CN105084929A - Heat-insulation fireproof wallboard for interior wall and preparation method of fireproof materials of heat-insulation fireproof wallboard - Google Patents
Heat-insulation fireproof wallboard for interior wall and preparation method of fireproof materials of heat-insulation fireproof wallboard Download PDFInfo
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- 239000000463 material Substances 0.000 title claims abstract description 77
- 238000009413 insulation Methods 0.000 title claims abstract description 22
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 56
- 229960001866 silicon dioxide Drugs 0.000 claims abstract description 38
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 36
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229920005990 polystyrene resin Polymers 0.000 claims abstract description 31
- 239000000741 silica gel Substances 0.000 claims abstract description 20
- 229910002027 silica gel Inorganic materials 0.000 claims abstract description 20
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims abstract description 19
- 229920000053 polysorbate 80 Polymers 0.000 claims abstract description 19
- 229960000583 acetic acid Drugs 0.000 claims abstract description 18
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 18
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 18
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 18
- 235000012239 silicon dioxide Nutrition 0.000 claims abstract description 18
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000004927 clay Substances 0.000 claims abstract description 17
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 16
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 16
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 15
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 15
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 15
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000004570 mortar (masonry) Substances 0.000 claims abstract description 8
- 239000003063 flame retardant Substances 0.000 claims description 30
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 22
- 229920003987 resole Polymers 0.000 claims description 20
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims description 18
- 235000019353 potassium silicate Nutrition 0.000 claims description 17
- 239000002699 waste material Substances 0.000 claims description 16
- 230000032683 aging Effects 0.000 claims description 15
- 238000004079 fireproofing Methods 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 238000002791 soaking Methods 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 7
- 239000006261 foam material Substances 0.000 claims description 6
- ZEMPKEQAKRGZGQ-AAKVHIHISA-N 2,3-bis[[(z)-12-hydroxyoctadec-9-enoyl]oxy]propyl (z)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCCC(O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(O)CCCCCC)COC(=O)CCCCCCC\C=C/CC(O)CCCCCC ZEMPKEQAKRGZGQ-AAKVHIHISA-N 0.000 claims description 5
- BSWXAWQTMPECAK-UHFFFAOYSA-N 6,6-diethyloctyl dihydrogen phosphate Chemical compound CCC(CC)(CC)CCCCCOP(O)(O)=O BSWXAWQTMPECAK-UHFFFAOYSA-N 0.000 claims description 5
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 5
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 5
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 5
- 229910052570 clay Inorganic materials 0.000 claims description 5
- 230000029087 digestion Effects 0.000 claims description 5
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 5
- 238000007599 discharging Methods 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 239000003999 initiator Substances 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims description 5
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 claims description 5
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 claims description 5
- 238000010792 warming Methods 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 3
- 239000004342 Benzoyl peroxide Substances 0.000 claims description 3
- AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 claims description 3
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 abstract description 3
- 239000001301 oxygen Substances 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract 1
- 239000004115 Sodium Silicate Substances 0.000 abstract 1
- 238000005299 abrasion Methods 0.000 abstract 1
- 239000002253 acid Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000004088 foaming agent Substances 0.000 abstract 1
- 239000004816 latex Substances 0.000 abstract 1
- 229920000126 latex Polymers 0.000 abstract 1
- 239000005011 phenolic resin Substances 0.000 abstract 1
- 229920001568 phenolic resin Polymers 0.000 abstract 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 abstract 1
- 229940068968 polysorbate 80 Drugs 0.000 abstract 1
- 229910052911 sodium silicate Inorganic materials 0.000 abstract 1
- -1 5 parts Chemical compound 0.000 description 7
- 230000000694 effects Effects 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 150000003626 triacylglycerols Chemical class 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000001413 cellular effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
Abstract
The invention discloses a heat-insulation fireproof wallboard for an interior wall. The wallboard comprises a base layer, a bonding layer, a heat insulation layer, a plastering mortar layer, a fireproof layer, a waterproof layer, a latex layer, a decoration coating and an abrasion resisting layer which are sequentially arranged from inside to outside. The fireproof layer is made of fireproof materials. The fireproof materials comprise, by weight, 20-30 parts of silica gel, 1-2 parts of glacial acetic acid, 30-40 parts of phenolic resin, 15-25 parts of modified polystyrene resin materials, 1-3 parts of foaming agent, 1-2 parts of polysorbate 80, 1-3 parts of magnesium oxide, 1-5 parts of aluminum oxide, 15-20 parts of building rubbish, 20-30 parts of clay, 2-8 parts of silicon dioxide, 5-10 parts of sodium silicate, 15-20 parts of manganolite, 5-15 parts of kaolin, 10-20 parts of water, 1-2 parts of p-toluenusulfonic acid and 0.52-1 part of phosphoric acid. The invention further discloses a preparation method of the fireproof materials of the heat-insulation fireproof wallboard for the interior wall. The technical requirements that materials of the wallboard are safe, saves energy and achieves heat insulation are met, and the limit oxygen index is larger than 40.
Description
Technical field
The present invention relates to wallboard technical field, particularly relate to the preparation method of a kind of insulated fire interior wall wallboard and fire-retardant material thereof.
Background technology
China's construction unit area energy consumption is developed country 3-5 times, vigorously promotes the use along with in residential housing, and wallboard is used for inner wall decoration and insulation is extensively promoted and approves.But meanwhile, the fire safety problem of wallboard is also put in face of us, in succession there is the situation of inner wall of building plate fire in recent year, cause serious personal's injures and deaths and property damage, build inflammable flammable inside thermal conservation material and become the new disaster hidden-trouble of a class, therefore, the upgrading of the fire resistance of inner wall of building wallboard has become problem in the urgent need to address, based on the high insulating effect of existing organic heat-insulation wall plate, fire resistance is poor, the fire resistance of mineral-type heat-insulation wall plate is good, the fact of heat insulation effect difference, how to prepare a kind of high temperature effective, the wallboard of fire resistance excellence becomes the current technical issues that need to address.
Summary of the invention
The present invention proposes a kind of insulated fire interior wall wallboard, meet the technical requirements of wall board material fire safety, energy-saving heat preserving, limiting oxygen index(LOI) index is greater than 40.
A kind of insulated fire interior wall wallboard that the present invention proposes, comprise set gradually from the inside to the outside basic unit, tack coat, thermal insulation layer, plastering mortar layer, fireproofing, waterproof layer, emulsion layer, decorative coveringn and wearing layer; Described fireproofing adopts fire-retardant material to make; Silica gel 20-30 part, glacial acetic acid 1-2 part, resol 30-40 part, modified polystyrene resin material 15-25 part, whipping agent 1-3 part, tween 80 1-2 part, magnesium oxide 1-3 part, aluminum oxide 1-5 part, building waste 15-20 part, clay 20-30 part, silicon-dioxide 2-8 part, water glass 5-10 part, manganolite 15-20 part, kaolin 5-15 part, water 10-20 part, to methylsulfonic acid 1-2 part, phosphoric acid 0.52-1 part.
Preferably, the production method of modified polystyrene resin material is:
Taking 100 parts of deionized waters by weight sends in agitator, controls agitator speed 200-300r/min; Add 1-2 part triethyl hexyl phosphoric acid, 5-10 part sodium sulfate mixes; Continue to add 20-40 part vinylbenzene, 1-3 part triglyceride, 1-2 part initiator benzoyl peroxide, 0.2-0.5 part peroxidized t-butyl perbenzoate and 0.5-1.2 part Viscotrol C to mix; The material obtained is sent in reactor, add 20-30 part Poly Brominated Diphenyl Ethers, 1-2 part dicumyl peroxide stirs, stirring velocity is 300-400r/min, from room temperature to 90-95 DEG C, heat-up rate controls at 1-2 DEG C/min, insulation reaction, soaking time is 2-6h, in reactor, add 0.1-0.2 part Tristearoylglycerol again stir, then be warming up to 130-140 DEG C, control pressure is 0.4-0.6Mpa, maintains 4h, be cooled to room temperature discharging, obtain modified polystyrene resin material.
Preferably, whipping agent is by one or more compositions of sodium hydroxide, sherwood oil, N, N-dinitrosopentamethlyene tetramine and the sub-terephthalamide of N, N-dimethyl-N, N-bis-.
Preferably, the weight ratio of silica gel, resol and modified polystyrene resin material is 24-26:34-36:20-23.
Preferably, building waste, clay, silicon-dioxide, water glass, manganolite and kaolinic weight ratio are 16-18:24-26:4-6:6-8:16-18:8-10.
Preferably, be 1.2-1.6:0.6-0.8:2-2.4:1.6-1.8 to the weight ratio of methylsulfonic acid, phosphoric acid, whipping agent and tween 80.
Preferably, the raw material of described fire-retardant material comprises by weight: silica gel 24-26 part, glacial acetic acid 1.2-1.4 part, resol 34-36 part, modified polystyrene resin material 20-23 part, whipping agent 2-2.4 part, tween 80 1.6-1.8 part, magnesium oxide 2-2.6 part, aluminum oxide 2-4 part, building waste 16-18 part, clay 24-26 part, silicon-dioxide 4-6 part, water glass 6-8 part, manganolite 16-18 part, kaolin 8-10 part, water 12-16 part, to methylsulfonic acid 1.2-1.6 part, phosphoric acid 0.6-0.8 part.
The preparation method of the fire-retardant material of a kind of insulated fire interior wall wallboard that the present invention also proposes, comprises the steps:
By silica gel, modified polystyrene resin material, glacial acetic acid and resol are placed in agitator and stir, churning time is 20-30min, whipping temp is 50-60 DEG C, continue to add building waste, clay, magnesium oxide, aluminum oxide, silicon-dioxide, water glass, manganolite, heat after kaolin and water mix, Heating temperature is 70-80 DEG C, continue to add tween 80, whipping agent, to methylsulfonic acid, phosphoric acid is uniformly mixed, churning time is 8-12min, then send in thermostatic chamber and be incubated 20-26h, soaking time is 60-70 DEG C, obtain foam material, extrusion molding, then ageing in ageing room is sent into, Aging Temperature is 50-60 DEG C, digestion time is 15-20h, obtain the fire-retardant material of insulated fire interior wall wallboard.
Preferably, silica gel, modified polystyrene resin material, glacial acetic acid and resol are placed in agitator and stir, churning time is 24-26min, and whipping temp is 55-57 DEG C.
Preferably, add tween 80, whipping agent, be uniformly mixed methylsulfonic acid, phosphoric acid, churning time is 10-11min, and then send in thermostatic chamber and be incubated 22-24h, soaking time is 64-66 DEG C.
In the present invention, silica gel, formed after glacial acetic acid and resol mixing there is certain coupled action can foam material, and with silicon-dioxide in goods, water glass, kaolin, manganolite acting in conjunction forms special silicon key, again with major ingredient modified polystyrene resin material, major ingredient resol, emulsifying agent, whipping agent, solidifying agent acting in conjunction is foamed, form similar cellular material, goods are insulated fire not only, and the material formed after foaming is wound around encirclement by special silicon key mutually, when fire occurs, the material formed burns into carbon shape structure instantaneously, the effect extinguished instantaneously can be played to flame, thus effectively organize fire spreading, goods not only maintain goods heat-insulating property, combustionproperty can be promoted to does not fire A2 level material, modified polystyrene resin material thermal conductivity prepared by the certain technique of further employing is low, flame retardant properties is good, act synergistically with other flame retardance elements, goods fire performance is very excellent, the present invention meets wall board material fire safety, the technical requirements of energy-saving heat preserving, limiting oxygen index(LOI) index is greater than 40.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of insulated fire interior wall wallboard, comprise set gradually from the inside to the outside basic unit, tack coat, thermal insulation layer, plastering mortar layer, fireproofing, waterproof layer, emulsion layer, decorative coveringn and wearing layer; Described fireproofing adopts fire-retardant material to make; The raw material of described fire-retardant material comprises by weight: 20 parts, silica gel, glacial acetic acid 2 parts, 30 parts, resol, modified polystyrene resin material 25 parts, whipping agent 1 part, tween 80 2 parts, 1 part, magnesium oxide, 5 parts, aluminum oxide, building waste 15 parts, clay 30 parts, silicon-dioxide 2 parts, water glass 10 parts, manganolite 15 parts, kaolin 15 parts, 10 parts, water, to methylsulfonic acid 2 parts, phosphoric acid 0.52 part.
Embodiment 2
A kind of insulated fire interior wall wallboard, comprise set gradually from the inside to the outside basic unit, tack coat, thermal insulation layer, plastering mortar layer, fireproofing, waterproof layer, emulsion layer, decorative coveringn and wearing layer; Described fireproofing adopts fire-retardant material to make; The raw material of described fire-retardant material comprises by weight: 30 parts, silica gel, glacial acetic acid 1 part, 40 parts, resol, modified polystyrene resin material 15 parts, whipping agent 3 parts, tween 80 1 part, 3 parts, magnesium oxide, 1 part, aluminum oxide, building waste 20 parts, clay 20 parts, silicon-dioxide 8 parts, water glass 5 parts, manganolite 20 parts, kaolin 5 parts, 20 parts, water, to methylsulfonic acid 1 part, phosphatase 11 part.
Embodiment 3
A kind of insulated fire interior wall wallboard, comprise set gradually from the inside to the outside basic unit, tack coat, thermal insulation layer, plastering mortar layer, fireproofing, waterproof layer, emulsion layer, decorative coveringn and wearing layer; Described fireproofing adopts fire-retardant material to make; The raw material of described fire-retardant material comprises by weight: 26 parts, silica gel, glacial acetic acid 1.2 parts, 36 parts, resol, modified polystyrene resin material 20 parts, whipping agent 2.4 parts, tween 80 1.6 parts, 2.6 parts, magnesium oxide, 2 parts, aluminum oxide, building waste 18 parts, clay 24 parts, silicon-dioxide 6 parts, water glass 6 parts, manganolite 18 parts, kaolin 8 parts, 16 parts, water, to methylsulfonic acid 1.2 parts, phosphoric acid 0.8 part.
Wherein whipping agent is N, N-dinitrosopentamethlyene tetramine.
The production method of modified polystyrene resin material is:
Taking 100 parts of deionized waters by weight sends in agitator, controls agitator speed 200r/min; Add 2 parts of triethyl hexyl phosphoric acid, 5 parts of sodium sulfate mix; Continue to add 40 parts of vinylbenzene, 1 part of triglyceride, 2 parts of initiator benzoyl peroxides, 0.2 part of peroxidized t-butyl perbenzoate and 1.2 parts of Viscotrol C mix; Sent in reactor by the material obtained, add 20 parts of Poly Brominated Diphenyl Ethers, 2 parts of dicumyl peroxides stir, stirring velocity is 300r/min, from room temperature to 95 DEG C, heat-up rate controls at 1 DEG C/min, insulation reaction, and soaking time is 6h, in reactor, add 0.1 part of Tristearoylglycerol again stir, then be warming up to 140 DEG C, control pressure is 0.4Mpa, maintains 4h, be cooled to room temperature discharging, obtain modified polystyrene resin material.
The preparation method of the fire-retardant material of above-mentioned insulated fire interior wall wallboard, comprises the steps:
By silica gel, modified polystyrene resin material, glacial acetic acid and resol are placed in agitator and stir, churning time is 30min, whipping temp is 50 DEG C, continue to add building waste, clay, magnesium oxide, aluminum oxide, silicon-dioxide, water glass, manganolite, heat after kaolin and water mix, Heating temperature is 80 DEG C, continue to add tween 80, whipping agent, to methylsulfonic acid, phosphoric acid is uniformly mixed, churning time is 8min, then send in thermostatic chamber and be incubated 26h, soaking time is 60 DEG C, obtain foam material, extrusion molding, then ageing in ageing room is sent into, Aging Temperature is 60 DEG C, digestion time is 15h, obtain the fire-retardant material of insulated fire interior wall wallboard.
Embodiment 4
A kind of insulated fire interior wall wallboard, comprise set gradually from the inside to the outside basic unit, tack coat, thermal insulation layer, plastering mortar layer, fireproofing, waterproof layer, emulsion layer, decorative coveringn and wearing layer; Described fireproofing adopts fire-retardant material to make; The raw material of described fire-retardant material comprises by weight: 24 parts, silica gel, glacial acetic acid 1.4 parts, 34 parts, resol, modified polystyrene resin material 23 parts, whipping agent 2 parts, tween 80 1.8 parts, 2 parts, magnesium oxide, 4 parts, aluminum oxide, building waste 16 parts, clay 26 parts, silicon-dioxide 4 parts, water glass 8 parts, manganolite 16 parts, kaolin 10 parts, 12 parts, water, to methylsulfonic acid 1.6 parts, phosphoric acid 0.6 part.
Wherein whipping agent is made up of sodium hydroxide and the sub-terephthalamide of N, N-dimethyl-N, N-bis-.
The production method of modified polystyrene resin material is:
Taking 100 parts of deionized waters by weight sends in agitator, controls agitator speed 300r/min; Add 1 part of triethyl hexyl phosphoric acid, 10 parts of sodium sulfate mix; Continue to add 20 parts of vinylbenzene, 3 parts of triglycerides, 1 part of initiator benzoyl peroxide, 0.5 part of peroxidized t-butyl perbenzoate and 0.5 part of Viscotrol C mix; Sent in reactor by the material obtained, add 30 parts of Poly Brominated Diphenyl Ethers, 1 part of dicumyl peroxide stirs, stirring velocity is 400r/min, from room temperature to 90 DEG C, heat-up rate controls at 2 DEG C/min, insulation reaction, and soaking time is 2h, in reactor, add 0.2 part of Tristearoylglycerol again stir, then be warming up to 130 DEG C, control pressure is 0.6Mpa, maintains 4h, be cooled to room temperature discharging, obtain modified polystyrene resin material.
The preparation method of the fire-retardant material of above-mentioned insulated fire interior wall wallboard, comprises the steps:
By silica gel, modified polystyrene resin material, glacial acetic acid and resol are placed in agitator and stir, churning time is 20min, whipping temp is 60 DEG C, continue to add building waste, clay, magnesium oxide, aluminum oxide, silicon-dioxide, water glass, manganolite, heat after kaolin and water mix, Heating temperature is 70 DEG C, continue to add tween 80, whipping agent, to methylsulfonic acid, phosphoric acid is uniformly mixed, churning time is 12min, then send in thermostatic chamber and be incubated 20h, soaking time is 70 DEG C, obtain foam material, extrusion molding, then ageing in ageing room is sent into, Aging Temperature is 50 DEG C, digestion time is 20h, obtain the fire-retardant material of insulated fire interior wall wallboard.
Embodiment 5
A kind of insulated fire interior wall wallboard, comprise set gradually from the inside to the outside basic unit, tack coat, thermal insulation layer, plastering mortar layer, fireproofing, waterproof layer, emulsion layer, decorative coveringn and wearing layer; Described fireproofing adopts fire-retardant material to make; The raw material of described fire-retardant material comprises by weight: 25 parts, silica gel, glacial acetic acid 1.3 parts, 35 parts, resol, modified polystyrene resin material 22 parts, the sub-terephthalamide of N, N-dimethyl-N, N-bis-2.2 parts, tween 80 1.7 parts, 2.3 parts, magnesium oxide, 3 parts, aluminum oxide, building waste 17 parts, clay 25 parts, silicon-dioxide 5 parts, water glass 7 parts, manganolite 17 parts, kaolin 9 parts, 14 parts, water, to methylsulfonic acid 1.4 parts, phosphoric acid 0.7 part.
The production method of modified polystyrene resin material is:
Taking 100 parts of deionized waters by weight sends in agitator, controls agitator speed 240r/min; Add 1.2 parts of triethyl hexyl phosphoric acid, 8 parts of sodium sulfate mix; Continue to add 30 parts of vinylbenzene, 2 parts of triglycerides, 1.5 parts of initiator benzoyl peroxides, 0.4 part of peroxidized t-butyl perbenzoate and 1 part of Viscotrol C mix; Sent in reactor by the material obtained, add 25 parts of Poly Brominated Diphenyl Ethers, 1.5 parts of dicumyl peroxides stir, stirring velocity is 350r/min, from room temperature to 93 DEG C, heat-up rate controls at 1.2 DEG C/min, insulation reaction, and soaking time is 4h, in reactor, add 0.13 part of Tristearoylglycerol again stir, then be warming up to 135 DEG C, control pressure is 0.5Mpa, maintains 4h, be cooled to room temperature discharging, obtain modified polystyrene resin material.
The preparation method of the fire-retardant material of above-mentioned insulated fire interior wall wallboard, comprises the steps:
By silica gel, modified polystyrene resin material, glacial acetic acid and resol are placed in agitator and stir, churning time is 25min, whipping temp is 55 DEG C, continue to add building waste, clay, magnesium oxide, aluminum oxide, silicon-dioxide, water glass, manganolite, heat after kaolin and water mix, Heating temperature is 75 DEG C, continue to add tween 80, whipping agent, to methylsulfonic acid, phosphoric acid is uniformly mixed, churning time is 10min, then send in thermostatic chamber and be incubated 23h, soaking time is 65 DEG C, obtain foam material, extrusion molding, then ageing in ageing room is sent into, Aging Temperature is 55 DEG C, digestion time is 18h, obtain the fire-retardant material of insulated fire interior wall wallboard.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (10)
1. an insulated fire interior wall wallboard, is characterized in that, comprise set gradually from the inside to the outside basic unit, tack coat, thermal insulation layer, plastering mortar layer, fireproofing, waterproof layer, emulsion layer, decorative coveringn and wearing layer; Described fireproofing adopts fire-retardant material to make;
The raw material of described fire-retardant material comprises by weight: silica gel 20-30 part, glacial acetic acid 1-2 part, resol 30-40 part, modified polystyrene resin material 15-25 part, whipping agent 1-3 part, tween 80 1-2 part, magnesium oxide 1-3 part, aluminum oxide 1-5 part, building waste 15-20 part, clay 20-30 part, silicon-dioxide 2-8 part, water glass 5-10 part, manganolite 15-20 part, kaolin 5-15 part, water 10-20 part, to methylsulfonic acid 1-2 part, phosphoric acid 0.52-1 part.
2. insulated fire interior wall wallboard according to claim 1, is characterized in that, the production method of modified polystyrene resin material is:
Taking 100 parts of deionized waters by weight sends in agitator, controls agitator speed 200-300r/min; Add 1-2 part triethyl hexyl phosphoric acid, 5-10 part sodium sulfate mixes; Continue to add 20-40 part vinylbenzene, 1-3 part triglyceride, 1-2 part initiator benzoyl peroxide, 0.2-0.5 part peroxidized t-butyl perbenzoate and 0.5-1.2 part Viscotrol C to mix; The material obtained is sent in reactor, add 20-30 part Poly Brominated Diphenyl Ethers, 1-2 part dicumyl peroxide stirs, stirring velocity is 300-400r/min, from room temperature to 90-95 DEG C, heat-up rate controls at 1-2 DEG C/min, insulation reaction, soaking time is 2-6h, in reactor, add 0.1-0.2 part Tristearoylglycerol again stir, then be warming up to 130-140 DEG C, control pressure is 0.4-0.6Mpa, maintains 4h, be cooled to room temperature discharging, obtain modified polystyrene resin material.
3. insulated fire interior wall wallboard according to claim 1 and 2, is characterized in that, whipping agent is by one or more compositions of sodium hydroxide, sherwood oil, N, N-dinitrosopentamethlyene tetramine and the sub-terephthalamide of N, N-dimethyl-N, N-bis-.
4. the insulated fire interior wall wallboard according to any one of claim 1-3, is characterized in that, the weight ratio of silica gel, resol and modified polystyrene resin material is 24-26:34-36:20-23.
5. the insulated fire interior wall wallboard according to any one of claim 1-4, is characterized in that, building waste, clay, silicon-dioxide, water glass, manganolite and kaolinic weight ratio are 16-18:24-26:4-6:6-8:16-18:8-10.
6. the insulated fire interior wall wallboard according to any one of claim 1-5, is characterized in that, is 1.2-1.6:0.6-0.8:2-2.4:1.6-1.8 to the weight ratio of methylsulfonic acid, phosphoric acid, whipping agent and tween 80.
7. the insulated fire interior wall wallboard according to any one of claim 1-6, it is characterized in that, the raw material of described fire-retardant material comprises by weight: silica gel 24-26 part, glacial acetic acid 1.2-1.4 part, resol 34-36 part, modified polystyrene resin material 20-23 part, whipping agent 2-2.4 part, tween 80 1.6-1.8 part, magnesium oxide 2-2.6 part, aluminum oxide 2-4 part, building waste 16-18 part, clay 24-26 part, silicon-dioxide 4-6 part, water glass 6-8 part, manganolite 16-18 part, kaolin 8-10 part, water 12-16 part, to methylsulfonic acid 1.2-1.6 part, phosphoric acid 0.6-0.8 part.
8. a preparation method for the fire-retardant material of the insulated fire interior wall wallboard according to any one of claim 1-7, is characterized in that, comprise the steps:
By silica gel, modified polystyrene resin material, glacial acetic acid and resol are placed in agitator and stir, churning time is 20-30min, whipping temp is 50-60 DEG C, continue to add building waste, clay, magnesium oxide, aluminum oxide, silicon-dioxide, water glass, manganolite, heat after kaolin and water mix, Heating temperature is 70-80 DEG C, continue to add tween 80, whipping agent, to methylsulfonic acid, phosphoric acid is uniformly mixed, churning time is 8-12min, then send in thermostatic chamber and be incubated 20-26h, soaking time is 60-70 DEG C, obtain foam material, extrusion molding, then ageing in ageing room is sent into, Aging Temperature is 50-60 DEG C, digestion time is 15-20h, obtain the fire-retardant material of insulated fire interior wall wallboard.
9. the preparation method of the fire-retardant material of insulated fire interior wall wallboard according to claim 8, it is characterized in that, silica gel, modified polystyrene resin material, glacial acetic acid and resol are placed in agitator stir, churning time is 24-26min, and whipping temp is 55-57 DEG C.
10. the preparation method of the fire-retardant material of insulated fire interior wall wallboard according to claim 8 or claim 9, it is characterized in that, add tween 80, whipping agent, methylsulfonic acid, phosphoric acid are uniformly mixed, churning time is 10-11min, then send in thermostatic chamber and be incubated 22-24h, soaking time is 64-66 DEG C.
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| CN105713506A (en) * | 2016-03-24 | 2016-06-29 | 安徽德全新型建材科技有限公司 | High-temperature-resistant and fire-proof external wallboard |
| CN105796277A (en) * | 2016-04-20 | 2016-07-27 | 苏州兴新维碳纤维有限公司 | Carbon fiber operating table and manufacturing process thereof |
| CN105838024A (en) * | 2016-05-16 | 2016-08-10 | 安徽德全新型建材科技有限公司 | Building external wall panel |
| CN105968703A (en) * | 2016-05-16 | 2016-09-28 | 安徽德全新型建材科技有限公司 | Heat-preservation building outer wallboard |
| CN106049786A (en) * | 2016-06-16 | 2016-10-26 | 安徽德全新型建材科技有限公司 | Elastic fireproof wallboard |
| CN106587888A (en) * | 2016-10-31 | 2017-04-26 | 南宁市大江保温材料有限公司 | Roof thermal insulation layer material |
| CN107569802A (en) * | 2017-10-30 | 2018-01-12 | 山东金立车业有限公司 | A kind of electric fire fighting truck |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN105713506A (en) * | 2016-03-24 | 2016-06-29 | 安徽德全新型建材科技有限公司 | High-temperature-resistant and fire-proof external wallboard |
| CN105796277A (en) * | 2016-04-20 | 2016-07-27 | 苏州兴新维碳纤维有限公司 | Carbon fiber operating table and manufacturing process thereof |
| CN105838024A (en) * | 2016-05-16 | 2016-08-10 | 安徽德全新型建材科技有限公司 | Building external wall panel |
| CN105968703A (en) * | 2016-05-16 | 2016-09-28 | 安徽德全新型建材科技有限公司 | Heat-preservation building outer wallboard |
| CN106049786A (en) * | 2016-06-16 | 2016-10-26 | 安徽德全新型建材科技有限公司 | Elastic fireproof wallboard |
| CN106049786B (en) * | 2016-06-16 | 2018-05-01 | 安徽德全新型建材科技有限公司 | A kind of elastic fireproof wallboard |
| CN106587888A (en) * | 2016-10-31 | 2017-04-26 | 南宁市大江保温材料有限公司 | Roof thermal insulation layer material |
| CN107569802A (en) * | 2017-10-30 | 2018-01-12 | 山东金立车业有限公司 | A kind of electric fire fighting truck |
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| CN105084929B (en) | 2018-05-08 |
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