CN105178550A - Photocatalyst antibacterial silent composite floor and process for manufacturing same - Google Patents
Photocatalyst antibacterial silent composite floor and process for manufacturing same Download PDFInfo
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- CN105178550A CN105178550A CN201510417092.8A CN201510417092A CN105178550A CN 105178550 A CN105178550 A CN 105178550A CN 201510417092 A CN201510417092 A CN 201510417092A CN 105178550 A CN105178550 A CN 105178550A
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Abstract
The invention relates to a photocatalyst antibacterial silent composite floor, and belongs to the field of functional environment-friendly healthful floors. The photocatalyst antibacterial silent composite floor is characterized in that a base material layer is a flame-retardant oriented shaving plate layer; the flame-retardant oriented shaving plate layer comprises an upper surface layer, a lower surface layer, a core shaving layer, a first flame-retardant layer and a second flame-retardant layer, and glue-mixed shaving is longitudinally arranged on the upper surface layer according to fiber directions; a closed cell foam layer, a semi-open cell foam layer, a decoration layer, an abrasion-resistant primer layer and a photocatalyst antibacterial oil decoration layer are sequentially arranged above the base material layer; a balance layer is arranged below the base material layer. A process for manufacturing the photocatalyst antibacterial silent composite floor includes collating the shaving plate layer; preparing glue; primarily distributing the glue and assembling blanks; carrying out primary cold-pressing; finishing cores; secondarily distributing the glue and assembling blanks; carrying out secondary cold-pressing; carrying out primary hot-pressing; carrying out thickness defining sanding; cutting edges; applying putty; carrying out polishing; carrying out sorting; carrying out maintenance; distributing the glue and attaching veneer; carrying out tertiary cold-pressing; carrying out secondary hot-pressing; sawing multiple sheets; carrying out sanding; milling each double ends; applying primer; preparing finish paint; applying the finish paint. The photocatalyst antibacterial silent composite floor and the process have the advantages that the composite floor has an excellent antibacterial function and is high in strength and good in abrasion-resistant property, and users feel comfortable in the feet.
Description
Technical field
The present invention relates to a kind of photo-catalytic antibacterial mute composite floor, belong to field, functional form environment protection health floor.
Background technology
In the dwelling environment of people, there is various volatile organic matter and harmful microorganism, directly affect the physical and mental health of people.In living environment, most of pathogenic bacteria are toward contact to aspects such as ground dirt and pets, and the microorganism growing germ and bacterium directly and human contact, is easilier passed to human body by floor.The antimildew and antibacterial agent of past people chemicals is sprayed at the surrounding in room, solve the air quality problems in room by this, and the toxicity of common antimildew and antibacterial agent is comparatively large, heat-resisting, endurance quality is poor, be sprayed at floor and surface of decorative plate easily makes its variable color and affects attractive in appearance.Along with the requirement of people to domestic environment is more and more higher, the demand on the health environment-friendly floor of functional form is brought into schedule.First very high to the environmental protection class requirement on floor itself, reach without aldehyde level.Next requires floor to have to purify air and antibacterial functions.
CN202467086U(2012-2-29) disclose a kind of photo-catalytic antibacterial floor, but the structure on this floor and performance thereof still have much room for improvement.
Summary of the invention
The object of this invention is to provide a kind of have high-environmental and antibacterial functions, intensity is high, abrasion resistance good, the photo-catalytic antibacterial mute composite floor of comfortable foot feeling.
Above-mentioned technical purpose of the present invention is achieved by the following technical programs:
A kind of photo-catalytic antibacterial mute composite floor, is the layer structure comprising substrate layer, it is characterized in that: the Form aldehyde release limitation < 0.3mg/L of described composite floor board; Antibiotic rate >=90%; Surface abrasion resistance≤0.08g/100r;
Described substrate layer is fire-retardant oriented shaving flaggy;
Described fire-retardant oriented shaving flaggy comprise by glue mixing wood shavings by the upper epidermis of its machine direction longitudinal arrangement, layer, by glue mixing wood shavings by the transversely arranged sandwich layer wood shavings layer of its machine direction, the second flame-retardant layer of being arranged on the first flame-retardant layer between upper epidermis and sandwich layer wood shavings layer and being arranged between layer and sandwich layer wood shavings layer;
Layer is covered or decorate with paint according to apart from described substrate layer layer of closed-cell foam, half open cell foam layer, decorative layer, wear-resistant primer layer and the photo-catalytic antibacterial of comprising at least successively near and far above described substrate layer;
It is nanoscale TiO that described photo-catalytic antibacterial covers or decorate with paint layer
2photocatalyst material, Nano Silver and UV scratch-resistant finish paint in mass ratio 1-2:0.2-0.4:15-20 mix the mixture layer formed;
Balance layer is comprised below described substrate layer;
Described decorative layer is the wood floors fabric of thickness 0.6-4.0mm, and described decorative layer is rotary-cut material, slicing material or sawn timber; Described balance layer is the veneer of thickness 0.3-1.2mm, and described balance layer is rotary-cut material.Antibiotic rate operative norm LY/T1926-2010 of the present invention antibacterial wood (bamboo) quality plate, surface abrasion resistance operative norm GB/T18103-2013 composite floor board.
Nanoscale TiO
2photocatalyst material, produces similar photosynthetic catalytic reaction, the oxygen in air and hydrone is excited under the irradiation of sunshine or visible ray, forms the extremely strong hydroxyl free radical of oxidation capacity and active oxygen.The extremely strong free radical of these oxidation capacities can catch and kill the planktonic bacteria in air, and removes that cigarette is smelly, rubbish is smelly, mud is smelly, and organic pollution is constantly degraded into free of contamination water and carbon dioxide etc., thus reaches the object of environment purification and air.For improving TiO
2the photocatalytic activity of photocatalyst, adopts Nano Silver as active catalyst.Silver in inorganic nano-silver is noble metal, can improve nanoscale TiO by surface deposition
2the photocatalytic activity of photocatalyst material, improves the effect that it is antibacterial.Nano Silver itself has antibacterial action, and silver ion has raising nanoscale TiO simultaneously
2the photocatalysis of photocatalyst material, makes TiO
2photocatalyst material just can produce stronger activity under the visible ray that wavelength is longer, improves the utilization rate of luminous energy.The environment protection health composite antibacterial floor with photo-catalytic antibacterial function made by composite floor board element plate after wear-resistant primer, photocatalyst surface are covered or decorate with paint.
As preferably, described half perforate foamed material layer is half perforate EPDM foam sponge layer or half perforate PVC foam material layer; Described closed cell foamed material layer is EPS foaming, EPE, IXPE, XPE, rubber expanded material, EVA material layer or closed-cell polyethylene modification insulation material layer.
If communicate between hole, be then called perforate.Full open aperture expanded material refers to and all communicates between the hole in material.If each hole and surrounding hole separate completely, be then called closed pore.If hole half perforate semi-closure hole, be then called half perforate foamed material layer.
Set of the present invention half perforate expanded material and the advantage of closed-cell materials layer in sound insulation and noise reduction, adopt MULTILAYER COMPOSITE technology, effectively overcome the shortcoming of each material itself, can solve the noise as high frequency, low frequency, make it effective sound insulation and noise reduction, effectively reduce the noise between floor, can reduce and obviously improve 95% from impact sound (knock that high-heeled shoes or other hard object produce) upstairs, thus improve quality of the life;
Be different from the single differentiation to high frequency noise and low frequency noise of traditional product, the present invention is a transboundary product efficiently.Press test result on year-on-year basis, this invention product can improve more than 2 times than the sound insulation and noise reduction rate of original traditional product.
As preferably, described wear-resistant primer layer is optical curing of UV prime coat, one side coating weight 30-40g/m
2.
As preferably, it is photocuring antimicrobial paint surface layer that described photo-catalytic antibacterial covers or decorate with paint layer, and one side coating weight is 10-14g/m
2.
A production technology for photo-catalytic antibacterial mute composite floor, it comprises the following steps successively:
(1) wood shavings flaggy arranges;
(2) impregnation: preparation living beings rubber made from soybean cake, viscosity controls at 30000-100000cps;
(3) first substandard cloth glue, assembly: the shaving board put in order is carried out even cloth glue, and spread controls at 160-220g/m
2, without flower glue phenomenon;
(4) first time colds pressing: the slab that assembly is good is entered cold press and colds pressing, time controling is at 20-40min;
(5) core finishing: repaired by the slab of having colded pressing, cut off overlap, fills up scarce core gap;
(6) second substandard cloth glue, assembly: the slab having repaiied core is combined again by product thickness and structure;
(7) second time is colded pressing: the slab again combined is carried out precompressed, makes its just one-step forming;
(8) first time hot pressing: the slab of first one-step forming is entered press and carries out hot pressing, glue is solidified completely, slab is completely shaping;
(9) fixed thick sanding: slab is carried out surely thick sanding by setting thickness;
(10) cutting edge: blanket is cut into regulatory specifications size by processing request;
(11) scrape greasy: indentation, the crack place putty homochromy with plate face are filled and led up;
(12) polishing: by further for plate face light weight sand, the putty that sand remains except plate face and thicker burr, guarantee the bright and clean of plate face;
(13) sorting: the substrate after polishing is graded, qualified warehouse-in, underproof doing over again is repaired or is directly divided into substandard products;
(14) health: qualified substrate is put into health preserving room, makes moisture content even;
(15) cloth glue, veneer: the substrate after health sticks decorative layer and balance layer, decorative layer thickness 0.6-4.0mm, balance layer thickness 0.3-1.2mm, one side coating weight 120-200g/m
2, according to the line of base material, musculus cutaneus is pasted onto on base material one by one;
(16) third time colds pressing: the slab posting decorative layer and balance layer is entered cold press and carries out precompressed, pressure 0.8-1.2MPa, time 20-60min, guarantees base material, balance layer, decorative layer energy just one-step forming;
(17) second time hot pressing: the slab of first one-step forming is carried out hot pressing, makes glue curing;
(18) multiple blade saw: cut by line by the slab posting face base plate, obtains required ground laminin plate;
(19) sanding: plain plate is carried out sanding;
(20) two-ends milling machine: the plain plate good to sanding carries out groove milling on request;
(21) priming: the plain plate of complete for milling groove is carried out priming paint and covers or decorate with paint, one side coating weight 30-40g/m
2, and with UV lamp, irradiation solidification is carried out to it, thus make wear-resistant primer face;
(22) finish paint is adjusted: by nanoscale TiO
2photocatalyst material, Nano Silver mix in the ratio of 1-2:0.2-0.4:15-20 with UV scratch-resistant finish paint three, dispersed, make the scratch-resistant UV finish paint with antibacterial functions;
(23) upper finish paint: finish paint process is carried out to the plain plate having gone up priming paint, one side coating weight 10-14g/m
2, and with UV lamp, irradiation solidification is carried out to it, thus make antibacterial lacquer painting;
(24) test package.
The specific technique of employing the present invention can by aqueous inorganic Nano Silver and nanoscale TiO
2photocatalyst material is applied in water-based UV finish paint equably, covers or decorate with paint the surface on floor through roller coating technology, makes environmental protection photo-catalytic antibacterial floor.Adopt living beings rubber made from soybean cake as special adhesive without aldehyde level composite floor substrate, it is made up of auxiliary agent and soy meal, for ensureing its storage life, allocates at the scene during use.It is nanoscale TiO that photocatalyst covers or decorate with paint layer
2the mixture of photocatalyst material, Nano Silver and UV scratch-resistant finish paint, its three according to a certain percentage, carries out high speed by multi-function variable-speed gyratory shaker and fully stirs, disperse uniformly.Nano Silver itself has antibacterial action, and silver ion has the photocatalysis improving nanosized TiO_2 photocatalyst material simultaneously, makes TiO2 photocatalyst material under the visible ray that wavelength is longer, just can produce stronger activity, improves the utilization rate of luminous energy.Living beings rubber made from soybean cake is by auxiliary agent and bean powder through stirring, and the main component of auxiliary agent is water, alkali, polyvinyl alcohol, hexamethyl-epoxy chlorobutane, kaolin, isocyanates etc., and bean powder is that soybean grease processed side product forms through the process such as degreasing, grinding.
As preferably, described step (4) first time colds pressing pressure 0.8-1.2MPa.
As preferably, described step (7) second time is colded pressing pressure 0.8-1.2MPa, and cold pressing time 30-60min.
As preferably, described step (8) hot pressing temperature 110-120 DEG C, hot pressing time: 70-80s/mm, hot pressing pressure 0.8-1.2MPa.
As preferably, during described substrate layer cloth glue, adopt living beings rubber made from soybean cake; Described living beings rubber made from soybean cake comprises the raw material of following mass parts:
100 parts, water;
Soyabean protein powder 15-40 part;
Alkali 3-8 part;
Silicate 0.5-3 part;
Modifier urea 0.2-5 part;
Curing compound polyamide polyamine-epichlorohydrin 0.3-2.5 part;
Acid 0.1-4 part;
Water-borne acrylic resin 0.1-20 part;
Pyrethroid insect-proof agent 0.1-1.5 part;
Filler 1-10 part.
The addition of insect-proof agent of the present invention is through the present inventor and studies for a long period of time gained, this addition coordinates other composition in rubber made from soybean cake, not only can not affect the bond strength of rubber made from soybean cake of the present invention but also good insect protected, antiseptic effect can also be played, more effectively solving existing sheet material and cause product because of the reduction of burst size of methanal easily by defect that worm ant corrodes.Adding of insect-proof agent makes vermins-proof effect lasting, make product possess certain drugloading rate, reach the function of long-acting insect protected, and there is certain antiseptic property, effectively can extend the shelf life of modified soybean glue, prevent rubber made from soybean cake from going bad in advance and affecting the bonding strength of final products.
Rubber made from soybean cake prepared by the present inventor is low containing formaldehyde amount, and soybean protein can be made to have appropriate degree to launch protein molecule, the increase contact area that the protein molecule of this expansion not only can react with other admixture and bonding force is strengthened, and the protein molecule hydrophobic grouping of modification is toward the outside many, be easy to penetrate into need viscose glue product such as timber in, produce stronger adhesive strength and hydrophobicity, thus show good shear strength and water-resistance; Make vermins-proof effect lasting adding of insect-proof agent simultaneously, make product possess certain drugloading rate, reach the function of long-acting insect protected, and there is certain antiseptic property, effectively can extend the shelf life of modified soybean glue, prevent rubber made from soybean cake from going bad in advance and affecting the bonding strength of final products.
As preferably, described pyrethroid insect-proof agent is at least one in cypermethrin, fenvalerate, Permethrin, Biphenthrin and cyphenothrin.
As preferably, described living beings rubber made from soybean cake also comprises the sulphite that mass parts is 0.5-3 part.
The protein adhesive of alkali modification of the present invention also has higher viscosity, and viscosity too conference affect the mobility of bonding adhesive, therefore, the present invention reduces its intermolecular interaction by adding sulphite and then reduces viscosity, because the existence of disulfide bond affects its mounted molecule and extensibility in natural protein molecules, adding sulphite can coordinate silicate to play the intermolecular or intramolecular disulfide bond effect of shearing as reducing agent, thus improve protein molecule surface hydrophobic and foaming characteristic and bubble stability, but disulfide bonds too much can reduce rubber made from soybean cake surface hydrophobic greatly, therefore, the addition of sulphite of the present invention is also through inventor and studies for a long period of time and coordinate other composition jointly to play a role, to ensure the adhesive effect of rubber made from soybean cake.
In sum, the present invention has following beneficial effect:
1, by adopting living beings rubber made from soybean cake as special adhesive, the high-environmental of ground laminin plate is guaranteed.
2, the stable performance of inorganic nano-silver, not volatile, with UV finish paint non-interference.The silver of nanoscale discharges silver ion sustainedly and stably by ionization and enters in bacterial body, thus keeps antibacterial functions for a long time.
3, nanoscale TiO
2photocatalyst material, produces similar photosynthetic catalytic reaction, the oxygen in air and hydrone is excited under the irradiation of sunshine or visible ray, forms the extremely strong hydroxyl free radical of oxidation capacity and active oxygen.The extremely strong free radical of these oxidation capacities can catch and kill the planktonic bacteria in air, and removes that cigarette is smelly, rubbish is smelly, mud is smelly, and organic pollution is constantly degraded into free of contamination water and carbon dioxide etc., thus reaches the object of environment purification and air.
4, the silver in inorganic nano-silver is noble metal, can improve nanoscale TiO by surface deposition
2the photocatalytic activity of photocatalyst material, improves the effect that it is antibacterial.
Accompanying drawing explanation
Fig. 1 is the structural representation of photo-catalytic antibacterial mute composite floor of the present invention;
Fig. 2 is substrate layer structural representation of the present invention.
Detailed description of the invention
Below in conjunction with accompanying drawing, the present invention is described in further detail.
Embodiment one
Prepared by living beings rubber made from soybean cake: in three mouthfuls of round-bottomed flasks, add 3g alkali and 100g water, described alkali is NaOH, stir 3 minutes, NaOH is dissolved, then in alkali lye, add 0.5g silicate, 0.5g sulphite and 0.2g modifier, described silicate is silicate of soda, described modifier is urea, and described sulphite is sulphite sodium, and stirs 3 minutes, temperature is 80-96 DEG C, obtains preliminary mixed solution; Then in described preliminary mixed solution, add the soy-derived product of 15g, described soy-derived product are soybean protein isolate, and stir 10 minutes, temperature is 80 DEG C, makes soybean protein isolate be well dispersed in solution, obtains mixed solution; Then add 0.3g, mass concentration is the aqueous solution of the curing compound polyamide polyamine-epichlorohydrin (PAE) of 12.5%, stirs 10 minutes, obtains solidifying mixed liquor; Then add acid, described acid be 0.1 mass concentration be the phosphoric acid of 35%, stir 5 minutes, obtain the regulator solution that pH value is 6; Then in described adjustment mixed liquor, add 10g water-borne acrylic resin, stir 20 minutes, adjusted mixed liquor.The most backward described adjustment mixed liquor adds 0.1g insect-proof agent and 1g filler, and insect-proof agent is cypermethrin, and filler is kaolin, stirs 10 minutes, pours out i.e. rubber made from soybean cake processed.
The production technology of photo-catalytic antibacterial mute composite floor:
1, wood shavings flaggy arranges;
2, impregnation: preparation living beings rubber made from soybean cake, viscosity controls at 30000-100000cps;
3, the first substandard cloth glue, assembly: the shaving board put in order is carried out even cloth glue, and spread controls at 160-220g/m
2, without flower glue phenomenon;
4, cold pressing: the slab that assembly is good is entered cold press and colds pressing, time controling is at 20min.
5, core finishing: repaired by the slab of having colded pressing, cut off overlap, fills up scarce core gap.
6, cloth glue, assembly: the slab having repaiied core is combined again by product thickness and structure.
7, cold pressing: the slab again combined is carried out precompressed, make its just one-step forming, cold pressing pressure 0.8MPa, the time: 30min;
8, hot pressing: the slab of first one-step forming is entered press and carries out hot pressing, glue is solidified completely, slab is completely shaping.Hot pressing temperature: 110 DEG C, time: 70s/mm, pressure: 0.8MPa;
9, fixed thick sanding: slab is carried out surely thick sanding by setting thickness, and abrasive band is generally 40-60 order, and required thickness is even, and sanding puts in place.
10, cutting edge: blanket is cut into regulatory specifications size by processing request.
11, scrape greasy: indentation, the crack place putty homochromy with plate face are filled and led up.
12, polishing: by further for plate face light weight sand, the putty that sand remains except plate face and thicker burr, guarantee the bright and clean of plate face.
13, sorting: graded by the substrate after polishing, qualified warehouse-in, underproof doing over again is repaired or is directly divided into substandard products.
14, health: qualified substrate is put into health preserving room, makes it moisture content even.
15, cloth glue, veneer: decorative layer and balance layer are sticked, decorative layer thickness 0.6mm, balance layer thickness 0.3mm, the general 120g/m of coating weight to the substrate after health
2(one side), according to the line of base material, is pasted onto on base material one by one by musculus cutaneus.
16, cold pressing: the slab posting decorative layer and balance layer is entered cold press and carries out precompressed, pressure 0.8MPa, time 20min, guarantee that base material, balance layer, decorative layer can first one-step formings.
17, hot pressing: the slab of first one-step forming is carried out hot pressing, makes glue solidify completely and guarantees that its physicochemical property is qualified.
18, multiple blade saw: cut by line by the slab posting face base plate, obtains required ground laminin plate.
19, sanding: plain plate is carried out sanding, abrasive band is generally 100-150 order.
20, two-ends milling machine: the plain plate good to sanding carries out groove milling on request.
21, priming: the plain plate of complete for milling groove is carried out UV wear-resistant primer and covers or decorate with paint, generally needs 6 times, coating weight 30g/m
2, and with UV lamp, irradiation solidification is carried out to it, thus make wear-resistant primer face.
22, finish paint is adjusted: by nanoscale TiO
2photocatalyst material, Nano Silver mix in the ratio of 1:0.4:20 with UV scratch-resistant finish paint three, carry out high speed and fully stir, disperse uniformly, thus make the scratch-resistant UV finish paint with antibacterial functions by multi-function variable-speed gyratory shaker.
23, upper finish paint: finish paint process is carried out to the plain plate having gone up priming paint, general roller coat 2 times, coating weight 10g/m
2, and with UV lamp, irradiation solidification is carried out to it, thus make antibacterial lacquer painting.Both ensure the brightness and plumpness etc. in plate face, give again its antibacterial functions.
24, test package: tested by product standard on the floor of having painted, qualified packaging and warehousing, Packaging Box is indicated kind, title, specification, quantity, look number, environmental protection grade etc.
The composite floor board finally made as depicted in figs. 1 and 2, Form aldehyde release limitation < 0.3mg/L; Antibiotic rate >=90%; Surface abrasion resistance≤0.08g/100r; Substrate layer 1 is fire-retardant oriented shaving flaggy; Substrate layer is fire-retardant oriented shaving flaggy, comprise by glue mixing wood shavings by the upper epidermis 11 of its machine direction longitudinal arrangement, layer 13, by glue mixing wood shavings by the transversely arranged sandwich layer wood shavings layer 12 of its machine direction, the second flame-retardant layer 15 of being arranged on the first flame-retardant layer 14 between upper epidermis and sandwich layer wood shavings layer and being arranged between layer and sandwich layer wood shavings layer.By the bonding of living beings rubber made from soybean cake adhesion coating between each layer of fire-retardant oriented shaving flaggy.Comprise layer of closed-cell foam 5, half open cell foam layer 6, decorative layer 2, wear-resistant primer layer 3 and photo-catalytic antibacterial above substrate layer 1 successively and cover or decorate with paint layer 4.Closed cell foamed material layer 5 is IXPE insulation material layer; Half perforate foamed material layer is half perforate EPDM foam sponge layer.
Decorative layer 2 is the wood floors fabric of thickness 0.6mm, and decorative layer 2 is rotary-cut material, slicing material or sawn timber; Balance layer 0 is the veneer of thickness 0.3mm, and balance layer 0 is rotary-cut material; Wear-resistant primer layer 3 is optical curing of UV prime coat, one side coating weight 30g/m
2; Photo-catalytic antibacterial covers or decorate with paint layer 4 for photocuring antimicrobial paint surface layer, and one side coating weight is 10g/m
2.Antibiotic rate meets the antibacterial wood of standard LY/T1926-2010 (bamboo) quality plate, and surface abrasion resistance meets standard GB/T18103-2013.
Embodiment two
Prepared by living beings rubber made from soybean cake: in three mouthfuls of round-bottomed flasks, add 8g alkali and 100g water, alkali is NaOH, stir 10 minutes, NaOH is dissolved, then in alkali lye, add 3g silicate, 3g sulphite and 5g modifier, silicate is silicate of soda, modifier is urea, and sulphite is sulphite sodium, and stirs 10 minutes, temperature is 96 DEG C, obtains preliminary mixed solution; Then in preliminary mixed solution, add the soy-derived product of 40g, soy-derived product are soybean protein isolate, and stir 60 minutes, temperature is 96 DEG C, makes soybean protein isolate be well dispersed in solution, obtains mixed solution; Then add 2.5g, mass concentration is the aqueous solution of the curing compound polyamide polyamine-epichlorohydrin (PAE) of 12.5%, stirs 60 minutes, obtains solidifying mixed liquor; Then add acid, acid is the mass concentration of 4g is the phosphoric acid of 35%, stirs 10 minutes, obtains the regulator solution that pH value is 8; Then in adjustment mixed liquor, add 20g water-borne acrylic resin, stir 40 minutes, adjusted mixed liquor.The most backward adjustment mixed liquor adds 1.5g insect-proof agent and 10g filler, and insect-proof agent is cypermethrin, and filler is kaolin, stirs 30 minutes, pours out i.e. rubber made from soybean cake processed.
The production technology of photo-catalytic antibacterial mute composite floor:
1, wood shavings flaggy arranges;
2, impregnation: preparation living beings rubber made from soybean cake, viscosity controls at 30000-100000cps;
3, the first substandard cloth glue, assembly: the shaving board put in order is carried out even cloth glue, and spread controls at 160-220g/m
2, without flower glue phenomenon;
4, cold pressing: the slab that assembly is good is entered cold press and colds pressing, time controling is at 40min.
5, core finishing: repaired by the slab of having colded pressing, cut off overlap, fills up scarce core gap.
6, cloth glue, assembly: the slab having repaiied core is combined again by product thickness and structure.
7, cold pressing: the slab again combined is carried out precompressed, make its just one-step forming, cold pressing pressure 1.2MPa, the time: 60min;
8, hot pressing: the slab of first one-step forming is entered press and carries out hot pressing, glue is solidified completely, slab is completely shaping.Hot pressing temperature: 120 DEG C, time: 80s/mm, pressure: 1.2MPa;
9, fixed thick sanding: slab is carried out surely thick sanding by setting thickness, and abrasive band is generally 40-60 order, and required thickness is even, and sanding puts in place.
10, cutting edge: blanket is cut into regulatory specifications size by processing request.
11, scrape greasy: indentation, the crack place putty homochromy with plate face are filled and led up.
12, polishing: by further for plate face light weight sand, the putty that sand remains except plate face and thicker burr, guarantee the bright and clean of plate face.
13, sorting: graded by the substrate after polishing, qualified warehouse-in, underproof doing over again is repaired or is directly divided into substandard products.
14, health: qualified substrate is put into health preserving room, makes it moisture content even.
15, cloth glue, veneer: decorative layer and balance layer are sticked, decorative layer thickness 4.0mm, balance layer thickness 1.2mm, the general 200g/m of coating weight to the substrate after health
2(one side), according to the line of base material, is pasted onto on base material one by one by musculus cutaneus.
16, cold pressing: the slab posting decorative layer and balance layer is entered cold press and carries out precompressed, pressure 1.2MPa, time 60min, guarantee that base material, balance layer, decorative layer can first one-step formings.
17, hot pressing: the slab of first one-step forming is carried out hot pressing, makes glue solidify completely and guarantees that its physicochemical property is qualified.
18, multiple blade saw: cut by line by the slab posting face base plate, obtains required ground laminin plate.
19, sanding: plain plate is carried out sanding, abrasive band is generally 100-150 order.
20, two-ends milling machine: the plain plate good to sanding carries out groove milling on request.
21, priming: the plain plate of complete for milling groove is carried out priming paint and covers or decorate with paint, generally needs 6 times, coating weight 40g/m
2, and with UV lamp, irradiation solidification is carried out to it, thus make wear-resistant primer face.
22, finish paint is adjusted: by nanoscale TiO
2photocatalyst material, Nano Silver mix in the ratio of 2:0.2:15 with UV scratch-resistant finish paint three, carry out high speed and fully stir, disperse uniformly, thus make the scratch-resistant UV finish paint with antibacterial functions by multi-function variable-speed gyratory shaker.
23, upper finish paint: finish paint process is carried out to the plain plate having gone up priming paint, general roller coat 2 times, coating weight 14g/m
2, and with UV lamp, irradiation solidification is carried out to it, thus make antibacterial lacquer painting.Both ensure the brightness and plumpness etc. in plate face, give again its antibacterial functions.
24, test package: tested by product standard on the floor of having painted, qualified packaging and warehousing, Packaging Box is indicated kind, title, specification, quantity, look number, environmental protection grade etc.
The composite floor board finally made as depicted in figs. 1 and 2, Form aldehyde release limitation < 0.3mg/L; Antibiotic rate >=90%; Surface abrasion resistance≤0.08g/100r; Substrate layer 1 is fire-retardant oriented shaving flaggy; Substrate layer is fire-retardant oriented shaving flaggy, comprise by glue mixing wood shavings by the upper epidermis 11 of its machine direction longitudinal arrangement, layer 13, by glue mixing wood shavings by the transversely arranged sandwich layer wood shavings layer 12 of its machine direction, the second flame-retardant layer 15 of being arranged on the first flame-retardant layer 14 between upper epidermis and sandwich layer wood shavings layer and being arranged between layer and sandwich layer wood shavings layer.By the bonding of living beings rubber made from soybean cake adhesion coating between each layer of fire-retardant oriented shaving flaggy.Comprise layer of closed-cell foam 5, half open cell foam layer 6, decorative layer 2, wear-resistant primer layer 3 and photo-catalytic antibacterial above substrate layer 1 successively and cover or decorate with paint layer 4.Closed cell foamed material layer 5 is rubber expanded material layer; Half perforate foamed material layer is half perforate PVC foam material layer.
Decorative layer is the wood floors fabric of thickness 4.0mm, and decorative layer is rotary-cut material, slicing material or sawn timber; Balance layer is the veneer of thickness 1.2mm, and balance layer is rotary-cut material; Wear-resistant primer layer is optical curing of UV prime coat, one side coating weight 40g/m
2; It is photocuring antimicrobial paint surface layer that photo-catalytic antibacterial covers or decorate with paint layer, and one side coating weight is 14g/m
2.Antibiotic rate meets the antibacterial wood of standard LY/T1926-2010 (bamboo) quality plate, and surface abrasion resistance meets standard GB/T18103-2013.
Embodiment three
Prepared by living beings rubber made from soybean cake: in three mouthfuls of round-bottomed flasks, add 5g alkali and 100g water, alkali is NaOH, stir 6 minutes, NaOH is dissolved, then in alkali lye, add 2g silicate, 2g sulphite and 2g modifier, silicate is silicate of soda, modifier is urea, and sulphite is sulphite sodium, and stirs 6 minutes, temperature is 90 DEG C, obtains preliminary mixed solution; Then in preliminary mixed solution, add the soy-derived product of 25g, soy-derived product are soybean protein isolate, and stir 30 minutes, temperature is 90 DEG C, makes soybean protein isolate be well dispersed in solution, obtains mixed solution; Then add 3g, mass concentration is the aqueous solution of the curing compound polyamide polyamine-epichlorohydrin (PAE) of 12.5%, stirs 30 minutes, obtains solidifying mixed liquor; Then add acid, acid is the mass concentration of 2g is the phosphoric acid of 35%, stirs 7 minutes, obtains the regulator solution that pH value is 7; Then in adjustment mixed liquor, add 15g water-borne acrylic resin, stir 30 minutes, adjusted mixed liquor.The most backward adjustment mixed liquor adds 1g insect-proof agent and 5g filler, and insect-proof agent is cypermethrin, and filler is kaolin, stirs 20 minutes, pours out i.e. rubber made from soybean cake processed.
The production technology of photo-catalytic antibacterial mute composite floor:
1, wood shavings flaggy arranges;
2, impregnation: preparation living beings rubber made from soybean cake, viscosity controls at 30000-100000cps;
3, the first substandard cloth glue, assembly: the shaving board put in order is carried out even cloth glue, and spread controls at 160-220g/m
2, without flower glue phenomenon;
4, cold pressing: the slab that assembly is good is entered cold press and colds pressing, time controling is at 30min.
5, core finishing: repaired by the slab of having colded pressing, cut off overlap, fills up scarce core gap.
6, cloth glue, assembly: the slab having repaiied core is combined again by product thickness and structure.
7, cold pressing: the slab again combined is carried out precompressed, make its just one-step forming, cold pressing pressure 0.9MPa, the time: 40min;
8, hot pressing: the slab of first one-step forming is entered press and carries out hot pressing, glue is solidified completely, slab is completely shaping.Hot pressing temperature: 115 DEG C, time: 75s/mm, pressure: 1.1MPa;
9, fixed thick sanding: slab is carried out surely thick sanding by setting thickness, and abrasive band is generally 40-60 order, and required thickness is even, and sanding puts in place.
10, cutting edge: blanket is cut into regulatory specifications size by processing request.
11, scrape greasy: indentation, the crack place putty homochromy with plate face are filled and led up.
12, polishing: by further for plate face light weight sand, the putty that sand remains except plate face and thicker burr, guarantee the bright and clean of plate face.
13, sorting: graded by the substrate after polishing, qualified warehouse-in, underproof doing over again is repaired or is directly divided into substandard products.
14, health: qualified substrate is put into health preserving room, makes it moisture content even.
15, cloth glue, veneer: decorative layer and balance layer are sticked, decorative layer thickness 3.0mm, balance layer thickness 0.9mm, the general 190g/m of coating weight to the substrate after health
2(one side), according to the line of base material, is pasted onto on base material one by one by musculus cutaneus.
16, cold pressing: the slab posting decorative layer and balance layer is entered cold press and carries out precompressed, pressure 0.9MPa, time 40min, guarantee that base material, balance layer, decorative layer can first one-step formings.
17, hot pressing: the slab of first one-step forming is carried out hot pressing, makes glue solidify completely and guarantees that its physicochemical property is qualified.
18, multiple blade saw: cut by line by the slab posting face base plate, obtains required ground laminin plate.
19, sanding: plain plate is carried out sanding, abrasive band is generally 100-150 order.
20, two-ends milling machine: the plain plate good to sanding carries out groove milling on request.
21, priming: the plain plate of complete for milling groove is carried out UV wear-resistant primer and covers or decorate with paint, generally needs 6 times, coating weight 35g/m
2, and with UV lamp, irradiation solidification is carried out to it, thus make wear-resistant primer face.
22, finish paint is adjusted: by nanoscale TiO
2photocatalyst material, Nano Silver mix in the ratio of 1.5:0.3:18 with UV scratch-resistant finish paint three, carry out high speed and fully stir, disperse uniformly, thus make the scratch-resistant UV finish paint with antibacterial functions by multi-function variable-speed gyratory shaker.
23, upper finish paint: finish paint process is carried out to the plain plate having gone up priming paint, general roller coat 2 times, coating weight 11g/m
2, and with UV lamp, irradiation solidification is carried out to it, thus make antibacterial lacquer painting.Both ensure the brightness and plumpness etc. in plate face, give again its antibacterial functions.
24, test package: tested by product standard on the floor of having painted, qualified packaging and warehousing, Packaging Box is indicated kind, title, specification, quantity, look number, environmental protection grade etc.
The composite floor board finally made as depicted in figs. 1 and 2, Form aldehyde release limitation < 0.3mg/L; Antibiotic rate >=90%; Surface abrasion resistance≤0.08g/100r; Substrate layer 1 is fire-retardant oriented shaving flaggy; Substrate layer is fire-retardant oriented shaving flaggy, comprise by glue mixing wood shavings by the upper epidermis 11 of its machine direction longitudinal arrangement, layer 13, by glue mixing wood shavings by the transversely arranged sandwich layer wood shavings layer 12 of its machine direction, the second flame-retardant layer 15 of being arranged on the first flame-retardant layer 14 between upper epidermis and sandwich layer wood shavings layer and being arranged between layer and sandwich layer wood shavings layer.By the bonding of living beings rubber made from soybean cake adhesion coating between each layer of fire-retardant oriented shaving flaggy.Comprise layer of closed-cell foam 5, half open cell foam layer 6, decorative layer 2, wear-resistant primer layer 3 and photo-catalytic antibacterial above substrate layer 1 successively and cover or decorate with paint layer 4.Closed cell foamed material layer 5 is EPS foaming sound-proof material layer; Half perforate foamed material layer is half perforate EPDM foam sponge layer.
Decorative layer is the wood floors fabric of thickness 3.0mm, and decorative layer is rotary-cut material, slicing material or sawn timber; Balance layer is the veneer of thickness 0.9mm, and balance layer is rotary-cut material; Wear-resistant primer layer is optical curing of UV prime coat, one side coating weight 35g/m
2; It is photocuring antimicrobial paint surface layer that photo-catalytic antibacterial covers or decorate with paint layer, and one side coating weight is 11g/m
2.Antibiotic rate meets the antibacterial wood of standard LY/T1926-2010 (bamboo) quality plate, and surface abrasion resistance meets standard GB/T18103-2013.
This specific embodiment is only explanation of the invention; it is not limitation of the present invention; those skilled in the art can make to the present embodiment the amendment not having creative contribution as required after reading this manual, as long as but be all subject to the protection of Patent Law in right of the present invention.
Claims (10)
1. a photo-catalytic antibacterial mute composite floor, is the layer structure comprising substrate layer, it is characterized in that: the Form aldehyde release limitation < 0.3mg/L of described composite floor board; Antibiotic rate >=90%; Surface abrasion resistance≤0.08g/100r;
Described substrate layer is fire-retardant oriented shaving flaggy;
Described fire-retardant oriented shaving flaggy comprise by glue mixing wood shavings by the upper epidermis of its machine direction longitudinal arrangement, layer, by glue mixing wood shavings by the transversely arranged sandwich layer wood shavings layer of its machine direction, the second flame-retardant layer of being arranged on the first flame-retardant layer between upper epidermis and sandwich layer wood shavings layer and being arranged between layer and sandwich layer wood shavings layer;
Layer is covered or decorate with paint according to apart from described substrate layer layer of closed-cell foam, half open cell foam layer, decorative layer, wear-resistant primer layer and the photo-catalytic antibacterial of comprising at least successively near and far above described substrate layer;
It is nanoscale TiO that described photo-catalytic antibacterial covers or decorate with paint layer
2photocatalyst material, Nano Silver and UV scratch-resistant finish paint in mass ratio 1-2:0.2-0.4:15-20 mix the mixture layer formed;
Balance layer is comprised below described substrate layer;
Described decorative layer is the wood floors fabric of thickness 0.6-4.0mm, and described decorative layer is rotary-cut material, slicing material or sawn timber; Described balance layer is the veneer of thickness 0.3-1.2mm, and described balance layer is rotary-cut material.
2. a kind of photo-catalytic antibacterial mute composite floor according to claim 1, is characterized in that: described closed cell foamed material layer is EPS foaming, EPE, IXPE, XPE, rubber expanded material, EVA material layer or closed-cell polyethylene modification insulation material layer; Described half perforate foamed material layer is half perforate EPDM foam sponge layer or half perforate PVC foam material layer.
3. a kind of photo-catalytic antibacterial mute composite floor according to claim 2, is characterized in that: described wear-resistant primer layer is optical curing of UV prime coat, one side coating weight 30-40g/m
2.
4. a kind of photo-catalytic antibacterial mute composite floor according to claim 3, is characterized in that: it is photocuring antimicrobial paint surface layer that described photo-catalytic antibacterial covers or decorate with paint layer, and one side coating weight is 10-14g/m
2.
5. the production technology of a kind of photo-catalytic antibacterial mute composite floor according to any one of claim 1-4, is characterized in that comprising the following steps successively:
(1) wood shavings flaggy arranges;
(2) impregnation: preparation living beings rubber made from soybean cake, viscosity controls at 30000-100000cps;
(3) first substandard cloth glue, assembly: the shaving board put in order is carried out even cloth glue, and spread controls at 160-220g/m
2, without flower glue phenomenon;
(4) first time colds pressing: the slab that assembly is good is entered cold press and colds pressing, time controling is at 20-40min;
(5) core finishing: repaired by the slab of having colded pressing, cut off overlap, fills up scarce core gap;
(6) second substandard cloth glue, assembly: the slab having repaiied core is combined again by product thickness and structure;
(7) second time is colded pressing: the slab again combined is carried out precompressed, makes its just one-step forming;
(8) first time hot pressing: the slab of first one-step forming is entered press and carries out hot pressing, glue is solidified completely, slab is completely shaping;
(9) fixed thick sanding: slab is carried out surely thick sanding by setting thickness;
(10) cutting edge: blanket is cut into regulatory specifications size by processing request;
(11) scrape greasy: indentation, the crack place putty homochromy with plate face are filled and led up;
(12) polishing: by further for plate face light weight sand, the putty that sand remains except plate face and thicker burr, guarantee the bright and clean of plate face;
(13) sorting: the substrate after polishing is graded, qualified warehouse-in, underproof doing over again is repaired or is directly divided into substandard products;
(14) health: qualified substrate is put into health preserving room, makes moisture content even;
(15) cloth glue, veneer: the substrate after health sticks decorative layer and balance layer, decorative layer thickness 0.6-4.0mm, balance layer thickness 0.3-1.2mm, one side coating weight 120-200g/m
2, according to the line of base material, musculus cutaneus is pasted onto on base material one by one;
(16) third time colds pressing: the slab posting decorative layer and balance layer is entered cold press and carries out precompressed, pressure 0.8-1.2MPa, time 20-60min, guarantees base material, balance layer, decorative layer energy just one-step forming;
(17) second time hot pressing: the slab of first one-step forming is carried out hot pressing, makes glue curing;
(18) multiple blade saw: cut by line by the slab posting face base plate, obtains required ground laminin plate;
(19) sanding: plain plate is carried out sanding;
(20) two-ends milling machine: the plain plate good to sanding carries out groove milling on request;
(21) priming: the plain plate of complete for milling groove is carried out priming paint and covers or decorate with paint, one side coating weight 30-40g/m
2, and with UV lamp, irradiation solidification is carried out to it, thus make wear-resistant primer face;
(22) finish paint is adjusted: by nanoscale TiO
2photocatalyst material, Nano Silver mix in the ratio of 1-2:0.2-0.4:15-20 with UV scratch-resistant finish paint three, dispersed, make the scratch-resistant UV finish paint with antibacterial functions;
(23) upper finish paint: finish paint process is carried out to the plain plate having gone up priming paint, one side coating weight 10-14g/m
2, and with UV lamp, irradiation solidification is carried out to it, thus make antibacterial lacquer painting; Photo-catalytic antibacterial mute composite floor needed for final acquisition.
6. the production technology of a kind of photo-catalytic antibacterial mute composite floor according to claim 5, is characterized in that: described step (7) is colded pressing pressure 0.8-1.2MPa, and cold pressing time 30-60min.
7. the production technology of a kind of photo-catalytic antibacterial mute composite floor according to claim 5, is characterized in that: described step (8) hot pressing temperature 110-120 DEG C, hot pressing time: 70-80s/mm, hot pressing pressure 0.8-1.2MPa.
8. a kind of photo-catalytic antibacterial mute composite floor according to claim 7, is characterized in that: adopt living beings rubber made from soybean cake during described substrate layer cloth glue; Described living beings rubber made from soybean cake comprises the raw material of following mass parts:
100 parts, water;
Soyabean protein powder 15-40 part;
Alkali 3-8 part;
Silicate 0.5-3 part;
Modifier urea 0.2-5 part;
Curing compound polyamide polyamine-epichlorohydrin 0.3-2.5 part;
Acid 0.1-4 part;
Water-borne acrylic resin 0.1-20 part;
Pyrethroid insect-proof agent 0.1-1.5 part;
Filler 1-10 part.
9. a kind of photo-catalytic antibacterial mute composite floor according to claim 7, is characterized in that: described pyrethroid insect-proof agent is at least one in cypermethrin, fenvalerate, Permethrin, Biphenthrin and cyphenothrin.
10. a kind of photo-catalytic antibacterial mute composite floor according to claim 9, is characterized in that: described living beings rubber made from soybean cake also comprises the sulphite that mass parts is 0.5-3 part.
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