CN105084929B - A kind of preparation method of insulated fire interior wall wallboard and its fire proofing material - Google Patents
A kind of preparation method of insulated fire interior wall wallboard and its fire proofing material Download PDFInfo
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- CN105084929B CN105084929B CN201510491412.4A CN201510491412A CN105084929B CN 105084929 B CN105084929 B CN 105084929B CN 201510491412 A CN201510491412 A CN 201510491412A CN 105084929 B CN105084929 B CN 105084929B
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- 239000000463 material Substances 0.000 title claims abstract description 84
- 238000004079 fireproofing Methods 0.000 title claims abstract description 33
- 238000002360 preparation method Methods 0.000 title abstract description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 52
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 45
- AFVFQIVMOAPDHO-UHFFFAOYSA-N Methanesulfonic acid Chemical compound CS(O)(=O)=O AFVFQIVMOAPDHO-UHFFFAOYSA-N 0.000 claims abstract description 38
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 36
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims abstract description 36
- 229920005990 polystyrene resin Polymers 0.000 claims abstract description 31
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 28
- 239000004088 foaming agent Substances 0.000 claims abstract description 21
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000005011 phenolic resin Substances 0.000 claims abstract description 20
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 20
- 239000000741 silica gel Substances 0.000 claims abstract description 20
- 229910002027 silica gel Inorganic materials 0.000 claims abstract description 20
- 229940098779 methanesulfonic acid Drugs 0.000 claims abstract description 19
- 229960000583 acetic acid Drugs 0.000 claims abstract description 18
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims abstract description 18
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 18
- 239000004927 clay Substances 0.000 claims abstract description 17
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 16
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 16
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 16
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 16
- 235000019795 sodium metasilicate Nutrition 0.000 claims abstract description 16
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 16
- 239000002699 waste material Substances 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 14
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims abstract description 10
- 229920000053 polysorbate 80 Polymers 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- 239000004570 mortar (masonry) Substances 0.000 claims abstract description 3
- 238000002156 mixing Methods 0.000 claims description 27
- 238000006243 chemical reaction Methods 0.000 claims description 12
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 10
- 230000032683 aging Effects 0.000 claims description 10
- 238000002791 soaking Methods 0.000 claims description 10
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 9
- 238000009413 insulation Methods 0.000 claims description 9
- 229920000136 polysorbate Polymers 0.000 claims description 9
- 229910052570 clay Inorganic materials 0.000 claims description 6
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical class C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 claims description 5
- 235000019400 benzoyl peroxide Nutrition 0.000 claims description 5
- 239000004359 castor oil Substances 0.000 claims description 5
- 235000019438 castor oil Nutrition 0.000 claims description 5
- 230000029087 digestion Effects 0.000 claims description 5
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims description 5
- 238000001125 extrusion Methods 0.000 claims description 5
- 239000006261 foam material Substances 0.000 claims description 5
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 5
- PHNWGDTYCJFUGZ-UHFFFAOYSA-N hexyl dihydrogen phosphate Chemical compound CCCCCCOP(O)(O)=O PHNWGDTYCJFUGZ-UHFFFAOYSA-N 0.000 claims description 5
- 238000004519 manufacturing process Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229910052938 sodium sulfate Inorganic materials 0.000 claims description 5
- 235000011152 sodium sulphate Nutrition 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000003643 water by type Substances 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 4
- 150000002978 peroxides Chemical class 0.000 claims description 4
- 238000005187 foaming Methods 0.000 claims description 3
- 239000003999 initiator Substances 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- -1 tricarboxylic acid glycerols Ester Chemical class 0.000 claims description 3
- 241000790917 Dioxys <bee> Species 0.000 claims description 2
- 229910003978 SiClx Inorganic materials 0.000 claims description 2
- 238000007599 discharging Methods 0.000 claims description 2
- 125000003976 glyceryl group Chemical group [H]C([*])([H])C(O[H])([H])C(O[H])([H])[H] 0.000 claims description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims 2
- 230000004048 modification Effects 0.000 claims 2
- 235000011187 glycerol Nutrition 0.000 claims 1
- 239000003921 oil Substances 0.000 claims 1
- ORVGYTXFUWTWDM-UHFFFAOYSA-N silicic acid;sodium Chemical compound [Na].O[Si](O)(O)O ORVGYTXFUWTWDM-UHFFFAOYSA-N 0.000 claims 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 3
- 229910052760 oxygen Inorganic materials 0.000 abstract description 3
- 239000001301 oxygen Substances 0.000 abstract description 3
- 235000011007 phosphoric acid Nutrition 0.000 description 12
- DCXXMTOCNZCJGO-UHFFFAOYSA-N tristearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCCCCCC DCXXMTOCNZCJGO-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 4
- 239000011777 magnesium Substances 0.000 description 4
- 229910052749 magnesium Inorganic materials 0.000 description 4
- 239000004342 Benzoyl peroxide Substances 0.000 description 3
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 3
- ASTZLJPZXLHCSM-UHFFFAOYSA-N dioxido(oxo)silane;manganese(2+) Chemical compound [Mn+2].[O-][Si]([O-])=O ASTZLJPZXLHCSM-UHFFFAOYSA-N 0.000 description 3
- 230000002265 prevention Effects 0.000 description 3
- 229910052883 rhodonite Inorganic materials 0.000 description 3
- 229910052710 silicon Inorganic materials 0.000 description 3
- 239000010703 silicon Substances 0.000 description 3
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 2
- 150000003626 triacylglycerols Chemical class 0.000 description 2
- 238000010792 warming Methods 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 102000004160 Phosphoric Monoester Hydrolases Human genes 0.000 description 1
- 108090000608 Phosphoric Monoester Hydrolases Proteins 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000034994 death Effects 0.000 description 1
- 231100000517 death Toxicity 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000001802 infusion Methods 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- ODGAOXROABLFNM-UHFFFAOYSA-N polynoxylin Chemical compound O=C.NC(N)=O ODGAOXROABLFNM-UHFFFAOYSA-N 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- MHSKRLJMQQNJNC-UHFFFAOYSA-N terephthalamide Chemical compound NC(=O)C1=CC=C(C(N)=O)C=C1 MHSKRLJMQQNJNC-UHFFFAOYSA-N 0.000 description 1
- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Building Environments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of insulated fire interior wall wallboard, including basic unit, tack coat, insulating layer, decorative mortar layer, fireprotection layer, waterproof layer, emulsion layer, decorative coveringn and the wearing layer set gradually from the inside to the outside；The fireprotection layer is made of fire proofing material；The raw material of the fire proofing material includes by weight：Silica gel 20 30, glacial acetic acid 12, phenolic resin 30 40, modified polystyrene resin material 15 25, foaming agent 13, Tween 80 12, magnesia 13, aluminium oxide 15, building waste 15 20, clay 20 30, silica 28, sodium metasilicate 5 10, manganolite 15 20, kaolin 5 15, water 10 20, to methanesulfonic acid 12, phosphoric acid 0.52 1.The invention also discloses a kind of preparation method of the fire proofing material of insulated fire interior wall wallboard.The present invention meets the technical requirements of wall board material fire safety, energy-saving heat preserving, and limited oxygen index index is more than 40.
Description
Technical field
The present invention relates to wallboard technical field, more particularly to the system of a kind of insulated fire interior wall wallboard and its fire proofing material
Preparation Method.
Background technology
China's construction unit area energy consumption is 3-5 times of developed country, with being vigorously promoted the use in residential housing, wallboard
It is widely popularized and is approved for inner wall decoration and insulation.But at the same time, the fire safety problem of wallboard is also put ours
In front, recent year causes serious personal's injures and deaths and property loss in succession there is a situation where inner wall of building plate fire, and building is easy
Fire flammable inside thermal conservation material becomes a new class of fire hazard, and therefore, the upgrading of the fire protecting performance of inner wall of building wallboard is
Through as it is in the urgent need to address the problem of, based on the high insulating effect of existing organic heat-insulation wall plate, fire protecting performance is poor, inorganic
How the fact that the fire protecting performance of class heat-insulation wall plate is good, and heat insulation effect is poor, prepare that a kind of high temp effect is good, and fire protecting performance is excellent
Wallboard becomes the current technical issues that need to address.
The content of the invention
The present invention proposes a kind of insulated fire interior wall wallboard, meets the skill of wall board material fire safety, energy-saving heat preserving
Art requirement, limited oxygen index index are more than 40.
A kind of insulated fire interior wall wallboard proposed by the present invention, including set gradually from the inside to the outside basic unit, tack coat,
Insulating layer, decorative mortar layer, fireprotection layer, waterproof layer, emulsion layer, decorative coveringn and wearing layer；The fireprotection layer uses fire proofing wood
Material is made；20-30 parts of silica gel, 1-2 parts of glacial acetic acid, 30-40 parts of phenolic resin, 15-25 parts of modified polystyrene resin material, hair
1-3 parts of infusion, 1-2 parts of Tween 80,1-3 parts of magnesia, 1-5 parts of aluminium oxide, 15-20 parts of building waste, 20-30 parts of clay, two
2-8 parts of silica, 5-10 parts of sodium metasilicate, 15-20 parts of manganolite, 5-15 parts of kaolin, 10-20 parts of water, to methanesulfonic acid 1-2
Part, 0.52-1 parts of phosphoric acid.
Preferably, the production method of modified polystyrene resin material is：
100 parts of deionized waters are weighed by weight to be sent into blender, control agitator speed 200-300r/min；Add
1-2 parts of triethyl group hexyl phosphoric acids, 5-10 parts of sodium sulphate are uniformly mixed；It is sweet to continuously add 20-40 parts of styrene, 1-3 parts of tricarboxylic acids
Grease, 1-2 parts of initiator benzoyl peroxides, 0.2-0.5 parts of peroxidized t-butyl perbenzoates and 0.5-1.2 parts of castor oil mixing
Uniformly；Obtained material is sent into reaction kettle, adds 20-30 parts of polybrominated diphenyl ethers, 1-2 parts of cumyl peroxides are stirred
Mix, mixing speed 300-400r/min, from room temperature to 90-95 DEG C, programming rate is controlled at 1-2 DEG C/min, and insulation is anti-
Should, soaking time 2-6h, then add 0.1-0.2 parts of glyceryl tristearates into reaction kettle and stir evenly, then heat to
130-140 DEG C, control pressure 0.4-0.6Mpa, 4h is maintained, discharging is cooled to room temperature, obtains modified polystyrene resin material
Material.
Preferably, foaming agent is by sodium hydroxide, petroleum ether, N, and N- dinitrosopentamethlyene tetramines and N, N- dimethyl-
One or more kinds of compositions of the sub- terephthalamide of N, N- bis-.
Preferably, the weight ratio of silica gel, phenolic resin and modified polystyrene resin material is 24-26：34-36：20-
23。
Preferably, building waste, clay, silica, sodium metasilicate, manganolite and kaolinic weight ratio are 16-
18：24-26：4-6：6-8：16-18：8-10.
Preferably, the weight ratio to methanesulfonic acid, phosphoric acid, foaming agent and Tween 80 is 1.2-1.6：0.6-0.8：2-2.4：
1.6-1.8。
Preferably, the raw material of the fire proofing material includes by weight：24-26 parts of silica gel, 1.2-1.4 parts of glacial acetic acid, phenol
34-36 parts of urea formaldehyde, 20-23 parts of modified polystyrene resin material, 2-2.4 parts of foaming agent, 1.6-1.8 parts of Tween 80, oxidation
2-2.6 parts of magnesium, 2-4 parts of aluminium oxide, 16-18 parts of building waste, 24-26 parts of clay, 4-6 parts of silica, 6-8 parts of sodium metasilicate,
16-18 parts of manganolite, 8-10 parts of kaolin, 12-16 parts of water, to 1.2-1.6 parts of methanesulfonic acid, 0.6-0.8 parts of phosphoric acid.
A kind of preparation method of the fire proofing material for insulated fire interior wall wallboard that the present invention also proposes, including following step
Suddenly：
Silica gel, modified polystyrene resin material, glacial acetic acid and phenolic resin are placed in blender and stirred, mixing time
For 20-30min, whipping temp is 50-60 DEG C, continuously adds building waste, clay, magnesia, aluminium oxide, silica, silicon
Sour sodium, manganolite, kaolin and water are heated after mixing, and heating-up temperature is 70-80 DEG C, continuously adds tween
80th, foaming agent, methanesulfonic acid, phosphoric acid are stirred, mixing time 8-12min, is then fed into thermostatic chamber and keeps the temperature 20-26h,
Soaking time is 60-70 DEG C, obtains foam material, extrusion forming, is then fed into ageing room and is aged, Aging Temperature 50-60
DEG C, digestion time 15-20h, obtains the fire proofing material of insulated fire interior wall wallboard.
Preferably, silica gel, modified polystyrene resin material, glacial acetic acid and phenolic resin are placed in blender and stirred,
Mixing time is 24-26min, and whipping temp is 55-57 DEG C.
Preferably, Tween 80, foaming agent are added, methanesulfonic acid, phosphoric acid are stirred, mixing time 10-11min, so
It is sent into afterwards in thermostatic chamber and keeps the temperature 22-24h, soaking time is 64-66 DEG C.
In the present invention, the expandable material with certain coupled action is formed after silica gel, glacial acetic acid and phenolic resin mixing,
And special silicon key is cooperatively formed with silica, sodium metasilicate, kaolin, manganolite in product, then change with major ingredient
Property polystyrene resin material, major ingredient phenolic resin, emulsifying agent, foaming agent, the foaming of curing agent collective effect, form similar honeycomb
The material of shape, product not only insulated fire, and the material formed after foaming is mutually wound encirclement by special silicon key, when fire is sent out
Raw, the material moment of formation burns into carbon shape structure, and the effect of moment extinguishing can be played to flame, so as to effectively organize the intensity of a fire climing
Prolong, product not only maintains product heat-insulating property, and combustibility can be promoted to non-ignitable A2 grades of material, further using certain technique
The modified polystyrene resin material thermal conductivity of preparation is low, fire resistance is good, acts synergistically with other flame retardance elements, and product is resistance to
Fiery performance is extremely excellent, and the present invention meets the technical requirements of wall board material fire safety, energy-saving heat preserving, and limited oxygen index index is big
In 40.
Embodiment
In the following, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of insulated fire interior wall wallboard, including set gradually from the inside to the outside basic unit, tack coat, insulating layer, plastering
Screed, fireprotection layer, waterproof layer, emulsion layer, decorative coveringn and wearing layer；The fireprotection layer is made of fire proofing material；It is described
The raw material of fire proofing material includes by weight：20 parts of silica gel, 2 parts of glacial acetic acid, 30 parts of phenolic resin, modified polystyrene resin material
25 parts of material, 1 part of foaming agent, 2 parts of Tween 80,1 part of magnesia, 5 parts of aluminium oxide, 15 parts of building waste, 30 parts of clay, silica
2 parts, 10 parts of sodium metasilicate, 15 parts of manganolite, 15 parts of kaolin, 10 parts of water, to 2 parts of methanesulfonic acid, 0.52 part of phosphoric acid.
Embodiment 2
A kind of insulated fire interior wall wallboard, including set gradually from the inside to the outside basic unit, tack coat, insulating layer, plastering
Screed, fireprotection layer, waterproof layer, emulsion layer, decorative coveringn and wearing layer；The fireprotection layer is made of fire proofing material；It is described
The raw material of fire proofing material includes by weight：30 parts of silica gel, 1 part of glacial acetic acid, 40 parts of phenolic resin, modified polystyrene resin material
15 parts of material, 3 parts of foaming agent, 1 part of Tween 80,3 parts of magnesia, 1 part of aluminium oxide, 20 parts of building waste, 20 parts of clay, silica
8 parts, 5 parts of sodium metasilicate, 20 parts of manganolite, 5 parts of kaolin, 20 parts of water, to 1 part of methanesulfonic acid, phosphatase 11 part.
Embodiment 3
A kind of insulated fire interior wall wallboard, including set gradually from the inside to the outside basic unit, tack coat, insulating layer, plastering
Screed, fireprotection layer, waterproof layer, emulsion layer, decorative coveringn and wearing layer；The fireprotection layer is made of fire proofing material；It is described
The raw material of fire proofing material includes by weight：26 parts of silica gel, 1.2 parts of glacial acetic acid, 36 parts of phenolic resin, modified polystyrene resin
20 parts of material, 2.4 parts of foaming agent, 1.6 parts of Tween 80,2.6 parts of magnesia, 2 parts of aluminium oxide, 18 parts of building waste, 24 parts of clay,
6 parts of silica, 6 parts of sodium metasilicate, 18 parts of manganolite, 8 parts of kaolin, 16 parts of water, to 1.2 parts of methanesulfonic acid, phosphoric acid 0.8
Part.
Wherein foaming agent is N, N- dinitrosopentamethlyene tetramines.
The production method of modified polystyrene resin material is：
100 parts of deionized waters are weighed by weight to be sent into blender, control agitator speed 200r/min；Add 2 parts
Triethyl group hexyl phosphoric acid, 5 parts of sodium sulphate are uniformly mixed；Continuously add 40 parts of styrene, 1 part of triglyceride, 2 parts of initiators
Benzoyl peroxide, 0.2 part of peroxidized t-butyl perbenzoate and 1.2 parts of castor oil are uniformly mixed；Obtained material is sent into anti-
Answer in kettle, add 20 parts of polybrominated diphenyl ethers, 2 parts of cumyl peroxides are stirred, mixing speed 300r/min, from room temperature
It is warming up to 95 DEG C, programming rate control is at 1 DEG C/min, insulation reaction, soaking time 6h, then 0.1 part is added into reaction kettle
Glyceryl tristearate stirs evenly, and then heats to 140 DEG C, control pressure 0.4Mpa, maintains 4h, is cooled to room temperature out
Material, obtains modified polystyrene resin material.
The preparation method of the fire proofing material of above-mentioned insulated fire interior wall wallboard, includes the following steps：
Silica gel, modified polystyrene resin material, glacial acetic acid and phenolic resin are placed in blender and stirred, mixing time
For 30min, whipping temp is 50 DEG C, continuously adds building waste, clay, magnesia, aluminium oxide, silica, sodium metasilicate, magnesium
Rhodonite, kaolin and water are heated after mixing, and heating-up temperature is 80 DEG C, continuously add Tween 80, foaming agent, right
Methanesulfonic acid, phosphoric acid are stirred, and mixing time 8min, is then fed into thermostatic chamber and keeps the temperature 26h, and soaking time is 60 DEG C, is obtained
To foam material, extrusion forming, is then fed into ageing room and is aged, Aging Temperature is 60 DEG C, and digestion time 15h, is protected
The fire proofing material of temperature fire prevention interior wall wallboard.
Embodiment 4
A kind of insulated fire interior wall wallboard, including set gradually from the inside to the outside basic unit, tack coat, insulating layer, plastering
Screed, fireprotection layer, waterproof layer, emulsion layer, decorative coveringn and wearing layer；The fireprotection layer is made of fire proofing material；It is described
The raw material of fire proofing material includes by weight：24 parts of silica gel, 1.4 parts of glacial acetic acid, 34 parts of phenolic resin, modified polystyrene resin
23 parts of material, 2 parts of foaming agent, 1.8 parts of Tween 80,2 parts of magnesia, 4 parts of aluminium oxide, 16 parts of building waste, 26 parts of clay, dioxy
4 parts of SiClx, 8 parts of sodium metasilicate, 16 parts of manganolite, 10 parts of kaolin, 12 parts of water, to 1.6 parts of methanesulfonic acid, 0.6 part of phosphoric acid.
Wherein foaming agent is by sodium hydroxide and N, the sub- terephthalamide composition of N- dimethyl-N, N- bis-.
The production method of modified polystyrene resin material is：
100 parts of deionized waters are weighed by weight to be sent into blender, control agitator speed 300r/min；Add 1 part
Triethyl group hexyl phosphoric acid, 10 parts of sodium sulphate are uniformly mixed；Continuously add 20 parts of styrene, 3 parts of triglycerides, 1 part of initiation
Agent benzoyl peroxide, 0.5 part of peroxidized t-butyl perbenzoate and 0.5 part of castor oil are uniformly mixed；Obtained material is sent into
In reaction kettle, 30 parts of polybrominated diphenyl ethers are added, 1 part of cumyl peroxide is stirred, mixing speed 400r/min, from room
Temperature is warming up to 90 DEG C, and programming rate control is at 2 DEG C/min, insulation reaction, soaking time 2h, then 0.2 is added into reaction kettle
Part glyceryl tristearate stirs evenly, and then heats to 130 DEG C, control pressure 0.6Mpa, maintains 4h, is cooled to room temperature out
Material, obtains modified polystyrene resin material.
The preparation method of the fire proofing material of above-mentioned insulated fire interior wall wallboard, includes the following steps：
Silica gel, modified polystyrene resin material, glacial acetic acid and phenolic resin are placed in blender and stirred, mixing time
For 20min, whipping temp is 60 DEG C, continuously adds building waste, clay, magnesia, aluminium oxide, silica, sodium metasilicate, magnesium
Rhodonite, kaolin and water are heated after mixing, and heating-up temperature is 70 DEG C, continuously add Tween 80, foaming agent, right
Methanesulfonic acid, phosphoric acid are stirred, and mixing time 12min, is then fed into thermostatic chamber and keeps the temperature 20h, and soaking time is 70 DEG C, is obtained
To foam material, extrusion forming, is then fed into ageing room and is aged, Aging Temperature is 50 DEG C, and digestion time 20h, is protected
The fire proofing material of temperature fire prevention interior wall wallboard.
Embodiment 5
A kind of insulated fire interior wall wallboard, including set gradually from the inside to the outside basic unit, tack coat, insulating layer, plastering
Screed, fireprotection layer, waterproof layer, emulsion layer, decorative coveringn and wearing layer；The fireprotection layer is made of fire proofing material；It is described
The raw material of fire proofing material includes by weight：25 parts of silica gel, 1.3 parts of glacial acetic acid, 35 parts of phenolic resin, modified polystyrene resin
22 parts, N of material, sub- 2.2 parts of the terephthalamide of N- dimethyl-N, N- bis-, 1.7 parts of Tween 80,2.3 parts of magnesia, aluminium oxide 3
Part, 17 parts of building waste, 25 parts of clay, 5 parts of silica, 7 parts of sodium metasilicate, 17 parts of manganolite, 9 parts of kaolin, water 14
Part, to 1.4 parts of methanesulfonic acid, 0.7 part of phosphoric acid.
The production method of modified polystyrene resin material is：
100 parts of deionized waters are weighed by weight to be sent into blender, control agitator speed 240r/min；Add 1.2
Part triethyl group hexyl phosphoric acid, 8 parts of sodium sulphate are uniformly mixed；Continuously add 30 parts of styrene, 2 parts of triglycerides, 1.5 parts draw
Hair agent benzoyl peroxide, 0.4 part of peroxidized t-butyl perbenzoate and 1 part of castor oil are uniformly mixed；Obtained material is sent into
In reaction kettle, 25 parts of polybrominated diphenyl ethers of addition, 1.5 parts of cumyl peroxides are stirred, mixing speed 350r/min, from
Room temperature is to 93 DEG C, and programming rate control is at 1.2 DEG C/min, insulation reaction, soaking time 4h, then into reaction kettle plus
Enter 0.13 part of glyceryl tristearate to stir evenly, then heat to 135 DEG C, control pressure 0.5Mpa, maintain 4h, be cooled to
Room temperature discharges, and obtains modified polystyrene resin material.
The preparation method of the fire proofing material of above-mentioned insulated fire interior wall wallboard, includes the following steps：
Silica gel, modified polystyrene resin material, glacial acetic acid and phenolic resin are placed in blender and stirred, mixing time
For 25min, whipping temp is 55 DEG C, continuously adds building waste, clay, magnesia, aluminium oxide, silica, sodium metasilicate, magnesium
Rhodonite, kaolin and water are heated after mixing, and heating-up temperature is 75 DEG C, continuously add Tween 80, foaming agent, right
Methanesulfonic acid, phosphoric acid are stirred, and mixing time 10min, is then fed into thermostatic chamber and keeps the temperature 23h, and soaking time is 65 DEG C, is obtained
To foam material, extrusion forming, is then fed into ageing room and is aged, Aging Temperature is 55 DEG C, and digestion time 18h, is protected
The fire proofing material of temperature fire prevention interior wall wallboard.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should be covered by the protection scope of the present invention.
Claims (8)
- A kind of 1. insulated fire interior wall wallboard, it is characterised in that including set gradually from the inside to the outside basic unit, tack coat, guarantor Warm layer, decorative mortar layer, fireprotection layer, waterproof layer, emulsion layer, decorative coveringn and wearing layer；The fireprotection layer uses fire proofing material It is made；The raw material of the fire proofing material includes by weight：20-30 parts of silica gel, 1-2 parts of glacial acetic acid, 30-40 parts of phenolic resin, changes 15-25 parts of polystyrene resin material of property, 1-3 parts of foaming agent, 1-2 parts of Tween 80,1-3 parts of magnesia, 1-5 parts of aluminium oxide, builds 15-20 parts of building refuse, 20-30 parts of clay, 2-8 parts of silica, 5-10 parts of sodium metasilicate, 15-20 parts of manganolite, kaolin 5-15 parts, 10-20 parts of water, to 1-2 parts of methanesulfonic acid, 0.52-1 parts of phosphoric acid；The production method of modified polystyrene resin material is：100 parts of deionized waters are weighed by weight to be sent into blender, control agitator speed 200-300r/min；Add 1-2 Part triethyl group hexyl phosphoric acid, 5-10 parts of sodium sulphate are uniformly mixed；Continuously add 20-40 parts of styrene, 1-3 parts of tricarboxylic acid glycerols Ester, 1-2 parts of initiator benzoyl peroxides, 0.2-0.5 parts of peroxidized t-butyl perbenzoates and 0.5-1.2 parts of castor oil mixing are equal It is even；Obtained material is sent into reaction kettle, adds 20-30 parts of polybrominated diphenyl ethers, 1-2 parts of cumyl peroxides are stirred Mix, mixing speed 300-400r/min, from room temperature to 90-95 DEG C, programming rate is controlled at 1-2 DEG C/min, and insulation is anti- Should, soaking time 2-6h, then add 0.1-0.2 parts of glyceryl tristearates into reaction kettle and stir evenly, then heat to 130-140 DEG C, control pressure 0.4-0.6Mpa, 4h is maintained, discharging is cooled to room temperature, obtains modified polystyrene resin material Material；The method for preparing the fire proofing material of the insulated fire interior wall wallboard, includes the following steps：Silica gel, modified polystyrene resin material, glacial acetic acid and phenolic resin are placed in blender and stirred, mixing time is 20-30min, whipping temp are 50-60 DEG C, continuously add building waste, clay, magnesia, aluminium oxide, silica, silicic acid Sodium, manganolite, kaolin and water are heated after mixing, heating-up temperature be 70-80 DEG C, continuously add Tween 80, Foaming agent, be stirred methanesulfonic acid, phosphoric acid, and mixing time 8-12min, is then fed into thermostatic chamber and keeps the temperature 20-26h, protects The warm time is 60-70 DEG C, obtains foam material, and extrusion forming, is then fed into ageing room and is aged, and Aging Temperature is 50-60 DEG C, Digestion time is 15-20h, obtains the fire proofing material of insulated fire interior wall wallboard.
- 2. insulated fire interior wall wallboard according to claim 1, it is characterised in that foaming agent is by sodium hydroxide, oil The one or more of ether, N, N- dinitrosopentamethlyene tetramines and the sub- terephthalamide of N, N- dimethyl-N, N- bis- Composition.
- 3. insulated fire interior wall wallboard according to claim 1 or 2, it is characterised in that silica gel, phenolic resin and modification The weight ratio of polystyrene resin material is 24-26：34-36：20-23.
- 4. insulated fire interior wall wallboard according to claim 1 or 2, it is characterised in that building waste, clay, dioxy SiClx, sodium metasilicate, manganolite and kaolinic weight ratio are 16-18：24-26：4-6：6-8：16-18：8-10.
- 5. insulated fire interior wall wallboard according to claim 1 or 2, it is characterised in that to methanesulfonic acid, phosphoric acid, foaming The weight ratio of agent and Tween 80 is 1.2-1.6：0.6-0.8：2-2.4：1.6-1.8.
- 6. insulated fire interior wall wallboard according to claim 1 or 2, it is characterised in that the raw material of the fire proofing material Include by weight：24-26 parts of silica gel, 1.2-1.4 parts of glacial acetic acid, 34-36 parts of phenolic resin, modified polystyrene resin material 20-23 parts, 2-2.4 parts of foaming agent, 1.6-1.8 parts of Tween 80,2-2.6 parts of magnesia, 2-4 parts of aluminium oxide, building waste 16- 18 parts, 24-26 parts of clay, 4-6 parts of silica, 6-8 parts of sodium metasilicate, 16-18 parts of manganolite, 8-10 parts of kaolin, water 12-16 parts, to 1.2-1.6 parts of methanesulfonic acid, 0.6-0.8 parts of phosphoric acid.
- 7. the fire proofing material of insulated fire interior wall wallboard according to claim 1, it is characterised in that by silica gel, modification Polystyrene resin material, glacial acetic acid and phenolic resin, which are placed in blender, to be stirred, mixing time 24-26min, whipping temp For 55-57 DEG C.
- 8. the fire proofing material of insulated fire interior wall wallboard according to claim 1, it is characterised in that addition Tween 80, Foaming agent, be stirred methanesulfonic acid, phosphoric acid, and mixing time 10-11min, is then fed into thermostatic chamber and keeps the temperature 22-24h, protects The warm time is 64-66 DEG C.
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| CN105713506A (en) * | 2016-03-24 | 2016-06-29 | 安徽德全新型建材科技有限公司 | High-temperature-resistant and fire-proof external wallboard |
| CN105796277A (en) * | 2016-04-20 | 2016-07-27 | 苏州兴新维碳纤维有限公司 | Carbon fiber operating table and manufacturing process thereof |
| CN105838024A (en) * | 2016-05-16 | 2016-08-10 | 安徽德全新型建材科技有限公司 | Building external wall panel |
| CN105968703A (en) * | 2016-05-16 | 2016-09-28 | 安徽德全新型建材科技有限公司 | Heat-preservation building outer wallboard |
| CN106049786B (en) * | 2016-06-16 | 2018-05-01 | 安徽德全新型建材科技有限公司 | A kind of elastic fireproof wallboard |
| CN106587888A (en) * | 2016-10-31 | 2017-04-26 | 南宁市大江保温材料有限公司 | Roof thermal insulation layer material |
| CN107569802A (en) * | 2017-10-30 | 2018-01-12 | 山东金立车业有限公司 | A kind of electric fire fighting truck |
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| CN103408891B (en) * | 2013-08-09 | 2015-11-18 | 南通南京大学材料工程技术研究院 | A kind of High-molecular flame-retardant foam material and preparation method thereof |
| CN103979833A (en) * | 2014-04-30 | 2014-08-13 | 盐城振旭新能源有限公司 | Fireproof insulation sheet material and processing technology thereof |
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