Summary of the invention
Last object of the present invention is for above-mentioned the deficiencies in the prior art, provides that a kind of toughness is high, graphite pebbles rate is high, simultaneously low, the not easy fracture or occur crackle and mechanical property is better of cost of manufacture, and heat treatable truck hub ductile cast iron material.
After of the present invention an object be to provide a kind of simple to operate, be convenient to implement and can the method for the above-mentioned truck hub ductile cast iron material of preparation of industrialized mass production.
Last technical scheme of the present invention is achieved in that a kind of truck hub ductile cast iron material, and this material mainly comprises the Chemical Composition of following mass percent: C:2.50 ~ 3.60%, Si:2.20 ~ 3.20%, Mn:0.45 ~ 1.20%, S :≤0.02%, P :≤0.03%, Cr:0.30 ~ 0.5%, Cu:0.35 ~ 0.55%, Mg:0.02 ~ 0.04%, RE:0.04 ~ 0.08%, Bi:0.01 ~ 0.06%, La:0.01 ~ 0.05%, surplus is iron.
In above-mentioned truck hub ductile cast iron material, this material mainly comprises the Chemical Composition of following mass percent: C:3.0 ~ 3.5%, Si:2.5 ~ 3.10%, Mn:0.50 ~ 1.10%, S :≤0.02%, P :≤0.03%, Cr:0.32 ~ 0.45%, Cu:0.40 ~ 0.45%, Mg:0.02 ~ 0.03%, RE:0.04 ~ 0.07%, Bi:0.03 ~ 0.06%, La:0.01 ~ 0.03%, surplus is iron.
In above-mentioned truck hub ductile cast iron material, this material also comprises the Chemical Composition of following mass percent: Mo:0.35 ~ 0.40%, Sb:0.002 ~ 0.006%.
In above-mentioned truck hub ductile cast iron material, this material also comprises the Chemical Composition of following mass percent: Mo:0.36 ~ 0.40%, Sb:0.004 ~ 0.006%.
In above-mentioned truck hub ductile cast iron material, this material also comprises the Chemical Composition of following mass percent: Ni:0.2 ~ 0.8%.
In above-mentioned truck hub ductile cast iron material, this material also comprises the Chemical Composition of following mass percent: Ni:0.25 ~ 0.70%.
After of the present invention, a technical scheme is achieved in that a kind of preparation method of truck hub ductile cast iron material, and the method comprises the steps:
(1) Smelting of iron: according to the good starting material of formulated, the starting material prepared are placed in medium-frequency induction furnace and add hot smelting, come out of the stove when iron liquid is heated to 1470 ~ 1550 DEG C;
(2) spheroidization and inoculation: adopt and pour method spheroidization and inoculation, nodulizing agent is placed in after bottom casting ladle, coverage inoculator above it, then cover raw scrap material compression, finally pour iron liquid again, spheroidization and inoculation 35 ~ 40 seconds obtained ductile iron liquid; Poured into when temperature 1360 ~ 1420 DEG C by above-mentioned ductile iron liquid in the sand mold adopting consecutive solidification principle to make in advance, the duration of pouring is 30 ~ 40 seconds, forms foundry goods after shaping cooling.
In the preparation method of above-mentioned truck hub ductile cast iron material, the nodulizing agent described in step (2) is FeSiMg7RE nodulizing agent, and add-on is 1.0 ~ 1.5% of raw material total mass.
In the preparation method of above-mentioned truck hub ductile cast iron material, the nucleating agent described in step (2) is HY-75Ba3 nucleating agent, and add-on is 0.5 ~ 1.2% of raw material total mass.
After the present invention adopts technique scheme, compared with existing ductile cast iron material and preparation method, there is following significant beneficial effect:
(1) the present invention is on the existing composition proportion basis of spheroidal graphite cast iron, and add the alloying element of appropriate amount as Sb, Cu and rare-earth elements La, the existing performance improving magnesium iron reaches and then optimizes the effect of its mechanical property.Rare-earth elements La Main Function refinement graphite also improves its shape.Further, in ductile iron material, add the Sb of trace, play refinement graphite, improve graphite form, suppress to occur chunky graphite in thick and large section, the Sb of trace can make the graphite pebbles in truck hub spheroidal graphite cast iron become rounding more; Meanwhile, the acting in conjunction of Sb and La element, adds appropriate La, and in magnesium iron, graphite pebbles obviously attenuates little, is evenly distributed, and the isolate effect of graphite to matrix obviously reduces, and significantly improves the mechanical property of magnesium iron.The Sb amount of adding in the application, be far smaller than its conventional addition, but experiment proves, adds the Sb of trace, considerably improve the performance of whole ductile cast iron material in the present invention's formula.
Meanwhile, preferably, the Ni of appropriate amount is added, Ni well promotes perlite effect, and it is obvious that appropriate Ni improves cast iron mechanical property, avoids the undesirable action because segregation causes, improve the homogeneity of the tissue of large section casting parts, intensity and hardness simultaneously, reduce sensitivity profile.
(2) adjust rare earth element and add the comprehensive mechanical property that nickel element mainly improves truck hub ductile cast iron material, being applicable to industrialized mass production, reducing defect and occur;
(3) Cr of trace is strong stabilizing pearlite, and preferably, add suitable Mo, Mo mainly improves as-cast pearlitic and ferritic microhardness, and meanwhile, Mo can stablize and refine pearlite, makes cast iron materials performance more excellent.
(4) the inventive method utilizes unselected clay sand molding, places dark chill and guarantees consecutive solidification, casting after mould drying in die cavity, can mass production wheel hub.
(5) the wheel hub ductile cast iron material using present component proportioning and preparation method to prepare has good mechanical property, can meet the performance requirement of wheel hub to intensity, antifatigue and hardness.Have and there is certain toughness, ensure safety requirements that is not cracked in using and that break.
Embodiment
Below in conjunction with embodiment, the present invention is described in further detail, but do not form any limitation of the invention.
A kind of truck hub ductile cast iron material of the present invention, this material mainly comprises the Chemical Composition of following mass percent: C:2.50 ~ 3.60%, Si:2.20 ~ 3.20%, Mn:0.45 ~ 1.20%, S :≤0.02%, P :≤0.03%, Cr:0.30 ~ 0.5%, Cu:0.35 ~ 0.55%, Mg:0.02 ~ 0.04%, RE:0.04 ~ 0.08%, Bi:0.01 ~ 0.06%, La:0.01 ~ 0.05%, surplus is iron.
Preferably, this material mainly comprises the Chemical Composition of following mass percent: C:3.0 ~ 3.5%, Si:2.5 ~ 3.10%, Mn:0.50 ~ 1.10%, S :≤0.02%, P :≤0.03%, Cr:0.32 ~ 0.45%, Cu:0.40 ~ 0.45%, Mg:0.02 ~ 0.03%, RE:0.04 ~ 0.07%, Bi:0.03 ~ 0.06%, La:0.01 ~ 0.03%, surplus is iron.
Further, for improving the mechanical property of product, this material also comprises the Chemical Composition of following mass percent: Mo:0.35 ~ 0.40%, Sb:0.002 ~ 0.006%.The preferable range of above-mentioned Chemical Composition is Mo:0.36 ~ 0.40%, Sb:0.004 ~ 0.006%.
Meanwhile, this material also comprises the Chemical Composition of following mass percent: Ni:0.2 ~ 0.8%.The preferable range of this Chemical Composition is Ni:0.25 ~ 0.70%.
The preparation method of a kind of truck hub ductile cast iron material of the present invention, the method comprises the steps:
(1) Smelting of iron: according to formulated low-sulfur high duty pig iron, ferromanganese, cast iron foundry returns and steel scrap, the starting material prepared are placed in medium-frequency induction furnace and add hot smelting, come out of the stove when iron liquid is heated to 1470 ~ 1550 DEG C;
(2) spheroidization and inoculation: adopt and pour method spheroidization and inoculation, nodulizing agent is placed in after bottom casting ladle, coverage inoculator above it, finally pours iron liquid again, spheroidization and inoculation 35 ~ 40 seconds obtained ductile iron liquid; Poured into when temperature 1360 ~ 1420 DEG C by above-mentioned ductile iron liquid in the sand mold adopting consecutive solidification principle to make in advance, the duration of pouring is 30 ~ 40 seconds, forms foundry goods after shaping cooling.Wherein said nodulizing agent is FeSiMg7RE nodulizing agent, and add-on is 1.0 ~ 1.5% of raw material total mass.Described nucleating agent is HY-75Ba3 nucleating agent, and add-on is 0.5 ~ 1.2% of raw material total mass.
Embodiment 1
Formula (composition and mass percent): C:3.38%, Si:3.06%, Mn:0.52%, S:0.009%, P:0.018%, Cr:0.35%, Cu:0.42%, Mo:0.37%, Mg:0.022%, RE:0.055%, Sb:0.0042%, Bi:0.032%, Ni:0.27%, La:0.023%, surplus is iron.
Preparation method: (1) Smelting of iron: alloy raw material such as the preparation pig iron, ferromanganese etc., medium-frequency induction furnace adds hot smelting, treats that iron liquid is heated to 1520 DEG C and comes out of the stove;
(2) iron liquid spheroidization and inoculation process: adopt and pour method spheroidization and inoculation technique, FeSiMg7RE type rare earth magnesium nodularizer is placed in after bottom casting ladle, after covering HY-75Ba3 type nucleating agent above it, finally pouring iron liquid, spheroidization and inoculation 40 seconds obtained ductile iron liquid; Poured into when temperature 1400 DEG C by above-mentioned ductile iron liquid in the sand mold adopting consecutive solidification principle to make in advance, 35 seconds durations of pouring, shaping cooling, forms foundry goods.Obtain the ductile cast iron material of truck hub of the present invention.Performance is in table 1.
Embodiment 2
Formula (composition and mass percent): C:3.0%, Si:2.5%, Mn:0.5%, S:0.016%, P:0.015%, Cu:0.40%, Cr:0.32%, Mo:0.36%, Mg:0.02%, RE:0.04%, Sb:0.004%, Bi:0.03%, Ni0.25%, La:0.01%, surplus is iron.
Preparation method: (1) Smelting of iron: alloy raw material such as the preparation pig iron, ferromanganese etc., medium-frequency induction furnace adds hot smelting, treats that iron liquid is heated to 1510 DEG C and comes out of the stove;
(2) iron liquid spheroidization and inoculation process: adopt and pour method spheroidization and inoculation technique, FeSiMg7RE type rare earth magnesium nodularizer is placed in after bottom casting ladle, after covering HY-75Ba3 type nucleating agent above it, finally pouring iron liquid, spheroidization and inoculation 35 seconds obtained ductile iron liquid; Poured into when temperature 1380 DEG C by above-mentioned ductile iron liquid in the sand mold adopting consecutive solidification principle to make in advance, 30 seconds durations of pouring, shaping cooling, forms foundry goods.Obtain the ductile cast iron material of truck hub of the present invention.Performance is in table 1.
Embodiment 3
Formula (composition and mass percent): C:3.5%, Si:3.10%, Mn:1.10%, S:0.02%, P:0.03%, Cr:0.45%, Cu:0.45%, Mo:0.40%, Mg:0.03%, RE0.07%, Sb:0.006%, Bi:0.06%, Ni:0.70%, La:0.03%, surplus is iron.
Preparation method: (1) Smelting of iron: alloy raw material such as the preparation pig iron, ferromanganese etc., medium-frequency induction furnace adds hot smelting, treats that iron liquid is heated to 1490 DEG C and comes out of the stove;
(2) iron liquid spheroidization and inoculation process: adopt and pour method spheroidization and inoculation technique, FeSiMg7RE type rare earth magnesium nodularizer is placed in after bottom casting ladle, after covering HY-75Ba3 type nucleating agent above it, finally pouring iron liquid, spheroidization and inoculation 36 seconds obtained ductile iron liquid; Poured into when temperature 1360 DEG C by above-mentioned ductile iron liquid in the sand mold adopting consecutive solidification principle to make in advance, 32 seconds durations of pouring, shaping cooling, forms foundry goods.Obtain the ductile cast iron material of truck hub of the present invention.Performance is in table 1.
Table 1 embodiment performance
Embodiment 4
Formula (composition and mass percent): C:3.33%, Si:2.72%, Mn:0.62%, S:0.016%, P:0.015%, Cu:0.45%, Cr:0.38%, Mg:0.024%, RE:0.06%, Bi:0.035%, Ni0.34%, La:0.013%, surplus is iron.
Preparation method: (1) Smelting of iron: alloy raw material such as the preparation pig iron, ferromanganese etc., medium-frequency induction furnace adds hot smelting, treats that iron liquid is heated to 1550 DEG C and comes out of the stove;
(2) iron liquid spheroidization and inoculation process: adopt and pour method spheroidization and inoculation technique, FeSiMg7RE type rare earth magnesium nodularizer is placed in after bottom casting ladle, after covering HY-75Ba3 type nucleating agent above it, finally pouring iron liquid, spheroidization and inoculation 40 seconds obtained ductile iron liquid; Poured into when temperature 1420 DEG C by above-mentioned ductile iron liquid in the sand mold adopting consecutive solidification principle to make in advance, 40 seconds durations of pouring, shaping cooling, forms foundry goods.Obtain the ductile cast iron material of truck hub of the present invention.
Embodiment 5
Formula (composition and mass percent): C:3.10%, Si:2.72%, Mn:0.61%, S:0.008%, P:0.015%, Cu:0.43%, Cr:0.41%, Mo:0.39%, Mg:0.024%, RE:0.06%, Sb:0.005%, Bi:0.042%, La:0.016%, surplus is iron.
Preparation method: (1) Smelting of iron: alloy raw material such as the preparation pig iron, ferromanganese etc., medium-frequency induction furnace adds hot smelting, treats that iron liquid is heated to 1470 DEG C and comes out of the stove;
(2) iron liquid spheroidization and inoculation process: adopt and pour method spheroidization and inoculation technique, FeSiMg7RE type rare earth magnesium nodularizer is placed in after bottom casting ladle, after covering HY-75Ba3 type nucleating agent above it, finally pouring iron liquid, spheroidization and inoculation 35 seconds obtained ductile iron liquid; Poured into when temperature 1370 DEG C by above-mentioned ductile iron liquid in the sand mold adopting consecutive solidification principle to make in advance, 35 seconds durations of pouring, shaping cooling, forms foundry goods.Obtain the ductile cast iron material of truck hub of the present invention.
Embodiment 6
Formula (composition and mass percent): C:3.38%, Si:3.06%, Mn:0.52%, S:0.009%, P:0.018%, Cr:0.35%, Cu:0.42%, Mg:0.022%, RE:0.055%, Bi:0.032%, La:0.023%, surplus is iron.
Preparation method: (1) Smelting of iron: alloy raw material such as the preparation pig iron, ferromanganese etc., medium-frequency induction furnace adds hot smelting, treats that iron liquid is heated to 1520 DEG C and comes out of the stove;
(2) iron liquid spheroidization and inoculation process: adopt and pour method spheroidization and inoculation technique, FeSiMg7RE type rare earth magnesium nodularizer is placed in after bottom casting ladle, after covering HY-75Ba3 type nucleating agent above it, cover a little raw scrap material again to compress, finally pouring iron liquid, spheroidization and inoculation 38 seconds obtained ductile iron liquid; Poured into when temperature 1360 DEG C by above-mentioned ductile iron liquid in the sand mold adopting consecutive solidification principle to make in advance, 38 seconds durations of pouring, shaping cooling, forms foundry goods.Obtain the ductile cast iron material of truck hub of the present invention.
Embodiment 7
Formula (composition and mass percent): C:2.50%, Si:2.20%, Mn:0.45%, S:0.001%, P:0.004%, Cr:0.30%, Cu:0.35%, Mg:0.02%, RE:0.048%, Bi:0.016%, La:0.015%, surplus is iron.
Preparation method: (1) Smelting of iron: alloy raw material such as the preparation pig iron, ferromanganese etc., medium-frequency induction furnace adds hot smelting, treats that iron liquid is heated to 1545 DEG C and comes out of the stove;
(2) iron liquid spheroidization and inoculation process: adopt and pour method spheroidization and inoculation technique, FeSiMg7RE type rare earth magnesium nodularizer is placed in after bottom casting ladle, after covering HY-75Ba3 type nucleating agent above it, finally pouring iron liquid, spheroidization and inoculation 36 seconds obtained ductile iron liquid; Poured into when temperature 1395 DEG C by above-mentioned ductile iron liquid in the sand mold adopting consecutive solidification principle to make in advance, 39 seconds durations of pouring, shaping cooling, forms foundry goods.Obtain the ductile cast iron material of truck hub of the present invention.
Embodiment 8
Formula (composition and mass percent): C:3.60%, Si:3.20%, Mn:1.20%, S:0.02%, P:0.03%, Cr:0.5%, Cu0.55%, Mg:0.04%, RE:0.08%, Bi:0.06%, La:0.05%, surplus is iron.
Preparation method: (1) Smelting of iron: alloy raw material such as the preparation pig iron, ferromanganese etc., medium-frequency induction furnace adds hot smelting, treats that iron liquid is heated to 1500 DEG C and comes out of the stove;
(2) iron liquid spheroidization and inoculation process: adopt and pour method spheroidization and inoculation technique, FeSiMg7RE type rare earth magnesium nodularizer is placed in after bottom casting ladle, after covering HY-75Ba3 type nucleating agent above it, cover a little raw scrap material again to compress, finally pouring iron liquid, spheroidization and inoculation 40 seconds obtained ductile iron liquid; Poured into when temperature 1380 DEG C by above-mentioned ductile iron liquid in the sand mold adopting consecutive solidification principle to make in advance, 36 seconds durations of pouring, shaping cooling, forms foundry goods.Obtain the ductile cast iron material of truck hub of the present invention.
Above illustrated embodiment is better embodiment of the present invention, only be used for conveniently the present invention being described, not any pro forma restriction is done to the present invention, have in any art and usually know the knowledgeable, if do not depart from the present invention carry in the scope of technical characteristic, utilize the Equivalent embodiments that the done local of disclosed technology contents is changed or modified, and do not depart from technical characteristic content of the present invention, all still belong in the scope of the technology of the present invention feature.