CN105102407B - 链烷烃转化成烯烃的方法和其中使用的催化剂 - Google Patents

链烷烃转化成烯烃的方法和其中使用的催化剂 Download PDF

Info

Publication number
CN105102407B
CN105102407B CN201480018621.0A CN201480018621A CN105102407B CN 105102407 B CN105102407 B CN 105102407B CN 201480018621 A CN201480018621 A CN 201480018621A CN 105102407 B CN105102407 B CN 105102407B
Authority
CN
China
Prior art keywords
catalyst
range
temperature
contact
weight
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201480018621.0A
Other languages
English (en)
Chinese (zh)
Other versions
CN105102407A (zh
Inventor
孔吉·苏里耶
武蒂贴·贾里瓦差拉
布鲁帕尼亚·莱克恩加姆
阿努瓦·农卡姆翁
克萨达·素蒂乌姆蓬
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SCG Chemicals PCL
Original Assignee
SCG Chemicals PCL
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SCG Chemicals PCL filed Critical SCG Chemicals PCL
Priority to CN201810205533.1A priority Critical patent/CN108404903A/zh
Publication of CN105102407A publication Critical patent/CN105102407A/zh
Application granted granted Critical
Publication of CN105102407B publication Critical patent/CN105102407B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333Catalytic processes
    • C07C5/3335Catalytic processes with metals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/08Silica
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/10Magnesium; Oxides or hydroxides thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24Chromium, molybdenum or tungsten
    • B01J23/30Tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/90Regeneration or reactivation
    • B01J23/92Regeneration or reactivation of catalysts comprising metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084Y-type faujasite
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/90Regeneration or reactivation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00Catalysts, in general, characterised by their form or physical properties
    • B01J35/19Catalysts containing parts with different compositions
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/16Reducing
    • B01J37/18Reducing with gases containing free hydrogen
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/02Heat treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00Regeneration or reactivation of catalysts, in general
    • B01J38/04Gas or vapour treating; Treating by using liquids vaporisable upon contacting spent catalyst
    • B01J38/12Treating with free oxygen-containing gas
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333Catalytic processes
    • C07C5/3332Catalytic processes with metal oxides or metal sulfides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C6/00Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
    • C07C6/02Metathesis reactions at an unsaturated carbon-to-carbon bond
    • C07C6/04Metathesis reactions at an unsaturated carbon-to-carbon bond at a carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02Boron or aluminium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08Silica
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10Magnesium; Oxides or hydroxides thereof
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18Carbon
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/28Molybdenum
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24Chromium, molybdenum or tungsten
    • C07C2523/30Tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32Manganese, technetium or rhenium
    • C07C2523/36Rhenium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/08Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • C07C2529/16Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/65Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00Catalysts comprising molecular sieves
    • C07C2529/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/584Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201480018621.0A 2013-04-03 2014-03-28 链烷烃转化成烯烃的方法和其中使用的催化剂 Expired - Fee Related CN105102407B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810205533.1A CN108404903A (zh) 2013-04-03 2014-03-28 链烷烃转化成烯烃的方法和其中使用的催化剂

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP13162080.9 2013-04-03
EP13162080.9A EP2786978B1 (en) 2013-04-03 2013-04-03 Process for converting paraffin to olefin and catalyst for use therein
PCT/TH2014/000012 WO2014163590A1 (en) 2013-04-03 2014-03-28 Process for converting paraffin to olefin and catalyst for use therein

Related Child Applications (1)

Application Number Title Priority Date Filing Date
CN201810205533.1A Division CN108404903A (zh) 2013-04-03 2014-03-28 链烷烃转化成烯烃的方法和其中使用的催化剂

Publications (2)

Publication Number Publication Date
CN105102407A CN105102407A (zh) 2015-11-25
CN105102407B true CN105102407B (zh) 2018-03-16

Family

ID=48050484

Family Applications (2)

Application Number Title Priority Date Filing Date
CN201810205533.1A Pending CN108404903A (zh) 2013-04-03 2014-03-28 链烷烃转化成烯烃的方法和其中使用的催化剂
CN201480018621.0A Expired - Fee Related CN105102407B (zh) 2013-04-03 2014-03-28 链烷烃转化成烯烃的方法和其中使用的催化剂

Family Applications Before (1)

Application Number Title Priority Date Filing Date
CN201810205533.1A Pending CN108404903A (zh) 2013-04-03 2014-03-28 链烷烃转化成烯烃的方法和其中使用的催化剂

Country Status (8)

Country Link
US (2) US10329219B2 (OSRAM)
EP (2) EP2975013A1 (OSRAM)
JP (2) JP6289607B2 (OSRAM)
KR (1) KR20150139870A (OSRAM)
CN (2) CN108404903A (OSRAM)
SG (1) SG11201508020XA (OSRAM)
TW (2) TWI629255B (OSRAM)
WO (1) WO2014163590A1 (OSRAM)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2975013A1 (en) 2013-04-03 2016-01-20 Scg Chemicals Co. Ltd. Catalyst for converting paraffin to olefin
EP3000800A1 (en) * 2014-09-23 2016-03-30 Borealis AG An endothermic gas phase catalytic dehydrogenation process
JP6533589B2 (ja) * 2014-10-28 2019-06-19 エスエムエイチ カンパニー,リミテッド 混合金属酸化物−ゼオライト担体上のメタセシス触媒およびそれを使用するためのプロセス
EP3050621A1 (en) * 2015-01-30 2016-08-03 Terramark Markencreation GmbH Metathesis catalyst and process for producing olefin
EP3238819B1 (en) * 2015-03-20 2020-11-04 SMH Co., Ltd. Process for olefin metathesis
WO2017003014A1 (ko) * 2015-06-30 2017-01-05 한국화학연구원 환원가스 전처리 후 연속 반응-재생 및 유동식 올레핀 제조방법
US10221110B2 (en) * 2016-12-08 2019-03-05 Evonik Degussa Gmbh Dehydrogenation of olefin-rich hydrocarbon mixtures
ES2881638T3 (es) * 2016-12-13 2021-11-30 Smh Co Ltd Proceso para la conversión de una alimentación de hidrocarburos que comprende un compuesto hidrocarburo saturado a productos de olefinas
PL3335793T3 (pl) * 2016-12-13 2020-11-02 SMH Co., Ltd. Katalizator konwersji wsadu węglowodorowego zawierającego nasycony związek węglowodorowy w produkty olefinowe
CA3043870A1 (en) * 2016-12-13 2018-06-21 SMH Co., Ltd. Hydrocarbon conversion catalyst system
KR101971085B1 (ko) * 2016-12-30 2019-04-22 에스케이가스 주식회사 올레핀 제조용 촉매 및 이를 이용한 연속 반응-재생 올레핀 제조방법
KR102179574B1 (ko) * 2017-06-07 2020-11-16 에스케이가스 주식회사 환원 전처리를 포함하는 올레핀 제조 방법
MX2020000608A (es) * 2017-07-18 2020-09-10 Lummus Technology Inc Proceso integrado de craqueo termico y deshidrogenacion para la produccion de olefinas.
CN109833903A (zh) * 2017-11-29 2019-06-04 中国科学院大连化学物理研究所 一种低碳烷烃无氧脱氢制烯烃催化剂及其制备和应用
ES2972823T3 (es) * 2018-07-20 2024-06-17 Scg Chemicals Co Ltd Proceso para la separación de etilbenceno de otros compuestos aromáticos C8
KR102834941B1 (ko) * 2018-12-26 2025-07-17 피티티 글로벌 케미컬 퍼블릭 컴퍼니 리미티드 C4-c7 탄화수소로부터 경질 올레핀의 제조를 위한 촉매
JP6802311B2 (ja) * 2019-03-26 2020-12-16 エスエムエイチ カンパニー,リミテッド 混合金属酸化物−ゼオライト担体上のメタセシス触媒およびそれを使用するためのプロセス

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4138326A (en) * 1977-08-12 1979-02-06 Gulf Research & Development Hydrotreating process and catalyst
US4956517A (en) * 1989-12-29 1990-09-11 Mobil Oil Corporation Dehydrogenation process utilizing a pillared layered silicate plus a base metal or noble metal
CN1639091A (zh) * 2002-03-07 2005-07-13 Abb拉默斯环球有限公司 从c4烯烃物流生产丙烯和己烯的方法
CN1795153A (zh) * 2003-03-25 2006-06-28 Cpe里昂继续培训与研究公司 固定在载体上的金属化合物、所述化合物的制造方法及其在烃的复分解反应中的用途
CN1852878A (zh) * 2003-07-15 2006-10-25 Abb拉默斯环球有限公司 用于最大量生产丙烯的c4烯烃料流的加工方法
CN101023050A (zh) * 2004-07-02 2007-08-22 Cpe里昂继续培训与研究公司 包含烯属双键的化合物、特别是烯烃的复分解方法
WO2010111199A2 (en) * 2009-03-25 2010-09-30 Lummus Technology Inc. Production of propylene from butane

Family Cites Families (43)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2124584A (en) * 1936-09-30 1938-07-26 Universal Oil Prod Co Conversion of hydrocarbons
US3173855A (en) 1961-12-29 1965-03-16 Socony Mobil Oil Co Inc Catalytic conversion with activated catalyst
US3175967A (en) 1962-01-11 1965-03-30 Socony Mobil Oil Co Inc Catalytic conversion with activated catalyst
US3321545A (en) * 1964-06-30 1967-05-23 Exxon Research Engineering Co Olefins by hydrogen transfer
FR2016856A6 (OSRAM) 1968-08-02 1970-05-15 Sun Oil Co
US3598725A (en) 1969-03-20 1971-08-10 Universal Oil Prod Co Hydrocarbon desulfurization with a rhenium catalyst on siliceous carrier material
US3598723A (en) 1969-06-30 1971-08-10 Universal Oil Prod Co Hydrocarbon hydroprocessing
US4323482A (en) * 1979-08-14 1982-04-06 University Of Delaware Catalyst and method of preparation
FR2561946B1 (fr) 1984-03-30 1986-10-03 Pro Catalyse Nouveau catalyseur d'hydrocraquage destine a la production de distillats moyens
US4684755A (en) * 1985-09-27 1987-08-04 Ici Australia Limited Catalyzed process
JPS6328452A (ja) * 1986-07-22 1988-02-06 Babcock Hitachi Kk 窒素酸化物還元用触媒およびその製造方法
EP0276096A1 (en) * 1987-01-21 1988-07-27 Mobil Oil Corporation An olefin metathesis process
AU6818090A (en) * 1989-12-21 1991-06-27 Mobil Oil Corporation Dehydrogenation of hydrocarbons over pillared silicates
US5171921A (en) 1991-04-26 1992-12-15 Arco Chemical Technology, L.P. Production of olefins
GB9208154D0 (en) * 1991-05-03 1992-05-27 Ici Plc Transhydrogenation
JPH07509272A (ja) * 1992-07-28 1995-10-12 ユニオン、オイル、カンパニー、オブ、カリフォルニア 中間留分触媒を用いる水素化分解
FR2770521B1 (fr) * 1997-10-31 1999-12-10 Inst Francais Du Petrole Procede de deshydrogenation d'hydrocarbures aliphatiques satures en hydrocarbures olefiniques
GB9819645D0 (en) 1998-09-10 1998-11-04 Bp Chem Int Ltd Process
US6239057B1 (en) 1999-01-15 2001-05-29 Uop Llc Catalyst for the conversion of low carbon number aliphatic hydrocarbons to higher carbon number hydrocarbons, process for preparing the catalyst and process using the catalyst
US6534437B2 (en) 1999-01-15 2003-03-18 Akzo Nobel N.V. Process for preparing a mixed metal catalyst composition
US6346228B1 (en) 1999-02-19 2002-02-12 Council Of Scientific And Industrial Research Hydrophobic multicomponent catalyst useful for direct oxidation of hydrogen to hydrogen peroxide
AU6541200A (en) * 1999-07-06 2001-01-22 Sasol Technology (Pty) Ltd. High temperature metathesis process
US20050124839A1 (en) * 2001-06-13 2005-06-09 Gartside Robert J. Catalyst and process for the metathesis of ethylene and butene to produce propylene
CN1151883C (zh) * 2001-08-29 2004-06-02 中国科学院大连化学物理研究所 用于由乙烯和丁烯歧化制丙烯反应的催化剂及其制备方法
EP1693107A1 (en) * 2005-02-11 2006-08-23 Rohm And Haas Company Method for preparing mixed-metal oxide catalysts and the catalysts produced thereby
CN1872961B (zh) * 2005-05-31 2010-05-12 中国石油化工股份有限公司 一种烃油加氢处理方法
KR101270191B1 (ko) * 2005-08-15 2013-05-31 상하이 리서치 인스티튜트 오브 페트로케미칼 테크놀로지 시노펙 유동상 촉매를 사용하여 촉매 분해에 의하여 에틸렌 및 프로필렌을 제조하는 방법
CN101112685B (zh) * 2006-07-27 2011-11-09 中国石油化工股份有限公司 一种高活性w基催化剂的制备方法及其应用
CN101172247B (zh) * 2006-10-31 2010-05-19 中国石油化工股份有限公司 碳四烯烃制丙烯和乙烯的催化剂、再生及其应用
US7795469B2 (en) * 2006-12-21 2010-09-14 Rohm And Haas Company Process for the selective (AMM) oxidation of lower molecular weight alkanes and alkenes
US8802582B2 (en) 2007-01-09 2014-08-12 Catalytic Solutions, Inc. High temperature ammonia SCR catalyst and method of using the catalyst
DE102007006647A1 (de) * 2007-02-06 2008-08-07 Basf Se Verfahren zur Regenerierung eines im Rahmen einer heterogen katalysierten partiellen Dehydrierung eines Kohlenwasserstoffs deaktivierten Katalysatorbetts
US7823827B2 (en) * 2007-07-11 2010-11-02 Piasecki Frederick W Vectored thruster augmented aircraft
US20090145808A1 (en) 2007-11-30 2009-06-11 Saudi Arabian Oil Company Catalyst to attain low sulfur diesel
CN101939100A (zh) * 2008-01-28 2011-01-05 埃克森美孚化学专利公司 由甲烷生产芳族化合物
US8343335B2 (en) * 2008-02-21 2013-01-01 Exxonmobil Research And Engineering Company Production of shaped silica bodies
US8906971B2 (en) 2009-08-10 2014-12-09 Mississippi State University Catalysts and process for liquid hydrocarbon fuel production
US10850266B2 (en) 2009-08-10 2020-12-01 Mississippi State University Catalysts and process for liquid hydrocarbon fuel production
JP5711993B2 (ja) * 2011-02-15 2015-05-07 旭化成ケミカルズ株式会社 導電性の流動層反応用触媒及びその製造方法並びにプロピレンの製造方法
US9079159B2 (en) * 2011-04-14 2015-07-14 Uop Llc Olefin metathesis process using a treated tungsten oxide catalyst
EP2975013A1 (en) * 2013-04-03 2016-01-20 Scg Chemicals Co. Ltd. Catalyst for converting paraffin to olefin
JP6533589B2 (ja) 2014-10-28 2019-06-19 エスエムエイチ カンパニー,リミテッド 混合金属酸化物−ゼオライト担体上のメタセシス触媒およびそれを使用するためのプロセス
EP3050621A1 (en) 2015-01-30 2016-08-03 Terramark Markencreation GmbH Metathesis catalyst and process for producing olefin

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4138326A (en) * 1977-08-12 1979-02-06 Gulf Research & Development Hydrotreating process and catalyst
US4956517A (en) * 1989-12-29 1990-09-11 Mobil Oil Corporation Dehydrogenation process utilizing a pillared layered silicate plus a base metal or noble metal
CN1639091A (zh) * 2002-03-07 2005-07-13 Abb拉默斯环球有限公司 从c4烯烃物流生产丙烯和己烯的方法
CN1795153A (zh) * 2003-03-25 2006-06-28 Cpe里昂继续培训与研究公司 固定在载体上的金属化合物、所述化合物的制造方法及其在烃的复分解反应中的用途
CN1852878A (zh) * 2003-07-15 2006-10-25 Abb拉默斯环球有限公司 用于最大量生产丙烯的c4烯烃料流的加工方法
CN101023050A (zh) * 2004-07-02 2007-08-22 Cpe里昂继续培训与研究公司 包含烯属双键的化合物、特别是烯烃的复分解方法
WO2010111199A2 (en) * 2009-03-25 2010-09-30 Lummus Technology Inc. Production of propylene from butane

Also Published As

Publication number Publication date
WO2014163590A1 (en) 2014-10-09
SG11201508020XA (en) 2015-10-29
TWI629255B (zh) 2018-07-11
EP2975013A1 (en) 2016-01-20
TWI648245B (zh) 2019-01-21
TW201805264A (zh) 2018-02-16
US10329220B2 (en) 2019-06-25
CN105102407A (zh) 2015-11-25
CN108404903A (zh) 2018-08-17
US20170190639A9 (en) 2017-07-06
US20170267609A1 (en) 2017-09-21
JP2018069231A (ja) 2018-05-10
US10329219B2 (en) 2019-06-25
EP2786978A1 (en) 2014-10-08
KR20150139870A (ko) 2015-12-14
JP6289607B2 (ja) 2018-03-07
TW201504199A (zh) 2015-02-01
US20160326069A1 (en) 2016-11-10
EP2786978B1 (en) 2016-12-07
JP6563457B2 (ja) 2019-08-21
JP2016519681A (ja) 2016-07-07

Similar Documents

Publication Publication Date Title
CN105102407B (zh) 链烷烃转化成烯烃的方法和其中使用的催化剂
US20130261365A1 (en) Process for the Production of Xylenes and Light Olefins from Heavy Aromatics
US9221037B2 (en) Multimetal zeolites based catalyst for transalkylation of heavy reformate to produce xylenes and petrochemical feedstocks
AU2016220415B2 (en) Upgrading paraffins to distillates and lube basestocks
CA2945839A1 (en) Catalyst and method for aromatization of c3-c4 gases, light hydrocarbon fractions and aliphatic alcohols, as well as mixtures thereof
JP6728351B2 (ja) 非環式c5化合物の生成
CN103058814B (zh) 一种由液化气生产芳烃和烯烃的方法
BR112017027711B1 (pt) Processo para fabricar éter metil terc-butílico (mtbe) e hidrocarbonetos
CA3043870A1 (en) Hydrocarbon conversion catalyst system
Sineva et al. Synergistic effect in Co–zeolite catalyzed transformations of hydrocarbons under Fischer–Tropsch conditions
EP2788305A1 (en) Mixed-phase operation of butenes metathesis process for maximizing propylene production
WO2025146438A1 (en) Systems and methods of producing olefins products using alternate upstream and downstream separation processes at low-temperature metathesis conditions
WO2025109559A2 (en) Methods and systems to produce ethylene, propylene, and/or 1-hexene from butenes using metathesis in combination with steam cracking or fluid catalytic cracking
WO2025132350A1 (en) Methods and systems for producing ethylene and propylene involving metathesis of a butene stream
WO2025157807A1 (en) Systems and methods of producing hex-1-ene, ethene, and propene using low-temperature metathesis
JP2019059704A (ja) 芳香族化合物の製造方法
BRPI0918229B1 (pt) Catalisador de metátese de isomerização bifuncional, processo para a produção de propileno e processo de preparação de um catalisador de metátese de isomerização bifuncional

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20180316

Termination date: 20210328