CN102418260B - Calamine alginate fiber fabrics pretreatment, dyeing and finishing technology - Google Patents

Calamine alginate fiber fabrics pretreatment, dyeing and finishing technology Download PDF

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Publication number
CN102418260B
CN102418260B CN2011102851122A CN201110285112A CN102418260B CN 102418260 B CN102418260 B CN 102418260B CN 2011102851122 A CN2011102851122 A CN 2011102851122A CN 201110285112 A CN201110285112 A CN 201110285112A CN 102418260 B CN102418260 B CN 102418260B
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dyeing
calamine
air
flow
washing
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CN102418260A (en
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高炳生
张俊峰
许漪
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FUJIAN ZHONGHE Co Ltd
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FUJIAN ZHONGHE Co Ltd
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Abstract

The invention discloses a calamine alginate fiber fabrics pretreatment, dyeing and finishing technology. The process flow comprises steps of: calamine alginate fiber fabrics greige cloth preparation, biological enzyme air-flow desizing, air-flow scouring and bleaching, cellulase processing, air-flow machine dyeing, and tentering preshrinking to finally obtain the finished product. The calamine alginate fiber fabrics produced in the invention has good strength and medical advantages, has medicinal and health-care functions, has a plurality of biological activities, is helpful for enhancing cell vitality, has curative effects of treating eye opacity, astringing dampness, relieving itching, engendering flesh and astringing sores, can be used for treating eczema, wet sore and persistent ulceration, and has remarkable efficacy of ultraviolet resistance, bacteriostasis, skin nourishing and the like. The fabrics produced in the invention can be widely applied in the preparation of medical, civil and skin-contacting clothes with good warmth retention and moisture retention, has antibacterial and skin nourishing effects, can resist ultraviolet ray and prevent skin cancer, and is an ideal material for man's and women's hat, jacket, upper outer garment, underwear, swimsuit and the like.

Description

A kind of pre-treatment of calamine alginate fibre fabric, dyeing and finishing technique
Technical field
The manufacturing dyeing and finishing technique field that the present invention relates to weave especially relates to a kind of pre-treatment, dyeing and finishing technique of calamine alginate fibre fabric.
Background technology
Textile garment is one of the mankind's primary demand of depending on for existence, and is along with the growth of the size of population and the raising of quality of life, also more and more higher to the requirement of weaving face fabric.People wish that weaving face fabric when having traditional resisting cold, general function such as attractive in appearance, has special miscellaneous function again.As waterproof, grease proofing, fire-retardant, easy decontamination, medicinal health function etc.Along with people's environmental consciousness is constantly strengthened, 21 century " green garment ", " green consumption " will be dominated world textile product and clothes trend.21 century will be the century of ocean, will enter darker field to the utilization of marine resources.In recent years, alginate fibre had obtained concern because of its various excellent properties in medical field, had obtained using widely in textile industry.
China is maximum in the world algae culturing and processing state, and alginate output accounts for the over half of the world, is very beneficial for acquisition and the large-scale development production of alginate fibre raw material.China's seaweed chemical product is very abundant, is the alginate fibre of development of raw materials with the alginate, and the field that obtains fiber has been expanded to the ocean from land, has increased the source of textile fabric.Simultaneously, the production of alginate fibre raw material does not take oil and land resource, owing to take from the ocean, alginate fibre has essential anti-flammability.These advantageous feature of alginate fibre add good textile processibility energy, make it not only can make common clothing, can also be for the manufacture of the clothes of specific uses such as fire-entry suit, protective clothing, medical treatment clothes.It is reported that alginate fibre fabric has broad application prospects in fields such as high-grade health-care clothing, toy for children and fire-fighting, medical treatment, military affairs and environmental protection.
Calamine has very high medicinal and health care and is worth, and the medicinal function of calamine is at multiple successive dynasties medicine ancient books, and is all on the books on the modern drug encyclopedia.Calamine is crude drug simply: the medicine name: calamine, and English name: luganshi, nature and flavor: sweet flat, return liver, the stomach warp.Main component is zinc carbonate (ZnCO 3), aqueous carbonic acid zinc (ZnCO 32Zn (OH) 2H 2O), zinc oxide (ZnO).The calamine effect: detoxifcation makes eye bright, and removes the screen hygroscopic, and with controlling red eye, swell pain, order is given birth to the screen film, the mashed dizzy eye of wind; Hygroscopic is antipruritic, and regenerating tissue to heal wond is with controlling the wet sore of eczema, unhealing ulcer.The clinical treatment that can be used for multiple contact dermatitis, skin disorder, in particular for unhealing ulcer, pus is dripping, wet sore, skin is disturbed treatment of conditions such as itch.
High-tenacity alginate fibre textiles is combined with calamine medicinal health function, and high-tenacity calamine alginate fibre fabric except medical, the medical advantage with high-tenacity and alginate fibre, also gives the high-tenacity alginate fibre medicinal and health care.High-tenacity calamine alginate fibre fabric has multiple physiologically active, help to strengthen cell viability, can play conditioning skin, body beautification health effect, and high-tenacity calamine alginate fibre also has significant anti-ultraviolet property, and there is shielding action in UVA district and the ultraviolet ray of UVB district, visible light transmissivity is big, also have good antibacterial performance in addition, therefore, high-tenacity calamine alginate fibre fabric is the desirable green algae fabric lining with Chinese medicine function. 
Although the calamine fabric lining has plurality of advantages, up to the present still nobody develops the dyeing and finishing technology technology of this fabric.
The key of textile industry development is the exploitation of new product.At present, compoundization of textile technology is international textile technology main development tendency, and health medicine and textiles mutually combine, to obtain new taking and functional.Adopt new technology, new equipment, new technology development has multipurpose, high-performance, high value-added product has become the new development trend of textiles.The textile garment product that market survey finds to have health care is to be subjected to popular expectation for a long time deeply and to like.The calamine alginate fibre fabric is that the inventor is according to a kind of high-grade textile garment fabric of mass market investigation project verification exploitation.
Because the particularity of calamine alginate fibre fabric morphological element is formulated 3 points that mainly contain that its dyeing and finishing processing method needs especially attention.
The first, guarantee the health care of calamine alginate fibre fabric.
The second, guarantee the good wearability of calamine alginate fibre fabric product.
Three, whole process of production reaches energy-saving and emission-reduction, green purpose of producing.
In view of this, the pre-treatment of air-flow machine, dyeing and the finishing technique of the sweet rock-block field algae of blind roaster fabric lining summed up and improved out to this process on the basis through a series of research and test, and this case produces thus.
Summary of the invention
The object of the present invention is to provide a kind of pre-treatment, dyeing and finishing technique of calamine alginate fibre fabric, so that fabric whiteness, capillary effect, cloth cover etc. after dyeing and finishing is handled reach effect preferably, the health care of calamine alginate fibre fabric there is not too big damage again.
To achieve these goals, solution of the present invention is as follows:
A kind of pre-treatment of calamine alginate fibre fabric, dyeing and finishing technique, technological process is: calamine alginate fibre fabric grey cloth, the destarch of biology enzyme air-flow, air-flow boil float, cellulase processing, air-flow engine dyeing look, stentering preshrinking, obtain finished product at last.
In the described calamine alginate fibre fabric, calamine content is counted 1-6% by the fabric percentage by weight.
The technological process of described biology enzyme destarch is: enzyme is handled, washing, and washing at twice;
The prescription of working solution:
High temperature destarch enzyme BS-GTI (can reach chemical industry Co., Ltd by blue sky, Guangdong wound provides) 3 g/L
Penetrating agent JFC (fatty alcohol-polyoxyethylene ether) 3 g/L
NaCl 5 g/L
Precious DXB-626 in the bath (can be provided by Guangdong dolantin chemical industry Co., Ltd) 1.5g/L
Desizing condition: 100 ℃ of destarch treatment temperatures, min(minute times 20); 80 ℃ of washing 10 min; 60 ℃ of washing 10 min.
Described air-flow boils the technological process of floating: boil float, hot water wash, cold wash;
The working solution prescription:
Na 2CO 3 3g/L
H 2O 2 3g/L
Hydrogen peroxide bleaching stabilizer OH(can be provided by hundred million Lay chemical industry Co., Ltds in the ShenZhen,GuangDong) 4g/L
Na 2SiO 4 3g/L
Precious DXB-626 in the bath (can be provided by Guangdong Demei Fine Chemical Co., Ltd.) 1.5g/L
Process conditions: boil and float 100 ℃ of temperature, reaction time 20min, 80 ℃ of hot water wash temperature, times 10 min, 60 ℃ of Warm Wash, times 10 min.
The technological process that described cellulase is handled is: enzyme is handled, inactivation treatment, washing;
The working solution prescription is:
By the percentage of fabric weight,
Cellulase DM-8628(can be provided by Guangdong Demei Fine Chemical Co., Ltd.) 1%
Penetrating agent JFC 3 g/L
Precious DXB-626 in the bath (can be provided by Guangdong Demei Fine Chemical Co., Ltd.) 1.5g/L
pH 5-5.5
Process conditions: 55 ℃ of enzyme treatment temperatures, times 30 min, 90 ℃ of inactivation treatment, time 15min, 60 ℃ of washing temperature, time 15min.
The technological process of described air-flow engine dyeing look is: following cloth, intensification, dyeing, adding soda ash fixation, cleaning, saponification, cleaning; Air-flow engine dyeing look process conditions: advance cloth, be warming up to 40 ℃ and add 1/2 dyestuff, add 1/2 Na 2SO 4Dyeing 20min; Add 1/2 dyestuff, 1/2 Na 2SO 4Dyeing 10min adds soda ash, the 1 ℃/min to 60 ℃ that heats up, and fixation 30-45min soaps, and washes;
The working solution prescription is:
Press the percentage of cloth weight, it is the o.w.f meter, REACTIVE DYES 0.1%-8%, Negel (can be provided by the extremely prosperous chemical industry in Shanghai Co., Ltd) 2-4 g/L, sodium sulphate 20-80 g/L, sodium carbonate 5-20 g/L, precious DXB-626 (but being provided by Guangdong Demei Fine Chemical Co., Ltd.) 1.5 g/L in the bath, the compound of leveling agent d S(ester fat amine polyoxyethylene ether) 1g/L [ can step weaving dying (China) Co., Ltd by Hensel provides ]; PH stabilizing agent (AB-55) 0.8 g/L[can step weaving dying (China) Co., Ltd by Hensel and provide]; Above-mentioned REACTIVE DYES is that FN-3GL is red, N-P is yellow, any one or a few mixing among the FN-R blue [can step weaving dying (China) Co., Ltd by Hensel provide].
Described percentage % is the percentage by weight of each ingredients constitute cloth; G/L is the grams that adds each component in every liter of working solution.
Treasured and pH stabilizing agent AB-55, Negel are the commercially available prod in leveling agent d S, the bath.Treasured can be produced by Guangdong Demei Fine Chemical Co., Ltd. in the bath, and leveling agent d S, pH stabilizing agent AB-55 can step weaving dying (China) Co., Ltd by Hensel and produce, and Negel can be produced by the extremely prosperous chemical industry in Shanghai Co., Ltd.
The purposes of above auxiliary agent is:
Precious in the bath: as to be conducive to the scratch problem that prevents that fabric from causing in the dyeing operation process.
Leveling agent d S: the level-dyeing property that increases textile dyeing prevents that look flower phenomenon from producing.
PH stabilizing agent AB-55: various dyestuffs different pH values (pH value) down the dye-uptake difference cause the colouring depth and coloured light to differ, this pH stabilizing agent is conducive to stablize pH value in the dye bath with assurance dye-uptake and color light stabilizing.
Air-flow engine dyeing look is compared with traditional handicraft, further energy-saving and emission-reduction, and air-flow engine dyeing look bath raio is expected to be reduced to 1:3.But under the condition of ultralow bath raio, dyestuff is easy to reunite and assemble, and after dyestuff is reunited, influences the dyeing ability of dyestuff greatly.The Negel series of surfactants has good solubilization to dyestuff, dye molecule can be in surfactant micella solubilising, simultaneously the high concentration dyestuff is had good depolymerization.
The technological process of described stentering preshrinking is: advance cloth, pad working solution, drying cylinder oven dry, cloth clamp tentering, oven for drying, preshrinking machine preshrunk;
The prescription of working solution:
Softener RT (can be produced by the chemical Co., Ltd of the permanent skill in Shantou) 8 g/L
Softener CGF(can be produced by hundred million Lay chemical industry Co., Ltds in Shenzhen) 20 g/L
Stentering preshrinking process conditions: pad working solution pick-up 60-80%, 95-100 ℃ of drying cylinder bake out temperature, time 1.5min; 110-130 ℃ of oven for drying temperature, time 3min.
After adopting such scheme, the beneficial effect of technology of the present invention is as follows:
Aspect environmental protection, because the textile dyeing and finishing industry is heavy polluter, environmental protection is the state basic policy that country advocates energetically.At the calamine alginate fibre fabric, need seek a kind for the treatment of conditions gentleness efficient and rational treatment process again, the biology enzyme pre-treatment provides good selection for us.The biology enzyme pre-treatment of this process using is because characteristics such as the biological mildness of its high efficiency, selectivity, processing and energy-saving and environmental protection have its unique advantage.This technology is used biological enzyme technology in calamine alginate fibre fabric pre-treatment process, make semi-products and finished product reach the requirement in production and market respectively.
Aspect process modification, this method has also adopted steam flow dyeing technique, new technology, new equipment to be applied to the calamine alginate fibre fabric.
Air-flow engine dyeing look is that the high-speed air flow that fabric relies on circulating fan to produce in closed container drives, dye liquor is through special nozzle, form the very little aqueous fabric face that is sprayed at of particle, dye liquor fully contacts with fabric, be back to the cell body bottom after the exchange, dye liquor circulates repeatedly and sprays fabric to reach the dyeing purpose.The extra small bath raio of production process, energy-conserving and environment-protective.
Negel is that surfactant has good solubilization to dyestuff, dye molecule can be in surfactant micella solubilising, simultaneously the high concentration dyestuff is had good depolymerization, realized the smooth implementation of extra small bath ratio dyeing.
Aspect improving the quality of products, the pre-treatment of a kind of calamine alginate fibre fabric provided by the invention, dyeing, arrangement novel technique method, the calamine alginate fibre fabric of producing is except having advantages such as pure natural, degradable, softness, also have simultaneously and resist ultraviolet ray invasion and attack and prevention cutaneum carcinoma performance significantly, the UVB district ultraviolet ray of UVA district is had shielding action, and visible light transmissivity is big.This fabric has broad-spectrum antiseptic, antibiotic dauer effect, and staphylococcus aureus, Escherichia coli, white viscose glue bacterium etc. are had significant anti-(pressing down) bacterium effect.Multiple contact dermatitis, skin disorder patient's treatment is played the effect of health care and medical assistance.This fabric has multiple physiologically active, helps to strengthen cell viability, can play conditioning skin, body beautification health effect.It is the first-class selection of men and women's jacket, upper garment, underwear, swimsuit class clothing making.
Aspect application prospect, the at present domestic producer that does not still have production calamine alginate fibre fabric.Pre-treatment, dyeing and the process method for finishing of the calamine alginate fibre fabric of this process exploitation provides assurance for the exploitation of calamine alginate fibre fabric new product.The successful exploitation of high-grade calamine alginate fibre fabric becomes the new focus in national textile product market.
The specific embodiment
One, calamine alginate fibre fabric grey cloth: institutional framework: 18tex/18tex, 483/10cm * 265/10cm; Calamine content (pressing the fabric weight percent meter): 1-6%.
Two, compound biological enzyme desizing flow process: enzyme is handled, washing (at twice);
The prescription of working solution:
Desizing agent BS-GTI 3 g/L
Penetrating agent JFC 3 g/L
NaCL 5 g/L
Precious DXB-626 1.5 g/L in the bath
Desizing condition: 100 ℃ of enzyme treatment temperatures, times 20 min; 80 ℃ of washing 10 min; 60 ℃ of washing 10 min.
Three, air-flow boils the technological process of floating: boil float, hot water wash, Warm Wash;
The working solution prescription:
Na 2CO 3 3g/L
H 2O 2 3g/L
Hydrogen peroxide bleaching stabilizer 4g/L
Na 2SiO 4 3g/L
Precious DXB-626 1.5 g/L in the bath
Process conditions: boil and float 100 ℃ of temperature, reaction time 20min, 80 ℃ of hot water wash temperature, times 10 min,
Four, cellulase handling process: enzyme is handled, inactivation treatment, washing.
The working solution prescription:
Cellulase DM8628 1g/L
Penetrating agent JFC 3 g/L
Precious DXB-626 1.5 g/L in the bath
pH 5-5.5
Process conditions: 55 ℃ of enzyme treatment temperatures, times 30 min, 90 ℃ of inactivation treatment temperature, time 15min, discharge opeing, 60 ℃ of washing temperature, times 15 min, normal temperature is washed 10 min.
Five, air-flow engine dyeing look technological process: following cloth, intensification, dyeing, adding soda ash fixation, cleaning, saponification, cleaning;
Air-flow engine dyeing look process conditions:
1) air-flow engine dyeing look prescription (%)
It is heavy that the red 0.09%(of FN-3GL accounts for cloth)
It is heavy that the yellow 0.26%(of NP accounts for cloth)
It is heavy that blue 0.43 %(of FN-R accounts for cloth)
Negel 4g/L
Glauber salt 60 g/L
Sodium carbonate 15 g/L
Precious DXB-626 5 g/L in the bath
Leveling agent d S 1 g/L
PH stabilizing agent AB-55 0.8 g/L.
More than each percentage be the heavy percentage by weight of each ingredients constitute cloth; G/L is the grams that adds each component in every liter of working solution.
2) air-flow engine dyeing look process conditions: advance cloth, be warming up to 40 ℃ and add 1/2 dyestuff, add 1/2Na 2SO 4And precious in bathing, levelling agent dyeing 20min; Add 1/2 dyestuff, 1/2 Na 2SO 4Dyeing 10min adds soda ash, heat up (1 ℃/min) to 60 ℃, fixation 30-45min soaps, washing.
Six, stentering preshrinking technological process: advance cloth, pad working solution, drying cylinder oven dry, cloth clamp tentering, oven for drying, preshrinking machine preshrunk.
The prescription of working solution:
RT 8 g/L
CGF 20 g/L
Stentering preshrinking process conditions: pad working solution pick-up 60-80%, 95-100 ℃ of drying cylinder bake out temperature, time 1.5min; Oven for drying temperature 110-130, time 3min.
Pre-treatment process has adopted biological enzyme technology, utilizes biodegradation to improve textile physical characteristic and dyeability.Extra small bath raio air-flow engine dyeing color method is adopted in dyeing, utilizes air-flow to spray the circulation of drive fabric and finishes dyeing course.Add the Negel series of surfactants in the dye liquor dyestuff had good solubilization, dye molecule can be in surfactant micella solubilising, simultaneously the high concentration dyestuff is had good depolymerization, realized the smooth implementation of extra small bath ratio dyeing.
Adopt the calamine alginate fibre fabric of manufacturing of the present invention except having advantages such as pure natural, degradable, softness, also have simultaneously and resist ultraviolet ray invasion and attack and prevention cutaneum carcinoma performance significantly, the UVB district ultraviolet ray of UVA district is had shielding action, and visible light transmissivity is big.This fabric has broad-spectrum antiseptic, antibiotic dauer effect, and staphylococcus aureus, Escherichia coli, white viscose glue bacterium etc. are had significant anti-(pressing down) bacterium effect.Health care and the auxiliary effect of expecting are played in multiple contact dermatitis, skin disorder patient's treatment.This fabric has multiple physiologically active, helps to strengthen cell viability, can play conditioning skin, body beautification health effect.
Being preferred embodiment of the present invention only below, is not the restriction to protection scope of the present invention, and all equivalent variations of doing according to the mentality of designing of this case all fall into the protection domain of this case.

Claims (3)

1. the pre-treatment of a calamine alginate fibre fabric, dyeing and finishing technique, it is characterized in that technological process is: calamine alginate fibre fabric grey cloth, the destarch of biology enzyme air-flow, air-flow boil float, cellulase processing, air-flow engine dyeing look, stentering preshrinking, obtain finished product at last;
The technological process of described biology enzyme air-flow destarch is: enzyme is handled, washing, and washing at twice;
The prescription of working solution:
High temperature destarch enzyme BS-GTI 3 g/L
Penetrating agent JFC 3 g/L
NaCl 5 g/L
Precious DXB-626 1.5g/L in the bath
Desizing condition: 100 ℃ of destarch treatment temperatures, times 20 min; 80 ℃ of washing 10 min; 60 ℃ of washing 10 min;
Described air-flow boils the technological process of floating: boil float, hot water wash, Warm Wash;
The working solution prescription:
Na 2CO 3 3g/L
H 2O 2 3g/L
Hydrogen peroxide bleaching stabilizer OH 4g/L
Na 2SiO 4 3g/L
Precious DXB-626 1.5g/L in the bath
Process conditions: boil and float 100 ℃ of temperature, reaction time 20min, 80 ℃ of hot water wash temperature, times 10 min, 60 ℃ of Warm Wash, times 10 min;
The technological process that described cellulase is handled is: enzyme is handled, inactivation treatment, washing;
The working solution prescription:
By the percentage of fabric weight, cellulase DM-8628 1%
Penetrating agent JFC 3 g/L
Precious DXB-626 1.5g/L in the bath
pH 5-5.5
Process conditions: 55 ℃ of enzyme treatment temperatures, times 30 min, 90 ℃ of inactivation treatment, time 15min, 60 ℃ of washing temperature, time 15min, normal temperature wash 10 min;
The technological process of described air-flow engine dyeing look is: following cloth, intensification, dyeing, adding soda ash fixation, cleaning, saponification, cleaning;
Air-flow engine dyeing look process conditions: advance cloth, be warming up to 40 ℃ and add 1/2 dyestuff, add 1/2 Na 2SO 4Dyeing 20min; Add 1/2 dyestuff, 1/2 Na 2SO 4Dyeing 10min adds soda ash, the 1 ℃/min to 60 ℃ that heats up, and fixation 30-45min,
Soap washing;
The working solution prescription is:
By the percentage of cloth weight, REACTIVE DYES 0.1%-8%
Negel 2-4 g/L
Sodium sulphate 20-80 g/L
Sodium carbonate 5-20 g/L
Precious DXB-626 1.5 g/L in the bath
Leveling agent d S 1g/L
PH stabilizing agent 0.8 g/L;
The technological process of described stentering preshrinking is: advance cloth, pad working solution, drying cylinder oven dry, cloth clamp tentering, oven for drying, preshrinking machine preshrunk;
The prescription of working solution:
Softener RT 8 g/L
Softener CGF 20 g/L
Stentering preshrinking process conditions: pad working solution pick-up 60-80%, 95-100 ℃ of drying cylinder bake out temperature, time 1.5min; 110-130 ℃ of oven for drying temperature, time 3min.
2. the pre-treatment of a kind of calamine alginate fibre fabric as claimed in claim 1, dyeing and finishing technique, it is characterized in that: in the described calamine alginate fibre fabric, calamine content is counted 1-6% by the fabric percentage by weight.
3. the pre-treatment of a kind of calamine alginate fibre fabric as claimed in claim 1, dyeing and finishing technique is characterized in that: described REACTIVE DYES be that FN-3GL is red, NP is yellow and FN-R blue in any one or a few mixing.
CN2011102851122A 2011-09-23 2011-09-23 Calamine alginate fiber fabrics pretreatment, dyeing and finishing technology Expired - Fee Related CN102418260B (en)

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Publication number Priority date Publication date Assignee Title
CN106567261B (en) * 2016-11-04 2019-05-03 罗莱生活科技股份有限公司 A kind of dyeing and finishing method of alginate fibre fabric
CN108385411B (en) * 2018-02-02 2020-03-24 山东理工大学 Printing paste for alginate fiber fabric and preparation method and application thereof
CN109518488B (en) * 2018-11-08 2021-07-20 浙江美欣达纺织印染科技有限公司 Low-salt low-alkali reactive dyeing process for air dyeing
CN109898317A (en) * 2019-01-24 2019-06-18 唐卫兵 A kind of preparation process of Multifunctional alginate fiber fabric

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN1995512A (en) * 2006-11-02 2007-07-11 上海中大科技发展有限公司 Chitosan fiber, alga fiber and natural fiber blend-spinning yarn and its preparation method and uses
CN101851803A (en) * 2010-05-28 2010-10-06 新乡化纤股份有限公司 Health-care function viscose fiber and preparation method thereof
CN101967698A (en) * 2010-10-02 2011-02-09 山东海龙股份有限公司 Method for preparing alginate/cellulose composite fibers

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1995512A (en) * 2006-11-02 2007-07-11 上海中大科技发展有限公司 Chitosan fiber, alga fiber and natural fiber blend-spinning yarn and its preparation method and uses
CN101851803A (en) * 2010-05-28 2010-10-06 新乡化纤股份有限公司 Health-care function viscose fiber and preparation method thereof
CN101967698A (en) * 2010-10-02 2011-02-09 山东海龙股份有限公司 Method for preparing alginate/cellulose composite fibers

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