CN105064604A - Anti-bacterial waterproof internal wall plate - Google Patents

Anti-bacterial waterproof internal wall plate Download PDF

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Publication number
CN105064604A
CN105064604A CN201510435455.0A CN201510435455A CN105064604A CN 105064604 A CN105064604 A CN 105064604A CN 201510435455 A CN201510435455 A CN 201510435455A CN 105064604 A CN105064604 A CN 105064604A
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China
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parts
layer
water
wall panel
organosilicon
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CN201510435455.0A
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Chinese (zh)
Inventor
杨金平
卜春华
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Anhui Max Technology Co Ltd
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Anhui Max Technology Co Ltd
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Priority to CN201510435455.0A priority Critical patent/CN105064604A/en
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Abstract

The invention discloses an anti-bacterial waterproof internal wall plate. The anti-bacterial waterproof internal wall plate sequentially comprises a base layer, an adhesion layer, a heat-insulation layer, a plastering mortar layer, a fireproof layer, a waterproof layer, an emulsion layer, a decorative coating and a wear-resistant layer from inside to outside; the waterproof layer is made of acrylic acid coating; and the acrylic acid coating comprises the following raw materials in part by weight: 20-30 parts of butyl acrylate, 10-25 parts of styrene tar emulsion, 20-30 parts of methacrylic acid, 5-10 parts of hydroxymethyl acrylamide, 10-20 parts of diacetone acrylamide, 1-2 parts of adipic acid dihydrazide, 4-5 parts of organo-silicone waterproofing agents, 5-10 parts of barium stearate, 5-15 parts of kaolin, 5-15 parts of calcium carbonate, 2-8 parts of nanometer titania, 5-10 parts of mica powder, 1-3 parts of iron oxide red, 5-10 parts of poly tributyl tin methacrylate, 10-15 parts of polylactide, 5-10 parts of migration agents, 1-4 parts of water-based stearates, 0.5-1.5 parts of sodium tripolyphosphate, 2-5 parts of sodium phosphate, 1-2 parts of defoamer, 2-5 parts of ammonia water and 20-30 parts of water.

Description

A kind of antibacterial waterproof inner wall panel
Technical field
The present invention relates to board technology field, particularly relate to a kind of antibacterial waterproof inner wall panel.
Background technology
In recent years along with country is to the attention of building, the requirement of people to wallboard is more and more higher.Wallboard is divided into inner wall panel and the large class of side fascia two by using function.Inner wall panel is as a kind of novel house decorative material, there is sound insulation and fireproof function, being applicable to medium-to-high grade decoration, having lightweight, fire prevention, protection against the tide, easily process, install the features such as simple, there is the defects such as antibacterial and water resistance is poor in current inner wall panel mostly.
Summary of the invention
The present invention proposes a kind of antibacterial waterproof inner wall panel, good anti-bacterial effect, water resistance is excellent.
The antibacterial waterproof inner wall panel of one that the present invention proposes, comprise set gradually from the inside to the outside basic unit, tack coat, insulation layer, plastering mortar layer, fireprotection layer, waterproofing course, emulsion layer, decorative coveringn and wearing layer; Described waterproofing course adopts acrylic coating to make;
The raw material of described acrylic coating comprises by weight: butyl acrylate 20-30 part, styrene tar emulsion 10-25 part, methacrylic acid 20-30 part, NMA 5-10 part, DAAM 10-20 part, own acid dihydrazide 1-2 part, waterproofing agent of organosilicon 4-5 part, barium stearate 5-10 part, kaolin 5-15 part, calcium carbonate 5-15 part, nano titanium oxide 2-8 part, mica powder 5-10 part, iron oxide red 1-3 part, polymethylacrylic acid Tributyltin 5-10 part, polyethylene glycol 10-15 part, fluorine carbon coupling agent 5-10 part, water-based stearate 1-4 part, sodium phosphate trimer 0.5-1.5 part, sodium phosphate 2-5 part, defoamer 1-2 part, ammoniacal liquor 2-5 part, water 20-30 part.
Preferably, waterproofing agent of organosilicon adopts following technique to prepare: 1-3 part aminomethyl phenyl dichloro (alkoxyl) silane, 20-40 part silicone prepolymer and 1-3 part nonionic surface active agent are sent in agitator by weight and stir, mixing speed is 100-200r/min, mixing time is 20-50min, then rotating speed is raised to 2000-2400r/min, add 20-50 part water to continue to stir 5-10min, the quaternary ammonium silicone continuing to add 5-10 part stirs, and obtains waterproofing agent of organosilicon.
Preferably, nonionic surface active agent can be one or more compositions of the ethylene oxide adduct of APES, high-carbon fatty alcohol polyoxyethylene ether and polypropylene glycol.
Preferably, the weight ratio of butyl acrylate, styrene tar emulsion, methacrylic acid, NMA and DAAM is 24-26:20-24:24-26:6-8:12-14.
Preferably, the weight ratio of waterproofing agent of organosilicon and water-based stearate is 4.4-4.6:2-3.
Preferably, the weight ratio of kaolin, calcium carbonate, nano titanium oxide and mica powder is 6-10:6-10:4-6:6-8.
Preferably, the weight ratio of styrene tar emulsion and waterproofing agent of organosilicon is 20-24:4.4-4.6.
Preferably, the raw material of described acrylic coating comprises by weight: butyl acrylate 24-26 part, styrene tar emulsion 20-24 part, methacrylic acid 24-26 part, NMA 6-8 part, DAAM 12-14 part, own acid dihydrazide 1.2-1.4 part, waterproofing agent of organosilicon 4.4-4.6 part, barium stearate 6-8 part, kaolin 6-10 part, calcium carbonate 6-10 part, nano titanium oxide 4-6 part, mica powder 6-8 part, iron oxide red 1.5-2 part, polymethylacrylic acid Tributyltin 6-8 part, polyethylene glycol 12-14 part, fluorine carbon coupling agent 6-8 part, water-based stearate 2-3 part, sodium phosphate trimer 0.8-1 part, sodium phosphate 2-5 part, defoamer 1.4-1.6 part, ammoniacal liquor 3-4 part, water 22-24 part.
In the present invention, butyl acrylate, styrene tar emulsion, methacrylic acid NMA and DAAM are cross-linking monomer, own acid dihydrazide carries out crosslinking curing as curing compound, paint film density is large, intensity is high, water resistance is excellent, and it is good to substrate adhesion, in the waterproofing agent of organosilicon added, with silicone prepolymer, aminomethyl phenyl dichloro (alkoxyl) silane and quaternary ammonium silicone are Main Ingredients and Appearance, take water as decentralized medium, take nonionic surface active agent as emulsifier, through high speed shear emulsification, good waterproof performance, act synergistically with waterproofing agent of organosilicon after styrene tar emulsion curing cross-linked, effectively can completely cut off it to contact with extraneous water, also there is good application property simultaneously, environment-protecting asepsis and raw material is cheap, the nano titanium oxide added is shown in that light produces the oxygen of negatron in the middle of air and is combined generation active oxygen, there is extremely strong oxidative decomposition capacity, bacterium can be killed, mould, avoid coating to meet aquatic products to mildew spot, increase application life, and the migration agent added can to nano titanium oxide, waterproofing agent of organosilicon and water-based stearate carry out coated, and make bag by after material transport to coating, further raising water resistant and antibacterial effect.
Detailed description of the invention
Embodiment 1
A kind of antibacterial waterproof inner wall panel, comprise set gradually from the inside to the outside basic unit, tack coat, insulation layer, plastering mortar layer, fireprotection layer, waterproofing course, emulsion layer, decorative coveringn and wearing layer; Described waterproofing course adopts acrylic coating to make;
The raw material of described acrylic coating comprises by weight: butyl acrylate 20 parts, styrene tar emulsion 25 parts, methacrylic acid 20 parts, NMA 10 parts, DAAM 10 parts, own acid dihydrazide 2 parts, waterproofing agent of organosilicon 4 parts, barium stearate 10 parts, kaolin 5 parts, 15 parts, calcium carbonate, nano titanium oxide 2 parts, mica powder 10 parts, iron oxide red 1 part, polymethylacrylic acid Tributyltin 10 parts, polyethylene glycol 10 parts, fluorine carbon coupling agent 10 parts, water-based stearate 1 part, sodium phosphate trimer 1.5 parts, sodium phosphate 2 parts, defoamer 2 parts, ammoniacal liquor 2 parts, 30 parts, water.
Embodiment 2
A kind of antibacterial waterproof inner wall panel, comprise set gradually from the inside to the outside basic unit, tack coat, insulation layer, plastering mortar layer, fireprotection layer, waterproofing course, emulsion layer, decorative coveringn and wearing layer; Described waterproofing course adopts acrylic coating to make;
The raw material of described acrylic coating comprises by weight: butyl acrylate 30 parts, styrene tar emulsion 10 parts, methacrylic acid 30 parts, NMA 5 parts, DAAM 20 parts, own acid dihydrazide 1 part, waterproofing agent of organosilicon 5 parts, barium stearate 5 parts, kaolin 15 parts, 5 parts, calcium carbonate, nano titanium oxide 8 parts, mica powder 5 parts, iron oxide red 3 parts, polymethylacrylic acid Tributyltin 5 parts, polyethylene glycol 15 parts, fluorine carbon coupling agent 5 parts, water-based stearate 4 parts, sodium phosphate trimer 0.5 part, sodium phosphate 5 parts, defoamer 1 part, ammoniacal liquor 5 parts, 20 parts, water.
Embodiment 3
A kind of antibacterial waterproof inner wall panel, comprise set gradually from the inside to the outside basic unit, tack coat, insulation layer, plastering mortar layer, fireprotection layer, waterproofing course, emulsion layer, decorative coveringn and wearing layer; Described waterproofing course adopts acrylic coating to make;
The raw material of described acrylic coating comprises by weight: butyl acrylate 24 parts, styrene tar emulsion 24 parts, methacrylic acid 24 parts, NMA 8 parts, DAAM 12 parts, own acid dihydrazide 1.4 parts, waterproofing agent of organosilicon 4.4 parts, barium stearate 8 parts, kaolin 6 parts, 10 parts, calcium carbonate, nano titanium oxide 4 parts, mica powder 8 parts, iron oxide red 1.5 parts, polymethylacrylic acid Tributyltin 8 parts, polyethylene glycol 12 parts, fluorine carbon coupling agent 8 parts, water-based stearate 2 parts, sodium phosphate trimer 1 part, sodium phosphate 2 parts, defoamer 1.6 parts, ammoniacal liquor 3 parts, 24 parts, water.
Waterproofing agent of organosilicon adopts following technique to prepare: 1 part of aminomethyl phenyl dichloro (alkoxyl) silane, 40 parts of silicone prepolymer and 1 part of nonionic surface active agent are sent in agitator by weight and stir, mixing speed is 200r/min, mixing time is 20min, then rotating speed is raised to 2400r/min, add 20 parts of water to continue to stir 10min, the quaternary ammonium silicone continuing to add 5 parts stirs, and obtains waterproofing agent of organosilicon.Nonionic surface active agent is the ethylene oxide adduct of polypropylene glycol.
Embodiment 4
A kind of antibacterial waterproof inner wall panel, comprise set gradually from the inside to the outside basic unit, tack coat, insulation layer, plastering mortar layer, fireprotection layer, waterproofing course, emulsion layer, decorative coveringn and wearing layer; Described waterproofing course adopts acrylic coating to make;
The raw material of described acrylic coating comprises by weight: butyl acrylate 26 parts, styrene tar emulsion 20 parts, methacrylic acid 26 parts, NMA 6 parts, DAAM 14 parts, own acid dihydrazide 1.2 parts, waterproofing agent of organosilicon 4.6 parts, barium stearate 6 parts, kaolin 10 parts, 6 parts, calcium carbonate, nano titanium oxide 6 parts, mica powder 6 parts, iron oxide red 2 parts, polymethylacrylic acid Tributyltin 6 parts, polyethylene glycol 14 parts, fluorine carbon coupling agent 6 parts, water-based stearate 3 parts, sodium phosphate trimer 0.8 part, sodium phosphate 5 parts, defoamer 1.4 parts, ammoniacal liquor 4 parts, water 22-24 part.
Waterproofing agent of organosilicon adopts following technique to prepare: 3 parts of aminomethyl phenyl dichloro (alkoxyl) silane, 20 parts of silicone prepolymer and 3 parts of nonionic surface active agent are sent in agitator by weight and stir, mixing speed is 100r/min, mixing time is 50min, then rotating speed is raised to 2000r/min, add 50 parts of water to continue to stir 5min, the quaternary ammonium silicone continuing to add 10 parts stirs, and obtains waterproofing agent of organosilicon.Nonionic surface active agent is made up of APES, high-carbon fatty alcohol polyoxyethylene ether.
Embodiment 5
A kind of antibacterial waterproof inner wall panel, comprise set gradually from the inside to the outside basic unit, tack coat, insulation layer, plastering mortar layer, fireprotection layer, waterproofing course, emulsion layer, decorative coveringn and wearing layer; Described waterproofing course adopts acrylic coating to make;
The raw material of described acrylic coating comprises by weight: butyl acrylate 25 parts, styrene tar emulsion 21 parts, methacrylic acid 25 parts, NMA 7.5 parts, DAAM 13 parts, own acid dihydrazide 1.35 parts, waterproofing agent of organosilicon 4.5 parts, barium stearate 7.2 parts, kaolin 8 parts, 9 parts, calcium carbonate, nano titanium oxide 5 parts, mica powder 6.2 parts, iron oxide red 1.8 parts, polymethylacrylic acid Tributyltin 7.2 parts, polyethylene glycol 13 parts, fluorine carbon coupling agent 7.2 parts, water-based stearate 2.6 parts, sodium phosphate trimer 0.95 part, sodium phosphate 4 parts, defoamer 1.52 parts, ammoniacal liquor 3.6 parts, 23.5 parts, water.
Waterproofing agent of organosilicon adopts following technique to prepare: 2.6 parts of aminomethyl phenyl dichloro (alkoxyl) silane, 36 parts of silicone prepolymer and 1.6 parts of nonionic surface active agent are sent in agitator by weight and stir, mixing speed is 150r/min, mixing time is 45min, then rotating speed is raised to 2100r/min, add 20-50 part water to continue to stir 8min, the quaternary ammonium silicone continuing to add 8 parts stirs, and obtains waterproofing agent of organosilicon.Nonionic surface active agent is made up of the ethylene oxide adduct of APES, high-carbon fatty alcohol polyoxyethylene ether and polypropylene glycol.
The above; be only the present invention's preferably detailed description of the invention; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.

Claims (8)

1. an antibacterial waterproof inner wall panel, is characterized in that, comprise set gradually from the inside to the outside basic unit, tack coat, insulation layer, plastering mortar layer, fireprotection layer, waterproofing course, emulsion layer, decorative coveringn and wearing layer; Described waterproofing course adopts acrylic coating to make;
The raw material of described acrylic coating comprises by weight: butyl acrylate 20-30 part, styrene tar emulsion 10-25 part, methacrylic acid 20-30 part, NMA 5-10 part, DAAM 10-20 part, own acid dihydrazide 1-2 part, waterproofing agent of organosilicon 4-5 part, barium stearate 5-10 part, kaolin 5-15 part, calcium carbonate 5-15 part, nano titanium oxide 2-8 part, mica powder 5-10 part, iron oxide red 1-3 part, polymethylacrylic acid Tributyltin 5-10 part, polyethylene glycol 10-15 part, fluorine carbon coupling agent 5-10 part, water-based stearate 1-4 part, sodium phosphate trimer 0.5-1.5 part, sodium phosphate 2-5 part, defoamer 1-2 part, ammoniacal liquor 2-5 part, water 20-30 part.
2. antibacterial waterproof inner wall panel according to claim 1, it is characterized in that, waterproofing agent of organosilicon adopts following technique to prepare: by weight by 1-3 part aminomethyl phenyl dichloro (alkoxyl) silane, 20-40 part silicone prepolymer and 1-3 part nonionic surface active agent are sent in agitator and are stirred, mixing speed is 100-200r/min, mixing time is 20-50min, then rotating speed is raised to 2000-2400r/min, add 20-50 part water to continue to stir 5-10min, the quaternary ammonium silicone continuing to add 5-10 part stirs, obtain waterproofing agent of organosilicon.
3. antibacterial waterproof inner wall panel according to claim 2, is characterized in that, nonionic surface active agent can be one or more compositions of the ethylene oxide adduct of APES, high-carbon fatty alcohol polyoxyethylene ether and polypropylene glycol.
4. the antibacterial waterproof inner wall panel according to any one of claim 1-3, it is characterized in that, the weight ratio of butyl acrylate, styrene tar emulsion, methacrylic acid, NMA and DAAM is 24-26:20-24:24-26:6-8:12-14.
5. the antibacterial waterproof inner wall panel according to any one of claim 1-4, is characterized in that, the weight ratio of waterproofing agent of organosilicon and water-based stearate is 4.4-4.6:2-3.
6. the antibacterial waterproof inner wall panel according to any one of claim 1-5, is characterized in that, the weight ratio of kaolin, calcium carbonate, nano titanium oxide and mica powder is 6-10:6-10:4-6:6-8.
7. the antibacterial waterproof inner wall panel according to any one of claim 1-6, is characterized in that, the weight ratio of styrene tar emulsion and waterproofing agent of organosilicon is 20-24:4.4-4.6.
8. the antibacterial waterproof inner wall panel according to any one of claim 1-7, it is characterized in that, the raw material of described acrylic coating comprises by weight: butyl acrylate 24-26 part, styrene tar emulsion 20-24 part, methacrylic acid 24-26 part, NMA 6-8 part, DAAM 12-14 part, own acid dihydrazide 1.2-1.4 part, waterproofing agent of organosilicon 4.4-4.6 part, barium stearate 6-8 part, kaolin 6-10 part, calcium carbonate 6-10 part, nano titanium oxide 4-6 part, mica powder 6-8 part, iron oxide red 1.5-2 part, polymethylacrylic acid Tributyltin 6-8 part, polyethylene glycol 12-14 part, fluorine carbon coupling agent 6-8 part, water-based stearate 2-3 part, sodium phosphate trimer 0.8-1 part, sodium phosphate 2-5 part, defoamer 1.4-1.6 part, ammoniacal liquor 3-4 part, water 22-24 part.
CN201510435455.0A 2015-07-21 2015-07-21 Anti-bacterial waterproof internal wall plate Pending CN105064604A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105713506A (en) * 2016-03-24 2016-06-29 安徽德全新型建材科技有限公司 High-temperature-resistant and fire-proof external wallboard
CN111423804A (en) * 2020-04-30 2020-07-17 郑州一安水性高分子材料有限公司 Broad-spectrum long-acting antibacterial water-based environment-friendly coating and preparation method thereof

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6416872A (en) * 1987-07-10 1989-01-20 Showa Highpolymer Waterproof coating material composition for wall face
JP2005132926A (en) * 2003-10-29 2005-05-26 Mitsuboshi Belting Ltd Coating composition for waterproof sheet and method for applying waterproof layer
CN103436159A (en) * 2013-09-11 2013-12-11 王国玺 Composite high-polymer waterproof paint and preparation method thereof
CN103820995A (en) * 2014-01-22 2014-05-28 南雄鼎成化工有限公司 Method for preparing reinforced water-proof and mildew-proof organosilicon water-proof agent
CN203834794U (en) * 2014-05-28 2014-09-17 中铁十一局集团有限公司 Building heat-preservation wall board for civil engineering
CN104446125A (en) * 2014-12-07 2015-03-25 南雄鼎成化工有限公司 Organosilicon waterproofing agent of solid powder and preparation method of organosilicon waterproofing agent
CN104650296A (en) * 2013-11-20 2015-05-27 中国石油化工股份有限公司 Modified polyacrylate emulsion, preparation method and application thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6416872A (en) * 1987-07-10 1989-01-20 Showa Highpolymer Waterproof coating material composition for wall face
JP2005132926A (en) * 2003-10-29 2005-05-26 Mitsuboshi Belting Ltd Coating composition for waterproof sheet and method for applying waterproof layer
CN103436159A (en) * 2013-09-11 2013-12-11 王国玺 Composite high-polymer waterproof paint and preparation method thereof
CN104650296A (en) * 2013-11-20 2015-05-27 中国石油化工股份有限公司 Modified polyacrylate emulsion, preparation method and application thereof
CN103820995A (en) * 2014-01-22 2014-05-28 南雄鼎成化工有限公司 Method for preparing reinforced water-proof and mildew-proof organosilicon water-proof agent
CN203834794U (en) * 2014-05-28 2014-09-17 中铁十一局集团有限公司 Building heat-preservation wall board for civil engineering
CN104446125A (en) * 2014-12-07 2015-03-25 南雄鼎成化工有限公司 Organosilicon waterproofing agent of solid powder and preparation method of organosilicon waterproofing agent

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105713506A (en) * 2016-03-24 2016-06-29 安徽德全新型建材科技有限公司 High-temperature-resistant and fire-proof external wallboard
CN111423804A (en) * 2020-04-30 2020-07-17 郑州一安水性高分子材料有限公司 Broad-spectrum long-acting antibacterial water-based environment-friendly coating and preparation method thereof

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