CN105076138B - The Pesticidal combination of a kind of capillary and Nylar and its preparation and application - Google Patents
The Pesticidal combination of a kind of capillary and Nylar and its preparation and application Download PDFInfo
- Publication number
- CN105076138B CN105076138B CN201510520298.3A CN201510520298A CN105076138B CN 105076138 B CN105076138 B CN 105076138B CN 201510520298 A CN201510520298 A CN 201510520298A CN 105076138 B CN105076138 B CN 105076138B
- Authority
- CN
- China
- Prior art keywords
- capillary
- nylar
- pesticidal combination
- insecticide
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Abstract
The invention discloses a kind of capillary and the Pesticidal combination and its preparation of Nylar and application.The Pesticidal combination is (0.1~10) by mass ratio：1 capillary and Nylar composition.Preferably, the mass ratio of the capillary and Nylar is (0.1~0.25)：1 or (4~10)：1, but be not 0.25：1 and 4：1.The insecticide as made from the Pesticidal combination, its acceptable auxiliary material on above-mentioned Pesticidal combination and its pesticidal preparations is made, wherein, the weight/mass percentage composition of Pesticidal combination is 2%~60%.The present invention has obvious synergistic effect to Bradysia odoriphaga by after capillary and Nylar according to a certain percentage mixture；Because capillary and two kinds of pharmacy effect mechanism of Nylar are different, the application of composition helps to delay the development of pest resistance to insecticide, extends the service life of medicament；The insecticide that the present invention is made up of the Pesticidal combination after capillary and Nylar mixture, has preferable prevention effect to Bradysia odoriphaga.
Description
Technical field
The present invention relates to a kind of capillary and the Pesticidal combination and its preparation of Nylar and application, belong to pesticide technology neck
Domain.
Background technology
Capillary (Chlorfenapyr), chemical name is the bromo- 2- of 4- (4- chlorphenyls) -1- ethoxyl methyl -5- trifluoros
Methylpyrrole -3- nitriles, are that American Cyanamid Company is transformed the late 1980s by the chemical constitution to natural antibiotics
And a kind of aryl pyrrolines insecticidal/acaricidal agent for successfully developing is able to, it is that a kind of insect bodies mitochondrial oxidative phosphorylation is made
Blocking agent.
Nylar (Pyriproxyfen), chemical name is 4- phenoxy phenyls (RS) -2- (2- pyridine radicals oxygen) propyl ether, is
Phenylate class upsets the insect growth regulator, IGR of insect growth, belongs to the novel pesticide of juvenoid, with low toxicity, holding effect
The characteristics of phase is long, it is small to eco-environmental impact to fish low toxicity to crop safety.
Agricultural chemicals single dose is often restricted by prevention effect, using factors such as scope and poisoning when in use, and with disease pest
The drug-fast enhancing of evil, prevention effect reduction.Agriculture chemical compounding can overcome the use defect of original agricultural chemicals single dose, come for insecticide
Say, conventional compounding mode has：Organic phosphates and organic phosphates, organophosphor with intend chrysanthemum esters, organophosphor and carbamates,
Organic nitrogen is with carbamates and organic nitrogen with intending chrysanthemum esters etc..
Bradysia odoriphaga (Bradysia odoriphaga Yang et Zhang), is commonly called as fragrant-flowered garlic maggot, belongs to Diptera, long
Angle suborder, eye Sciaridae, Bradysia Sciara is to cause harm northern China Specialty vegetable leek, garlic, round onions and shallot importantly
Lower insect, wherein it is aggrieved the most serious with leek, it is to cause the current leek underproduction and the exceeded one of the main reasons of residues of pesticides.
In recent years, due to the increase of facility leek cultivated area, the harm of fragrant-flowered garlic maggot is caused to aggravate year after year.Common insecticides are more
Year is continuous, and using causing pest resistance to insecticide to increase, prevention effect is undesirable, and some local vegetable growers are high in order to protect production Misuse
Malicious insecticide, has triggered food-safety problem again and again.Therefore, efficient, low toxicity, safe, environment-friendly medicament is screened very must
Will.
The content of the invention
It is an object of the invention to provide a kind of capillary and the Pesticidal combination and its preparation of Nylar and application.The present invention
By the way that capillary and Nylar are compounded, there is obtained Pesticidal combination obvious synergy to make to Bradysia odoriphaga
With, be it is a kind of efficiently, the composition pesticide of low toxicity, low-residual；The Pesticidal combination is made to the insecticide of various formulations, to fragrant-flowered garlic
The prevention effect that dish Bradysia fungus gnat has been respectively provided with.
A kind of Pesticidal combination that the present invention is provided, it is (0.1~10) by mass ratio：1 capillary and Nylar group
Into.
In above-mentioned Pesticidal combination, the controlling object of capillary mainly has diamondback moth, cabbage caterpillar, beet armyworm, twill
The vegetable-crop pest-insects such as noctuid, Oeobia undalis, vegetable aphid, liriomyza bryoniae and thrips.
In above-mentioned Pesticidal combination, the controlling object of Nylar mainly has Homoptera (Bemisia tabaci, Trialeurodes vaporariorum Westwood, peach
Aphid, arrowhead scales, blow cotton a red-spotted lizard and ceroplastes rubens etc.), Thysanoptera (palm thrips), Lepidoptera (diamondback moth), Corrodentia (l.bostrychophila),
The insects such as Blattaria (Groton bug), Siphonaptera (flea), coleoptera (harmonia axyridia), Neuroptera (the lacewing Chrysopa sinica sandfly), to aleyrodid,
Scale insect and blattaria have special efficacy.
The present invention is compounded capillary and Nylar according to a certain percentage, is screened by substantial amounts of biologicall test, is sent out
Existing Pesticidal combination of the present invention shows obvious synergistic effect to Bradysia odoriphaga.With reference to Sun Yunpei (Sun YP) method evaluation
The mixed interaction of two kinds of different activities components in the present invention, wherein, it is synergistic effect that co-toxicity coefficient, which is more than 120, altogether poison
It is antagonism that coefficient, which is less than 80, and co-toxicity coefficient is summation action therebetween.It is mixed with Nylar by calculating capillary
Co-toxicity coefficient afterwards, evaluates both mixed rear effects, as a result shows, in above-mentioned Pesticidal combination, the capillary and Nylar
Mass ratio can be (0.1~10)：1, concretely (0.1~5)：1st, (0.1~1)：1st, (0.1~0.2)：1st, (0.2~10)：
1st, (0.2~5)：1st, (0.2~1)：1st, (1~10)：1st, (1~5)：1st, (5~10)：1、0.1：1、0.2：1、1：1、5：1 or 10：
1, in the range of above-mentioned mass ratio, show synergistic effect.
In above-mentioned Pesticidal combination, the mass ratio of the capillary and Nylar is preferably (0.1~0.25)：1 or (4
~10)：1, but be not 0.25：1 and 4：1；More preferably (0.2~0.25)：1 or (4~5)：1, but be not 0.25：1 and 4：1；
More preferably 0.2：1 or 5：1.
Synergistic effect after being compounded due to above-mentioned capillary and Nylar according to aforementioned proportion, above-mentioned provided of the invention
The application of the capillary of meaning mass ratio and the Pesticidal combination of Nylar composition in preventing and treating Bradysia odoriphaga, also in the present invention
Protection domain in.
Because active compound can not be used directly, invention further provides a kind of insecticide, it is by above-mentioned desinsection
Acceptable auxiliary material is made on composition and its pesticidal preparations, wherein, the weight/mass percentage composition of the Pesticidal combination can be 2%
~60%, concretely 6%~24%, 6%~20%, 6%~12%, 12%~24%, 12%~20%, 20%~
24%th, 6%, 12%, 20% or 24%.
In above-mentioned insecticide, the weight/mass percentage composition of the Pesticidal combination is preferably 10%~60%, more preferably
12%~24%, more preferably 12%~20% or 20%~24%.
In implementation process of the present invention, because the content of active ingredient in active compound is unlikely to be 100%, such as 95% capillary
Active compound refers to that the weight/mass percentage composition of capillary in capillary active compound is 95%, and Pesticidal combination and insecticide of the present invention are being calculated
During, the content for being converted to active compound in the consumption of active ingredient, i.e. Pesticidal combination and insecticide each means it
The content of active ingredient.
In above-mentioned insecticide, the insecticide can be processed into the system of dosage forms using known method any at present
Agent, suitable formulation includes but is not limited to：Suspending agent, suspension seed-coating agent, suspension emulsion, missible oil, aqueous emulsion, microemulsion, moisture dissipate
Granula, wettable powder, granule, dashing agent, drops, microcapsule suspending agent, microcapsule suspension-suspendinagent agent etc., preferably suspending agent agent
Type；During usual auxiliaries are wetting agent, dispersant, solvent, interleaving agent, stabilizer, antifreezing agent, preservative, filler, adhesive etc.
One or more, are known substance, are the usual auxiliaries in insecticides adjuvant, can be varied from according to formulation situation.
Application of the above-mentioned insecticide in preventing and treating Bradysia odoriphaga, also within the scope of the present invention, dispenser result
Show, 21 days and 35 days after administration, compared with single dose, there is insecticide of the present invention obvious preventing and treating to imitate to Bradysia odoriphaga
Really；The amount of application of total active ingredient (Pesticidal combination) in the insecticide is 200~600g/hm2, concretely 200~
400g/hm2, 400~600g/hm2、200g/hm2、400g/hm2Or 600g/hm2, preferably 400~600g/hm2, more preferably
600g/hm2。
The present invention has the advantages that：
(1) present invention has after capillary and Nylar according to a certain percentage mixture obvious to Bradysia odoriphaga
Synergistic effect.
(2) because capillary and two kinds of pharmacy effect mechanism of Nylar are different, the application of composition helps to delay
The development of pest resistance to insecticide, extends the service life of medicament.
(3) pesticidal preparations that the Pesticidal combination after capillary and Nylar mixture is made, equal to Bradysia odoriphaga
With preferable prevention effect.
Embodiment
Experimental method used in following embodiments is conventional method unless otherwise specified.
Material, reagent used etc., unless otherwise specified, are commercially obtained in following embodiments.
After different pesticide species mixtures, typically exhibit three kinds of type of action, i.e. summation action, synergistic effect and antagonism and make
With, but be specially which kind of effect, only just it can know that by lot of experiments.Good compound synergic formula, can significantly improve reality
Border prevention effect, expands medicament insecticidal spectrum, and help to delay the generation speed of pest resistance to insecticide.
In following embodiments 1, by substantial amounts of screening test, capillary and Nylar are answered according to different ratio
Match somebody with somebody, it is found that capillary and pyriproxyfen compound have significant synergistic function to Bradysia odoriphaga.
Embodiment 1, Pesticidal combination and its compounding effect
It is respectively 10 according to mass ratio by capillary and Nylar in the present embodiment：1、5：1、1：1、1：5 or 1：10 ratio
Example is compounded, and tests the co-toxicity to the age of Bradysia odoriphaga two and four-age larva respectively.
Subjects：The age of Bradysia odoriphaga two and four-age larva.
Test medicine：95% capillary active compound and 97% Nylar active compound.Active compound (after folding hundred) is prepared according to a conventional method
Into the test medicine of needs.
Experimental method：Using stomach toxicity tag co-toxicity method carry out indoor bioassay, respectively select indoor feeding fragrant-flowered garlic
Dish Bradysia fungus gnat second instar larvae and four-age larva are target pest, and 25 larvas are handled per concentration, and often processing is repeated 4 times, and is placed
Raised always to emergence of pupating in breeding observing in 25 ± 1 DEG C of constant incubators, and by survival larva, the final normal emergence of record
Into borer population.Using probit analysis method and DPSv7.5 software data processings, lethal concentration of 50 LC is calculated50, use LC50Value presses Sun Yunpei
Method calculates co-toxicity coefficient, shown in calculation formula such as formula (1).
Formula (1)
If confection is M, each single dose of composition is A, B, C ....LC50AFor the medicament A lethal concentration of 50；LC50BFor medicine
The agent B lethal concentration of 50, LC50 mixFor the lethal concentration of 50 of medicament A+ medicament B+ medicaments C+ ... mixture, mixture co-toxicity coefficient is
CTC, the percentage composition of active ingredient is P.
Co-toxicity coefficient (CTC) >=120 shows as synergistic effect, and CTC≤80 show as antagonism, the tables of 80 ＜ CTC ＜ 120
It is now summation action.
Co-toxicity test result such as table 1 institute of the Pesticidal combination of the present invention to the age of Bradysia odoriphaga two and four-age larva
Show.
Table 1, capillary are mixed with Nylar to the age of Bradysia odoriphaga two and the co-toxicity of four-age larva
As can be seen from Table 1, in Pesticidal combination of the present invention, capillary is 10 with Nylar mass ratio：1、5：1、1：1、
1：5 and 1：When 10, synergistic effect is shown, wherein 5：1、1：1 and 1：5 co-toxicity coefficient is larger, when ratio is 5：When 1, altogether
Malicious coefficient highest, i.e. synergistic effect is most obvious.
Following embodiment 2- embodiments 7 are respectively the various preparations that Pesticidal combination of the present invention is made, can be known to
Method be prepared into any one formulation of suitable agricultural use, relatively good formulation is suspending agent, suspension seed-coating agent, outstanding breast
It is agent, missible oil, aqueous emulsion, microemulsion, water dispersible granules, wettable powder, granule, dashing agent, drops, microcapsule suspending agent, micro-
Capsule suspension-suspending agent.
For the clearer and more definite objects, technical solutions and advantages of the present invention, the present invention is illustrated with specific examples below,
But its active component and its proportioning, auxiliary agent etc. are all not limited only to following examples.
Embodiment 2, the Nylar suspending agent of 10% capillary+2%
First, it is formulated
In terms of weight/mass percentage composition, the present embodiment suspending agent is made up of following components：
2nd, preparation method
Suspending agent is prepared in accordance with the following steps：
The each components such as active component, dispersant, wetting agent and water are mixed according to the ratio of formula, it is high through 10000r/min
Speed shearing uniformly adds sand mill and is ground to required particle diameter (average grain diameter is less than 3 microns), 10% worm mite is made for 5 minutes
The Nylar suspending agent of nitrile+2%.
Embodiment 3, the Nylar suspending agent of 10% capillary+10%
First, it is formulated
In terms of weight/mass percentage composition, the present embodiment suspending agent is made up of following components：
2nd, preparation method
Suspending agent is prepared in accordance with the following steps：
The each components such as active component, dispersant, wetting agent and water are mixed according to the ratio of formula, it is high through 10000r/min
Speed shearing uniformly adds sand mill and is ground to required particle diameter (average grain diameter is less than 3 microns), 10% worm mite is made for 5 minutes
The Nylar suspending agent of nitrile+10%.
Embodiment 4, the Nylar suspending agent of 2% capillary+10%
First, it is formulated
In terms of weight/mass percentage composition, the present embodiment suspending agent is made up of following components：
2nd, preparation method
Suspending agent is prepared in accordance with the following steps：
The each components such as active component, dispersant, wetting agent and water are mixed according to the ratio of formula, it is high through 10000r/min
Speed shearing uniformly adds sand mill and is ground to required particle diameter (average grain diameter is less than 3 microns), 2% capillary is made for 5 minutes
+ 10% Nylar suspending agent.
Embodiment 5, the Nylar granule of 5% capillary+1%
First, it is formulated
In terms of weight/mass percentage composition, the present embodiment granule is made up of following components：
2nd, preparation method
Granule is prepared in accordance with the following steps：
Said components are well mixed, softwood is made, the softwood made is granulated by Squeezinggranulator, dries, that is, makes
Into the Nylar granule of 5% capillary+1%.
Embodiment 6, the Nylar wettable powder of 10% capillary+2%
First, it is formulated
In terms of weight/mass percentage composition, the present embodiment wettable powder is made up of following components：
2nd, preparation method
Wettable powder is prepared in accordance with the following steps：
Said components are well mixed, is mixed by air-flow crushing, then fully, that is, the Nylar of 10% capillary+2% is made
Wettable powder.
Embodiment 7, the Nylar microcapsule suspension-suspendinagent agent of 10% capillary+2%
The present embodiment prepares microcapsule suspension suspending agent in accordance with the following methods, comprises the following steps that：
The Nylar active compounds of 4.12g 97% are added and fully dissolved in 10g dimethylbenzene, 3g isocyanates and 1.5g is added
PEG 600, is fully stirred evenly, and is used as oil phase；0.2g triphenyl vinyl phenols APEO, 3g calcium lignosulfonates and the poly- second of 0.1g
Enol is uniformly mixed as aqueous phase with 53.54g water；Oil phase is mixed with water, and uses high-shear homogenizer emulsification pretreatment, obtains stabilization
O/W emulsion；O/W emulsion is transferred in flask, stirred with 200 revs/min of speed, 65 DEG C are warming up to, reaction 4 is small
When, with lemon acid for adjusting pH value 6-6.5；2g ethylene glycol is added, 0.14g xanthans stirs, and water supplies 100g, that is, obtains
4% Nylar micro-capsule suspension.
Weigh the capillary active compounds of 21.05g 95%, 5g styrene phenol formaldehyde resin polyoxyethylene poly-oxygen propylene aethers, 3g wood
Quality sulfoacid calcium, 1.5g NPEs, 0.12g xanthans, 3g ethylene glycol, organic silicon defoamer 0.5g, water is supplied
100g.Weigh each component according to above-mentioned formula to be placed in beaker, open high-speed shearing machine 5 minutes, then 1500 turns of sand mill/
Minute grinding, detection sample particle diameter more than 95% is at 1-5 microns, and average grain diameter obtains the suspension of 20% capillary below 3 microns
Agent.
4% Nylar microcapsule suspending agent and 20% capillary suspending agent are compared 1 according to weight：1 it is well mixed obtain,
The capillary microcapsule suspension-suspendinagent agent of 2% Nylar+10%.
Embodiment 8, field control effectiveness test
The field efficacy examination of preventing and treating Bradysia odoriphaga is carried out to the preparation of various formulations made from embodiment 2- embodiments 7
Test, investigate its practical application effect.
1) application method
Using pouring root pesticide application technology, applied uniformly being rushed with water after preparation preliminarily diluted.Operating method is as follows：In leek Bradysia
Fungus gnat occurs the phase and the formulations such as the suspending agent of said composition, wettable powder add water is made into suspension and applies pouring root with water punching, or spray
Pouring is watered behind leek root to be used；The granule of said composition can refinement sand mix after spread fertilizer over the fields to water behind leek root and make
With.
2) plot area and repetition (leek)
Plot area：30m2。
Number of repetition：It is repeated 4 times.
3) investigation method
Aggrieved strain rate investigation：The sampling per 5 points of cell " Z " font, every take 1m row length leek, count aggrieved strain number.
4) control time and number of times：
In investigation prevention effect after dispenser 21d and 35d, investigate 2 times altogether.
5) computational methods：
Calculate the Revision insect recluced rate and Rectifying efficacies of each processing.Calculation formula is as follows：
Insect population number × 100 (2) before Revision insect recluced rate (%)=(insect population number after insect population number-preventing and treating before preventing and treating)/preventing and treating
Rectifying efficacies (%)=(chemicals treatment district Revision insect recluced rate-check plot Revision insect recluced rate)/(1- check plots insect population subtracts
Move back rate) × 100 (3)
Experimental result is as shown in table 2.
The capillary of table 2 is counted with Nylar mixture preventing and treating Bradysia odoriphaga field control effectiveness test result
The result of table 2 shows, when the formulations of pesticide are all suspending agent, (the capillary of embodiment 2：Nylar=5：1), embodiment
3 (capillaries：Nylar=1：1) with (capillary of embodiment 4：Nylar=1：5) preventive effect to Bradysia odoriphaga is above
Preventive effect when two kinds of medicaments are used alone, wherein, (the capillary of embodiment 2：Nylar=5：1) effect is fairly obvious, with this
There is Pesticidal combination under ratio the result of optimal synergistic effect to be consistent.When the ratio of capillary and Nylar is
5：1, but during formulation difference, as can be seen from the results：Wherein the preventive effect of suspending agent is preferably, secondly microcapsule suspension suspending agent and can
WP, the preventive effect of granule is poor.
Claims (4)
1. a kind of application of Pesticidal combination in preventing and treating Bradysia odoriphaga, the Pesticidal combination is by capillary and Nylar
Composition；The mass ratio of the capillary and Nylar is 5：1.
2. a kind of application of insecticide in preventing and treating Bradysia odoriphaga, the insecticide is as the desinsection group described in claim 1
Acceptable auxiliary material is made on compound and its pesticidal preparations, wherein, the weight/mass percentage composition of the Pesticidal combination for 2%~
60%.
3. application according to claim 2, it is characterised in that：In the insecticide, the quality hundred of the Pesticidal combination
It is 6%~24% to divide content.
4. the application according to Claims 2 or 3, it is characterised in that：The formulation of the insecticide is suspending agent, suspended seed coating
Agent, suspension emulsion, missible oil, aqueous emulsion, microemulsion, water dispersible granules, wettable powder, granule, dashing agent, drops, micro-capsule hang
Floating any of agent and microcapsule suspension-suspendinagent agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510520298.3A CN105076138B (en) | 2015-08-21 | 2015-08-21 | The Pesticidal combination of a kind of capillary and Nylar and its preparation and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510520298.3A CN105076138B (en) | 2015-08-21 | 2015-08-21 | The Pesticidal combination of a kind of capillary and Nylar and its preparation and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105076138A CN105076138A (en) | 2015-11-25 |
| CN105076138B true CN105076138B (en) | 2017-08-04 |
Family
ID=54558206
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510520298.3A Active CN105076138B (en) | 2015-08-21 | 2015-08-21 | The Pesticidal combination of a kind of capillary and Nylar and its preparation and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105076138B (en) |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59199673A (en) * | 1983-04-25 | 1984-11-12 | Sumitomo Chem Co Ltd | Nitrogen-containing heterocyclic compound, its preparation and pesticide containing the same |
| CN101803602B (en) * | 2010-04-22 | 2012-07-04 | 上海生农生化制品有限公司 | Composition for controlling diamondback moth of brassicaceous vegetable and preparation and application thereof |
| CN102246758A (en) * | 2011-06-04 | 2011-11-23 | 海利尔药业集团股份有限公司 | Insecticidal composition |
| CN104472520B (en) * | 2014-12-08 | 2016-06-22 | 山东农业大学 | A kind of composition pesticide of pyriproxyfen-containing and HEXAFLUMURON |
-
2015
- 2015-08-21 CN CN201510520298.3A patent/CN105076138B/en active Active
Also Published As
| Publication number | Publication date |
|---|---|
| CN105076138A (en) | 2015-11-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105123699A (en) | Miticide and insecticide composite containing thymol and pyriproxyfen | |
| CN104488943A (en) | Insecticidal composition | |
| CN108077303A (en) | A kind of Pesticidal combination of brominated worm fluorobenzene bisamide and indoxacarb | |
| CN105746584B (en) | A kind of Pesticidal combination and its preparation method and application containing Metarhizium anisopliae and cyromazine | |
| CN108208000A (en) | A kind of nematicidal agent composition containing imicyafos | |
| CN104585224A (en) | Pesticide composition containing fluensulfone and pyrethroid insecticide | |
| CN105076138B (en) | The Pesticidal combination of a kind of capillary and Nylar and its preparation and application | |
| CN102428922A (en) | Diacylhydrazine pesticide compounded pesticidal composition | |
| CN102246778A (en) | Efficiency enhanced insecticidal composition, and application thereof | |
| CN105028461A (en) | Insecticidal composition containing diflubenzuron and deltamethrin and application thereof | |
| CN106489969B (en) | A kind of Pesticidal combination of containing chlorine fluorine cyanogen insect amide and flubenzuron | |
| CN101473828B (en) | Agricultural chemical composition for disinsection and use thereof | |
| CN104855399B (en) | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide | |
| CN106561656A (en) | Insecticide composite containing celastrus angulatus and spinosad | |
| CN103518773B (en) | Insecticidal composition with synergism | |
| CN103027066B (en) | Insecticide composition, insecticide and application of insecticide | |
| CN107743973A (en) | A kind of composition pesticide containing Osthole | |
| CN105746523B (en) | A kind of Pesticidal combination of pyriproxyfen-containing | |
| CN108849963A (en) | A kind of Pesticidal combination containing novaluron and Fenpropathrin | |
| CN103704258B (en) | A kind of Fungicidal insecticidal composition containing abietic acid ketone | |
| CN107494580A (en) | A kind of Synergistic insecticidal compositions containing guadipyr | |
| CN103053581B (en) | Insecticidal composition of indoxacarb and cartap | |
| CN107372522A (en) | A kind of composition pesticide containing fenazaquin | |
| CN103734181B (en) | A kind of Fungicidal insecticidal composition containing cyflufenamid | |
| CN108013060A (en) | A kind of Pesticidal combination containing diflubenzuron and ring bromine insect amide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |