CN105143303A - 制备共聚物的方法 - Google Patents
制备共聚物的方法 Download PDFInfo
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- CN105143303A CN105143303A CN201480016425.XA CN201480016425A CN105143303A CN 105143303 A CN105143303 A CN 105143303A CN 201480016425 A CN201480016425 A CN 201480016425A CN 105143303 A CN105143303 A CN 105143303A
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- Prior art keywords
- cyclic ester
- group
- ring
- multipolymer
- lactone
- Prior art date
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- 238000004519 manufacturing process Methods 0.000 title abstract description 4
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- 125000004429 atom Chemical group 0.000 claims abstract description 32
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
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- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 13
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 12
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 11
- 125000005842 heteroatom Chemical group 0.000 claims abstract description 11
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 claims abstract description 9
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- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims description 57
- 125000003118 aryl group Chemical group 0.000 claims description 35
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- 125000000217 alkyl group Chemical group 0.000 claims description 29
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- 229910052739 hydrogen Inorganic materials 0.000 claims description 28
- 239000001257 hydrogen Substances 0.000 claims description 28
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 15
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- VEUMANXWQDHAJV-UHFFFAOYSA-N 2-[2-[(2-hydroxyphenyl)methylideneamino]ethyliminomethyl]phenol Chemical compound OC1=CC=CC=C1C=NCCN=CC1=CC=CC=C1O VEUMANXWQDHAJV-UHFFFAOYSA-N 0.000 claims description 5
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- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical group CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 claims description 4
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- SIXSYDAISGFNSX-UHFFFAOYSA-N scandium atom Chemical compound [Sc] SIXSYDAISGFNSX-UHFFFAOYSA-N 0.000 claims description 4
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N anhydrous guanidine Natural products NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 3
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- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 3
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- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 claims description 2
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- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical group C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- 125000005073 adamantyl group Chemical group C12(CC3CC(CC(C1)C3)C2)* 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims description 2
- 125000004432 carbon atom Chemical group C* 0.000 claims description 2
- 229910017052 cobalt Inorganic materials 0.000 claims description 2
- 239000010941 cobalt Substances 0.000 claims description 2
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- 239000004643 cyanate ester Substances 0.000 claims description 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 claims description 2
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 229920000515 polycarbonate Polymers 0.000 claims description 2
- 239000004417 polycarbonate Substances 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 claims description 2
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- 229940079593 drug Drugs 0.000 description 1
- 125000004185 ester group Chemical group 0.000 description 1
- 125000001033 ether group Chemical group 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 238000005194 fractionation Methods 0.000 description 1
- IPBFYZQJXZJBFQ-UHFFFAOYSA-N gamma-octalactone Chemical compound CCCCC1CCC(=O)O1 IPBFYZQJXZJBFQ-UHFFFAOYSA-N 0.000 description 1
- 238000000769 gas chromatography-flame ionisation detection Methods 0.000 description 1
- 230000026030 halogenation Effects 0.000 description 1
- 238000005658 halogenation reaction Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 description 1
- 125000005638 hydrazono group Chemical group 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000003550 marker Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000000269 nucleophilic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- ZYDGQQTXLBNSGJ-UHFFFAOYSA-N oxonan-2-one Chemical compound O=C1CCCCCCCO1 ZYDGQQTXLBNSGJ-UHFFFAOYSA-N 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 150000004032 porphyrins Chemical class 0.000 description 1
- 230000001376 precipitating effect Effects 0.000 description 1
- 238000003822 preparative gas chromatography Methods 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 229960000380 propiolactone Drugs 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- WBHHMMIMDMUBKC-QJWNTBNXSA-N ricinoleic acid Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(O)=O WBHHMMIMDMUBKC-QJWNTBNXSA-N 0.000 description 1
- 229960003656 ricinoleic acid Drugs 0.000 description 1
- FEUQNCSVHBHROZ-UHFFFAOYSA-N ricinoleic acid Natural products CCCCCCC(O[Si](C)(C)C)CC=CCCCCCCCC(=O)OC FEUQNCSVHBHROZ-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 150000003384 small molecules Chemical class 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 125000000383 tetramethylene group Chemical class [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- CHJMFFKHPHCQIJ-UHFFFAOYSA-L zinc;octanoate Chemical compound [Zn+2].CCCCCCCC([O-])=O.CCCCCCCC([O-])=O CHJMFFKHPHCQIJ-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/06—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from hydroxycarboxylic acids
- C08G63/08—Lactones or lactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/823—Preparation processes characterised by the catalyst used for the preparation of polylactones or polylactides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/04—Polyesters derived from hydroxycarboxylic acids, e.g. lactones
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP13001358.4 | 2013-03-18 | ||
| EP13001358 | 2013-03-18 | ||
| PCT/IB2014/059897 WO2014147546A1 (en) | 2013-03-18 | 2014-03-17 | Process for preparing a copolymer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105143303A true CN105143303A (zh) | 2015-12-09 |
Family
ID=47901748
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201480016425.XA Pending CN105143303A (zh) | 2013-03-18 | 2014-03-17 | 制备共聚物的方法 |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9512268B2 (enExample) |
| EP (1) | EP2976375B1 (enExample) |
| JP (1) | JP2016512857A (enExample) |
| KR (1) | KR20150132552A (enExample) |
| CN (1) | CN105143303A (enExample) |
| BR (1) | BR112015019566A2 (enExample) |
| WO (1) | WO2014147546A1 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2014203209A1 (en) | 2013-06-20 | 2014-12-24 | Saudi Basic Industries Corporation | Pe-like polyesters |
| WO2016198243A1 (en) | 2015-05-22 | 2016-12-15 | Sabic Global Technologies B.V. | Improved heterophasic polypropylene |
| WO2016188817A1 (en) | 2015-05-22 | 2016-12-01 | Sabic Global Technologies B.V. | Polymer composition |
| US10450450B2 (en) | 2015-05-22 | 2019-10-22 | Sabic Global Technologies B.V. | Polyester block compatibilizer for polyethylene polypropylene blends |
| US10144802B2 (en) * | 2016-12-05 | 2018-12-04 | Novomer, Inc. | Beta-propiolactone based copolymers containing biogenic carbon, methods for their production and uses thereof |
| EP4013809B1 (en) | 2019-08-18 | 2023-07-19 | SABIC Global Technologies, B.V. | Use of a composition for the manufacture of a foamed article |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6262278B1 (en) * | 1995-03-14 | 2001-07-17 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
| JP2003064174A (ja) * | 2001-08-24 | 2003-03-05 | Nagoya Industrial Science Research Inst | ラクトンの開環重合用触媒、ポリエステルの製造方法、及びブロック共重合体の製造方法。 |
| CN1544504A (zh) * | 2003-11-27 | 2004-11-10 | 中国科学院长春应用化学研究所 | 环酯开环聚合催化剂及制备方法 |
| US20090124787A1 (en) * | 2005-04-12 | 2009-05-14 | Peter Preishuber-Pflugl | Method for Producing Polyhydroxyalkanoates |
| WO2010110460A1 (ja) * | 2009-03-27 | 2010-09-30 | 国立大学法人名古屋大学 | ラクチド・ε－カプロラクトン共重合体の製造方法 |
| WO2012065711A1 (en) * | 2010-11-18 | 2012-05-24 | Saudi Basic Industries Corporation | Process for preparing a polyester |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2535562A1 (de) | 1975-08-08 | 1977-02-17 | Wolfgang Dr Ast | Ungesaettigte polyester-kautschuk- copolymerisate und verfahren zu ihrer herstellung |
| JP3408347B2 (ja) | 1994-06-08 | 2003-05-19 | 高砂香料工業株式会社 | 光学活性ブロック共重合ポリエステル及びその製造方法 |
| CA2333379C (en) | 1998-05-28 | 2008-08-05 | Gunze Limited | Lactide-containing polymer and medical material |
| GB0305927D0 (en) | 2003-03-14 | 2003-04-23 | Ic Innovations Ltd | Compound |
| US7915375B2 (en) | 2006-03-01 | 2011-03-29 | Firestone Polymers, Llc | Metathesis interpolymers having terminal functional group(s) |
| US20100048813A1 (en) | 2006-11-14 | 2010-02-25 | Basf Se | Highly-branched or hyper-branched polyester and the production and application thereof |
| DE102008055870A1 (de) | 2008-10-31 | 2010-05-06 | Gkss-Forschungszentrum Geesthacht Gmbh | Multiphasen Polymernetzwerk mit Triple-Shape-Eigenschaften und Formgedächtniseffekt |
| CN102617369B (zh) | 2012-02-17 | 2014-10-15 | 华东理工大学 | 类salan单酚类配体金属络合物及其制备方法与应用 |
| US9080012B2 (en) | 2013-07-10 | 2015-07-14 | Xerox Corporation | One-pot, neat ring opening polymerization to prepare resin |
-
2014
- 2014-03-17 KR KR1020157030041A patent/KR20150132552A/ko not_active Withdrawn
- 2014-03-17 US US14/766,254 patent/US9512268B2/en not_active Expired - Fee Related
- 2014-03-17 JP JP2016503756A patent/JP2016512857A/ja active Pending
- 2014-03-17 BR BR112015019566A patent/BR112015019566A2/pt not_active IP Right Cessation
- 2014-03-17 EP EP14718751.2A patent/EP2976375B1/en not_active Not-in-force
- 2014-03-17 WO PCT/IB2014/059897 patent/WO2014147546A1/en not_active Ceased
- 2014-03-17 CN CN201480016425.XA patent/CN105143303A/zh active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6262278B1 (en) * | 1995-03-14 | 2001-07-17 | President And Fellows Of Harvard College | Stereoselective ring opening reactions |
| JP2003064174A (ja) * | 2001-08-24 | 2003-03-05 | Nagoya Industrial Science Research Inst | ラクトンの開環重合用触媒、ポリエステルの製造方法、及びブロック共重合体の製造方法。 |
| CN1544504A (zh) * | 2003-11-27 | 2004-11-10 | 中国科学院长春应用化学研究所 | 环酯开环聚合催化剂及制备方法 |
| US20090124787A1 (en) * | 2005-04-12 | 2009-05-14 | Peter Preishuber-Pflugl | Method for Producing Polyhydroxyalkanoates |
| WO2010110460A1 (ja) * | 2009-03-27 | 2010-09-30 | 国立大学法人名古屋大学 | ラクチド・ε－カプロラクトン共重合体の製造方法 |
| WO2012065711A1 (en) * | 2010-11-18 | 2012-05-24 | Saudi Basic Industries Corporation | Process for preparing a polyester |
Non-Patent Citations (2)
| Title |
|---|
| AJAY KUMAR等: "Efficient Ring-Opening Polymerization and Copolymerization of ε-Caprolactone and ω-Pentadecalactone Catalyzed by Candida antartica Lipase B", 《MACROMOLECULES》 * |
| MILOUD BOUYAHYI等: "ω-Pentandecalactone Polymerization and ω-Pentadecalactone/ε-Caprolactone Copolymerization Reactions Using Organic Catalysts", 《MACROMOLECULES》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| BR112015019566A2 (pt) | 2017-07-18 |
| EP2976375B1 (en) | 2017-11-29 |
| KR20150132552A (ko) | 2015-11-25 |
| US9512268B2 (en) | 2016-12-06 |
| JP2016512857A (ja) | 2016-05-09 |
| US20150376330A1 (en) | 2015-12-31 |
| EP2976375A1 (en) | 2016-01-27 |
| WO2014147546A1 (en) | 2014-09-25 |
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