CN105040410A - Method for treating thermal inductance non-ironing all-cotton shirt - Google Patents
Method for treating thermal inductance non-ironing all-cotton shirt Download PDFInfo
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Abstract
The invention relates to a method for treating a thermal inductance non-ironing all-cotton shirt. The method comprises the steps of conducting liquefied ammonia treatment on all-cotton fabric; using a pre-shrinking machine for conducting pre-shrinking treatment on the fabric, and using antibacterial, heat-emitting, hydrophilic and non-ironing liquid for conducting electrostatic spraying on the all-cotton fabric which is preshrunk; conducting microwave treatment on the all-cotton fabric after the electrostatic spraying is finished; conducting vacuum treatment on the all-cotton fabric after the microwave treatment is finished; continuing to conduct cooking treatment on the all-cotton fabric with wood pulp after the vacuum treatment is finished, and the wood pulp is treated by the microwave treatment; Spin-drying the all-cotton fabric which is cooked with the wood pulp, and then placing the fabric in a freezing chamber for conducting freeze-drying treatment; putting the all-cotton fabric which is treated through the free-drying into impregnation liquid which contains warm-keeping finishing agents for conducting padding treatment, and conducting drying, cutting and clothing fabrication on the all-cotton fabric after the padding treatment is finished; using a baking shaping machine for conducting ironing and shaping on ready-made clothes, then conducting the trimming and packing, and finally putting the clothes in storage. The all-cotton shirt treated by the method has the heat-emitting, anti-bacterial and non-ironing effect.
Description
Technical field
The present invention relates to weaving and garment technology field, be specifically related to the processing method of the non-ironing cotton shirt of a kind of hotness.
Background technology
Along with improving constantly of living standard, the Functional Requirement of people to clothing is more and more higher, especially not only focuses on soft comfortable to the selection of underwear, more focuses on health, health care.Traditional Shirt with warm keeping filler usually adopts and thickeies design, although warmth retention property is good, has that clothing is too thick and heavy, a problem such as comfortableness and poor air permeability.Existing Shirt with warm keeping filler fabric poor durability, repeatedly after washing, warming effect weakens greatly.Therefore, develop a kind of i.e. non-toxic and safe, but also the Shirt with warm keeping filler with excellent durability become important research topic.
At present along with the raising of people's living standard, people require more and more higher to the dress of clothing.Traditional Shirt with warm keeping filler usually adopts and thickeies design, although warmth retention property is good, has that clothing is too thick and heavy, comfortableness and a poor air permeability, be inconvenient to move, put on after lack again the problem such as aesthetic feeling, fashion.Current insulation garment is constantly developed to underwear by coat, and people wish just can reach good warming effect by underwear comfortable and easy to wear, and as stopping the first line of defence that human heat scatters and disappears, the protective action of underwear to heat loss is very important.Therefore in the face of badly changeable atmospheric environment, develop frivolous warming, heating, comfortable, healthy insulation garment, underwear, can give cold-proof underwear, clothes bring huge industry added value and great market business opportunity.Now insulation garment commercially, mainly in clothes, add equipment with metal material, carbon fiber, Electric radiant Heating Film and similar electric baby's exothermic material, have that thermal conductivity factor is large, warmth retention property is bad, not energy-conservation, heating warm area is unbalanced, difference large, heat exhaustion amount is large, thermal energy conversion efficiency is low, far-infrared functional is low, not lasting, poor with mating of clothes, wear uncomfortable, not aesthetic feeling, fashion.The problems such as manufacturing technique is complicated, production efficiency is low.
The present age, clothes were not only for hiding body, the warming and general decoration of work, but to high-qualityization, stylishization, comfortableization future development.Be mainly or all cotton fiber in the face liber composition of cotton shirt.Cotton fiber has good hygroscopicity, and under normal conditions, fiber can absorb moisture in peripherad air, and its moisture content is 8 ~ 10%, so the skin of its contact people, makes people feel soft and not stiff.If cotton humidity increases, environment temperature is higher, and the amount of moisture contained in fiber can all leave in evaporation, makes fabric keep water equilibrated state, makes people feel comfortable.Therefore, compared with chemical fiber plus material, cotton fabric shirt has excellent moisture absorbability and moisture retentivity.But inside and outside stock, all cotton fibers clothes all do not possess the function of heating at present.How the advantage of heating clothes and all cotton fibers clothes is combined, become those skilled in the art and needed both to be felt technical problem.
Summary of the invention
The object of the invention is to overcome defect of the prior art, design one can make all cotton fibers clothes, has the processing method of the non-ironing cotton shirt of hotness of heating and antibiotic effect.
For achieving the above object, the technical solution adopted in the present invention is:
A processing method for the non-ironing cotton shirt of hotness, is characterized in that, described method comprises the steps:
The first step, carries out Liquid Ammonia Treatment to cotton fabric;
Second step, carries out shrunk finish with preshrinking machine to fabric, and steam pressure is 5 ~ 6kg/m
2, steam consumption is 30 ~ 45kg/h;
3rd step, with the cotton fabric after antibacterial, heating, hydrophilic non-ironing liquid electrostatic spraying preshrunk;
4th step, carries out microwave treatment to the cotton fabric after electrostatic spraying;
5th step, vacuumizes process to the cotton fabric after microwave treatment, is evacuated to vacuum for-0.04Mpa ~-0.03Mpa;
6th step, to vacuumizing the cotton fabric after process, then carries out boiling process with the wood pulp liquid crossed through microwave treatment;
7th step, dries with the cotton fabric after wood pulp liquid boiling process, then puts into refrigerating chamber and carry out freeze drying process;
8th step, by the cotton fabric after freeze drying process, drops in the maceration extract containing warming finishing agent and carries out padding process, maceration extract pressure 1.5 ~ 2kg/cm
2, liquid carrying rate 60 ~ 70%;
9th step, by padding that the cotton fabric after process carries out drying, cutting, clothing;
Tenth step, by the ready-made clothes made with baking and banking up with earth setting machine whole boiling hot sizing after 10 ~ 20 minutes at 140 ~ 150 DEG C, then carries out arranging, packs, puts in storage.
In order to adapt to the characteristic of cotton fabric, antibacterial heating liquid can be made all to penetrate into the inside of cotton fiber, its preferred technical scheme is, in described 3rd step, the spray distance of electrostatic spraying is 120mm ~ 150mm, the voltage of electrostatic spraying is 90V ~ 120V, and the air pressure of electrostatic spraying is 0.05 ~ 0.08Mpa.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, preferred technical scheme also has, and in described 3rd step, antibacterial heating liquid is made up of the raw material of following parts by weight:
Phthalic acid 10 ~ 15 parts, the furfuryl alcohol extracted from natural plants 3 ~ 5 parts, triethylene glycol 15 ~ 18 parts, glue acid 20 ~ 22 parts, tromethamine 2 ~ 6 parts, 3 ~ 5 parts, nickel oxygen powder, 1 ~ 2 part, zinc oxide, neoprene latex 10 ~ 12 parts, elastic plastic 100 ~ 110 parts, rubber softening oil 4 ~ 6 parts, 5 ~ 10 parts, carbonic acid ethane, dichlorobenzoperoxide 4 ~ 6 parts, beet molasses dregs 10 ~ 12 parts, emulsifying agent 2 ~ 6 parts, chitosan 10 ~ 15 parts, Tourmaline particle 0.1 ~ 0.2 part, negative ion powder 1 ~ 2 part, macromolecule resin 0.5 ~ 0.8 part, Nano Silver 10 × 10
~ 6~ 12 × 10
~ 6part, fire retardant 4 ~ 6 parts, ethyl cellulose 15 ~ 20 parts, deionized water 50 ~ 60 parts,
Described negative ion powder is made up of following components in mass portion: opal 10 ~ 25 parts; Medical stone 20 ~ 30 parts; 5 ~ 10 parts, shell; 2 ~ 10 parts, diatomite; Zirconic anhydride 10 ~ 15 parts; Nanometer silver-zirconium phosphate antimicrobial 8 ~ 10 parts;
Described emulsifying agent is alkylphenol polyoxyethylene, in castor oil, lauric alcohol sodium sulphate, lauryl sodium sulfate any one or its mix arbitrarily;
Described elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 1 ~ 2:1.5;
The solids content that described first elastic plastic comprises 40 ~ 45 parts of weight is the emulsion acrylic resin of 30 ~ 50%, the solids content of 5 ~ 8 parts of aqueous polyurethanes, 10 ~ 12 parts of acrylic resin powder, 7 ~ 10 parts of weight is the EVA emulsion of 10 ~ 15% and the chlorinated polypropylene of 7 ~ 10 parts of weight;
The preparation method of described second elastic plastic is: be the polyvinyl alcohol water solution of 20 ~ 25% by mass concentration, mass concentration be 15 ~ 20% the aqueous polyurethane aqueous solution and deionized water heat to 85 ~ 100 DEG C, be cooled to 60 ~ 70 DEG C and add acrylate 20 ~ 25%, then add NaOH 0.3 ~ 0.4% and be warming up to 85 ~ 95 DEG C, then add gelatine protein 10 ~ 12%, rosin fat 3 ~ 5%, the plant phenols 5 ~ 6% extracted from natural plants; React and be cooled to 60 ~ 65 DEG C in 1 ~ 2 hour, then add Sodium Benzoate 0.02 ~ 0.05%, di-t-butyl peroxide 0.03 ~ 0.04% and beet molasses dregs 0.1 ~ 0.3%, stir 2 ~ 2.5 hours, cooling, obtained described second elastic plastic, wherein deionized water is all the other compositions;
Described Nano Silver is prepared from according to following steps:
A, sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution to be added in silver nitrate aqueous solution and obtain mixed liquor, the mol ratio of described lauryl sodium sulfate and silver nitrate is 2 ~ 3:1; The mol ratio of described water polyacrylic acid and silver nitrate is 0.2 ~ 0.3:1; The mol ratio of described hydrazine hydrate and silver nitrate is 0.4 ~ 0.5:1;
B. in described mixed liquor, add crown ether and sodium metaphosphate, the mol ratio of described crown ether and silver nitrate is 1 ~ 2:1; The mol ratio of described sodium metaphosphate and silver nitrate is 0.3 ~ 0.6:1, and control ph is 10 ~ 11, obtains Nano Silver;
In described hydrophilic non-ironing treatment fluid, key component is hydrophilic no-ironing resin, fiber protection agent, softener, catalyst, PH conditioning agent and water; the content of key component is: hydrophilic no-ironing resin 60 ~ 200g/L, fiber protection agent 10 ~ 50g/L, softener 20 ~ 60g/L, catalyst 15 ~ 25g/L, and the pH value of described hydrophilic non-ironing treatment fluid is 3.5 ~ 6.
After penetrating into cotton fiber to make antibacterial heating liquid, can be long-time, and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, preferred technical scheme also has further, the preparation method of described emulsion acrylic resin is: the acrylate monomer mixed liquor of preparation 50 ~ 75 parts of weight is stand-by, then by OPEO, castor oil, lauryl sodium sulfate, the emulsifying agent of 2 ~ 4 parts of weight of several compositions in dodecyl phenenyl sulfate, the sodium bicarbonate of 0.8 ~ 1.2 part of weight and deionized water join in reactor, add the 1/4 acrylate monomer mixed liquor prepared again wherein, be warming up to 40 ~ 80 DEG C, abundant stirring 50 ~ 80min, be warming up to 80 ~ 120 DEG C, drip remaining 3/4 acrylate monomer mixed liquor and ammonium persulfate solution initator, it is 2 ~ 5h that time for adding controls, and ensures that monomer drips prior to initiator solution, dropwise rear insulation 2 ~ 5h, after cooling, regulate ph value of emulsion to about 7.5.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, preferred technical scheme also has further, before adding crown ether and sodium metaphosphate in described step B in described mixed liquor, described mixed liquor is heated to 65 ~ 70 DEG C; Described step B is heated to 60 ~ 65 DEG C add crown ether and sodium metaphosphate in described mixed liquor after, Keep agitation 5 ~ 8min.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred technical scheme also has, and the described furfuryl alcohol extracted from natural plants is selected from the furfuryl alcohol extracted from the wheat bran or bamboo wood chip of the core slag of corncob, oat or wheat; The described plant phenols extracted from natural plants is eugenol or anacardol.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, preferred technical scheme also has further, containing dilute sulfuric acid catalyst 0.3 ~ 0.5 part in described antiseptic solution.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, preferred technical scheme also has, microwave treatment in described 4th step, its microwave frequency is 130MHz ~ 280MHz, and microwave treatment time is 6 ~ 8min.
In order to make the antibacterial heating liquid penetrating into cotton fiber play its effect better, and its effect is further strengthened, preferred technical scheme also has.Warming finishing agent in described 8th step is made up of the component of following weight portion: 30 ~ 50 parts, marine alga carbon fiber, titanium dioxide 5 ~ 9 parts, 5 ~ 8 parts, zinc oxide, medical stone 30 ~ 50 parts, 6 ~ 8 parts, chromium oxide, silane coupler 6 ~ 10 parts, sodium polyacrylate disperant 1.2 ~ 1.5 parts, and adds water and be made into the padding liquid that mass concentration is 45 ~ 55%; Described sodium polyacrylate disperant viscosity is 200 ~ 300mPas.
The preferred technical scheme of the present invention is, described cotton worsted fabric is the high-accuracy cotton yarn knitted fabric of 120.
Advantage of the present invention and beneficial effect are: because method of the present invention is by antibacterial, heating, hydrophilic non-ironing liquid and warming finishing agent, by electrostatic spraying, to pad etc. after technique processes, far infrared radiation, stable components that is antibacterial, that wash rear non-ironing effect firm the can be received be attached to having in all cotton fibers institutional framework.The cotton clothes after process are made to have heat absorption, insulation, antibacterial and non-ironing effect for a long time.
Detailed description of the invention
Below in conjunction with embodiment, the specific embodiment of the present invention is further described.Following examples only for technical scheme of the present invention is clearly described, and can not limit the scope of the invention with this.
Embodiment 1
A processing method for the non-ironing cotton shirt of hotness, described method comprises the steps:
The first step, carries out Liquid Ammonia Treatment to cotton fabric;
Second step, carries out shrunk finish with preshrinking machine to fabric, and steam pressure is 5kg/m
2, steam consumption is 30kg/h;
3rd step, with the cotton fabric after antibacterial, heating, hydrophilic non-ironing liquid electrostatic spraying preshrunk;
4th step, carries out microwave treatment to the cotton fabric after electrostatic spraying;
5th step, vacuumizes process to the cotton fabric after microwave treatment, is evacuated to vacuum for-04Mpa;
6th step, to vacuumizing the cotton fabric after process, then carries out boiling process with the wood pulp liquid crossed through microwave treatment, and digestion time is 30min, and boiling temperature is 80 DEG C;
7th step, dry with the cotton fabric after wood pulp liquid boiling process, then put into refrigerating chamber and carry out freeze drying process, cryogenic temperature is 0 DEG C, and cooling time is 10min;
8th step, by the cotton fabric after freeze drying process, drops in the maceration extract containing warming finishing agent and carries out padding process, maceration extract pressure 1.5kg/cm
2, liquid carrying rate 60%;
9th step, by padding that the cotton fabric after process carries out drying, cutting, clothing;
Tenth step, by the ready-made clothes made with baking and banking up with earth setting machine whole boiling hot sizing after 20 minutes at 140 DEG C, then carries out arranging, packs, puts in storage.
In order to adapt to the characteristic of cotton fabric, antibacterial heating liquid can be made all to penetrate into the inside of cotton fiber, and its preferred technical scheme is, in described 3rd step, the spray distance of electrostatic spraying is 120mm, the voltage of electrostatic spraying is 120V, and the air pressure of electrostatic spraying is 0.05Mpa.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, preferred embodiment also has, and in described 3rd step, antibacterial heating liquid is made up of the raw material of following parts by weight:
Phthalic acid 10 parts, the furfuryl alcohol 3 parts extracted from natural plants, triethylene glycol 15 parts, glue acid 20 parts, tromethamine 2 parts, 3 parts, nickel oxygen powder, 1 part, zinc oxide, neoprene latex 10 parts, elastic plastic 100 parts, rubber softening oil 4 parts, 5 parts, carbonic acid ethane, dichlorobenzoperoxide 4 parts, beet molasses dregs 10 parts, emulsifying agent 2 parts, chitosan 10 parts, Tourmaline particle 0.1 part, negative ion powder 1 part, macromolecule resin 0.5 part, Nano Silver 10 × 10
~ 6part, fire retardant 4 parts, ethyl cellulose 15 parts, deionized water 50 parts;
Described negative ion powder is made up of following components in mass portion: opal 10 parts; Medical stone 20 parts; 5 parts, shell; 2 parts, diatomite; Zirconic anhydride 10 parts; Nanometer silver-zirconium phosphate antimicrobial 8 parts;
Described emulsifying agent is alkylphenol polyoxyethylene, in castor oil, lauric alcohol sodium sulphate, lauryl sodium sulfate any one or its mix arbitrarily;
Described elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 1:1.5;
The solids content that described first elastic plastic comprises 40 parts of weight is the emulsion acrylic resin of 30%, the solids content of 5 parts of aqueous polyurethanes, 10 parts of acrylic resin powder, 7 parts of weight is the EVA emulsion of 10% and the chlorinated polypropylene of 7 parts of weight;
The preparation method of described second elastic plastic is: be the polyvinyl alcohol water solution of 20% by mass concentration, mass concentration be 15% the aqueous polyurethane aqueous solution and deionized water heat to 85 DEG C, be cooled to 60 DEG C and add acrylate 20%, then add NaOH 0.3% and be warming up to 85 DEG C, then add gelatine protein 10 %, rosin fat 3%, the plant phenols 5% extracted from natural plants; React and be cooled to 60 DEG C in 1 hour, then add Sodium Benzoate 0.02%, di-t-butyl peroxide 0.03% and beet molasses dregs 0.1%, stir 2 hours, cooling, obtained described second elastic plastic, wherein deionized water is all the other compositions;
Described Nano Silver is prepared from according to following steps:
A, sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution to be added in silver nitrate aqueous solution and obtain mixed liquor, the mol ratio of described lauryl sodium sulfate and silver nitrate is 2:1; The mol ratio of described water polyacrylic acid and silver nitrate is 0.2:1; The mol ratio of described hydrazine hydrate and silver nitrate is 0.4:1;
B. in described mixed liquor, add crown ether and sodium metaphosphate, the mol ratio of described crown ether and silver nitrate is 1:1; The mol ratio of described sodium metaphosphate and silver nitrate is 0.3:1, and control ph is 10, obtains Nano Silver
In described hydrophilic non-ironing treatment fluid, key component is hydrophilic no-ironing resin, fiber protection agent, softener, catalyst, PH conditioning agent and water; the content of key component is: hydrophilic no-ironing resin 60g/L, fiber protection agent 10g/L, softener 20g/L, catalyst 15g/L, and the pH value of described hydrophilic non-ironing treatment fluid is 3.5.
Wherein, described hydrophilic no-ironing resin is be selected from least one in modification bishydroxymethyl dihydroxy ethylene urea, nano-dispersed self-crosslinking polyether-polyurethane, modified alkyl dihydroxy ethylene urea.Described fiber protection agent is be selected from least one in the silicone emulsion of elastic polyurethane and the common emulsion of oxidized polyethylene homopolymers and amido silicon oil; Described softener is be selected from least one of to gather containing the amination polysiloxanes of polyether group and polyethylene in silicon compound compound body; Described catalyst is magnesium chloride, or is composite catalyst; Described composite catalyst is composited by metal salt catalyst and hydroxycarboxylic acid, and described metal salt catalyst is be selected from least one in magnesium chloride, magnesium nitrate, zinc chloride, zinc nitrate; Described hydroxycarboxylic acid is at least one in citric acid, dihydromethyl propionic acid, 2,3-dyhydrobutanedioic acids, and in described composite catalyst, the percentage by weight of metal salt catalyst is 80 ~ 90%; Described pH adjusting agent is be selected from the one in acetic acid, citric acid-sodium citrate buffer solution, acetic acid-sodium acetate buffer solution and sodium dihydrogen phosphate-citrate buffer solution.
After penetrating into cotton fiber to make antibacterial heating liquid, can be long-time, and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, the preparation method of described emulsion acrylic resin is: the acrylate monomer mixed liquor of preparation 50 parts of weight is stand-by, then by OPEO, castor oil, lauryl sodium sulfate, the emulsifying agent of 2 parts of weight of several compositions in dodecyl phenenyl sulfate, the sodium bicarbonate of 0.8 part of weight and deionized water join in reactor, add the 1/4 acrylate monomer mixed liquor prepared again wherein, be warming up to 40 DEG C, abundant stirring 50min, be warming up to 80 DEG C, drip remaining 3/4 acrylate monomer mixed liquor and ammonium persulfate solution initator, time for adding controls, for 2h, to ensure that monomer drips prior to initiator solution, dropwise rear insulation 2h, after cooling, regulate ph value of emulsion to about 7.5.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, before adding crown ether and sodium metaphosphate in described step B in described mixed liquor, described mixed liquor is heated to 65 DEG C; Described step B is heated to 60 DEG C add crown ether and sodium metaphosphate in described mixed liquor after, Keep agitation 5 ~ 8min.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, and the described furfuryl alcohol extracted from natural plants is selected from the furfuryl alcohol extracted from the wheat bran or bamboo wood chip of the core slag of corncob, oat or wheat; The described plant phenols extracted from natural plants is eugenol or anacardol.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, containing dilute sulfuric acid catalyst 0.3 part in described antiseptic solution.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, preferred embodiment also has, the microwave treatment in described 4th step, its microwave frequency is 130MHz, and microwave treatment time is 6min.
In order to make the antibacterial heating liquid penetrating into cotton fiber play its effect better, and its effect is further strengthened, preferred embodiment also has.Warming finishing agent in described 8th step is made up of the component of following weight portion: 30 parts, marine alga carbon fiber, titanium dioxide 5 parts, 5 parts, zinc oxide, medical stone 30 parts, 6 parts, chromium oxide, silane coupler 6 parts, sodium polyacrylate disperant 1.2 parts, and adds water and be made into the padding liquid that mass concentration is 45%; Described sodium polyacrylate disperant viscosity is 200mPas.
The preferred embodiment of the invention is, described cotton worsted fabric is the high-accuracy cotton yarn knitted fabric of 120.
Embodiment 2
A processing method for the non-ironing cotton shirt of hotness, described method comprises the steps:
The first step, carries out Liquid Ammonia Treatment to cotton fabric;
Second step, carries out shrunk finish with preshrinking machine to fabric, and steam pressure is 5.5kg/m
2, steam consumption is 37.5kg/h;
3rd step, with the cotton fabric after antibacterial, heating, hydrophilic non-ironing liquid electrostatic spraying preshrunk;
4th step, carries out microwave treatment to the cotton fabric after electrostatic spraying;
5th step, vacuumizes process to the cotton fabric after microwave treatment, is evacuated to vacuum for-0.035Mpa;
6th step, to vacuumizing the cotton fabric after process, then carries out boiling process with the wood pulp liquid crossed through microwave treatment, and digestion time is 40min, and boiling temperature is 90 DEG C;
7th step, dry with the cotton fabric after wood pulp liquid boiling process, then put into refrigerating chamber and carry out freeze drying process, cryogenic temperature is 2 DEG C, and cooling time is 15min;
8th step, by the cotton fabric after freeze drying process, drops in the maceration extract containing warming finishing agent and carries out padding process, maceration extract pressure 1.75kg/cm
2, liquid carrying rate 65%;
9th step, by padding that the cotton fabric after process carries out drying, cutting, clothing;
Tenth step, by the ready-made clothes made with baking and banking up with earth setting machine whole boiling hot sizing after 15 minutes at 145 DEG C, then carries out arranging, packs, puts in storage.
In order to adapt to the characteristic of cotton fabric, antibacterial heating liquid can be made all to penetrate into the inside of cotton fiber, and its preferred embodiment is, in described 3rd step, the spray distance of electrostatic spraying is 135mm, the voltage of electrostatic spraying is 115V, and the air pressure of electrostatic spraying is 0.065Mpa.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, preferred embodiment also has, and in described 3rd step, antibacterial heating liquid is made up of the raw material of following parts by weight:
Phthalic acid 12.5 parts, the furfuryl alcohol 4 parts extracted from natural plants, triethylene glycol 16.5 parts, glue acid 21 parts, tromethamine 4 parts, 4 parts, nickel oxygen powder, 1.5 parts, zinc oxide, neoprene latex 11 parts, elastic plastic 105 parts, rubber softening oil 5 parts, 7.5 parts, carbonic acid ethane, dichlorobenzoperoxide 5 parts, beet molasses dregs 11 parts, emulsifying agent 4 parts, chitosan 12.5 parts, Tourmaline particle 0.15 part, negative ion powder 1.5 parts, macromolecule resin 0.65 part, Nano Silver 11 × 10
~ 6part, fire retardant 5 parts, ethyl cellulose 17.5 parts, deionized water 55 parts;
Described negative ion powder is made up of following components in mass portion: opal 12.5 parts; Medical stone 25 parts; 7.5 parts, shell; 6 parts, diatomite; Zirconic anhydride 12.5 parts; Nanometer silver-zirconium phosphate antimicrobial 9 parts;
Described emulsifying agent is alkylphenol polyoxyethylene, in castor oil, lauric alcohol sodium sulphate, lauryl sodium sulfate any one or its mix arbitrarily;
Described elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 1.5:1.5;
The solids content that described first elastic plastic comprises 42.5 parts of weight is the emulsion acrylic resin of 40%, the solids content of 6.5 parts of aqueous polyurethanes, 11 parts of acrylic resin powder, 8.5 parts of weight is the EVA emulsion of 12.5% and the chlorinated polypropylene of 8.5 parts of weight;
The preparation method of described second elastic plastic is: be the polyvinyl alcohol water solution of 22.5% by mass concentration, mass concentration be 17.5% the aqueous polyurethane aqueous solution and deionized water heat to 92.5 DEG C, be cooled to 65 DEG C and add acrylate 22.5%, then add NaOH 0.3 ~ 0.4% and be warming up to 90 DEG C, then add gelatine protein 11 %, rosin fat 4%, the plant phenols 4% extracted from natural plants; React and be cooled to 62.5 DEG C in 1.5 hours, then add Sodium Benzoate 0.035%, di-t-butyl peroxide 0.035% and beet molasses dregs 0.2%, stir 2.25 hours, cooling, obtained described second elastic plastic, wherein deionized water is all the other compositions;
Described Nano Silver is prepared from according to following steps:
A, sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution to be added in silver nitrate aqueous solution and obtain mixed liquor, the mol ratio of described lauryl sodium sulfate and silver nitrate is 2.5:1; The mol ratio of described water polyacrylic acid and silver nitrate is 0.25:1; The mol ratio of described hydrazine hydrate and silver nitrate is 0.45:1;
B. in described mixed liquor, add crown ether and sodium metaphosphate, the mol ratio of described crown ether and silver nitrate is 1.5:1; The mol ratio of described sodium metaphosphate and silver nitrate is 0.45:1, and control ph is 10.5, obtains Nano Silver;
In described hydrophilic non-ironing treatment fluid, key component is hydrophilic no-ironing resin, fiber protection agent, softener, catalyst, PH conditioning agent and water, the content of key component is: hydrophilic no-ironing resin 130g/L, fiber protection agent 30g/L, softener 40g/L, catalyst 20g/L, and the pH value of described hydrophilic non-ironing treatment fluid is 4.25;
Wherein, described hydrophilic no-ironing resin is be selected from least one in modification bishydroxymethyl dihydroxy ethylene urea, nano-dispersed self-crosslinking polyether-polyurethane, modified alkyl dihydroxy ethylene urea.Described fiber protection agent is be selected from least one in the silicone emulsion of elastic polyurethane and the common emulsion of oxidized polyethylene homopolymers and amido silicon oil; Described softener is be selected from least one of to gather containing the amination polysiloxanes of polyether group and polyethylene in silicon compound compound body; Described catalyst is magnesium chloride, or is composite catalyst; Described composite catalyst is composited by metal salt catalyst and hydroxycarboxylic acid, and described metal salt catalyst is be selected from least one in magnesium chloride, magnesium nitrate, zinc chloride, zinc nitrate; Described hydroxycarboxylic acid is at least one in citric acid, dihydromethyl propionic acid, 2,3-dyhydrobutanedioic acids, and in described composite catalyst, the percentage by weight of metal salt catalyst is 80 ~ 90%; Described pH adjusting agent is be selected from the one in acetic acid, citric acid-sodium citrate buffer solution, acetic acid-sodium acetate buffer solution and sodium dihydrogen phosphate-citrate buffer solution.
After penetrating into cotton fiber to make antibacterial heating liquid, can be long-time, and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, the preparation method of described emulsion acrylic resin is: the acrylate monomer mixed liquor of preparation 62.5 parts of weight is stand-by, then by OPEO, castor oil, lauryl sodium sulfate, the emulsifying agent of 3 parts of weight of several compositions in dodecyl phenenyl sulfate, the sodium bicarbonate of 1 part of weight and deionized water join in reactor, add the 1/4 acrylate monomer mixed liquor prepared again wherein, be warming up to 60 DEG C, abundant stirring 65min, be warming up to 100 DEG C, drip remaining 3/4 acrylate monomer mixed liquor and ammonium persulfate solution initator, time for adding controls, for 3.5h, to ensure that monomer drips prior to initiator solution, dropwise rear insulation 3.5h, after cooling, regulate ph value of emulsion to about 7.5.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, before adding crown ether and sodium metaphosphate in described step B in described mixed liquor, described mixed liquor is heated to 67.5 DEG C; Described step B is heated to 62.5 DEG C add crown ether and sodium metaphosphate in described mixed liquor after, Keep agitation 6.5min.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, and the described furfuryl alcohol extracted from natural plants is selected from the furfuryl alcohol extracted from the wheat bran or bamboo wood chip of the core slag of corncob, oat or wheat; The described plant phenols extracted from natural plants is eugenol or anacardol.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, containing dilute sulfuric acid catalyst 0.4 part in described antiseptic solution.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, preferred technical scheme also has, the microwave treatment in described 4th step, its microwave frequency is 205MHz, and microwave treatment time is 7min.
In order to make the antibacterial heating liquid penetrating into cotton fiber play its effect better, and its effect is further strengthened, preferred embodiment also has.Warming finishing agent in described 8th step is made up of the component of following weight portion: 40 parts, marine alga carbon fiber, titanium dioxide 7 parts, 6.5 parts, zinc oxide, medical stone 40 parts, 7 parts, chromium oxide, silane coupler 8 parts, sodium polyacrylate disperant 1.35 parts, and adds water and be made into the padding liquid that mass concentration is 50%; Described sodium polyacrylate disperant viscosity is 250mPas.
The preferred technical scheme of the present invention is, described cotton worsted fabric is the high-accuracy cotton yarn knitted fabric of 120.
Embodiment 3
A processing method for the non-ironing cotton shirt of hotness, described method comprises the steps:
The first step, carries out Liquid Ammonia Treatment to cotton fabric;
Second step, carries out shrunk finish with preshrinking machine to fabric, and steam pressure is 6kg/m
2, steam consumption is 45kg/h;
3rd step, with the cotton fabric after antibacterial, heating, hydrophilic non-ironing liquid electrostatic spraying preshrunk;
4th step, carries out microwave treatment to the cotton fabric after electrostatic spraying;
5th step, vacuumizes process to the cotton fabric after microwave treatment, is evacuated to vacuum for-0.03Mpa;
6th step, to vacuumizing the cotton fabric after process, then carries out boiling process with the wood pulp liquid crossed through microwave treatment, and digestion time is 50min, and boiling temperature is 100 DEG C;
7th step, dry with the cotton fabric after wood pulp liquid boiling process, then put into refrigerating chamber and carry out freeze drying process, cryogenic temperature is 4 DEG C, and cooling time is 20min;
8th step, by the cotton fabric after freeze drying process, drops in the maceration extract containing warming finishing agent and carries out padding process, maceration extract pressure 2kg/cm
2, liquid carrying rate 70%;
9th step, by padding that the cotton fabric after process carries out drying, cutting, clothing;
Tenth step, by the ready-made clothes made with baking and banking up with earth setting machine whole boiling hot sizing after 10 minutes at 150 DEG C, then carries out arranging, packs, puts in storage.
In order to adapt to the characteristic of cotton fabric, antibacterial heating liquid can be made all to penetrate into the inside of cotton fiber, and its preferred embodiment is, in described 3rd step, the spray distance of electrostatic spraying is 150mm, the voltage of electrostatic spraying is 120V, and the air pressure of electrostatic spraying is 0.08Mpa.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, preferred embodiment also has, and in described 3rd step, antibacterial heating liquid is made up of the raw material of following parts by weight:
Phthalic acid 15 parts, the furfuryl alcohol 5 parts extracted from natural plants, triethylene glycol 18 parts, glue acid 22 parts, tromethamine 6 parts, 5 parts, nickel oxygen powder, 2 parts, zinc oxide, neoprene latex 12 parts, elastic plastic 110 parts, rubber softening oil 6 parts, 10 parts, carbonic acid ethane, dichlorobenzoperoxide 6 parts, beet molasses dregs 12 parts, emulsifying agent 6 parts, chitosan 15 parts, Tourmaline particle 0.2 part, negative ion powder 2 parts, macromolecule resin 0.8 part, Nano Silver 12 × 10
~ 6part, fire retardant 6 parts, ethyl cellulose 20 parts, deionized water 60 parts;
Described negative ion powder is made up of following components in mass portion: opal 25 parts; Medical stone 30 parts; 10 parts, shell; 10 parts, diatomite; Zirconic anhydride 15 parts; Nanometer silver-zirconium phosphate antimicrobial 10 parts;
Described emulsifying agent is alkylphenol polyoxyethylene, in castor oil, lauric alcohol sodium sulphate, lauryl sodium sulfate any one or its mix arbitrarily;
Described elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 2:1.5;
The solids content that described first elastic plastic comprises 45 parts of weight is the emulsion acrylic resin of 50%, the solids content of 8 parts of aqueous polyurethanes, 12 parts of acrylic resin powder, 10 parts of weight is the EVA emulsion of 15% and the chlorinated polypropylene of 10 parts of weight;
The preparation method of described second elastic plastic is: be the polyvinyl alcohol water solution of 25% by mass concentration, mass concentration be 20% the aqueous polyurethane aqueous solution and deionized water heat to 100 DEG C, be cooled to 70 DEG C and add acrylate 25%, then add NaOH 0.4% and be warming up to 95 DEG C, then add gelatine protein 12 %, rosin fat 5%, the plant phenols 6% extracted from natural plants; React and be cooled to 65 DEG C in 2 hours, then add Sodium Benzoate 0.05%, di-t-butyl peroxide 0.04% and beet molasses dregs 0.3%, stir 2.5 hours, cooling, obtained described second elastic plastic, wherein deionized water is all the other compositions;
Described Nano Silver is prepared from according to following steps:
A, sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution to be added in silver nitrate aqueous solution and obtain mixed liquor, the mol ratio of described lauryl sodium sulfate and silver nitrate is 3:1; The mol ratio of described water polyacrylic acid and silver nitrate is 0.3:1; The mol ratio of described hydrazine hydrate and silver nitrate is 0.5:1;
B. in described mixed liquor, add crown ether and sodium metaphosphate, the mol ratio of described crown ether and silver nitrate is 2:1; The mol ratio of described sodium metaphosphate and silver nitrate is 0.6:1, and control ph is 11, obtains Nano Silver;
In described hydrophilic non-ironing treatment fluid, key component is hydrophilic no-ironing resin, fiber protection agent, softener, catalyst, PH conditioning agent and water, the content of key component is: hydrophilic no-ironing resin 200g/L, fiber protection agent 50g/L, softener 60g/L, catalyst 25g/L, and the pH value of described hydrophilic non-ironing treatment fluid is 6;
Wherein, described hydrophilic no-ironing resin is be selected from least one in modification bishydroxymethyl dihydroxy ethylene urea, nano-dispersed self-crosslinking polyether-polyurethane, modified alkyl dihydroxy ethylene urea.Described fiber protection agent is be selected from least one in the silicone emulsion of elastic polyurethane and the common emulsion of oxidized polyethylene homopolymers and amido silicon oil; Described softener is be selected from least one of to gather containing the amination polysiloxanes of polyether group and polyethylene in silicon compound compound body; Described catalyst is magnesium chloride, or is composite catalyst; Described composite catalyst is composited by metal salt catalyst and hydroxycarboxylic acid, and described metal salt catalyst is be selected from least one in magnesium chloride, magnesium nitrate, zinc chloride, zinc nitrate; Described hydroxycarboxylic acid is at least one in citric acid, dihydromethyl propionic acid, 2,3-dyhydrobutanedioic acids, and in described composite catalyst, the percentage by weight of metal salt catalyst is 80 ~ 90%; Described pH adjusting agent is be selected from the one in acetic acid, citric acid-sodium citrate buffer solution, acetic acid-sodium acetate buffer solution and sodium dihydrogen phosphate-citrate buffer solution.
After penetrating into cotton fiber to make antibacterial heating liquid, can be long-time, and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, the preparation method of described emulsion acrylic resin is: the acrylate monomer mixed liquor of preparation 75 parts of weight is stand-by, then by OPEO, castor oil, lauryl sodium sulfate, the emulsifying agent of 4 parts of weight of several compositions in dodecyl phenenyl sulfate, the sodium bicarbonate of 1.2 parts of weight and deionized water join in reactor, add the 1/4 acrylate monomer mixed liquor prepared again wherein, be warming up to 80 DEG C, abundant stirring 80min, be warming up to 120 DEG C, drip remaining 3/4 acrylate monomer mixed liquor and ammonium persulfate solution initator, time for adding controls, for 5h, to ensure that monomer drips prior to initiator solution, dropwise rear insulation 2 ~ 5h, after cooling, regulate ph value of emulsion to about 7.5.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, before adding crown ether and sodium metaphosphate in described step B in described mixed liquor, described mixed liquor is heated to 70 DEG C; Described step B is heated to 65 DEG C add crown ether and sodium metaphosphate in described mixed liquor after, Keep agitation 8min.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, and the described furfuryl alcohol extracted from natural plants is selected from the furfuryl alcohol extracted from the wheat bran or bamboo wood chip of the core slag of corncob, oat or wheat; The described plant phenols extracted from natural plants is eugenol or anacardol.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, further preferred embodiment also has, containing dilute sulfuric acid catalyst 0.5 part in described antiseptic solution.
After penetrating into cotton fiber to make antibacterial heating liquid, can for a long time and after cyclic washing, it still can be kept to pin effective insulation antibiosis composition, do not come off, preferred embodiment also has, the microwave treatment in described 4th step, its microwave frequency is 280MHz, and microwave treatment time is 8min.
In order to make the antibacterial heating liquid penetrating into cotton fiber play its effect better, and its effect is further strengthened, preferred embodiment also has.Warming finishing agent in described 8th step is made up of the component of following weight portion: 50 parts, marine alga carbon fiber, titanium dioxide 9 parts, 8 parts, zinc oxide, medical stone 50 parts, 8 parts, chromium oxide, silane coupler 10 parts, sodium polyacrylate disperant 1.5 parts, and adds water and be made into the padding liquid that mass concentration is 55%; Described sodium polyacrylate disperant viscosity is 300mPas.
The preferred embodiment of the invention is, described cotton worsted fabric is the high-accuracy cotton yarn knitted fabric of 120.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (10)
1. a processing method for the non-ironing cotton shirt of hotness, is characterized in that, described method comprises the steps:
The first step, carries out Liquid Ammonia Treatment to cotton fabric;
Second step, carries out shrunk finish with preshrinking machine to fabric, and steam pressure is 5 ~ 6kg/m
2, steam consumption is 30 ~ 45kg/h;
3rd step, with the cotton fabric after antibacterial, heating, hydrophilic non-ironing liquid electrostatic spraying preshrunk;
4th step, carries out microwave treatment to the cotton fabric after electrostatic spraying;
5th step, vacuumizes process to the cotton fabric after microwave treatment, is evacuated to vacuum for-0.04Mpa ~-0.03Mpa;
6th step, to vacuumizing the cotton fabric after process, then carries out boiling process with the wood pulp liquid crossed through microwave treatment;
7th step, dries with the cotton fabric after wood pulp liquid boiling process, then puts into refrigerating chamber and carry out freeze drying process;
8th step, by the cotton fabric after freeze drying process, drops in the maceration extract containing warming finishing agent and carries out padding process, maceration extract pressure 1.5 ~ 2kg/cm
2, liquid carrying rate 60 ~ 70%;
9th step, by padding that the cotton fabric after process carries out baking, cutting, clothing;
Tenth step, by the ready-made clothes made with baking and banking up with earth setting machine whole boiling hot sizing after 10 ~ 20 minutes at 140 ~ 150 DEG C, then carries out arranging, packs, puts in storage.
2. the processing method of the non-ironing cotton shirt of hotness as claimed in claim 1, it is characterized in that, in described 3rd step, the spray distance of electrostatic spraying is 120mm ~ 150mm, and the voltage of electrostatic spraying is 90V ~ 120V, and the air pressure of electrostatic spraying is 0.05 ~ 0.08Mpa.
3. the processing method of the non-ironing cotton shirt of hotness as claimed in claim 2, it is characterized in that, in described 3rd step, antibacterial heating liquid is made up of the raw material of following parts by weight:
Phthalic acid 10 ~ 15 parts, the furfuryl alcohol extracted from natural plants 3 ~ 5 parts, triethylene glycol 15 ~ 18 parts, glue acid 20 ~ 22 parts, tromethamine 2 ~ 6 parts, 3 ~ 5 parts, nickel oxygen powder, 1 ~ 2 part, zinc oxide, neoprene latex 10 ~ 12 parts, elastic plastic 100 ~ 110 parts, rubber softening oil 4 ~ 6 parts, 5 ~ 10 parts, carbonic acid ethane, dichlorobenzoperoxide 4 ~ 6 parts, beet molasses dregs 10 ~ 12 parts, emulsifying agent 2 ~ 6 parts, chitosan 10 ~ 15 parts, Tourmaline particle 0.1 ~ 0.2 part, negative ion powder 1 ~ 2 part, macromolecule resin 0.5 ~ 0.8 part, Nano Silver 10 × 10
~ 6~ 12 × 10
~ 6part, fire retardant 4 ~ 6 parts, ethyl cellulose 15 ~ 20 parts, deionized water 50 ~ 60 parts,
Described negative ion powder is made up of following components in mass portion: opal 10 ~ 25 parts; Medical stone 20 ~ 30 parts; 5 ~ 10 parts, shell; 2 ~ 10 parts, diatomite; Zirconic anhydride 10 ~ 15 parts; Nanometer silver-zirconium phosphate antimicrobial 8 ~ 10 parts;
Described emulsifying agent is alkylphenol polyoxyethylene, in castor oil, lauric alcohol sodium sulphate, lauryl sodium sulfate any one or its mix arbitrarily;
Described elastic plastic comprises the first elastic plastic and the second elastic plastic that mix by weight 1 ~ 2:1.5;
The solids content that described first elastic plastic comprises 40 ~ 45 parts of weight is the emulsion acrylic resin of 30 ~ 50%, the solids content of 5 ~ 8 parts of aqueous polyurethanes, 10 ~ 12 parts of acrylic resin powder, 7 ~ 10 parts of weight is the EVA emulsion of 10 ~ 15% and the chlorinated polypropylene of 7 ~ 10 parts of weight;
The preparation method of described second elastic plastic is: be the polyvinyl alcohol water solution of 20 ~ 25% by mass concentration, mass concentration be 15 ~ 20% the aqueous polyurethane aqueous solution and deionized water heat to 85 ~ 100 DEG C, be cooled to 60 ~ 70 DEG C and add acrylate 20 ~ 25%, then add NaOH 0.3 ~ 0.4% and be warming up to 85 ~ 95 DEG C, then add gelatine protein 10 ~ 12%, rosin fat 3 ~ 5%, the plant phenols 5 ~ 6% extracted from natural plants; React and be cooled to 60 ~ 65 DEG C in 1 ~ 2 hour, then add Sodium Benzoate 0.02 ~ 0.05%, di-t-butyl peroxide 0.03 ~ 0.04% and beet molasses dregs 0.1 ~ 0.3%, stir 2 ~ 2.5 hours, cooling, obtained described second elastic plastic, wherein deionized water is all the other compositions;
Described Nano Silver is prepared from according to following steps:
A, sodium dodecyl sulfate solution, water polyacrylic acid and hydrazine hydrate solution to be added in silver nitrate aqueous solution and obtain mixed liquor, the mol ratio of described lauryl sodium sulfate and silver nitrate is 2 ~ 3:1; The mol ratio of described water polyacrylic acid and silver nitrate is 0.2 ~ 0.3:1; The mol ratio of described hydrazine hydrate and silver nitrate is 0.4 ~ 0.5:1;
B, in described mixed liquor, add crown ether and sodium metaphosphate, the mol ratio of described crown ether and silver nitrate is 1 ~ 2:1; The mol ratio of described sodium metaphosphate and silver nitrate is 0.3 ~ 0.6:1, and control ph is 10 ~ 11, obtains Nano Silver;
In described hydrophilic non-ironing treatment fluid, key component is hydrophilic no-ironing resin, fiber protection agent, softener, catalyst, PH conditioning agent and water; the content of key component is: hydrophilic no-ironing resin 60 ~ 200g/L, fiber protection agent 10 ~ 50g/L, softener 20 ~ 60g/L, catalyst 15 ~ 25g/L, and the pH value of described hydrophilic non-ironing treatment fluid is 3.5 ~ 6.
4. the processing method of the non-ironing cotton shirt of hotness as claimed in claim 3, it is characterized in that, the preparation method of described emulsion acrylic resin is: the acrylate monomer mixed liquor of preparation 50 ~ 75 parts of weight is stand-by, then by OPEO, castor oil, lauryl sodium sulfate, the emulsifying agent of 2 ~ 4 parts of weight of several compositions in dodecyl phenenyl sulfate, the sodium bicarbonate of 0.8 ~ 1.2 part of weight and deionized water join in reactor, add the 1/4 acrylate monomer mixed liquor prepared again wherein, be warming up to 40 ~ 80 DEG C, abundant stirring 50 ~ 80min, be warming up to 80 ~ 120 DEG C, drip remaining 3/4 acrylate monomer mixed liquor and ammonium persulfate solution initator, it is 2 ~ 5h that time for adding controls, and ensures that monomer drips prior to initiator solution, dropwise rear insulation 2 ~ 5h, after cooling, regulate ph value of emulsion to about 7.5.
5. the processing method of the non-ironing cotton shirt of hotness as claimed in claim 3, is characterized in that, before adding crown ether and sodium metaphosphate, described mixed liquor is heated to 65 ~ 70 DEG C in described step B in described mixed liquor; Described step B is heated to 60 ~ 65 DEG C add crown ether and sodium metaphosphate in described mixed liquor after, Keep agitation 5 ~ 8min.
6. the processing method of the non-ironing cotton shirt of hotness as claimed in claim 3, is characterized in that, the described furfuryl alcohol extracted from natural plants is selected from the furfuryl alcohol extracted from the wheat bran or bamboo wood chip of the core slag of corncob, oat or wheat; The described plant phenols extracted from natural plants is eugenol or anacardol.
7. the processing method of the non-ironing cotton shirt of hotness as claimed in claim 3, is characterized in that, containing dilute sulfuric acid catalyst 0.3 ~ 0.5 part in described antiseptic solution.
8. the processing method of the non-ironing cotton shirt of hotness as claimed in claim 1, it is characterized in that, the microwave treatment in described 4th step, its microwave frequency is 130MHz ~ 280MHz, and microwave treatment time is 6 ~ 8min.
9. the processing method of the non-ironing cotton shirt of hotness as claimed in claim 1, it is characterized in that, warming finishing agent in described 8th step is made up of the component of following weight portion: 30 ~ 50 parts, marine alga carbon fiber, titanium dioxide 5 ~ 9 parts, 5 ~ 8 parts, zinc oxide, medical stone 30 ~ 50 parts, 6 ~ 8 parts, chromium oxide, silane coupler 6 ~ 10 parts, sodium polyacrylate disperant 1.2 ~ 1.5 parts, and adds water and be made into the padding liquid that mass concentration is 45 ~ 55%; Described sodium polyacrylate disperant viscosity is 200 ~ 300mPas.
10. the processing method of the non-ironing cotton shirt of hotness as claimed in claim 1, it is characterized in that, described cotton worsted fabric is the high-accuracy cotton yarn knitted fabric of 120.
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| CN105970409A (en) * | 2016-05-16 | 2016-09-28 | 长兴华海纺织有限公司 | Preparation method of antibacterial and flame-retardant curtain fabric |
| CN106638002A (en) * | 2016-11-10 | 2017-05-10 | 董晓 | Preparation method of non-ironing garment material fabric stiffening agent |
| CN107142718A (en) * | 2017-07-05 | 2017-09-08 | 陕西科技大学 | Nano zine oxide/silver complex antimicrobials and preparation method thereof |
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