CN101130103B - Highly effective composite type foreign smell eliminating agent containing wood, bamboo vinegar liquid extractive - Google Patents

Highly effective composite type foreign smell eliminating agent containing wood, bamboo vinegar liquid extractive Download PDF

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Publication number
CN101130103B
CN101130103B CN 200710069600 CN200710069600A CN101130103B CN 101130103 B CN101130103 B CN 101130103B CN 200710069600 CN200710069600 CN 200710069600 CN 200710069600 A CN200710069600 A CN 200710069600A CN 101130103 B CN101130103 B CN 101130103B
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China
Prior art keywords
bamboo vinegar
wood
eliminating agent
extract
composite type
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Expired - Fee Related
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CN 200710069600
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Chinese (zh)
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CN101130103A (en
Inventor
王衍彬
钱华
童晓青
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Zhejiang Academy of Forestry
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Zhejiang Academy of Forestry
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Publication of CN101130103A publication Critical patent/CN101130103A/en
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Publication of CN101130103B publication Critical patent/CN101130103B/en
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Abstract

The invention discloses a high-effectively composite peculiar smell eliminator of wood and bamboo vinegar liquid extract for indoor and outdoor environment, poultry culturing place and pet, which comprises the following parts: 75-88% wood and bamboo vinegar liquid extract, 10-20% agave plant extract and 0. 5-5% surface activator. The making method of the wood and bamboo vinegar liquid extract comprises the following steps: depositing the wood and bamboo vinegar liquid extract naturally to sediment 7-45d; filtering through diatomite; collecting the filtrate; decompressing and distilling at 60+-2 deg. c under 300+-50pa for 2-5h; collecting distillate liquid. The inveniton can remove odor effectively, which has advantages of nature, security and long time.

Description

A kind of composite type foreign smell eliminating agent that contains wood, bamboo vinegar extract
Technical field
The present invention relates to a kind of composite type foreign smell eliminating agent, especially a kind ofly be used for the composite type foreign smell eliminating agent that contains wood, bamboo vinegar extract that decontamination chamber internal and external environment, poultry are raised place and abnormal flavour that house pet produces.
Background technology
Smell substance is meant that all stimulate organum olfactorium to cause the gaseous matter of people's unhappiness, damage living environment and health.Along with economic growth and social progress, environmental protection consciousness improves gradually, and people have higher requirement to air quality.Abnormal flavour has become one of the world's seven big public hazards as a kind of environmental pollution.
Sources of odor has industrial source and life source.Industrial source is mainly concentrated in process of production, and is healthy very harmful to labourer, influential to everyways such as respiratory system, blood circulation, digestive system, hormonal system, nervous system, mental status.People's work meeting forfeiture olfactory sensation in the serious working environment of stench for a long time, the imbalance of cerebral cortex regulatory function makes people's anorexia, nauseating, dysphoria; absent-minded; efficient is low, and judgment, hypomnesis have very big influence to health and labor protection.The life source occurs in daily life, people always wish that own living environment is with fresh air, but always some abnormal flavour can appear, influence people's mood and healthy, as the stink of the greasy smell in the medicated cigarette flavor in the musty of wardrobe, room, kitchen and fishlike smell, refuse receptacle and toilet, house pet stink on one's body etc.These abnormal flavour mainly are made up of materials such as hydrogen sulfide, ethyl mercaptan, ammonia, trimethylamine, tar, are having a strong impact on people's physical and mental health.Therefore carry out the research of deodorization technology, the elimination stench has major and immediate significance to the harm of health.
At present, the deodorant method has physics method, chemical method, bioanalysis, natural botanical extraction liquid nebulization etc., and the achievement that Japan and Germany obtain in this respect is particularly remarkable.In countries such as the U.S., Canada, utilize the deodorization equipment of spray technique increasingly mature.Though but the deodorizer kind is many, and deficiency is respectively arranged.For example, cover type deodorizer can only be sheltered smelly covering, can not remove, thereby often want residual foreign odor; Absorbent-type deodorizer, because of adsorption capacity is limit, absorbability must reduce or lose when the time comes; Acid-base neutralization type deodorizer, deodorization scope are only limited to the material that can combine with soda acid; Contain the deodorizer of citric acid and maleic acid class, can not remove thio-alcohol foul smell etc.
Summary of the invention
Technical problem to be solved by this invention provide a kind of natural safe, effectively remove the composite type foreign smell eliminating agent that contains wood, bamboo vinegar extract of abnormal flavour, long action time.
The present invention addresses the above problem the technical scheme that is adopted: this foreign smell eliminating agent by weight percentage, wood vinegar extract by 75~88% or bamboo vinegar extract, 10~20% Agavaceae plant extract, 0.5~5% surfactant are formed.
Foreign smell eliminating agent of the present invention is a weak yellow liquid, and pH value is 4~6.
Wood of the present invention, bamboo vinegar extract prepare with following method, and wood vinegar extract or Bamboo vinegar solution were placed precipitation 7~45 days naturally; Use diatomite filtration; The collection filtrate, distilling under reduced pressure is 2~5 hours under 60 ± 2 ℃, 300 ± 50Pa vacuum, collects distillate.
Surfactant of the present invention is one or more the mixture in dodecylbenzene sodium sulfonate, dodecyl sodium sulfate, fatty acid potassium soap, single Tryfac 5573, the hydroxy methocel.
The present invention compared with prior art has following beneficial effect: 1, adopting wood vinegar extract or bamboo vinegar extract, Agavaceae plant extract, surfactant is raw material, and raw material is easy to get, and is cheap, easy to manufacture, and easy to use; 2, wood vinegar extract wherein, bamboo vinegar extract are kept activated state between can be often, the ammonia that makes it with ammonia, amine in smelly forms complex, generate OH-S (phenol-sulfur) key with the sulfur in the sulfur-containing foul, all can effectively remove for Ammonia stench and sulfur-containing foul, the deodorization scope is wide; 3, raw materials used all is the natural materials of generally acknowledging, even contact with food, also can guarantee safety; 4, this foreign smell eliminating agent can be made various forms. be used in every field, the purposes scope is wide, be used for lavatory, refuse bin, freezer, refrigerator etc., deodorization all has good result, especially for the stench of removing Ammonia, thio-alcohol, have better effect, with the liquid deodorant impregnated paper of this agent, cloth etc., make deodorizing sheet or deodorization paper, can directly wrap up fish, food such as meat, seasoning is in refrigerator, and freezer prevents that its stink from shifting and taint of odour to other food, or be used to remove the abnormal flavour of refrigerator, freezer, good result is also arranged.
Description of drawings
Fig. 1 is the concentration curve of ammonia.
Fig. 2 is the concentration curve of hydrogen sulfide.
Fig. 3 is the concentration curve of trimethylamine.
Fig. 4 is the concentration curve of ethyl mercaptan.
The specific embodiment
Foreign smell eliminating agent is made up of 85% bamboo vinegar extract, 13% Agavaceae plant extract and 2% surfactant in the present embodiment.
Bamboo vinegar extract wherein prepares with following method:
(1) gets the 100Kg Bamboo vinegar solution, placed precipitation 30 days naturally;
(2) pass through diatomite filtration;
(3) collect filtrate, distilling under reduced pressure is 4 hours under 60 ℃, 300Pa vacuum, collects distillate 80Kg.This distillate is bamboo vinegar extract.
In bamboo vinegar extract, add Agavaceae plant extract 13Kg then, add dodecyl sodium sulfate 2Kg.Homogenizing 30 minutes under 40Mpa, 60 ℃ of conditions obtains finished product at last.
Wherein bamboo vinegar extract also can be the wood vinegar extract, and the wood vinegar extract prepares with wood vinegar.Tongue orchid extract is the active substance that contains polysaccharide, Saponin and Polyphenols that extracts from Agavaceae plant, and its preparation method is a prior art, no longer describes in detail.Surfactant liquid also can be one or more the mixture in dodecylbenzene sodium sulfonate, dodecyl sodium sulfate, fatty acid potassium soap, single Tryfac 5573, the hydroxy methocel
Using method one: get this foreign smell eliminating agent and be sprayed on toilet, the every cubic metre of amount of spraying is 10mL, and per three days once, can better remove peculiar smell in toilet.
Using method two: get this foreign smell eliminating agent 50mL, be dissolved in 5 liters of 35 ℃ of warm water, be used for pet bathing, can better remove house pet abnormal flavour on one's body.
The effect test of this foreign smell eliminating agent is as follows:
1, assay device
Assay device is the sealed container that lucite is made, the A that partial volume is identical, B two cabins, and the A cabin is a sensing chamber, and the B cabin is the contrast chamber, and volume is 0.28m 3, internal diameter size is 0.65m * 0.65m * 0.67m (wide * height * length), built-in gas collecting device, and planchet, the container top has spray orifice and wire guide.The front has movably seals sampling gate.Deodorizer can be in spray orifice enters closed container during test, and smelly source can conveniently be sent to or take out by sampling gate.The gas collecting bottle also carries out the collection of gas and the analysis of sample by moving door.
Smelly source is all sent in A, B cabin, and the A cabin sprays into deodorizer, and the B cabin does not spray into deodorizer.
2, test specimen
This foreign smell eliminating agent product.
3, detection method foundation
The mensuration gas chromatography of GB/T 14676 air quality trimethylamines
The mensuration gas chromatography of GB/T 14678 air quality hydrogen sulfide, methanthiol, methyl sulfide, methyl disulfide
Mensuration sodium hypochlorite-salicylic acid the spectrophotography of GB/T 14679 air quality ammonia
QB/T2761-2006 light industry standard-indoor air purification product clean-up effect assay method
4, sense environmental conditions
The work chamber actual volume is 0.28m 3Temperature: 18 ℃; Humidity: 56%RH; Illumination: 20W daylight lamp.
5, instrument
Gas chromatogram: Agilent 6890N
403B compressed air type nebulizer: Yuyue Medical Apparatus Co., Ltd., Jiangsu produces.
6, result of the test
Ammonia concentration curve in A, B two cabins referring to Fig. 1, concentration of hydrogen sulfide change curve referring to Fig. 2, trimethylamine concentration curve referring to Fig. 3, ethyl mercaptan concentration curve referring to Fig. 4.

Claims (4)

1. composite type foreign smell eliminating agent that contains wood, bamboo vinegar extract, it by weight percentage, wood vinegar extract by 75~88% or bamboo vinegar extract, 10~20% Agavaceae plant extract, 0.5~5% surfactant are formed, and described Agavaceae plant extract is the active substance that contains polysaccharide, Saponin and Polyphenols that extracts from Agavaceae plant.
2. the composite type foreign smell eliminating agent that contains wood, bamboo vinegar extract according to claim 1 is characterized in that: this foreign smell eliminating agent is a weak yellow liquid, and pH value is 4~6.
3. the composite type foreign smell eliminating agent that contains wood, bamboo vinegar extract according to claim 1 and 2 is characterized in that: described wood vinegar extract or bamboo vinegar extract prepare with following method,
(1) wood vinegar or Bamboo vinegar solution were placed precipitation 7~45 days naturally;
(2) use diatomite filtration;
(3) collect filtrate, distilling under reduced pressure is 2~5 hours under 60 ± 2 ℃, 300 ± 50Pa vacuum, collects distillate.
4. the composite type foreign smell eliminating agent that contains wood, bamboo vinegar extract according to claim 1 is characterized in that: described surfactant is one or more the mixture in dodecylbenzene sodium sulfonate, dodecyl sodium sulfate, fatty acid potassium soap, single Tryfac 5573, the hydroxy methocel.
CN 200710069600 2007-08-03 2007-08-03 Highly effective composite type foreign smell eliminating agent containing wood, bamboo vinegar liquid extractive Expired - Fee Related CN101130103B (en)

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Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
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CN101130103B true CN101130103B (en) 2011-01-12

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Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101433730B (en) * 2008-11-28 2012-08-22 浙江林学院 Treatment agent for domestic refuse containing plant vinegar liquor and uses thereof
CN103333785B (en) * 2013-07-28 2014-08-27 南陵县生产力促进中心 Preparation method of ottelia alismoides vinegar
CN103922868A (en) * 2014-04-24 2014-07-16 南开大学 Odorless organic fertilizer containing charcoal and preparation method thereof
CN104784727A (en) * 2015-03-25 2015-07-22 湖北金日生态能源有限公司 Biological deodorant and using method thereof
CN105435276A (en) * 2015-11-25 2016-03-30 杭州银帆环境科技有限公司 Air deodorant liquid containing wood vinegar and producing method of air deodorant liquid
CN105396163A (en) * 2015-11-25 2016-03-16 杭州银帆环境科技有限公司 Air smell removing liquid containing bamboo vinegar and preparing method of air smell removing liquid
CN105381485A (en) * 2015-11-25 2016-03-09 杭州银帆环境科技有限公司 Herb vinegar-containing air deodorizing liquid and manufacturing method thereof
CN105963745A (en) * 2016-06-01 2016-09-28 浙江华腾牧业有限公司 Deodorant used in pig farm and preparation method thereof
CN107226928A (en) * 2017-06-21 2017-10-03 郑州久源化工有限公司 Rubber eliminating smell agent and preparation method thereof
CN107509640B (en) * 2017-09-15 2020-12-01 彭鸿博 Method for treating pig house excrement and urine by wood vinegar stock solution
CN107980775A (en) * 2017-12-13 2018-05-04 郑州依侬生物科技有限公司 It is a kind of to utilize method of the bamboo vinegar extraction with disease-preventing and yield-increasing functional preparation
CN108479352B (en) * 2018-05-03 2020-10-16 中国海洋大学 Domestic garbage deodorizing bacteriostatic agent and preparation method and treatment method thereof
CN111493088A (en) * 2020-04-29 2020-08-07 广西夏阳环保科技有限公司 Efficient composite 84 disinfectant and preparation method thereof

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