CN105153751A - High fluidity modified calcium carbonate for plastics and preparation method thereof - Google Patents
High fluidity modified calcium carbonate for plastics and preparation method thereof Download PDFInfo
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- CN105153751A CN105153751A CN201510378563.9A CN201510378563A CN105153751A CN 105153751 A CN105153751 A CN 105153751A CN 201510378563 A CN201510378563 A CN 201510378563A CN 105153751 A CN105153751 A CN 105153751A
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Abstract
The invention discloses a high fluidity modified calcium carbonate for plastics and a preparation method thereof. The high fluidity modified calcium carbonate is characterized by being prepared from the following raw materials by weight part: 100-150 of calcium carbonate, 30-50 of sodium oleate, 0.3-0.7 of sodium dodecyl benzene sulfonate, 1-3 of sodium bicarbonate, 4-8 of styrene, 0.02-0.05 of potassium persulfate, 3-5 of fumed silica, 2-3 of organic bentonite, 0.4-1 of dioctyl phthalate, 1-2 of pregelatinized starch, 1-3 of zinc stearate, and a proper amount of deionized water. The dioctyl phthalate, pregelatinized starch and zinc stearate added in the invention can enhance the self-lubrication and fluidity of calcium carbonate, can reduce material loss during processing, also can enhance the toughness and hardness of plastics, and improve the quality of plastic parts. The high fluidity modified calcium carbonate for plastics provided by the invention has the advantages of simple preparation method, convenient raw material sources, and low cost, and has the effect of reinforcing all performance of products as an industrial filler, thus being worth popularizing.
Description
Technical field
The present invention relates to industrial filler field, particularly a kind of plastics high-flowability modified calcium carbonate and preparation method thereof.
Background technology
Calcium carbonate is as rubber, the filler of plastics, the thermotolerance of goods can be improved, wear resistance, dimensional stability, rigidity and workability, and reduce the cost of goods, but the hydroxyl that its surface has wetting ability stronger, present stronger alkalescence, the affinity of the calcium carbonate that this hydrophilic thin oil properties makes and organic polymer is poor, easy formation aggregate, part in superpolymer is caused to disperse uneven, thus cause boundary defect between bi-material, direct effect is bad, and calcium carbonate is as filler, its acid resistance, slickness, the performances such as whiteness need further raising, therefore, in order to improve the physicals of the strengthening action of calcium carbonate and dispersing property in the composite and modified calcium carbonate filled composite materials, be necessary to adopt different surface-modifying agents and treatment process to carry out surface modification to calcium carbonate powders, and then widen the Application Areas of calcium carbonate.
Polymer/inorganic particle matrix material is a kind of type material, which overcome simple inorganic particulate not easily to process, organic polymer intensity is lower, the shortcomings such as less stable, under synergistic effect, can obtain upgrading than inorganic particulate and organic polymer, more excellent performance, improve the stability of composite prod and the dispersiveness in organic phase, the performances such as physical strength, the present invention adopts polymer overmold modified calcium carbonate, solve the hydrophilic oleophobic of carbonic acid carbon, dispersed bad, free settling, physical strength is not high, the problems such as enhancement cannot be reached with polymer compatibility difference, improve the range of application of calcium carbonate.
Summary of the invention
The object of this invention is to provide a kind of plastics high-flowability modified calcium carbonate and preparation method thereof.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of plastics high-flowability modified calcium carbonate and preparation method thereof, is made up of the raw material of following weight part: calcium carbonate 100-150, sodium oleate 30-50, Sodium dodecylbenzene sulfonate 0.3-0.7, sodium bicarbonate 1-3, vinylbenzene 4-8, Potassium Persulphate 0.02-0.05, aerosil 3-5, organobentonite 2-3, dioctyl phthalate (DOP) 0.4-1, pregelatinized Starch 1-2, Zinic stearas 1-3, deionized water are appropriate;
A kind of plastics high-flowability modified calcium carbonate and preparation method thereof of the present invention, be made up of following concrete steps:
(1) sodium oleate is added the aqueous solution sodium oleate that deionized water dissolving makes 1%, electric stirring 10min raised temperature to 60 ° C, add calcium carbonate and stir 1.5h, stirred suction filtration after rear standing 4-6h, with deionized water wash, dry for standby under 80 ° of C in an oven;
(2) modified calcium carbonate obtained for step (1) is added in the four-necked bottle with driven stirring rod and reflux condensing tube, adding appropriate water stirring makes modified calcium carbonate become slurries, stirring is stopped to add Sodium dodecylbenzene sulfonate and sodium bicarbonate, vinylbenzene is added after stirring 0.5h in a nitrogen atmosphere, persulfate aqueous solution is dripped after mixture being warming up to 80 ° of C, constant temperature is centrifugal after keeping 80 ° of C8h, with dry under 80 ° of C in an oven after deionized water rinsing, after to be ground into 300-400 order for subsequent use;
(3) the methanol solution activation 0.5h of 3-5 times amount is added after organobentonite and aerosil being mixed, 5 μm are less than to particle diameter again at grinding machine for grinding 2-3h, add deionized water ultrasonic disperse more even, transfer in flask the product adding step (2) gained again, raised temperature is to 80-100 ° of C, the ultrasonic methyl alcohol that is back to volatilizees, and dries product;
(4) by remaining mixing of materials, stir when being heated to 40-60 ° of C, then the product adding step (3) gained is under the rotating speed of 1300-1500 rev/min, stirs 8-10min, naturally cool to room temperature after insulation 10-15min, grind to form nanometer powdery.
Advantage of the present invention is: the present invention's sodium oleate makes calcium carbonate surface organise as properties-correcting agent, calcium carbonate particles surface is made to have certain hydrophobicity, and double bond is introduced calcium carbonate surface, using modified calcium carbonate particle as seed, the method of letex polymerization has prepared polystyrene coated caco3 composite particles, enhance the consistency of calcium carbonate and polymkeric substance, and easily disperse, not easily reunite, physical strength is high, the present invention is also by aerosil and organobentonite activation aftertreatment modified calcium carbonate, silicon-dioxide is made to stick to the surface of calcium carbonate, not free settling, be uniformly dispersed, suspension stability is good, and further enhancing the oilness of calcium carbonate, water tolerance and high thermal resistance, calcium carbonate is had a wide range of applications in the industry, the dioctyl phthalate (DOP) added, pregelatinized Starch and Zinic stearas can strengthen self lubricity and the mobility of calcium carbonate, material unaccounted-for (MUF) can be reduced when processing, and there is the toughness of reinforced plastics, hardness, improve the quality of plastic part, preparation method of the present invention is simple, raw material sources are convenient, cost is low, there is as industrial filler the effect strengthening product various aspects of performance, be worthy to be popularized.
Specific embodiments
Below by specific examples, the present invention is described in detail.
A kind of plastics high-flowability modified calcium carbonate and preparation method thereof, is made up of the raw material of following weight part (kilogram): calcium carbonate 150, sodium oleate 46, Sodium dodecylbenzene sulfonate 0.6, sodium bicarbonate 3, vinylbenzene 6, Potassium Persulphate 0.04, aerosil 4, organobentonite 3, dioctyl phthalate (DOP) 0.6, pregelatinized Starch 1, Zinic stearas 2, deionized water are appropriate;
A kind of plastics high-flowability modified calcium carbonate and preparation method thereof of the present invention, be made up of following concrete steps:
(1) sodium oleate is added the aqueous solution sodium oleate that deionized water dissolving makes 1%, electric stirring 10min raised temperature to 60 ° C, add calcium carbonate and stir 1.5h, stirred suction filtration after rear standing 6h, with deionized water wash, dry for standby under 80 ° of C in an oven;
(2) modified calcium carbonate obtained for step (1) is added in the four-necked bottle with driven stirring rod and reflux condensing tube, adding appropriate water stirring makes modified calcium carbonate become slurries, stirring is stopped to add Sodium dodecylbenzene sulfonate and sodium bicarbonate, vinylbenzene is added after stirring 0.5h in a nitrogen atmosphere, persulfate aqueous solution is dripped after mixture being warming up to 80 ° of C, constant temperature is centrifugal after keeping 80 ° of C8h, with dry under 80 ° of C in an oven after deionized water rinsing, after to be ground into 400 orders for subsequent use;
(3) the methanol solution activation 0.5h of 5 times amount is added after organobentonite and aerosil being mixed, 5 μm are less than to particle diameter again at grinding machine for grinding 3h, add deionized water ultrasonic disperse more even, transfer in flask the product adding step (2) gained again, raised temperature to 100 ° C, the ultrasonic methyl alcohol that is back to volatilizees, and dries product;
(4) by remaining mixing of materials, stir when being heated to 50 ° of C, then the product adding step (3) gained is under the rotating speed of 1500 revs/min, stirs 10min, naturally cool to room temperature after insulation 10min, grind to form nanometer powdery.
The modified calcium carbonate produce the present invention and unmodified calcium carbonate performance compare, obtain modified calcium carbonate and reduce 53.8% than unmodified calcium carbonate oil-absorption(number), settling volume reduces 62.8%, viscosity reduces 58.5%, and tap density reduces 21.3%, and modified calcium carbonate oleophilic drainage is described, good with polymer compatibility, and tap density diminishes, illustrate that calcium carbonate dispersing property is good, not easily reunite.
Claims (2)
1. plastics high-flowability modified calcium carbonate and preparation method thereof, it is characterized in that, be made up of the raw material of following weight part: calcium carbonate 100-150, sodium oleate 30-50, Sodium dodecylbenzene sulfonate 0.3-0.7, sodium bicarbonate 1-3, vinylbenzene 4-8, Potassium Persulphate 0.02-0.05, aerosil 3-5, organobentonite 2-3, dioctyl phthalate (DOP) 0.4-1, pregelatinized Starch 1-2, Zinic stearas 1-3, deionized water are appropriate.
2. a kind of plastics high-flowability modified calcium carbonate and preparation method thereof according to claim 1, is characterized in that, be made up of following concrete steps:
(1) sodium oleate is added the aqueous solution sodium oleate that deionized water dissolving makes 1%, electric stirring 10min raised temperature to 60 ° C, add calcium carbonate and stir 1.5h, stirred suction filtration after rear standing 4-6h, with deionized water wash, dry for standby under 80 ° of C in an oven;
(2) modified calcium carbonate obtained for step (1) is added in the four-necked bottle with driven stirring rod and reflux condensing tube, adding appropriate water stirring makes modified calcium carbonate become slurries, stirring is stopped to add Sodium dodecylbenzene sulfonate and sodium bicarbonate, vinylbenzene is added after stirring 0.5h in a nitrogen atmosphere, persulfate aqueous solution is dripped after mixture being warming up to 80 ° of C, constant temperature is centrifugal after keeping 80 ° of C8h, with dry under 80 ° of C in an oven after deionized water rinsing, after to be ground into 300-400 order for subsequent use;
(3) the methanol solution activation 0.5h of 3-5 times amount is added after organobentonite and aerosil being mixed, 5 μm are less than to particle diameter again at grinding machine for grinding 2-3h, add deionized water ultrasonic disperse more even, transfer in flask the product adding step (2) gained again, raised temperature is to 80-100 ° of C, the ultrasonic methyl alcohol that is back to volatilizees, and dries product;
(4) by remaining mixing of materials, stir when being heated to 40-60 ° of C, then the product adding step (3) gained is under the rotating speed of 1300-1500 rev/min, stirs 8-10min, naturally cool to room temperature after insulation 10-15min, grind to form nanometer powdery.
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Cited By (4)
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| CN106397838A (en) * | 2016-09-29 | 2017-02-15 | 贺州钟山县双文碳酸钙新材料有限公司 | Modified calcium carbonate for cables |
| CN106496638A (en) * | 2016-09-29 | 2017-03-15 | 贺州钟山县双文碳酸钙新材料有限公司 | A kind of plastics modified calcium carbonate |
| CN106496637A (en) * | 2016-09-29 | 2017-03-15 | 贺州钟山县双文碳酸钙新材料有限公司 | A kind of rubber modified calcium carbonate |
| CN107698801A (en) * | 2017-09-30 | 2018-02-16 | 广西华洋矿源材料有限公司 | A kind of modified and light calcium carbonate |
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| CN106397838A (en) * | 2016-09-29 | 2017-02-15 | 贺州钟山县双文碳酸钙新材料有限公司 | Modified calcium carbonate for cables |
| CN106496638A (en) * | 2016-09-29 | 2017-03-15 | 贺州钟山县双文碳酸钙新材料有限公司 | A kind of plastics modified calcium carbonate |
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| CN107698801A (en) * | 2017-09-30 | 2018-02-16 | 广西华洋矿源材料有限公司 | A kind of modified and light calcium carbonate |
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Application publication date: 20151216 |