CN105038321A - Modified calcium carbonate with good heatproof property and preparation method thereof - Google Patents

Abstract

The invention discloses modified calcium carbonate with a good heatproof property and a preparation method thereof. The modified calcium carbonate is characterized by being prepared from the following raw materials in parts by weight: 100 to 150 parts of calcium carbonate, 30 to 50 parts of sodium oleate, 0.3 to 0.7 parts of sodium dodecyl benzene sulfonate, 1 to 3 parts of sodium bicarbonate, 4 to 8 parts of styrene, 0.02 to 0.05 part of potassium persulfate, 3 to 5 parts of gas-phase silicon dioxide, 2 to 3 parts of organic bentonite, 3 to 4 parts of quartz powder, 1 to 2 parts of alum, 1 to 2 parts of terpineol, and a proper amount of deionized water. The added quartz powder, alum, and terpineol cooperate with each other to improve the properties of calcium carbonate powder such as heatproof property, antibacterial property, fireproof performance, mechanical strength, and the like. The modified calcium carbonate can be used as filler and applied to the fields such as paints, construction, pigments, and the like. Moreover, the preparation technology is simple, the cost is low, and the modified calcium carbonate can be massively produced and is worthy to promote.

Description

Modified calcium carbonate that a kind of thermotolerance is good and preparation method thereof

Technical field

The present invention relates to industrial filler field, modified calcium carbonate that particularly a kind of thermotolerance is good and preparation method thereof.

Background technology

Calcium carbonate is as rubber, the filler of plastics, the thermotolerance of goods can be improved, wear resistance, dimensional stability, rigidity and workability, and reduce the cost of goods, but the hydroxyl that its surface has wetting ability stronger, present stronger alkalescence, the affinity of the calcium carbonate that this hydrophilic thin oil properties makes and organic polymer is poor, easy formation aggregate, part in superpolymer is caused to disperse uneven, thus cause boundary defect between bi-material, direct effect is bad, and calcium carbonate is as filler, its acid resistance, slickness, the performances such as whiteness need further raising, therefore, in order to improve the physicals of the strengthening action of calcium carbonate and dispersing property in the composite and modified calcium carbonate filled composite materials, be necessary to adopt different surface-modifying agents and treatment process to carry out surface modification to calcium carbonate powders, and then widen the Application Areas of calcium carbonate.

Polymer/inorganic particle matrix material is a kind of type material, which overcome simple inorganic particulate not easily to process, organic polymer intensity is lower, the shortcomings such as less stable, under synergistic effect, can obtain upgrading than inorganic particulate and organic polymer, more excellent performance, improve the stability of composite prod and the dispersiveness in organic phase, the performances such as physical strength, the present invention adopts polymer overmold modified calcium carbonate, solve the hydrophilic oleophobic of carbonic acid carbon, dispersed bad, free settling, physical strength is not high, the problems such as enhancement cannot be reached with polymer compatibility difference, improve the range of application of calcium carbonate.

Summary of the invention

The object of this invention is to provide good modified calcium carbonate of a kind of thermotolerance and preparation method thereof.In order to realize object of the present invention, the present invention is by following scheme implementation:

Modified calcium carbonate that a kind of thermotolerance is good and preparation method thereof, is made up of the raw material of following weight part: calcium carbonate 100-150, sodium oleate 30-50, Sodium dodecylbenzene sulfonate 0.3-0.7, sodium bicarbonate 1-3, vinylbenzene 4-8, Potassium Persulphate 0.02-0.05, aerosil 3-5, organobentonite 2-3, silica powder 3-4, alum 1-2, Terpineol 350 1-2, deionized water are appropriate;

Modified calcium carbonate that a kind of thermotolerance of the present invention is good and preparation method thereof, be made up of following concrete steps:

(1) sodium oleate is added the aqueous solution sodium oleate that deionized water dissolving makes 1%, electric stirring 10min raised temperature to 60 ° C, add calcium carbonate and stir 1.5h, stirred suction filtration after rear standing 4-6h, with deionized water wash, dry for standby under 80 ° of C in an oven;

(2) modified calcium carbonate obtained for step (1) is added in the four-necked bottle with driven stirring rod and reflux condensing tube, adding appropriate water stirring makes modified calcium carbonate become slurries, stirring is stopped to add Sodium dodecylbenzene sulfonate and sodium bicarbonate, vinylbenzene is added after stirring 0.5h in a nitrogen atmosphere, persulfate aqueous solution is dripped after mixture being warming up to 80 ° of C, constant temperature is centrifugal after keeping 80 ° of C8h, with dry under 80 ° of C in an oven after deionized water rinsing, after to be ground into 300-400 order for subsequent use;

(3) the methanol solution activation 0.5h of 3-5 times amount is added after organobentonite and aerosil being mixed, 5 μm are less than to particle diameter again at grinding machine for grinding 2-3h, add deionized water ultrasonic disperse more even, transfer in flask the product adding step (2) gained again, raised temperature is to 80-100 ° of C, the ultrasonic methyl alcohol that is back to volatilizees, and dries product;

(4) by remaining mixing of materials, stir when being heated to 40-60 ° of C, then the product adding step (3) gained is under the rotating speed of 1300-1500 rev/min, stirs 8-10min, naturally cool to room temperature after insulation 10-15min, grind to form nanometer powdery.

Advantage of the present invention is: the present invention's sodium oleate makes calcium carbonate surface organise as properties-correcting agent, calcium carbonate particles surface is made to have certain hydrophobicity, and double bond is introduced calcium carbonate surface, using modified calcium carbonate particle as seed, the method of letex polymerization has prepared polystyrene coated caco3 composite particles, enhance the consistency of calcium carbonate and polymkeric substance, and easily disperse, not easily reunite, physical strength is high, and the present invention is also by aerosil and organobentonite activation aftertreatment modified calcium carbonate, and make silicon-dioxide stick to the surface of calcium carbonate, not free settling, is uniformly dispersed, and suspension stability is good, and further enhancing the oilness of calcium carbonate, water tolerance and high thermal resistance, make calcium carbonate have a wide range of applications in the industry, the silica powder of interpolation, alum and the mutual promoter action of Terpineol 350 three, improve the thermotolerance of calcium carbonate powders, antibacterial, fire-resistant, the performances such as physical strength, add paint to as filler, building, in the fields such as pigment, there is good application, and preparation technology is simple, cost is low, can be mass-produced, be worthy to be popularized.

Specific embodiments

Below by specific examples, the present invention is described in detail.

Modified calcium carbonate that a kind of thermotolerance is good and preparation method thereof, is made up of the raw material of following weight part (kilogram): calcium carbonate 150, sodium oleate 46, Sodium dodecylbenzene sulfonate 0.5, sodium bicarbonate 2, vinylbenzene 6, Potassium Persulphate 0.04, aerosil 5, organobentonite 3, silica powder 4, alum 2, Terpineol 350 1, deionized water are appropriate;

Modified calcium carbonate that a kind of thermotolerance of the present invention is good and preparation method thereof, be made up of following concrete steps:

(1) sodium oleate is added the aqueous solution sodium oleate that deionized water dissolving makes 1%, electric stirring 10min raised temperature to 60 ° C, add calcium carbonate and stir 1.5h, stirred suction filtration after rear standing 4h, with deionized water wash, dry for standby under 80 ° of C in an oven;

(2) modified calcium carbonate obtained for step (1) is added in the four-necked bottle with driven stirring rod and reflux condensing tube, adding appropriate water stirring makes modified calcium carbonate become slurries, stirring is stopped to add Sodium dodecylbenzene sulfonate and sodium bicarbonate, vinylbenzene is added after stirring 0.5h in a nitrogen atmosphere, persulfate aqueous solution is dripped after mixture being warming up to 80 ° of C, constant temperature is centrifugal after keeping 80 ° of C8h, with dry under 80 ° of C in an oven after deionized water rinsing, after to be ground into 400 orders for subsequent use;

(3) the methanol solution activation 0.5h of 5 times amount is added after organobentonite and aerosil being mixed, 5 μm are less than to particle diameter again at grinding machine for grinding 2h, add deionized water ultrasonic disperse more even, transfer in flask the product adding step (2) gained again, raised temperature to 100 ° C, the ultrasonic methyl alcohol that is back to volatilizees, and dries product;

(4) by remaining mixing of materials, stir when being heated to 60 ° of C, then the product adding step (3) gained is under the rotating speed of 1500 revs/min, stirs 8min, naturally cool to room temperature after insulation 10min, grind to form nanometer powdery.

The modified calcium carbonate produce the present invention and unmodified calcium carbonate performance compare, obtain modified calcium carbonate and reduce 55.8% than unmodified calcium carbonate oil-absorption(number), settling volume reduces 65.7%, viscosity reduces 61.5%, and tap density reduces 17.8%, and modified calcium carbonate oleophilic drainage is described, good with polymer compatibility, and tap density diminishes, illustrate that calcium carbonate dispersing property is good, not easily reunite.

Claims (2)

1. modified calcium carbonate that a thermotolerance is good and preparation method thereof, it is characterized in that, be made up of the raw material of following weight part: calcium carbonate 100-150, sodium oleate 30-50, Sodium dodecylbenzene sulfonate 0.3-0.7, sodium bicarbonate 1-3, vinylbenzene 4-8, Potassium Persulphate 0.02-0.05, aerosil 3-5, organobentonite 2-3, silica powder 3-4, alum 1-2, Terpineol 350 1-2, deionized water are appropriate.

2. modified calcium carbonate that a kind of thermotolerance is good according to claim 1 and preparation method thereof, is characterized in that, be made up of following concrete steps:

(1) sodium oleate is added the aqueous solution sodium oleate that deionized water dissolving makes 1%, electric stirring 10min raised temperature to 60 ° C, add calcium carbonate and stir 1.5h, stirred suction filtration after rear standing 4-6h, with deionized water wash, dry for standby under 80 ° of C in an oven;

(2) modified calcium carbonate obtained for step (1) is added in the four-necked bottle with driven stirring rod and reflux condensing tube, adding appropriate water stirring makes modified calcium carbonate become slurries, stirring is stopped to add Sodium dodecylbenzene sulfonate and sodium bicarbonate, vinylbenzene is added after stirring 0.5h in a nitrogen atmosphere, persulfate aqueous solution is dripped after mixture being warming up to 80 ° of C, constant temperature is centrifugal after keeping 80 ° of C8h, with dry under 80 ° of C in an oven after deionized water rinsing, after to be ground into 300-400 order for subsequent use;

(3) the methanol solution activation 0.5h of 3-5 times amount is added after organobentonite and aerosil being mixed, 5 μm are less than to particle diameter again at grinding machine for grinding 2-3h, add deionized water ultrasonic disperse more even, transfer in flask the product adding step (2) gained again, raised temperature is to 80-100 ° of C, the ultrasonic methyl alcohol that is back to volatilizees, and dries product;

(4) by remaining mixing of materials, stir when being heated to 40-60 ° of C, then the product adding step (3) gained is under the rotating speed of 1300-1500 rev/min, stirs 8-10min, naturally cool to room temperature after insulation 10-15min, grind to form nanometer powdery.