CN105126602A - Manufacturing method of controlled natural biological odor-removal formaldehyde-removal product - Google Patents

Manufacturing method of controlled natural biological odor-removal formaldehyde-removal product Download PDF

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Publication number
CN105126602A
CN105126602A CN201510502624.8A CN201510502624A CN105126602A CN 105126602 A CN105126602 A CN 105126602A CN 201510502624 A CN201510502624 A CN 201510502624A CN 105126602 A CN105126602 A CN 105126602A
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China
Prior art keywords
formaldehyde
except
natural biological
taste removal
removal
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Pending
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CN201510502624.8A
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Chinese (zh)
Inventor
王平
斯航
陆红
王天桃
潘涛
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Jiangsu Grams Of Micro Nano Science And Technology Co Ltd
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Individual
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Priority to CN201510502624.8A priority Critical patent/CN105126602A/en
Publication of CN105126602A publication Critical patent/CN105126602A/en
Priority to CN201610679504.XA priority patent/CN106178928A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/84Biological processes
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • A61L9/01Deodorant compositions
    • A61L9/013Deodorant compositions containing animal or plant extracts, or vegetable material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/62Carbon oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/68Halogens or halogen compounds
    • B01D53/70Organic halogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/95Specific microorganisms
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/20Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Biomedical Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Zoology (AREA)
  • Botany (AREA)
  • Molecular Biology (AREA)
  • Epidemiology (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Beans For Foods Or Fodder (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

The present invention relates to a manufacturing method of a controlled natural biological odor-removal formaldehyde-removal product, a plant is put in ice, added with a solvent, put in a mortar for grinding with liquid nitrogen, and after grinding, the plant is put into an extracting liquid for standing in the ice for 3 ~ 4h, and centrifuged at a low temperature of 4 DEG C with a centrifuge in the rate of 11100rpm / 20min to extract a supernatant to obtain plant protein enzyme. The protein enzyme and water are mixed for preparation, and added into a plastic bottle, by use of a cylinder7mm *70mm porous enamel rod for suction floating and use of a top heater for continuous controlled evaporation at a certain temperature, the purpose of removal of indoor formaldehyde and odor can be achieved, and 95% of carbon monoxide, 99 % of formaldehyde, 95% of nitrogen peroxide, 90% of benzene and 92% of trichloro ethylene can be removed.

Description

A kind of controlled natural biological taste removal is except the manufacture method of formaldehyde products
Technical field
The present invention relates to the manufacture method of a kind of controlled natural biological taste removal except formaldehyde products, we are the proteases extracted from plant, are dissolved in certain density water, are floated by the suction of enamel rod, constantly evaporate through top heater controllable temperature, reach taste removal except effect of formaldehyde.
Background technology
In recent decades, along with the raising of expanding economy and human living standard, curb environmental pollution and more and more become a global difficult problem.In the process of curbing environmental pollution, people have employed various method, achieve a large amount of successfully experience.And in the practice process of process debirs, biological method gets the nod gradually, and becomes the processing method of main flow.
Chemistry management: use chemicals and pernicious gas to show effect chemical change, as photocatalyst, formaldehyde remove agent, gram benzene spirit, eliminating smell agent etc. and is oxidized the gas polluted.
Biological management: select plant to absorb the pernicious gas in air, or carry out biological oxidation, decomposition with microorganism, enzyme.
Aspidlsiraelatior, Monstera deliciosa can root out the harmful substance in air, the formaldehyde of brave bracketplant, bracketplant Absorbable rod indoor more than 80%, can also " eat " the indoor carbon monoxide of 96%, the hyponitric acid of 86%; Aloe then can absorb 1 cubic metres of air total contained 90% formaldehyde.
Milan, wintersweet etc. can root out the nuisance such as sulfur dioxide, carbon monoxide in air effectively.
The cilium of the plants such as orchid, sweet osmanthus, wintersweet can retain and the airborne particles absorbed and retain in air and flue dust.
Ivy, sago cycas can in effective absorption chamber 85% benzene and 60% trichloro-ethylene.
Rhizoma arisaematis also can absorb the benzene of 80%, the trichloro-ethylene of 50%.
Current Main Developed Countries, as the U.S., Japan etc., has had more ripe scientific achievement in this respect.And teach headed by the western doctor of Beaune by the famous biology of Italy, by France, Italy, the research group that forms of the biological expert of Switzerland, " enzyme can nation " preparation (MAKERPAN) that the Research foundation in more than 10 years is developed is then handsome person wherein.Up to now, it has been widely used in the various fields such as industry all over the world, civilian, animal husbandry and agricultural, and in all many-sided environmental issues, serve remarkable effect, successfully utilizes biotechnology to solve the technical barrier of many environmental protection aspects.
The dozens of formula of " enzyme can nation " biological product, not only help people to solve formaldehyde odor and sanitary sewage, municipal refuse, zootechnical waste, also solve the difficult problem of environmental protections such as river, city body pollution, sewage ditch, petrifaction sewage for us and provide an effective way.
Its advantage is many-sided: the danger of nontoxicity, non-corrosiveness, non-secondary pollution; Quicker to organic degraded; Its full spectrum microorganism can play a role under aerobic and anaerobic state, even also can degradation of organic substances under the condition having various pollution sources; Without any specially requiring or avoiding by scope in using, easy to operate, simple and easy.
Along with popularizing of environmental protection knowledge, the nouns such as air detection, formaldehyde improvement are come into huge numbers of families, are more and more paid close attention to indoor environment health problem.Active carbon has formaldehyde adsorption, people easy to use accept, according to staff's introduction of certain active carbon producer, the active carbon of high-quality utilizes charcoal, bamboo charcoal, various shell and rare ore deposit soil etc. as raw material, at high temperature dry at temperature, its organic organization carbonized.Then physics or chemical species complete activation process, are formed and have pore structure prosperity, huge specific area, the features such as high iodine number, harmful substance in adsorbable air.
Photocatalyst is except the principle of formaldehyde.It is the construction technology by specialty, the spray of the titanium dioxide aqueous solution is implanted in the surface of pollution sources.Then under the irradiation of light, surface excitation goes out electronics, and the water in electronics and air reacts, and generates the free radical of hydrogen and oxygen.It easily with generation decomposition reaction containing hydrogen or oxygen in chemical formula, generation and carbon dioxide and water.Thus effectively can divide the pernicious gases such as the formaldehyde taken off in air, benzene, TVOC.
Biology enzyme is except the principle of formaldehyde.Biology enzyme is the protein extracted from plant, and the pernicious gases such as formaldehyde are dissolved in protein, so biology enzyme can reduce indoor formaldehyde equal size to a certain extent.But biology enzyme just occurred in recent years, from the principle, can formaldehyde be removed, but long-term spraying must be needed, just can have certain effect, if only sprayed once, be to remove indoor pollutant, and a lot of company all says that the product of oneself is biology enzyme on the market, but real biology enzyme is few at all, a lot of company hangs out a sheep's head but actually sell dog's meat, and consumer must remove the scales from eyes.There is Urine scent ability.
Summary of the invention
Plant weight (1g sample adds 3.5ml extract, suitably can add according to material difference), prepares extract and is placed on ice.
Sample is placed in mortar and uses liquid nitrogen grinding, add after grinding in extract and leaving standstill (3-4 hour) on ice.
With centrifuge 8000rpm/40min/4 DEG C or 11100rpm/20min/4 DEG C.
Extract supernatant and obtain phytoprotein enzyme.
Phytoprotein enzyme gets certain amount, is dissolved in water, is added in 45ml bottle, can uses 300h.
Floated by the suction of Cylinder 7mm × 70mm enamel rod.
Constantly evaporate through top heater 54 DEG C ~ 56 DEG C controllable temperatures, reach taste removal except formaldehyde special-effect.
Solve phytoprotein enzyme and do not reach the unvaporized problem of temperature.
Solve and solved taste removal at that time except formaldehyde odor by spraying, can not long-acting taste removal except the problem of formaldehyde.
The method natural biological product, nonpoisonous and tasteless, continuous action, safe and reliable, be 500 times of effects of active carbon.
Detailed description of the invention
Detailed description of the invention one
Plant (soya bean, broad bean and mung bean) 100Kg, be placed on ice, putting into 500L grinds in still, add acetone 350Kg, be placed in mortar and use liquid nitrogen grinding, add after grinding in extract and leaving standstill 3h on ice, temperature is at-6 DEG C, with centrifuge 11100rpm/20min/4 DEG C, extraction obtains supernatant and obtains phytoprotein enzyme 520g, content 99.9%.Getting protease is 0.05g, be dissolved in 100ml water, be added in 45ml plastic bottle, floated by the suction of Cylinder 7mm × 70mm porous enamel rod, constantly evaporate through top heater 54 DEG C ~ 56 DEG C controllable temperatures, reach taste removal except formaldehyde special-effect, carbon monoxide, the formaldehyde of 99%, the hyponitric acid of 95% of " eating " indoor 95%, absorb the benzene of 90%, the trichloro-ethylene of 92%.
Detailed description of the invention two
Plant (corn, wheat and rice) 100Kg, be placed on ice, putting into 500L grinds in still, add acetone 350Kg, be placed in mortar and use liquid nitrogen grinding, add after grinding in extract and leaving standstill 3h on ice, temperature is at-6 DEG C, with centrifuge 11100rpm/20min/4 DEG C, extraction obtains supernatant and obtains phytoprotein enzyme 480g, content 99.9%.Getting protease is 0.05g, be dissolved in 100ml water, be added in 45ml plastic bottle, floated by the suction of Cylinder 7mm × 70mm porous enamel rod, constantly evaporate through top heater 54 DEG C ~ 56 DEG C controllable temperatures, reach taste removal except formaldehyde special-effect, carbon monoxide, the formaldehyde of 99%, the hyponitric acid of 95% of " eating " indoor 95%, absorb the benzene of 90%, the trichloro-ethylene of 92%.
Detailed description of the invention three
Plant (red bean, black soya bean and soybean) 100Kg, be placed on ice, putting into 500L grinds in still, add acetone 350Kg, be placed in mortar and use liquid nitrogen grinding, add after grinding in extract and leaving standstill 3h on ice, temperature is at-6 DEG C, with centrifuge 11100rpm/20min/4 DEG C, extraction obtains supernatant and obtains phytoprotein enzyme 580g, content 99.9%.Getting protease is 0.05g, be dissolved in 100ml water, be added in 45ml plastic bottle, floated by the suction of Cylinder 7mm × 70mm porous enamel rod, constantly evaporate through top heater 54 DEG C ~ 56 DEG C controllable temperatures, reach taste removal except formaldehyde special-effect, carbon monoxide, the formaldehyde of 99%, the hyponitric acid of 95% of " eating " indoor 95%, absorb the benzene of 90%, the trichloro-ethylene of 92%.
Detailed description of the invention four
Plant (wooden bait and mood ear fungus) 100Kg, be placed on ice, putting into 500L grinds in still, add acetone 350Kg, be placed in mortar and use liquid nitrogen grinding, add after grinding in extract and leaving standstill 3h on ice, temperature is at-6 DEG C, with centrifuge 11100rpm/20min/4 DEG C, extraction obtains supernatant and obtains phytoprotein enzyme 460g, content 99.9%.Getting protease is 0.05g, is dissolved in 100ml water, is added in 45ml plastic bottle, is floated, constantly evaporate through top heater 54 DEG C ~ 56 DEG C controllable temperatures by the suction of Cylinder 7mm × 70mm porous enamel rod, reaches taste removal except formaldehyde.

Claims (6)

1. a controlled natural biological taste removal is except the manufacture method of formaldehyde products
Plant is placed on ice, adds solvent, is placed on by liquid nitrogen grinding in mortar,
Add after grinding in extract and leaving standstill 3 ~ 4h on ice, low temperature,
With centrifuge 11100rpm/20min/4 DEG C, extraction obtains supernatant and obtains phytoprotein enzyme.
Get protease and water preparation, be added in plastic bottle,
Floated by the suction of Cylinder 7mm × 70mm porous enamel rod,
Constantly evaporate through the controlled uniform temperature of top heater, reach indoor deodoring except formaldehyde
The carbon monoxide of 95%, the formaldehyde of 99%, the hyponitric acid of 95%, the benzene of 90%, the trichloro-ethylene of 92%.
2. a kind of controlled natural biological taste removal as claimed in claim 1 is except the manufacture method of formaldehyde products, it is characterized in that: described plant is soya bean, broad bean, mung bean, corn, wheat, rice, red bean, black soya bean, soybean, wooden bait and mood ear fungus.
3. a kind of controlled natural biological taste removal as described in claim 1 formula 2, except the manufacture method of formaldehyde products, is characterized in that: described solvent is ethanol, ethyl acetate, acetone, methyl alcohol and DMF.
4. a kind of controlled natural biological taste removal as described in claim 1 formula 2, except the manufacture method of formaldehyde products, is characterized in that: described centrifuge 8000rpm/40min/-4 ~ 10 DEG C or 11100rpm/20min/-4 ~ 10 DEG C.
5. a kind of controlled natural biological taste removal as described in claim 1 formula 2, except the manufacture method of formaldehyde products, is characterized in that: described Cylinder is porous enamel rod, wooden stick, fiber rod, paper is excellent, cellular glass is excellent and cloth is excellent.
6. a kind of controlled natural biological taste removal as described in claim 1 formula 2, except the manufacture method of formaldehyde products, is characterized in that: described heater controllable temperature is 40 DEG C ~ 100 DEG C.
CN201510502624.8A 2015-08-17 2015-08-17 Manufacturing method of controlled natural biological odor-removal formaldehyde-removal product Pending CN105126602A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201510502624.8A CN105126602A (en) 2015-08-17 2015-08-17 Manufacturing method of controlled natural biological odor-removal formaldehyde-removal product
CN201610679504.XA CN106178928A (en) 2015-08-17 2016-08-16 A kind of controlled natural biological taste removal is except formaldehyde products and its preparation method and application

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Application Number Priority Date Filing Date Title
CN201510502624.8A CN105126602A (en) 2015-08-17 2015-08-17 Manufacturing method of controlled natural biological odor-removal formaldehyde-removal product

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CN201610679504.XA Pending CN106178928A (en) 2015-08-17 2016-08-16 A kind of controlled natural biological taste removal is except formaldehyde products and its preparation method and application

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106237831A (en) * 2016-08-24 2016-12-21 孙勤龙 A kind of manufacture method of natural plant essential oils taste removal plate
CN107158927A (en) * 2016-06-15 2017-09-15 张园 A kind of zein formaldehyde scavenger and preparation method thereof
CN114307586A (en) * 2022-01-13 2022-04-12 广州天与地投资服务有限公司 Formaldehyde scavenger combining photocatalyst with plant enzyme

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107583361A (en) * 2017-11-02 2018-01-16 无锡风正科技有限公司 A kind of non-dissolving type antibacterial filtrate and preparation method thereof

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2183772Y (en) * 1993-11-02 1994-11-30 中国人民解放军济南军区后勤部军事医学研究所 Air fumigating disinfecting apparatus for heating suction rod
KR101382198B1 (en) * 2012-05-11 2014-04-07 주식회사 화성산업 Manufacture of formaldehyde scavenger using protein hydrolyzates extracted from leather waste
CN103463953A (en) * 2013-09-05 2013-12-25 杨振生 Formaldehyde remover
CN104645819A (en) * 2013-11-21 2015-05-27 马啸天 Production process of soybean protein formaldehyde removing agent
CN104209000A (en) * 2014-08-06 2014-12-17 陈贻波 Method for treating indoor air pollution

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107158927A (en) * 2016-06-15 2017-09-15 张园 A kind of zein formaldehyde scavenger and preparation method thereof
CN106237831A (en) * 2016-08-24 2016-12-21 孙勤龙 A kind of manufacture method of natural plant essential oils taste removal plate
CN114307586A (en) * 2022-01-13 2022-04-12 广州天与地投资服务有限公司 Formaldehyde scavenger combining photocatalyst with plant enzyme

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