CN105061013A - Efficient foliar fertilizer prepared by degrading cotton seed hulls and preparation method for efficient foliar fertilizer - Google Patents

Abstract

The invention discloses an efficient foliar fertilizer prepared by degrading cotton seed hulls and a preparation method for the efficient foliar fertilizer. The efficient foliar fertilizer is prepared from the following raw materials in parts by weight: 30-45 parts of cotton seed hulls, 30-50 parts of bran, 10-20 parts of sour milk, 160-200 parts of a 4mol/L dilute hydrochloric acid solution, 20-40 parts of saturated ammonia water, 5-9 parts of trace elements, 10-15 parts of ammonium molybdate, 2-4 parts of chitin, 12-17 parts of sodium dihydrogen phosphate, 14-20 parts of ammonium nitrate, 18-25 parts of ammonium hydrogen carbonate, 4-5 parts of an active agent and a proper amount of water. Concentration of acid is properly reduced; low-protein substances such as waste cotton seed hulls, bran and the like in life are dissolved and then are centrifuged to obtain liquid supernatant; trace elements and a great number of elements are chelated to form the efficient foliar fertilizer under the improvement of the active agent; the efficient foliar fertilizer is low in cost, and practical; and the fertilizer is efficiently utilized, so that environmental pollution is reduced.

Description

High-efficiency foliage fertilizer of a kind of cotton seed hulls degraded preparation and preparation method thereof

Technical field

The invention belongs to the Technology field of fertilizer, be specifically related to high-efficiency foliage fertilizer of a kind of cotton seed hulls degraded preparation and preparation method thereof.

Background technology

Foliage fertilizer is that nutritive element is applied to farm crop blade surface; a kind of fertilizer type of its function is played by the absorption of blade; the blade of plant has upper and lower two-layer epidermis; be made up of epidermic cell; on table, there are stratum corneum and wax in the outside of cell, can protect the functions such as the enforcement of the mesophyll cell under face tissue is photosynthetic, breathing, by the impact of extraneous unfavourable condition change; blade surface also has many small pores, exercises the function that gas is changed.Research shows, stratum corneum is made up of a kind of Long carbon chain fatty acid polymer with hydroxyl and carboxyl, hydroxyl on the molecular gap of this polymkeric substance and molecule, carboxylated hydrophilic group can allow the aqueous solution penetrate in leaf, certainly, the pore of blade surface is that foliage fertilizer enters blade passage more easily.In chemical fertilizer, the stratum corneum of urea class material to epidermic cell has ramollescence, can accelerate the infiltration of other nutritive substance, so urea becomes the important moiety of foliage fertilizer.

The method for hydrolysis of protein mainly contains acid hydrolysis, water breakthrough solution and enzymic hydrolysis.The present invention uses acid-hydrolyzed method, in atmospheric conditions, concentration of hydrochloric acid optimal concentration when testing 110 DEG C, select same materials pig hair, the concentration of hydrochloric acid selected respectively is 12mol/L, 6mol/L and 2mol/L, wherein hydrochloric acid (ml) is respectively 2: 1,3: 1,4: 1,6: 1,8: 1 and 10: 1 with the proportioning of pig hair (g), then detects content amino acid whose in reactor at set intervals.According to showing that data show, be 4: 1 in hydrochloric acid (ml) and pig hair (g) proportioning, under the condition of hydrolysis time 15h, the aminoacids content of pig hair hydrolyzed solution is the highest 84.76%, and the result that different time is surveyed is all without significant difference.Due to along with the increase gradually by acid amount, the energy that next step decompression depickling is expended increases, and also can cause the waste of the energy.Therefore, consider from the cost-saving angle with the energy, the present invention adopts 6mol/L hydrochloric acid to be hydrolyzed, and the ratio of hydrochloric acid and material is about 4: 1, and hydrolysis time is 14 ~ 18h, can reach optimal hydrolysis effect.

Dimethyl dodecyl amine oxide: colourless to pale yellow viscous liquid, a kind of amphoterics, colourless transparent liquid, for weak cation tensio-active agent, in cationic in acidic medium, in nonionic in alkaline medium, there is good thickening, antistatic, soft, foam enhancing and detergency ability; This product pungency is low, effectively can reduce the negatively charged ion pungency in washing composition, also has the features such as sterilization, calcium soap dispersion, readily biodegradable.

Alkyl glycoside is the more comprehensive new non-ionic surfactants of a kind of performance, have the characteristic of conventional nonionic and ionic surface active agent concurrently, having high surface, good ecological security and intermiscibility, is internationally recognized first-selection " green " functional surfactant.

The effect of promoting agent is the penetrating quality increasing foliar nutrient, improve utilization rate of fertilizer, foliage fertilizer absorbs mainly through the blade of plant, promoting agent of the present invention contains kinds of surface active substance, the penetrating power of liquid fertilizer can be improved, reduce the surface tension of liquid fertilizer, increase the contact area of Liquid Fertilizer and blade, slow down velocity of evaporation, penetration enhancement, foliage fertilizer excessive concentration or the too fast blade of likely burning of moisture evaporation, cause fertilizer damage, add a certain amount of activity and stimulating component, be conducive to the cutin destroying blade table confluent monolayer cells, improve absorption rate, improve stress resistance of plant.

Summary of the invention

A kind of high-efficiency foliage fertilizer of cotton seed hulls degraded preparation, it is characterized in that, be made up of the raw material of following weight part: cotton seed hulls 30 ~ 45, wheat bran 30 ~ 50, rotten milk 10 ~ 20,4mol/L dilute hydrochloric acid solution 160 ~ 200, saturated ammoniacal liquor 20 ~ 40, trace element 5 ~ 9, ammonium molybdate 10 ~ 15, chitin 2 ~ 4, SODIUM PHOSPHATE, MONOBASIC 12 ~ 17, ammonium nitrate 14 ~ 20, bicarbonate of ammonia 18 ~ 25, promoting agent 4 ~ 5 and appropriate water;

Described promoting agent is made up of the raw material of following weight part: sodium bicarbonate 1 ~ 3, urea 4 ~ 8, dimethyl dodecyl amine oxide 2 ~ 3, kaolin 8 ~ 12, methyl-silicone oil 2 ~ 5, alkyl glycoside 4 ~ 7 and appropriate water; Preparation method is: (1), in reaction cylinder, mixing dimethyl dodecyl amine oxide and alkyl glycoside, be blended into the water dilution of about 20 times its total weight parts, then add methyl-silicone oil, stirs 30 ~ 50min to bubbling under 300 ~ 400r/min condition; (2) kaolin micronizing is crossed 140 mesh sieves, mixing urea and sodium bicarbonate join in the solution described in (1), are heated to 40 ~ 60 DEG C, insulated and stirred 20 ~ 35min.

A preparation method for the high-efficiency foliage fertilizer of cotton seed hulls degraded preparation, is characterized in that, comprise following step:

(1) cotton seed hulls, wheat bran and rotten milk are mixed, put into the reactor filling 4mol/L dilute hydrochloric acid solution together, be heated to 60 ~ 95 DEG C, under the heat-retaining condition of 300 ~ 500r/min, stir 10 ~ 16h;

(2) neutralize the solution described in (1) with saturated ammoniacal liquor, adjustment pH is 4.5 ~ 6, centrifugal supernatant liquid under 1200 ~ 2000r/min centrifugal condition;

(3) mixed trace elements, ammonium molybdate, chitin, SODIUM PHOSPHATE, MONOBASIC, ammonium nitrate and bicarbonate of ammonia, adds the water of 4 ~ 5 times, and heated and stirred is dissolved, and is cooled to room temperature and obtains nutritive medium;

(4) mix the clear liquid of (2) and the nutritive medium of (3), add promoting agent and other remaining component, be heated to 80 ~ 100 DEG C and stir 1 ~ 3h carry out chelating, after completing.

Beneficial effect of the present invention: the present invention is by suitably reducing the concentration of acid, for the material of the dead meal cotton seed hulls, wheat bran etc. in life containing low albumen is degraded, then centrifugally supernatant liquor is obtained, for chelated microelement and macroelement, under the improvement of promoting agent, become a kind of foliar nutrient efficiently, with low cost, finished product is practical, the fertilizer of efficiency utilization, reduces environmental pollution.

Embodiment

Embodiment 1:

A kind of high-efficiency foliage fertilizer of cotton seed hulls degraded preparation, it is characterized in that, be made up of the raw material of following weight part (Kg): cotton seed hulls 38, wheat bran 40, rotten milk 16,4mol/L dilute hydrochloric acid solution 165, saturated ammoniacal liquor 25, trace element 7, ammonium molybdate 12, chitin 3, SODIUM PHOSPHATE, MONOBASIC 17, ammonium nitrate 20, bicarbonate of ammonia 20, promoting agent 4 and appropriate water;

Described promoting agent is made up of the raw material of following weight part: sodium bicarbonate 1, urea 6, dimethyl dodecyl amine oxide 2, kaolin 12, methyl-silicone oil 3, alkyl glycoside 6 and appropriate water; Preparation method is: (1), in reaction cylinder, mixing dimethyl dodecyl amine oxide and alkyl glycoside, be blended into the water dilution of about 20 times its total weight parts, then add methyl-silicone oil, stirs 30 ~ 50min to bubbling under 300 ~ 400r/min condition; (2) kaolin micronizing is crossed 140 mesh sieves, mixing urea and sodium bicarbonate join in the solution described in (1), are heated to 40 ~ 60 DEG C, insulated and stirred 20 ~ 35min.

A preparation method for the high-efficiency foliage fertilizer of cotton seed hulls degraded preparation, is characterized in that, comprise following step:

(1) cotton seed hulls, wheat bran and rotten milk are mixed, put into the reactor filling 4mol/L dilute hydrochloric acid solution together, be heated to 60 ~ 95 DEG C, under the heat-retaining condition of 300 ~ 500r/min, stir 10 ~ 16h;

(2) neutralize the solution described in (1) with saturated ammoniacal liquor, adjustment pH is 4.5 ~ 6, centrifugal supernatant liquid under 1200 ~ 2000r/min centrifugal condition;

(3) mixed trace elements, ammonium molybdate, chitin, SODIUM PHOSPHATE, MONOBASIC, ammonium nitrate and bicarbonate of ammonia, adds the water of 4 ~ 5 times, and heated and stirred is dissolved, and is cooled to room temperature and obtains nutritive medium;

(4) mix the clear liquid of (2) and the nutritive medium of (3), add promoting agent and other remaining component, be heated to 80 ~ 100 DEG C and stir 1 ~ 3h carry out chelating, after completing.

The high-efficiency foliage fertilizer of cotton seed hulls degraded preparation of the present invention is used for planting common agricultural experiment; select 5 mu of planting bases; mix to insert and spray fertilizer of the present invention; as experimental group; common fertilizer is executed in 5 mu of bases of control group routinely planting requirement; other condition is identical; experiment proves; experimental group plantation farm crop, its stalk and branches and leaves more sturdy, growing way is obviously better than control group; greatly reduce base fertilizer usage quantity simultaneously; save labour, protection of the environment, produce in the fruit time limit and disease and insect resistance etc. in prolongation fruit tree and play significant role.

Claims (2)

1. the high-efficiency foliage fertilizer of a cotton seed hulls degraded preparation, it is characterized in that, be made up of the raw material of following weight part: cotton seed hulls 30 ~ 45, wheat bran 30 ~ 50, rotten milk 10 ~ 20,4mol/L dilute hydrochloric acid solution 160 ~ 200, saturated ammoniacal liquor 20 ~ 40, trace element 5 ~ 9, ammonium molybdate 10 ~ 15, chitin 2 ~ 4, SODIUM PHOSPHATE, MONOBASIC 12 ~ 17, ammonium nitrate 14 ~ 20, bicarbonate of ammonia 18 ~ 25, promoting agent 4 ~ 5 and appropriate water;

Described promoting agent is made up of the raw material of following weight part: sodium bicarbonate 1 ~ 3, urea 4 ~ 8, dimethyl dodecyl amine oxide 2 ~ 3, kaolin 8 ~ 12, methyl-silicone oil 2 ~ 5, alkyl glycoside 4 ~ 7 and appropriate water; Preparation method is: (1), in reaction cylinder, mixing dimethyl dodecyl amine oxide and alkyl glycoside, be blended into the water dilution of about 20 times its total weight parts, then add methyl-silicone oil, stirs 30 ~ 50min to bubbling under 300 ~ 400r/min condition; (2) kaolin micronizing is crossed 140 mesh sieves, mixing urea and sodium bicarbonate join in the solution described in (1), are heated to 40 ~ 60 DEG C, insulated and stirred 20 ~ 35min.

2. the preparation method of the high-efficiency foliage fertilizer of a kind of cotton seed hulls degraded preparation according to claim 1, is characterized in that, comprise following step:

(1) cotton seed hulls, wheat bran and rotten milk are mixed, put into the reactor filling 4mol/L dilute hydrochloric acid solution together, be heated to 60 ~ 95 DEG C, under the heat-retaining condition of 300 ~ 500r/min, stir 10 ~ 16h;

(2) neutralize the solution described in (1) with saturated ammoniacal liquor, adjustment pH is 4.5 ~ 6, centrifugal supernatant liquid under 1200 ~ 2000r/min centrifugal condition;

(3) mixed trace elements, ammonium molybdate, chitin, SODIUM PHOSPHATE, MONOBASIC, ammonium nitrate and bicarbonate of ammonia, adds the water of 4 ~ 5 times, and heated and stirred is dissolved, and is cooled to room temperature and obtains nutritive medium;

(4) mix the clear liquid of (2) and the nutritive medium of (3), add promoting agent and other remaining component, be heated to 80 ~ 100 DEG C and stir 1 ~ 3h carry out chelating, after completing.