene glycol monomethyl ether, zinc phosphate, baryta yellow, ethanol and polyacrylic ester in container, stir, obtained mixture B.
(3) preparation of mixture C: add spirit-soluble resin, diacetone alcohol and zinc oxide again in container, high-speed stirring is even, obtained mixture C.
(4) preparation of mixture D: stop heating, when temperature is down to room temperature, adds tolylene diisocyanate, N-BUTYL ACETATE, benzophenone and trolamine, stir, obtained mixture D.
(5) finished product: finally add diphenylpolysiloxane, adds water and dilutes, then Keep agitation for some time at 35-45 DEG C, obtains the spray paint of described a kind of anticorrosion environmental protection.
Preferably, described step (1) Heating temperature is to 80-100 DEG C.
Preferably, the component of the water added in described step (5) is 7-9 part.
Preferably, the stirring time length in described step (5) is 35-40min.
Adopt technical scheme of the present invention, color of paint of the present invention is bright-coloured, sun-proof is effective, and the medium chrome yellow medium yellow that can substitute in mineral dye is applicable to the use of exterior coating, and the harm of heavy metal free, it is without any objectionable impurities, and environment protecting is good, taste is little, does not have peculiar smell after having brushed.Gloss of film degree is high, satisfactory mechanical property, electrical insulation capability is superior, moisture resistance waterproof, Rustproof cold-resistant, resistance to ozone ageing, can be widely used in all kinds of copper carving handicraft article of protection, and paint formulation of the present invention is reasonable, processing step is simple, easy to operate, and this process efficiency is high, greatly reduces enterprise cost, improves production efficiency.
Accompanying drawing explanation
Fig. 1 is the process flow sheet of the preparation technology of the spray paint of a kind of anticorrosion environmental protection of the present invention.
Embodiment
Below in conjunction with accompanying drawing, the preferred embodiments of the present invention are described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to the protection domain of invention.
embodiment 1:
A spray paint formula for anticorrosion environmental protection, the component proportioning (mass fraction) of the spray paint formula of described anticorrosion environmental protection comprises 28 parts, Glacial acetic acid, organic fluorine epoxy resin 3 parts, epoxy modified silicone resin liquid 7 parts, ethylene glycol monomethyl ether 2 parts, dimethyl sulfoxide (DMSO) 6 parts, zinc phosphate 8 parts, baryta yellow 8 parts, ethanol 1 part, polyacrylic ester 2 parts, spirit-soluble resin 1 part, diacetone alcohol 7 parts, 6 parts, zinc oxide, tolylene diisocyanate 8 parts, N-BUTYL ACETATE 3 parts, benzophenone 12 parts, trolamine 9 parts and diphenylpolysiloxane 3 parts.
The preparation technology of the spray paint of described anticorrosion environmental protection carries out according to following steps: the preparation of mixture A: get a heatable container, according to the dosage of formula Glacial acetic acid and epoxy modified silicone resin liquid poured into and wherein mix and heat, Heating temperature, to 80 DEG C, obtains mixture A ;the preparation of mixture B: under the condition stirred, then by organic fluorine epoxy resin, ethylene glycol monomethyl ether, zinc phosphate, baryta yellow, ethanol and polyacrylic ester in container, stir, obtained mixture B; The preparation of mixture C: add spirit-soluble resin, diacetone alcohol and zinc oxide again in container, high-speed stirring is even, obtained mixture C; The preparation of mixture D: stop heating, when temperature is down to room temperature, adds tolylene diisocyanate, N-BUTYL ACETATE, benzophenone and trolamine, stir, obtained mixture D; Finished product: finally add diphenylpolysiloxane, adds water and dilutes at 35 DEG C, and the component of the water added is 7 parts, and then Keep agitation for some time, the stirring time length is 35min, obtains the spray paint of described a kind of anticorrosion environmental protection.
embodiment 2:all the other are identical with embodiment 1, and difference is 29 parts, Glacial acetic acid, organic fluorine epoxy resin 4 parts, epoxy modified silicone resin liquid 8 parts, ethylene glycol monomethyl ether 2 parts, dimethyl sulfoxide (DMSO) 7 parts, zinc phosphate 9 parts, baryta yellow 9 parts, ethanol 2 parts, polyacrylic ester 3 parts, spirit-soluble resin 2 parts, diacetone alcohol 8 parts, 7 parts, zinc oxide, tolylene diisocyanate 9 parts, N-BUTYL ACETATE 4 parts, benzophenone 13 parts, trolamine 10 parts and diphenylpolysiloxane 4 parts; In described step (1), Heating temperature is to 85 DEG C; In described step (5), add water and dilute at 40 DEG C, the component of the water added is 8 parts, and then Keep agitation for some time, the stirring time length is 37min.
embodiment 3:all the other are identical with embodiment 1, and difference is 30 parts, described Glacial acetic acid, organic fluorine epoxy resin 5 parts, epoxy modified silicone resin liquid 9 parts, ethylene glycol monomethyl ether 3 parts, dimethyl sulfoxide (DMSO) 8 parts, zinc phosphate 10 parts, baryta yellow 10 parts, ethanol 3 parts, polyacrylic ester 4 parts, spirit-soluble resin 3 parts, diacetone alcohol 9 parts, 8 parts, zinc oxide, tolylene diisocyanate 10 parts, N-BUTYL ACETATE 5 parts, benzophenone 14 parts, trolamine 11 parts and diphenylpolysiloxane 5 parts; In described step (1), Heating temperature is to 90 DEG C; In described step (5), add water and dilute at 45 DEG C, the component of the water added is 9 parts, and then Keep agitation for some time, the stirring time length is 39min.
After above processing step, take out paint sample, to be measured:
From above data, the quality guaranteed period of the paint prepared is more than or equal to 5 years, shelf-life durations is long, point of ignition is more than or equal to 110 degrees Celsius, can not catch fire under normal conditions, avoid the generation of paint fire failure, freezing point is less than or equal to negative 42 degrees Celsius, even if under the environment of cold, paint is also not easy to freeze, and concentration is more than or equal to percent 95, improves the utilization rate of active components of paint, to sum up, this kind of paint can not only protection against corrosion, and energy-conserving and environment-protective, can also be used for spraying simultaneously, preparation technology is simple, is applicable to large batch of production.
Obvious specific implementation of the present invention is not subject to the restrictions described above; as long as have employed the improvement of the various unsubstantialities that method of the present invention is conceived and technical scheme is carried out; or design of the present invention and technical scheme directly applied to other occasion, all within protection scope of the present invention without to improve.

Claims (6)

1. the spray paint formula of an anticorrosion environmental protection, it is characterized in that: the component proportioning (mass fraction) of the spray paint formula of described anticorrosion environmental protection comprises Glacial acetic acid 28-35 part, organic fluorine epoxy resin 3-7 part, epoxy modified silicone resin liquid 7-12 part, ethylene glycol monomethyl ether 2-6 part, dimethyl sulfoxide (DMSO) 6-9 part, zinc phosphate 8-13 part, baryta yellow 8-13 part, ethanol 1-4 part, polyacrylic ester 2-7 part, spirit-soluble resin 1-4 part, diacetone alcohol 7-13 part, zinc oxide 6-9 part, tolylene diisocyanate 8-13 part, N-BUTYL ACETATE 3-7 part, benzophenone 12-16 part, trolamine 9-13 part and diphenylpolysiloxane 3-7 part.
2. the spray paint formula of a kind of anticorrosion environmental protection according to claim 1, it is characterized in that: the component proportioning (mass fraction) of the spray paint formula of described anticorrosion environmental protection comprises 28 parts, Glacial acetic acid, organic fluorine epoxy resin 3 parts, epoxy modified silicone resin liquid 7 parts, ethylene glycol monomethyl ether 2 parts, dimethyl sulfoxide (DMSO) 6 parts, zinc phosphate 8 parts, baryta yellow 8 parts, ethanol 1 part, polyacrylic ester 2 parts, spirit-soluble resin 1 part, diacetone alcohol 7 parts, 6 parts, zinc oxide, tolylene diisocyanate 8 parts, N-BUTYL ACETATE 3 parts, benzophenone 12 parts, trolamine 9 parts and diphenylpolysiloxane 3 parts.
3. the spray paint formula of a kind of anticorrosion environmental protection according to claim 1, is characterized in that: the preparation technology of the spray paint of described anticorrosion environmental protection carries out according to following steps:
The preparation of mixture A: get a heatable container, to pour into Glacial acetic acid and epoxy modified silicone resin liquid according to the dosage of formula and wherein mixes and heat, obtained mixture A; The preparation of mixture B: under the condition stirred, then by organic fluorine epoxy resin, ethylene glycol monomethyl ether, zinc phosphate, baryta yellow, ethanol and polyacrylic ester in container, stir, obtained mixture B; The preparation of mixture C: add spirit-soluble resin, diacetone alcohol and zinc oxide again in container, high-speed stirring is even, obtained mixture C; The preparation of mixture D: stop heating, when temperature is down to room temperature, adds tolylene diisocyanate, N-BUTYL ACETATE, benzophenone and trolamine, stir, obtained mixture D; Finished product: finally add diphenylpolysiloxane, adds water and dilutes, then Keep agitation for some time at 35-45 DEG C, obtains the spray paint of described a kind of anticorrosion environmental protection.
4. the spray paint formula of a kind of anticorrosion environmental protection according to claim 7, is characterized in that: described step (1) Heating temperature is to 80-100 DEG C.
5. the spray paint formula of a kind of anticorrosion environmental protection according to claim 3, is characterized in that: the component of the water added in described step (5) is 7-9 part.
6. the spray paint formula of a kind of anticorrosion environmental protection according to claim 3, is characterized in that: the stirring time length in described step (5) is 35-40min.
CN201510692638.0A 2015-10-23 2015-10-23 Anticorrosive environment-friendly spray paint formula Pending CN105199580A (en)

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107057567A (en) * 2017-06-27 2017-08-18 郑堂玲 A kind of paint formulation containing toluene di-isocyanate(TDI)
CN107083181A (en) * 2017-06-26 2017-08-22 郑堂玲 A kind of paint formulation containing diphenylpolysiloxane
CN107083177A (en) * 2017-06-15 2017-08-22 刘冬明 A kind of corrosion-resistant energy-saving coating and its preparation method and application
CN107090247A (en) * 2017-06-27 2017-08-25 郑堂玲 A kind of paint formulation containing trimellitic anhydride
CN107118691A (en) * 2017-06-27 2017-09-01 郑堂玲 A kind of paint formulation containing water-soluble poval powder
CN107446468A (en) * 2017-08-01 2017-12-08 巢湖鹏远金属焊管有限公司 A kind of acidproof lacquer spraying technique of ERW and its spray painting used
CN107663420A (en) * 2017-10-25 2018-02-06 成都纽兰晶茂商贸有限公司 A kind of preparation method of anti-aging paint
CN107663421A (en) * 2017-10-25 2018-02-06 成都纽兰晶茂商贸有限公司 A kind of formula of anti-aging paint
CN107699019A (en) * 2017-10-25 2018-02-16 成都纽兰晶茂商贸有限公司 A kind of preparation method of anti-corrosion fire-retardant paint
CN107722829A (en) * 2017-10-25 2018-02-23 成都纽兰晶茂商贸有限公司 A kind of wood furniture is painted with flame-proof antibiotic
CN107828257A (en) * 2017-10-25 2018-03-23 成都纽兰晶茂商贸有限公司 A kind of strong paint formulation of anti-corrosion fire resistance property
CN110791177A (en) * 2019-11-14 2020-02-14 徐州金港起重机制造有限公司 Anti-corrosion spraying paint suitable for in-paint machinery

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559630A (en) * 2014-12-30 2015-04-29 青岛佳尚创意文化有限公司 Environment-friendly paint formula
CN104559760A (en) * 2014-12-30 2015-04-29 青岛佳尚创意文化有限公司 Anti-corrosive paint formula

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104559630A (en) * 2014-12-30 2015-04-29 青岛佳尚创意文化有限公司 Environment-friendly paint formula
CN104559760A (en) * 2014-12-30 2015-04-29 青岛佳尚创意文化有限公司 Anti-corrosive paint formula

Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107083177B (en) * 2017-06-15 2019-05-21 佛山市顺德区鸿雨化工科技有限公司 A kind of corrosion-resistant energy-saving coating and its preparation method and application
CN107083177A (en) * 2017-06-15 2017-08-22 刘冬明 A kind of corrosion-resistant energy-saving coating and its preparation method and application
CN107083181A (en) * 2017-06-26 2017-08-22 郑堂玲 A kind of paint formulation containing diphenylpolysiloxane
CN107090247A (en) * 2017-06-27 2017-08-25 郑堂玲 A kind of paint formulation containing trimellitic anhydride
CN107118691A (en) * 2017-06-27 2017-09-01 郑堂玲 A kind of paint formulation containing water-soluble poval powder
CN107057567A (en) * 2017-06-27 2017-08-18 郑堂玲 A kind of paint formulation containing toluene di-isocyanate(TDI)
CN107446468A (en) * 2017-08-01 2017-12-08 巢湖鹏远金属焊管有限公司 A kind of acidproof lacquer spraying technique of ERW and its spray painting used
CN107663420A (en) * 2017-10-25 2018-02-06 成都纽兰晶茂商贸有限公司 A kind of preparation method of anti-aging paint
CN107699019A (en) * 2017-10-25 2018-02-16 成都纽兰晶茂商贸有限公司 A kind of preparation method of anti-corrosion fire-retardant paint
CN107722829A (en) * 2017-10-25 2018-02-23 成都纽兰晶茂商贸有限公司 A kind of wood furniture is painted with flame-proof antibiotic
CN107828257A (en) * 2017-10-25 2018-03-23 成都纽兰晶茂商贸有限公司 A kind of strong paint formulation of anti-corrosion fire resistance property
CN107663421A (en) * 2017-10-25 2018-02-06 成都纽兰晶茂商贸有限公司 A kind of formula of anti-aging paint
CN110791177A (en) * 2019-11-14 2020-02-14 徐州金港起重机制造有限公司 Anti-corrosion spraying paint suitable for in-paint machinery

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Application publication date: 20151230